H2O2 + 2I- + H+ -> I2 + 2H2O

I2 + 2S2O3 2- -> 2I- + S4O6 2-

tiempo cuando el Yodo se

manifiesta (s) [KI] [H2O2] Volumen (L)
Reacción 1 43 0.4016 0.0333 0.15
Reacción 2 45 0.4016 0.0167 0.3
Reacción 3 47 0.4016 0.0083 0.6
Reacción 4 42 0.4016 0.0333 0.15
Reacción 5 41 0.2008 0.0333 0.3
Reacción 6 40 0.1004 0.0333 0.6

𝑣𝑒𝑙𝑜𝑐𝑖𝑑𝑎𝑑=(𝑑[𝐻_2 𝑂_2])/𝑑𝑡=(𝑚𝑜𝑙𝑒𝑠 𝑑𝑒 𝐻_2 𝑂_2)/(𝑣𝑜𝑙𝑢𝑚𝑒𝑛 𝑡𝑜𝑡𝑎𝑙 ∗𝑡𝑖𝑒𝑚𝑝𝑜 𝑑𝑒 𝑟𝑒𝑎𝑐𝑐𝑖ó𝑛)

𝒓𝒆𝒍𝒂𝒄𝒊𝒐𝒏 𝒆𝒔𝒕𝒆𝒒𝒖𝒊𝒐𝒎𝒆𝒕𝒓𝒊𝒄𝒂:(𝟏 𝒎𝒐𝒍 𝒅𝒆 𝑯_𝟐 𝑶_𝟐)/(𝟏 𝒎𝒐𝒍 𝑰_𝟐 )

∗ (𝟏 𝒎𝒐𝒍 𝑰_𝟐)/(𝟐 𝒎𝒐𝒍 〖𝑵𝒂〗 _𝟐 𝑺_𝟐 𝑶_𝟑 )

Moles (S2O3)-2 0.00158

Molesconsumidas de
H2O2 0.00079
 Velocidades Log (velocidad) log [H2O2] log [KI]
0.0001225796645 -3.9115815716 -1.47755577 m= 1.0618
5.856583972E-05 -4.2323556254 -1.77728353 n= 0.9648
2.803683816E-05 -4.5522709652 -2.08092191
0.000125498228 -3.9013624064 -0.3962063
6.427958018E-05 -4.1919269684 -0.69723629
3.294328484E-05 -4.4822330986 -0.99826629 k = velocidad / [H2O2]m [I-]n

𝑑𝑒 𝑟𝑒𝑎𝑐𝑐𝑖ó𝑛) velocidad [H2O2]^m [KI]^n

0.0001225797 0.02699 0.41471
5.856584E-05 0.01297 0.41471
2.8036838E-05 0.00617 0.41471
0.0001254982 0.02699 0.41471
6.427958E-05 0.02699 0.21247
3.2943285E-05 0.02699 0.10886
Se puede concluir que ambos
órdenes de reacción son 1 k=
 log (velocidad) VS log ([H2O2])
-3.4
-2.2 -2.1 -2 -1.9 -1.8 -1.7 -1.6 -1.5 -1.4
-3.6

-3.8

Log (velocidad) f(x) = 1.06184043762037 x − 2.34349371714086 -4

R² = 0.999979607670155

-4.2

-4.4

dad / [H2O2]m [I-]n -4.6

-4.8
k Log [H2O2]
1.0953E-02
1.0890E-02
1.0952E-02
1.1214E-02 log (velocidad) VS log ([ki])
1.1211E-02 -3.6
-1.1 -1 -0.9 -0.8 - 0.7 -0.6 -0.5 -0.4 -0.3
1.1214E-02 -3.7
-3.8
1.1072E-02 -3.9
f(x) = 0.964805336054301 x − 3.51914352990303
Log (velocidad)

R² = 0.999999934020138 -4
-4.1
-4.2
-4.3
-4.4
-4.5
-4.6
Log (KI)
 -3.4
5 -1.4
-3.6

-3.8

-4

-4.2

-4.4

-4.6

-4.8

-3.6
0.4 -0.3
-3.7
-3.8
-3.9
-4
-4.1
-4.2
-4.3
-4.4
-4.5
-4.6