Van der Waals para vapor

Datos: Temperatura (K)

= 1+β-qβ(Z-β/(Z+εβ)(Z+σβ))
Z Presión1 (bar)
Pc 48.3 bar 1.101325
Tc 545.5 K Z
ε 0 Z
σ 0 Z
Ψ 0.421875 Z
Ω 0.125 Z
∝(Tr) 1 Z
R 83.14 cm3*bar/mol*K
Volumen1
Resumen:

Temperatura= 358.15 K Presión2 (bar)

Presión 1 1.101325 Volumen 1 26564.3434 1.6519875
Presión 2 1.6519875 Volumen 2 17558.4742 Z
Presión 3 2.20265 Volumen 3 13058.688 Z
Presión 4 2.7533125 Volumen 4 10361.2459 Z
Presión 5 3.303975 Volumen 5 8565.02149 Z
Presión 6 3.8546375 Volumen 6 7283.66699 Z
Presión 7 4.4053 Volumen 7 6324.09826 Z
Presión 8 4.9559625 Volumen 8 5579.02744 Z
Presión 9 5.506625 Volumen 9 4984.08249 Z
Presión 10 6.0572875 Volumen 10 4498.29997

Volumen2

Presión3 (bar)
2.20265
Z
Z
Z
Z
Z
Z
Z

Volumen3

Presión4
(bar)
2.7533125
Z
 Z
Z
Z
Z
Z
Z
Z

Volumen4

Presión5 (bar)
3.303975
Z
Z
Z
Z
Z
Z
Z
Z
Z

Volumen5

Presión6 (bar)
3.8546375
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Volumen6

Presión7 (bar)
4.4053
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Volumen7

Presión8 (bar)
 4.9559625
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Volumen8

Presión9 (bar)
5.506625
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Volumen9

Presión10
(bar)
6.0572875
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Volumen10

Datos: Temperatura (K)

= 1+β-qβ(Z-β/(Z+εβ)(Z+σβ))
Z Presión1 (bar)
Pc 48.3 bar 1.101325
Tc 545.5 K Z
ε 0 Z
 σ 0 Z
Ψ 0.421875 Z
Ω 0.125 Z
∝(Tr) 1 Z
R 83.14 cm3*bar/mol*K
Volumen1

Presión2 (bar)
1.6519875
Z
Z
Z
Z
Z
Z
Z

Volumen2

Presión3 (bar)
2.20265
Z
Z
Z
Z
Z
Z
Z
Z

Volumen3

Presión4
(bar)
2.7533125
Z
Z
Z
Z
Z
Z
Z
Z

Volumen4

Presión5 (bar)
3.303975
Z
Z
Z
Z
Z
 Z
Z
Z
Z

Volumen5

Presión6 (bar)
3.8546375
Z
Z
Z
Z
Z
Z
Z
Z
Z
Volumen6

Presión7 (bar)
4.4053
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z

Volumen7

Presión8 (bar)
4.9559625
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Volumen8

Presión9 (bar)
5.506625
Z
Z
 Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Volumen9

Presión10
(bar)
6.0572875
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Volumen10

Datos: Temperatura (K)

= 1+β-qβ(Z-β/(Z+εβ)(Z+σβ))
Z Presión1 (bar)
Pc 48.3 bar 1.101325
Tc 545.5 K Z
ε 0 Z
σ 0 Z
Ψ 0.421875 Z
Ω 0.125 Z
∝(Tr) 1 Z
R 83.14 cm3*bar/mol*K
Volumen1

Presión2 (bar)
1.6519875
Z
Z
Z
Z
Z
Z
Z

Volumen2
Presión3 (bar)
2.20265
Z
Z
Z
Z
Z
Z
Z
Z

Volumen2

Presión4
(bar)
2.7533125
Z
Z
Z
Z
Z
Z
Z
Z

Volumen2

Presión5 (bar)
3.303975
Z
Z
Z
Z
Z
Z
Z
Z
Z

Volumen2

Presión6 (bar)
3.8546375
Z
Z
Z
Z
Z
Z
Z
Z
Z
Volumen2
Presión7 (bar)
4.4053
Z
Z
Z
Z
Z
Z
Z
Z
Z

