PLATO DE SEPARACIÓN DE UNA COLUMNA DE DESTILACIÓN CUANDO SE CUMPLE LA LEY DE RAOUT MODIFICADA POR EL MODELO DE WI

120.00 T0 (K) = 300

v(i)
x(i) a (kcal/kmol) A(i) B(i) C(i) T(i)s (K)
(cm3/mol) (i,j)
0.0709 58.68 1,556.450 16.8958 3795.17 230.918 82.517
0.9291 106.85 210.52 13.9320 3056.96 217.625 116.670
0.0709 0.9291
0.5367 0.4633
s
P1 (kPa)(*) s
P2 (kPa) L12 L21 Q1 Q2 g1
365.242 112.250 0.2409 0.4177 0.2947 0.9587 4.8364
189.580 63.308 0.2165 0.4117 0.2721 0.9583 5.1645
175.997 59.317 0.2139 0.4111 0.2697 0.9582 5.2017
174.556 58.892 0.2136 0.4110 0.2694 0.9582 5.2058
174.398 58.845 0.2136 0.4110 0.2694 0.9582 5.2062
174.381 58.840 0.2136 0.4110 0.2694 0.9582 5.2063
0.0709 y1 = 0.5367
T (° C) T vs y1 hE vs x1 (hL - h0) vs x1 (hG - h0) vs y1
hxy Etanol
132.448 0.000 0.0 -21425.3 8994.0
kPa

Entalpía molar (kJ/kmol)

113.302 0.390 308.6 -23670.2 6043.4
1.0E+04
106.718 0.500 508.8 -24617.2 5238.6
103.685 0.549 638.0 -25231.5 4891.1 5.0E+03
102.038 0.577 719.7 -25735.3 4704.4
101.040 0.595 767.8 -26198.8 4589.3 0.0E+00
100.383 0.608 791.3 -26648.4 4510.5
99.918 0.619 795.9 -27094.8 4451.7 -5.0E+03
99.571 0.628 785.6 -27542.8 4404.3
99.299 0.637 763.2 -27994.1 4363.4 -1.0E+04
99.082 0.645 730.7 -28449.4 4325.8
98.908 0.654 689.6 -28908.3 4289.5 -1.5E+04
98.777 0.665 640.8 -29370.4 4252.9
98.695 0.677 585.2 -29834.8 4214.5 -2.0E+04
98.677 0.691 523.0 -30300.0 4172.8
98.751 0.709 454.5 -30764.3 4125.9 -2.5E+04
98.966 0.733 379.6 -31224.9 4071.1
99.400 0.766 297.8 -31677.3 4003.8 -3.0E+04
100.196 0.812 208.4 -32114.0 3914.8
101.611 0.883 110.0 -32521.9 3783.9 -3.5E+04
0.0 0.1 0
104.153 1.000 0.0 -32875.3 3558.1
Fr
F racción m olar del m etanol en el v apor, y 1

140.0
Txy Etanol(1)-Tolueno(2) a 120
kPa

130.0
Temperatura, ° C

T vs x1 T vs y1
Curva de equilibrio del sistema eta
1.0 120 kPa
120.0
0.9

0.8
110.0
0.7

0.6

100.0 0.5

0.4

90.0 0.3

0.2

0.1
80.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
0.0
 0.6

100.0 0.5

0.4

90.0 0.3

0.2

0.1
80.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
0.0
0.5 0.6 0.7 0.8
Fracción molar del metanol en el líquido, x1 Fracción molar del metanol en el líquido,
UT MODIFICADA POR EL MODELO DE WILSON: y(i) = [P(i)sg(i)/P]x(i) (EJERCICIO-1)

y(i) Cp(i)/R ¶lnP(i)s/¶T K(i)

0.5367 8.948 0.03628 7.57

0.4633 12.922 0.03178 0.50
CpmG = 89.701 (hvap) (hG - h0) = 5875.4 (SG - S0) = 21.94
CpmL = 105.090 35656.57 (hL - h0) = -28408.0 (SL - S0) = -71.01
g2 P*s (kPa) Tcalc DT
1.0152 189.580 94.820 -19.427
1.0168 175.997 92.755 -2.065
1.0170 174.556 92.528 -0.227
1.0170 174.398 92.503 -0.025 TB (K) = 365.50
1.0170 174.381 92.500 -0.003
1.0170 174.379 92.500 0.000 hE = 365.2

hxy Etanol(1)-Tolueno(2) a 120

kPa
Entalpía molar (kJ/kmol)

