EJEMPLO: Calcular la entalpía del gas con la siguiente composición a la

presión de 1010 psia ( ó lpca) y una temperatura de 120 oF (580 oR)

Nota: En estas condiciones el fluido se encuentra en estado gaseoso sin la formación de condensados.

datos: P= 1010 psia

T = 120 F = 580 R

Comp. Zi = yi MWi yi*MWi Tci yi*Tci Pci

C1 0.901 16.043 14.4547 343.34 309.3493 667
CO2 0.0106 44.01 0.4665 547.73 5.8059 10695
C2 0.0499 30.07 1.5005 550.07 27.4485 707.8
C3 0.0187 44.097 0.8246 665.92 12.4527 615
iC4 0.0065 58.123 0.3778 734.41 4.7737 527.9
nC4 0.0045 58.123 0.2616 765.51 3.4448 548.8
iC5 0.0017 72.15 0.1227 828.96 1.4092 490.4
nC5 0.0019 72.15 0.1371 845.7 1.6068 488.1
C6 0.0052 86.177 0.4481 911.8 4.7414 439.5
∑ 1 18.5936 371.0324

Hᵒm = 262.761 [Btu/lb]

Corrección de unidades a [Btu/lbmol] :
Hᵒ = Hᵒm* MWm
Hᵒ = 4885.6649 [Btu/lbmol]

Tsr = T/Tsc = 1.56 0.58

fig. 4-11
Psr = P/Psc = 1.31 fig. 4-12 0.02

(Hᵒ - H) = 427.749601 [Btu/lbmol]

H=Ho-(Ho-H)
H = 4457.92 [Btu/lbmol]
s.

𝑚_𝑖=( 〖𝑀𝑊〗 _(𝑖

∗ ) 𝑦_𝑖)/(∑▒
〖〖𝑀𝑊〗 _(𝑖 ∗ )
yi*Pci wi yi*wi 𝑦_𝑖 〗 ) mi Hᵒi mi*Hᵒi
600.9670 0.0108 0.0097 0.7774 292 227.0024
113.3670 0.2667 0.0028 0.0251 100 2.5090
35.3192 0.0972 0.0049 0.0807 190 15.3329
11.5005 0.1515 0.0028 0.0443 160 7.0959
3.4314 0.1852 0.0012 0.0203 150 3.0478
2.4696 0.1981 0.0009 0.0141 160 2.2507
0.8337 0.2286 0.0004 0.0066 158 1.0423
0.9274 0.251 0.0005 0.0074 150 1.1059
2.2854 0.299 0.0016 0.0241 140 3.3741
771.1011 0.0248 1 262.7610
 ejercicio numero 3
comp. Yi MWi Tci
CO2 0.02 44.01 547.73
N2 0.01 28.0134 227.51
H2S 0 34.082 627.4
C1 0.85 16.043 343.34
C2 0.04 30.07 550.07
C3 0.03 44.097 665.92
iC4 0.03 58.123 734.41
nC4 0.02 58.123 765.51
∑ 1

ejercicio numero 4

comp. Yi Mwi Tci

N2 0.003 28.0134 227.51
CO2 0.057 44.01 547.73
H2S 0.004 34.082 672.4
CH4 0.85 16.043 343.34
C2H6 0.072 30.07 550.07
C3H8 0.005 44.097 665.92
iC4H10 0.004 58.123 734.41
nC4H10 0.002 58.123 765.51
iC5H12 0.001 72.15 828.96
nC5H12 0.002 72.15 845.7
H2O 0.0399 18.0153 1165.11
∑ 1.0

Yi=normalizado/100
comp. normalizado Yi Mwi
N2 0.9504 0.01 28.013
CO2 3.0335 0.03 44.010
C1 92.5729 0.93 16.043
C2 2.3578 0.02 30.070
C3 0.6084 0.01 44.097
iC4 0.1166 0.00 58.123
nC4 0.1482 0.00 58.123
iC5 0.0713 0.00 72.150
nC5 0.0391 0.00 72.150
C6 0.0267 0.00 86.177
C7+ 0.0751 0.00 114.200
∑ 100 1.00
COMP. NORMALIZADO Yi FACTOR DE CONVERSION
N2 0.9722 0.0097

