A

B
C

Datos de equilibrio

Refinado Extracto
A B C A B C
98.0 2.0 0.0 2.3 97.7 0.0
95.2 2.2 2.6 2.7 92.3 5.0
92.2 2.4 5.4 3.0 87.0 10.0
88.9 2.6 8.5 3.2 81.8 15.0
85.3 2.8 11.9 3.7 76.3 20.0
81.5 3.0 15.5 4.3 70.7 25.0
77.2 3.3 19.5 5.3 64.7 30.0
71.8 4.0 24.2 6.8 58.2 35.0
65.7 5.1 29.2 8.8 51.2 40.0
57.5 7.3 35.2 12.6 42.0 45.4
34.7 18.8 46.5 34.7 18.8 46.5

Datos
Textraccion 25 °C

E1 lb
y1

F
xF
100
0.4
lb
1 R1
x1
 1

S lb
yS 0

a) Cantidades minima y maxima para solvente puro

En la grafica coloco alimentacion y solvente

x y
x 0 40 x
y 100.0 0 Ys

Del diagrama : SOLVENTE MINIMO PARTE SUPERIOR

y 36.665 xD 0.36665
x 8.58

x x 
Smin imo  F  F D 
 xD  y S 
Smin 9.095868 lb

Del diagrama: SOLVENTE MAXIMO EN LA PARTE SUPERIOR

y 1.64 yG 0.0164
x 95.96

 x  yG 
S max imo  F  F 
y
 G  y S 

Smax 2339.0244 lb

b) Cantidades maximas y minimas constituido por

metilisobutilcetona (98% peso) y acetona (2% peso)
Datos
Textraccion 25 °C

E1 lb
y1

F 100 lb
1 R1
xF 0.4 x1

S lb
yS 0.02
xS 0.98
48
47
46
45
En la grafica coloco alimentacion y solvente 44
43
42

x y 41
40
F 0 40 39
38
S xS 98 2 yS XD=[VALOR
37
DE Y]
36
35

Del diagrama: 34
33
32

xD
31
XD y 36.7 0.367 30

x 8.637
29
28
27

x x 
26
25

Smin imo F F D  24

23

 xD  y S 
22
21
20

Smin
19
9.5100865 lb 18
17
16
Del diagrama: 15
14
13

YG= y 3.54 yG 0.0354

12
11

x 93.9 10
9
8
7
6
5
4
3
 14
13
12
11
10
9
8
7

 xF  yG 
6
5

Smax imo  F  4

y  y
3

 G S  2
1
0
0 10 20 30 40 50
Smax 2367.5325 lb
 agua
metil isobutil cetona
acetona

48
47
46
45
44
43
42
41
40
39
38
XD=[VALOR DE Y]
lb
37
36
35
34
33
32
31
30
 40
39
38
XD=[VALOR DE Y]
37
36
35
34
33
32
31
30
29
28
27
26
25
24
23
22
21
20
19
18
17
16
15
14
13
12
11
10
9
8
7
6
5
4
3
2
YG=[VALOR DE Y]
1
0
0 10 20 30 40 50 60 70 80 90 100

E SUPERIOR
 lb

48
47
46
45
44
43
42
41
40
39
38
XD=[VALOR DE Y]
37
36
35
34
33
32
31
30
29
28
27
26
25
24
23
22
21
20
19
18
17
16
15
14
13
12
11
10
9
8
7
6
5
4
3
14
13
12
11
10
9
8
7
6
5
4
3
2
1

100 0
0
0 10 20 30 40 50 60 70 80 90 100

0 100
 A
B
C

Datos de equilibrio

Fase acuosa Fase etérea

Refinado Extracto
A B C A B
99.89 0.11 0.00 0.18 99.82
94.82 0.18 5.00 0.32 94.47
89.79 0.21 10.00 0.49 88.72
84.78 0.24 15.00 0.63 83.17
79.69 0.31 20.00 0.79 76.98
74.58 0.42 25.00 1.17 69.82
69.42 0.58 30.00 1.72 60.80
64.22 0.78 35.00 2.33 54.39
58,64 1.36 40.00 3.05 47.51
52.76 2.24 45.00 4.28 40.80
46.28 3.72 50.00 7.24 33.57
38.69 6.31 55.00 13.83 24.38
27.41 12.59 60.00 22.85 15.08
25.66 13.76 60.58 25.66 13.76

Datos
Textraccion 25 °C CASO A
 E1 kg
y1

1
F 100 kg R1
xF 0.5 x1

S 100 kg
yS 0

a) Cantidad y composicion de los productos y el porcentaje de recuperacion

de la acetona

En la grafica coloco alimentacion y solvente

x y
x 0 50 x
y 100.0 0 Ys

F  xF  S  y S
Hallar xM xM 
F S
TRAZO LINEA
xM 0.25 0 25
100 25
En el diagrama-UBICO PUNTO M PUNTO QUE CORTE M
X Y
xM 25 0.35 22.85
y 50 73 26