Volumen7

Presión8 (bar)
4.9559625
Z
Z
Z
Z
Z
Z
Z
Z
Z

Volumen8

Presión9 (bar)
5.506625
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Z
Volumen9

Presión10
(bar)
6.0572875
Z
Z
Z
Z
 Z
Z
Z
Z
Z
Z
Z
Volumen10

Chart Titl
3

2.5

1.5

0.5

0
0 5000 10000 15000 200
als para vapor

Temperatura (K) 358.15 Datos:

Tr Pr β q Z
0.656554 0.022802 0.004341184 5.14047885 Pc
1 Z0 0.982122297 Tc
0.982122297 Z1 0.982524811 ε
0.982524811 Z2 0.982515746 σ
0.982515746 Z3 0.982515950 Ψ
0.982515950 Z4 0.982515945 Ω
0.982515945 Z5 0.982515945 Z=Z5 ∝(Tr)
R
26564.34336783 cm3/mol

Tr Pr β q
0.656554 0.034203 0.006511776 5.14047885
1 Z0 0.973256103
0.973256103 Z1 0.974163463
0.973256103 Z2 0.974163463
0.974163463 Z3 0.974132661
0.974132661 Z4 0.974133707
0.974133707 Z5 0.974133671
0.974133671 Z6 0.974133673
0.974133673 Z7 0.974133673 Z=Z7

17558.4742318 cm3/mol

Tr Pr β q
0.656554 0.045604 0.008682368 5.14047885
1 Z0 0.964438347
0.964438347 Z1 0.966054622
0.964438347 Z2 0.966054622
0.966054622 Z3 0.965981093
0.965981093 Z4 0.965984438
0.965984438 Z5 0.965984285
0.965984285 Z6 0.965984292

0.965984292 Z7 0.965984292 Z=Z7

13058.68802288 cm3/mol

Tr Pr β q
0.656554 0.057004 0.010852960 5.14047885
1 Z0 0.975628843
0.975628843 Z1 0.955669030
0.975628843 Z2 0.957059310
0.957059310 Z3 0.957059310
0.957059310 Z4 0.958120217
0.958120217 Z5 0.958120217
0.958120217 Z6 0.958059567
0.958059567 Z7 0.958059567 Z=Z7

10361.24591054 cm3/mol

Tr Pr β q
0.656554 0.068405 0.013023552 5.14047885
1 Z0 0.946948152
0.946948152 Z1 0.950600260
0.946948152 Z2 0.950600260
0.950600260 Z3 0.950348304
0.950348304 Z4 0.950365683
0.950365683 Z5 0.950364485
0.950364485 Z6 0.950364567
0.950364567 Z7 0.950364562
0.950364562 Z8 0.950364562 Z=Z7

8565.021486194 cm3/mol

Tr Pr β q
0.656554 0.079806 0.015194144 5.14047885
1 Z0 0.938275711
0.938275711 Z1 0.943257973
0.938275711 Z2 0.943257973
0.943257973 Z3 0.942854629
0.942854629 Z4 0.942887274
0.942887274 Z5 0.942884632
0.942884632 Z6 0.942884846
0.942884846 Z7 0.942884828
0.942884828 Z8 0.942884830
0.942884830 Z9 0.942884830 Z=Z9
7283.666994397 cm3/mol

Tr Pr β q
0.656554 0.091207 0.017364735 5.14047885
1 Z0 0.929651710
0.929651710 Z1 0.936174675
0.929651710 Z2 0.936174675
0.936174675 Z3 0.935567510
0.935567510 Z4 0.935624003
0.935624003 Z5 0.935618747
0.935618747 Z6 0.935619236
0.935619236 Z7 0.935619190
0.935619190 Z8 0.935619194
0.935619194 Z9 0.935619194 Z=Z9
6324.098262182 cm3/mol

Tr Pr β q
 0.656554 0.102608 0.019535327 5.14047885
1 Z0 0.921076146
0.921076146 Z1 0.929352349
0.921076146 Z2 0.929352349
0.929352349 Z3 0.928480244
0.928480244 Z4 0.928572091
0.928572091 Z5 0.928562417
0.928562417 Z6 0.928563436
0.928563436 Z7 0.928563329
0.928563329 Z8 0.928563340
0.928563340 Z9 0.928563339
0.928563339 Z10 0.928563339 Z=Z10
5579.027435884 cm3/mol