CO2 3.0301 0.0303

C1 92.6632 0.9266
C2 2.3871 0.0239
C3 0.525 0.0053 27.4816
iC4 0.1056 0.0011 32.626
nC4 0.1257 0.0013 31.4433
iC5 0.0646 0.0006 36.1189
nC5 0.0332 0.0003 36.1189
C6 0.0215 0.0002 41.0157
C7 0.0718 0.0007 51.0516
∑ 100 1

PUNTO DE ROCIOES=43,505F
 Pci MWi*yi Tci*yi Pci*yi
1069.5 0.8802 10.9546 21.39
492.8 0.280134 2.2751 4.928
1300 0 0 0
667 13.63655 291.839 566.95
707.8 1.2028 22.0028 28.312
615 1.32291 19.9776 18.45
527.9 1.74369 22.0323 15.837
548.8 1.16246 15.3102 10.976
20.228744 384.3916 666.843

Yi
Pci MWi*yi Tci*yi Pci*yi F Yi*F
492.8 0.0807 0.6553 1.4194 0.9601 0.0029
1069.5 2.4085 29.9749 60.9615 0.9601 0.0547
1300 0.1309 2.5823 5.2000 0.9601 0.0038
667 13.0925 280.1946 566.9500 0.9601 0.8161
707.8 2.0787 38.0248 50.9616 0.9601 0.0691
615 0.2117 3.1967 3.0750 0.9601 0.0048
527.9 0.2232 2.8204 2.1116 0.9601 0.0038
548.8 0.1116 1.4699 1.0976 0.9601 0.0019
490.4 0.0693 0.7959 0.4904 0.9601 0.0010
488.1 0.1385 1.6239 0.9762 0.9601 0.0019
3200.1 0.6901 44.6330 127.6840 0.9601 0.0383
19.2356 405.9718 820.9273 1.00

Tci Pci Yi*MWi Yi*Tci Yi*Pci

227.51 492.8 0.266 2.162 4.684
547.73 1069.5 1.335 16.615 32.443
343.34 667 14.851 317.840 617.461
550.07 707.8 0.709 12.970 16.689
665.92 615 0.268 4.051 3.742
734.41 527.9 0.068 0.856 0.616
765.51 548.8 0.086 1.134 0.813
828.96 490.4 0.051 0.591 0.350
845.7 488.1 0.028 0.331 0.191
911.8 439.5 0.023 0.243 0.117
1024.2 360.7 0.086 0.769 0.271
17.772 357.564 677.376
GPM

GPM=2,2516

0.1443
0.0345
0.0395
0.0233
0.0120
0.0088
0.0367
0.2991
COMPONENTES Normalizado C9
Nitrogeno 1.4761
Dióxido de carbono 0.0305
Metano 83.8657
Etano 7.4749
Propano 3.7845
i-Butano 0.5556
n-Butano 1.2055
i-Pentano 0.3772
n-Pentano 0.3944
Hexanos 0.3722
Heptanos 0.3642
Octano 0.0665
Nonano 0.0327
TOTAL 100.0000

F=1-0,04
F=0,96
 Yi Mwi Tci Pci Yi*Mwi
0.0148 28.0134 227.5100 492.8000 0.4135
0.0003 44.0100 547.7300 1069.5000 0.0134
0.8387 16.0430 343.3400 667.0000 13.4546
0.0747 30.0700 550.0700 707.8000 2.2477
0.0378 44.0970 665.9200 615.0000 1.6689
0.0056 58.1230 734.4100 527.9000 0.3229
0.0121 58.1230 765.5100 548.8000 0.7007
0.0038 72.1500 828.9600 490.4000 0.2721
0.0039 72.1500 845.7000 488.1000 0.2846
0.0037 86.1770 911.8000 439.5000 0.3208
0.0036 100.2040 970.9000 397.4000 0.3649
0.0007 114.2000 1024.2000 360.7000 0.0759
0.0003 128.2580 610.8000 330.7000 0.0419
1.0000 20.1819