Obtengo lo siguiente

x1 0.2283369
y1 0.2607248
 M 200 kg

 x  x1 
E1  M  M 
y  x
 1 1 
E1 133.77289 kg

 y x 
R1  M  1 M 
 y1  x1 
R1 66.227112 kg

F  xF  R1  x1
%acetonarecuperada  100
F  xF

%acetona recuperado 69.755817

b) La cantida de solvente necesario, en una sola etapa de extraccion, para

reducir la concentracion del refinado a un 20% peso de acetona

Datos
Textraccion 25 °C

E1 kg
y1 0.2223

1
F 100 kg R1
xF 0.5 x1

S kg
yS 0
solver 0.00
x y
56.71712343 21.641438

xM 0.2164144

 x  xM 
S  F  F 
x
 M  y S 

S 131.03825 kg

 x  x1 
E1  M  M 
y  x
 1 1 
M 231.03825 kg

E1 170.06055 kg

 y1  xM 
R1  M  
y 
 1 1 x
R1 60.977699 kg

F  xF  R1  x1
%acetonarecuperada  100
F  xF
%acetona recuperado 75.60892 %
 Agua
Clorobenceno
Acetona

Fase etérea

C A B C
0.00 27.41 12.59 60.00
5.21 25.66 13.76 60.58
10.79 22.85 15.08 61.07
16.20 13.83 24.38 61.79
22.23 33.57 59.19
29.01
37.48
43.28
49.44
54.92
59.19
61.79
61.07 65

60.58 64

63

62

61

60

59

58

57

56

55

54
 62

61

60

59

58

57

56

55

54

53

52

51
kg 50

49 f(x) = − 0.5 x + 5
48

47
R² = 1
46

45

44

43

42

41

40

39

38

37

36

35

34

33
x igualando x x igualando x 32

31

30
25 44.86405 29.01 44.86405
29
x1 22.833687 50 y1 26.072479 50 28 f(x) = 0.0577809
20 56.718176 22.23 56.718176 27

26
R² = 1
25

24

23

22

21 f(x) = 0.0290856
20

19
R² = 1
18

17

16
REFINADO X1 15

EXTRACTO Y1 14

13

12

11

10

3
 11

10

0
0 5 10 15 20

65
Agua (A)-Clorobenceno (B)-Acetona (C
64

63

62

61

60

59

58

57

56

kg 55

54
0.2
53

52

51

50

49

48

47

46

45

44

43

42

41
49

48

47

46

45

44

43

42

41

40

39

38

37

36

35

34

33

32

31

30

29

28

27

26

25

24

23

22

21 f(x) = 0.029085691926438 x + 19.9909834355028

20
R² = 1
19

18

17

16

15

14

13

12

11

10

0
0 5 10 15 20 25 30 35 40 45 50 55 60
Agua (A)-Clorobenceno (B)-Acetona (C) 25 °C
(x) = − 0.5 x + 50
R² = 1

f(x) = 0.05778097982709 x + 24.9757319884726

R² = 1

f(x) = 0.029085691926438 x + 19.9909834355028

R² = 1
 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100

nceno (B)-Acetona (C) 25 °C

9909834355028

45 50 55 60 65 70 75 80 85 90 95 100
85 90 95 100
 A
B
C

Datos
Textraccion 25 °C

E1 kg
y1
NE1

1
F 100 kg/h R1
xF 0.4 x1
NF 0 NR1

S kg
yS 0
NS

a) Flujos maximos y minimos empleando anilina pura

Convertir todo en base libre de B

F '  ( A  C)
F´ 100 kg/h

C B
XF   0.4 NF  0
AC AC
 C B
XF   0.4 NF  0
AC AC

Colocar la linea de alimentaacion solvente

x y
0.4 0
0.4 11.048196 NG

S max  F´( N G  N F )
Smax 1104.8196 kg

ND 0.09413216

S min  F ´( N D  N F )
Smax 9.413216 kg

b) Flujo maximo y minimo empleando un solvente 95% peso de anilina

y 5% peso n-heptano

Textraccion 25 °C

E1 kg
y1
NE1

1
F 100 kg/h R1
xF 0.4 x1
NF 0 NR1

S kg
yS 0
NS
 A 5 %
B 95 %
C 0
Convertir en base libre deB

F '  ( A  C)
F' 100 kg/h

B C
NS  XF   0.4
AC AC
NS 19
XF 0.4

Colocar la linea de alimentaacion solvente

x y
XF 0.4 0
0 19 NS

0.00
x y
0.1093404 13.80633107 NG

S´max  F '( N F  N G ) / ( N G  N S )
S'max 265.8300181 kg/h

Smax  S´max (1  N S )
Smax 5316.600362 kg/h

ND 0.09452

S´min  F '( N F  N D ) / ( N D  N S )
S´min  F '( N F  N D ) / ( N D  N S )
S´min 0.499960858 kg/h