Tr Pr β q
0.656554 0.114009 0.021705919 5.14047885
1 Z0 0.912549021
0.912549021 Z1 0.922793133
0.912549021 Z2 0.922793133
0.922793133 Z3 0.921585893
0.921585893 Z4 0.921728052
0.921728052 Z5 0.921711310
0.921711310 Z6 0.921713282
0.921713282 Z7 0.921713050
0.921713050 Z8 0.921713077
0.921713077 Z9 0.921713074
0.921713074 Z10 0.921713074 Z=Z10
4984.082487821 cm3/mol

Tr Pr β q
0.656554 0.125410 0.023876511 5.14047885
1 Z0 0.904070335
0.904070335 Z1 0.916499328
0.904070335 Z2 0.916499328
0.916499328 Z3 0.914877247
0.914877247 Z4 0.915088718
0.915088718 Z5 0.915061145
0.915061145 Z6 0.915064740
0.915064740 Z7 0.915064271
0.915064271 Z8 0.915064332
0.915064332 Z9 0.915064325
0.915064325 Z10 0.915064326
0.915064326 Z11 0.915064325
0.915064325 Z12 0.915064325 Z=Z12
4498.299966287 cm3/mol

Temperatura (K) 388.15

Tr Pr β q
0.711549 0.022802 0.004005655 4.743172742
1 Z0 0.985082247
0.985082247 Z1 0.985367999
0.985367999 Z2 0.985362525
0.985362525 Z3 0.985362630
0.985362630 Z4 0.985362628
0.985362628 Z5 0.985362628 Z=Z5

28872.88621849 cm3/mol

Tr Pr β q
0.711549 0.034203 0.006008483 4.743172742
1 Z0 0.977680449
0.977680449 Z1 0.978324448
0.977680449 Z2 0.978324448
0.978324448 Z3 0.978305859
0.978305859 Z4 0.978306395
0.978306395 Z5 0.978306380
0.978306380 Z6 0.978306380 Z=Z6

19110.75037 cm3/mol

Tr Pr β q
0.711549 0.045604 0.008011310 4.743172742
1 Z0 0.970316705
0.970316705 Z1 0.971463551
0.970316705 Z2 0.971463551
0.971463551 Z3 0.971419209
0.971419209 Z4 0.971420924
0.971420924 Z5 0.971420857
0.971420857 Z6 0.971420860
0.971420860 Z7 0.971420860 Z=Z7

14232.1837503 cm3/mol

Tr Pr β q
0.711549 0.057004 0.010014138 4.743172742
1 Z0 0.977155901
0.977155901 Z1 0.962991013
0.977155901 Z2 0.964098580
0.964098580 Z3 0.964098580
0.964098580 Z4 0.964732372
0.964732372 Z5 0.964732372
0.964732372 Z6 0.964701595
0.964701595 Z7 0.964701595 Z=Z7

11306.99241355 cm3/mol

Tr Pr β q
0.711549 0.068405 0.012016965 4.743172742
1 Z0 0.955703373
0.955703373 Z1 0.958293182
0.955703373 Z2 0.958293182
0.958293182 Z3 0.958141519
0.958141519 Z4 0.958150400
 0.958150400 Z5 0.958149880
0.958149880 Z6 0.958149910
0.958149910 Z7 0.958149909
0.958149909 Z8 0.958149909 Z=Z7

9358.501638295 cm3/mol

Tr Pr β q
0.711549 0.079806 0.014019793 4.743172742
1 Z0 0.948453787
0.948453787 Z1 0.951985612
0.948453787 Z2 0.951985612
0.951985612 Z3 0.951743076
0.951743076 Z4 0.951759728
0.951759728 Z5 0.951758585
0.951758585 Z6 0.951758664
0.951758664 Z7 0.951758658
0.951758658 Z8 0.951758658 Z=Z8
7968.065674243 cm3/mol