PUNTO DE ROCIO ES=122,00

 Yi*Tci Pci F*H2O FACTOR DE CONVERCION
3.3583 7.2742 0.0142
0.1668 0.3258 0.0003
287.9445 559.3842 0.8051
41.1172 52.9073 0.0718
25.2017 23.2747 0.0363 27.4816
4.0804 2.9330 0.0053 32.6260
9.2283 6.6158 0.0116 31.4433
3.1268 1.8498 0.0036 36.1189
3.3354 1.9251 0.0038 36.1189
3.3937 1.6358 0.0036 41.0157
3.5360 1.4473 0.0035 46.0020
0.6811 0.2399 0.0006 51.0516
0.1997 0.1081 0.0003 56.1354
385.3701 659.9211 0.0400
1.0000
GPM
1.4171
0.0292
80.5111
7.1759
1.0400 3.6331
0.1813 0.5334
0.3791 1.1573
0.1362 0.3621
0.1425 0.3786
0.1527 0.3573
0.1675 0.3496
0.0339 0.0638
0.0184 0.0314
2.2516 4.0000
100.0000
 EJEMPLO: Calcular la entropía del gas con la siguiente composición a la presión
de 1010 psia ( ó lpca) y una temperatura de 120 oF (580 oR)

Nota: En estas condiciones el fluido se encuentra en estado gaseoso sin la formación de condensados.

datos: P= 1010 psia 68.7075 atm

T = 120 F = 580 R

Comp. Zi = yi MWi yi*MWi Tci yi*Tci

C1 0.901 16.043 14.4547 343.34 309.3493
CO2 0.0106 44.01 0.4665 547.73 5.8059
C2 0.0499 30.07 1.5005 550.07 27.4485
C3 0.0187 44.097 0.8246 665.92 12.4527
iC4 0.0065 58.123 0.3778 734.41 4.7737
nC4 0.0045 58.123 0.2616 765.51 3.4448
iC5 0.0017 72.15 0.1227 828.96 1.4092
nC5 0.0019 72.15 0.1371 845.7 1.6068
C6 0.0052 86.177 0.4481 911.8 4.7414
∑ 1 18.5936 371.0324

Sᵒ = 3.0087 [Btu/lb-R]

Correccion de unidades:
S0 = (∑ (yi *MWi)Si0 - R∑ yi * ln(yi))

Sᵒ = 53.1688 [Btu/lbmol-R]

 S 0  S  ( 0) 
1
( )
 S0  S  (Sᵒ - S) = 8.9794
( S  S )  R 
0
  w *    ln P 
 R   R  
 

Tsr = T/Tsc = 1.56

0.29
Psr = P/Psc = 1.31
0.06

S = (So – (So– S))

S= 44.1894 [Btu/lbmol-R]
condensados.

𝑚_𝑖=( 〖𝑀𝑊〗 _(
𝑖 ∗ ) 𝑦_𝑖)/(∑▒
〖〖𝑀𝑊〗 _(𝑖 ∗ )
Pci yi*Pci wi yi*wi 𝑦_𝑖 〗 )mi Sᵒi Sᵒi*yi Sᵒi*yi*MWi
667 600.9670 0.0108 0.0097 0.7774 3.150 2.8382 45.5324
10695 113.3670 0.2667 0.0028 0.0251 1.170 0.0124 0.5458
707.8 35.3192 0.0972 0.0049 0.0807 2.038 0.1017 3.0580
615 11.5005 0.1515 0.0028 0.0443 1.620 0.0303 1.3359
527.9 3.4314 0.1852 0.0012 0.0203 1.440 0.0094 0.5440
548.8 2.4696 0.1981 0.0009 0.0141 1.340 0.0060 0.3505
490.4 0.8337 0.2286 0.0004 0.0066 1.260 0.0021 0.1545
488.1 0.9274 0.251 0.0005 0.0074 1.240 0.0024 0.1700
439.5 2.2854 0.299 0.0016 0.0241 1.200 0.0062 0.5377
771.1011 0.0248 1 3.0087 52.2289

[Btu/lbmol-R]
 ln(yi) yi* ln(yi)
-0.1043 -0.0939
-4.5469 -0.0482
-2.9977 -0.1496
-3.9792 -0.0744
-5.0360 -0.0327
-5.4037 -0.0243
-6.3771 -0.0108
-6.2659 -0.0119
-5.2591 -0.0273
-0.4733