Estandarización de NaOH TITULACIÓN DE 10,0 mL DE HCl

Masa de biftalato (g) Gasto, V1 (mL) Ccorregida de NaOH (M) Gasto, V2 (mL) Ccorregida de HCl (M)
1.0209 9.9 0.5050 10.2 0.5103
1.0221 10.1 0.4955 10.0 0.5003
1.0217 10.0 0.5003 9.9 0.4953
Mpromedio NaOH (mol/L) = 0.5003
MBP(g/mol) = 204.22

TITULACIÓN DE 50,0 mL DE CH3COOH TITULACIÓN DE 50,0 mL DE NH4OH

Ccorregida de Cpromedio de CH3COOH Ccorregida de NH4OH

Gasto, V3 (mL) Gasto, V4 (mL)
CH3COOH (M) (M) (M)

10.3 0.1031 9.9 0.0994

9.9 0.0991 0.1007 10.4 0.1044
10.0 0.1001 9.9 0.0994
Ka = 1.819E-05 pKa = 4.74016730094 Kb =

Mediciones de pH
Buffer CH3COOH
pH Buffer básico NH4OH 0,1 M
ácido 0,1 M
Experim. 4.78 9.22 2.98 11.08
Calculado 4.74 9.25 2.87 11.13
% Error 0.83 -0.29 3.89 -0.42
10,0 mL DE HCl
Cpromedio de HCl (M)

0.5020

E 50,0 mL DE NH4OH Preparación del buffer ácido

Cpromedio de NH4OH (M) Vol [CH3COO_]

Masa de
CH3COOH /
CH3COON
17,4 M [CH COOH
a (g) 3
(mL) ]
0.1011
0.8229 0.57 0.9992
1.77E-05 pKb = 4.7520267
Preparación del buffer básico

Vol NH3 MCH3COONa (g/mol) = 83.0343

Masa de [NH4+] /
NH4Cl (g) 14,7 M [NH3]
(mL)
53.491
MNH4Cl (g/mol) =
0.5361 0.68 1.0026