S min  S´min (1  N S )
Smin 9.999217158 kg/h
 n-hepatno
anilina
metil ciclohexano

kg 16

14

12

10
 10

f(x) = 0− 7.50389755541167
f(x) = 153.2830811089 x⁵ − 639.7084462862
f(x) = 0.871547933152806 x³ −x⁴0.266769970243946
+ 1062.232401077
x⁴ + 13.4278540314709 x³ − 8.62
kg R² = 1 R² = 1 0.0R² = 1 0.1 0.2 0.3 0.4

20

f(x) = − 47.5 x + 19
R² = 1
 20

f(x) = − 47.5 x + 19
R² = 1
18

16

14

12

10

 NS ) 4
 NS ) 4

f(x)0= − f(x)
f(x) = 153.2830811089 x⁵ − 639.7084462862
7.50389755541167 x⁴ + 1062.232401077
x⁴ + 13.4278540314709
= 0.871547933152806 x²x³ − 877.01
x³ − 8.62445024609
x³ − 0.266769970243946 + 0.053145
0.0
R² = 1 R² = 1 R² = 1 0.1 0.2 0.3 0.4 0.5
62
x³ −x⁴0.266769970243946
+ 1062.232401077
4278540314709 x³
x² −+ 877.0157833863
x³ − 8.62445024609782 x² +x 360.0305102738
x² + 2.38336736525886
0.05314594762967 x − 58.68668900771
x − 0.146593600080589
+ 0.079913606911447
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
62.232401077 x²x³ − 877.0157833863
4709 x³ − 8.62445024609782
9970243946 x²
x + 360.0305102738
x² + 2.38336736525886
+ 0.05314594762967 x − 58.68668900771
x − 0.146593600080589
0.079913606911447
0.4 0.5 0.6 0.7 0.8 0.9 1.0
 A
B
C

Datos
Textraccion 98.3 °C

E1 kg
y1
NE1

F 100 kg/h R1
xF 0.5 1 x1 0.09
NF 0 NR1

S kg
yS
NS

A 1.8 %
B 98 %
C 0.2 %
 Convertir todo en base libre de B

F '  ( A  C)
F´ 100 kg/h

C B
XF   0.5 F
N  0
AC AC
XF 0.5

B C
NS  Ys 
AC AC
NS 49 yS 0.100

Transformar x1 a X1 en el refinado TRANFORMAR PARA HALLAR X

C=x1
X 1  x1 (1  N R1 )
9 %
B 39 leo del diagrama
A 52

B
N R1 
AC
NR1 0.6393443

X 1  x1 (1  N R1 )
X1 0.147541

Colocar la linea de alimentaacion solvente

x y
XF 0.5 0
0 49 NS
 x y
0.147541 1
0.147541 0

En el diaghrama de arriba

x y
X1 0.147541 0.639323 NR1
Y1 0.4046823 32.441472 NE1

Para el X'M

0.00
x y
X'M 0.3004744 19.55351 NM

 X  XM 
S '  F ' F 
X 
 M S Y
S' 99.526736 kg/h

S  S´(1  N S )
S 4976.3368 kg/h

 X  X1 
E '1  M '  M 
Y
 1  X 1 

M´ 199.52674 kg/h

E'1 118.66746 kg/h

E1  E '1 (1  N E1 )
E1 3968.4143 kg/h

 Y  XM 
R '1  M '  1 
Y
 1  X 1 

R'1 80.85928 kg/h

R1  R´1 (1  N R1 )
R1 132.55447 kg/h
 C
Ys 
AC

semillas de algodón 1.8 ys Ns 50

propano 98 0.1 49
acido oleico 0.2 50

kg
TRANSFORMAR

50

f(x) = − 98 x + 49
R² = 1

45

40
 f(x) = − 98 x + 49
R² = 1

45

40

35

f(x) = 123.675775842218 x − 17.6079226652452

30
R² = 1

25

20

15

10

0
0.0 0.1 0.2 0.3 0.4 0.5 0.6
DEBO CALCULAR EL VALOR DE y1 EN FRACCION PESO
Xf NF
0.5
6652452

0.5 0.6 0.7 0.8 0.9 1.0

1
f(x) = x
R² = 1

1
1
f(x) = x
R² = 1

0
0.0 0.1 0.2
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
0.8 0.9 1.0