Tr Pr β q
0.711549 0.091207 0.016022620 4.743172742
1 Z0 0.941242253
0.941242253 Z1 0.945864503
0.941242253 Z2 0.945864503
0.945864503 Z3 0.945499820
0.945499820 Z4 0.945528586
0.945528586 Z5 0.945526317
0.945526317 Z6 0.945526496
0.945526496 Z7 0.945526482
0.945526482 Z8 0.945526483
0.945526483 Z9 0.945526483 Z=Z8

6926.403991856 cm3/mol

Tr Pr β q
0.711549 0.102608 0.018025448 4.743172742
1 Z0 0.934068772
0.934068772 Z1 0.939930988
0.934068772 Z2 0.939930988
0.939930988 Z3 0.939407817
0.939407817 Z4 0.939454491
0.939454491 Z5 0.939450327
0.939450327 Z6 0.939450698
0.939450698 Z7 0.939450665
0.939450665 Z8 0.939450668
0.939450668 Z9 0.939450668 Z=Z9
6117.240828625 cm3/mol

Tr Pr β q
0.711549 0.114009 0.020028275 4.743172742
1 Z0 0.926933344
0.926933344 Z1 0.934186276
 0.926933344 Z2 0.934186276
0.934186276 Z3 0.933463014
0.933463014 Z4 0.933535102
0.933535102 Z5 0.933527916
0.933527916 Z6 0.933528632
0.933528632 Z7 0.933528561
0.933528561 Z8 0.933528568
0.933528568 Z9 0.933528567
0.933528567 Z10 0.933528568
0.933528568 Z11 0.933528568 Z=Z11
5470.811122281 cm3/mol

Tr Pr β q
0.711549 0.125410 0.022031103 4.743172742
1 Z0 0.919835968
0.919835968 Z1 0.928631654
0.919835968 Z2 0.928631654
0.928631654 Z3 0.927661229
0.927661229 Z4 0.927768224
0.927768224 Z5 0.927756427
0.927756427 Z6 0.927757727
0.927757727 Z7 0.927757584
0.927757584 Z8 0.927757600
0.927757600 Z9 0.927757598
0.927757598 Z10 0.927757598 Z=Z10
4942.719253515 cm3/mol

Temperatura (K) 418.15

Tr Pr β q
0.711549 0.022802 0.004005655 4.743172742
1 Z0 0.985082247
0.985082247 Z1 0.985367999
0.985367999 Z2 0.985362525
0.985362525 Z3 0.985362630
0.985362630 Z4 0.985362628
0.985362628 Z5 0.985362628 Z=Z5

31104.46315152 cm3/mol

Tr Pr β q
0.711549 0.034203 0.006008483 4.743172742
1 Z0 0.977680449
0.977680449 Z1 0.978324448
0.977680449 Z2 0.978324448
0.978324448 Z3 0.978305859
0.978305859 Z4 0.978306395
0.978306395 Z5 0.978306380
0.978306380 Z6 0.978306380 Z=Z6

17633.68606213 cm3/mol
 Tr Pr β q
0.711549 0.045604 0.008011310 4.743172742
1 Z0 0.970316705
0.970316705 Z1 0.971463551
0.970316705 Z2 0.971463551
0.971463551 Z3 0.971419209
0.971419209 Z4 0.971420924
0.971420924 Z5 0.971420857
0.971420857 Z6 0.971420860
0.971420860 Z7 0.971420860 Z=Z7

13132.18242991 cm3/mol

Tr Pr β q
0.711549 0.057004 0.010014138 4.743172742
1 Z0 0.977155901
0.977155901 Z1 0.962991013
0.977155901 Z2 0.964098580
0.964098580 Z3 0.964098580
0.964098580 Z4 0.964732372
0.964732372 Z5 0.964732372
0.964732372 Z6 0.964701595
0.964701595 Z7 0.964701595 Z=Z7

10433.07827621 cm3/mol

Tr Pr β q
0.711549 0.068405 0.012016965 4.743172742
1 Z0 0.955703373
0.955703373 Z1 0.958293182
0.955703373 Z2 0.958293182
0.958293182 Z3 0.958141519
0.958141519 Z4 0.958150400
0.958150400 Z5 0.958149880
0.958149880 Z6 0.958149910
0.958149910 Z7 0.958149909
0.958149909 Z8 0.958149909 Z=Z7

8635.185783217 cm3/mol

Tr Pr β q
0.711549 0.079806 0.014019793 4.743172742
1 Z0 0.948453787
0.948453787 Z1 0.951985612
0.948453787 Z2 0.951985612
0.951985612 Z3 0.951743076
0.951743076 Z4 0.951759728
0.951759728 Z5 0.951758585
0.951758585 Z6 0.951758664
0.951758664 Z7 0.951758658
0.951758658 Z8 0.951758658 Z=Z8
7352.216208245 cm3/mol
 Tr Pr β q
0.711549 0.091207 0.016022620 4.743172742
1 Z0 0.941242253
0.941242253 Z1 0.945864503
0.945864503 Z2 0.945499820
0.945499820 Z3 0.945528586
0.945528586 Z4 0.945526317
0.945526317 Z5 0.945526496
0.945526496 Z6 0.945526482
0.945526482 Z7 0.945526483
0.945526483 Z8 0.945526483 Z=Z8

6926.403991856 cm3/mol

Tr Pr β q
0.711549 0.102608 0.018025448 4.743172742
1 Z0 0.934068772
0.934068772 Z1 0.939930988
0.939930988 Z2 0.939407817
0.939407817 Z3 0.939454491
0.939454491 Z4 0.939450327
0.939450327 Z5 0.939450698
0.939450698 Z6 0.939450665
0.939450665 Z7 0.939450668
0.939450668 Z8 0.939450668 Z=Z8

6117.240828625 cm3/mol

Tr Pr β q
0.711549 0.114009 0.020028275 4.743172742
1 Z0 0.926933344
0.926933344 Z1 0.934186276
0.926933344 Z2 0.934186276
0.934186276 Z3 0.933463014
0.933463014 Z4 0.933535102
0.933535102 Z5 0.933527916
0.933527916 Z6 0.933528632
0.933528632 Z7 0.933528561
0.933528561 Z8 0.933528568
0.933528568 Z9 0.933528567
0.933528567 Z10 0.933528568
0.933528568 Z11 0.933528568 Z=Z11
5470.811122281 cm3/mol

Tr Pr β q
0.711549 0.125410 0.022031103 4.743172742
1 Z0 0.919835968
0.919835968 Z1 0.928631654
0.919835968 Z2 0.928631654
0.928631654 Z3 0.927661229
 0.927661229 Z4 0.927768224
0.927768224 Z5 0.927756427
0.927756427 Z6 0.927757727
0.927757727 Z7 0.927757584
0.927757584 Z8 0.927757600
0.927757600 Z9 0.927757598
0.927757598 Z10 0.927757598 Z=Z10
4942.719253515 cm3/mol

Chart Title

5000 10000 15000 20000 25000 30000 35000

 44

Datos:
= 1+β-qβ(Z-β/(Z+εβ)(Z+σβ))
48.3 bar
545.5 K
0
0
0.421875
0.125
1
83.14 cm3*bar/mol*K
 Soave/Redlich/Kwong para vapor

Datos:
= 1+β-qβ(Z-β/(Z+εβ)(Z+σβ))
Z
Pc 48.3 bar
Tc 545.5 K
ε 0
σ 1
Ψ 0.42748
Ω 0.08664
∝(Tr) =[1+(0.480+1.574*w-0.176*(w^2)(1-Tr^1/2)]^2
R 83.14 cm3*bar/mol*K
w =-1-log(Prsat
vapor

Datos:
=β+(Z+εβ)(Z+σβ)((1+β-Z)/qβ)
Z
Pc 48.3 bar
Tc 545.5 K
ε 0
σ 0
Ψ 27/64
Ω 1/8
∝(Tr) 1
R 83.14 cm3*bar/mol*K
 Soave/Redlich/Kwong para líquido

Datos:
(Z+εβ)(Z+σβ)((1+β-Z)/qβ)
48.3 bar
545.5 K
0
0
27/64
1/8
1
83.14 cm3*bar/mol*K