1.0E+04

5.0E+03

0.0E+00

-5.0E+03
(hL - h0) vs x1 (hG - h0) vs y1
-1.0E+04

-1.5E+04

-2.0E+04

-2.5E+04

-3.0E+04

-3.5E+04
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Fracción molar del metanol en el líquido, x1
Entalpía molar en exceso (kJ/kmol)

hEx del sistema Etanol(1)-Tolueno(2)

kPa
8.0E+02

va de equilibrio del sistema etanol(1)-tolueno(2) a 7.0E+02

kPa
6.0E+02

5.0E+02

4.0E+02

3.0E+02

2.0E+02

1.0E+02
 4.0E+02

3.0E+02

2.0E+02

1.0E+02

0.6 0.7 0.8 0.9 1.0 0.0E+00

0.5 0.6 0.6 0.7 0.7 0.8 0.8 0.9 0.9
Fracción molar del metanol en el líquido, x1
Fracción molar del metanol en el líquido, x1
 kJ/Kmol
kJ/Kmol

Etanol(1)-Tolueno(2) a 120
 0.8 0.8 0.9 0.9 1.0 1.0
metanol en el líquido, x1
 ANÁLISIS DE UN PLATO DE SEPARACIÓN DE UNA COLUMNA DE DESTILACIÓN BASADO EN LA LEY DE RAOUT MODIFICADA POR E
P (kPa) = 120.00 T0 (K) = 300
v(i)
x(i) a (kcal/kmol) A(i) B(i) C(i)
(cm3/mol) (i,j)
etanol (1) 0.0943 58.68 1,556.450 16.8958 3795.17 230.918
Tolueno (2) 0.9057 106.85 210.52 13.9320 3056.96 217.625
x= 0.0943 0.9057
y= 0.5782 0.4218
T (° C) s
P1 (kPa)(*) s
P2 (kPa) L12 L21 Q1 Q2
113.450 356.067 109.789 0.2399 0.4175 0.3115 0.9451
92.273 172.945 58.415 0.2133 0.4109 0.2874 0.9445
90.227 160.484 54.710 0.2107 0.4102 0.2851 0.9444
90.023 159.282 54.351 0.2105 0.4102 0.2849 0.9444
90.003 159.163 54.315 0.2104 0.4102 0.2849 0.9444
90.001 159.151 54.311 0.2104 0.4102 0.2849 0.9444
x1 = 0.0943 y1 = 0.5782
T vs x1 T (° C) T vs y1 hE vs x1 (hL - h0) vs x1 (hG - h0) vs y1
0.000 132.448 0.000 0.0 -21425.3 8994.0
Diagram
0.050 113.302 0.390 308.6 -23670.2 6043.4 kPa
1.0E+04

Entalpía molar (kJ/kmol)

0.100 106.718 0.500 508.8 -24617.2 5238.6
0.150 103.685 0.549 638.0 -25231.5 4891.1 5.0E+03
(hL
0.200 102.038 0.577 719.7 -25735.3 4704.4 Line
0.250 101.040 0.595 767.8 -26198.8 4589.3 0.0E+00
0.300 100.383 0.608 791.3 -26648.4 4510.5
0.350 99.918 0.619 795.9 -27094.8 4451.7 -5.0E+03
0.400 99.571 0.628 785.6 -27542.8 4404.3
0.450 99.299 0.637 763.2 -27994.1 4363.4 -1.0E+04
0.500 99.082 0.645 730.7 -28449.4 4325.8
0.550 98.908 0.654 689.6 -28908.3 4289.5 -1.5E+04
0.600 98.777 0.665 640.8 -29370.4 4252.9
0.650 98.695 0.677 585.2 -29834.8 4214.5 -2.0E+04
0.700 98.677 0.691 523.0 -30300.0 4172.8
0.750 98.751 0.709 454.5 -30764.3 4125.9 -2.5E+04
0.800 98.966 0.733 379.6 -31224.9 4071.1
0.850 99.400 0.766 297.8 -31677.3 4003.8 -3.0E+04
0.900 100.196 0.812 208.4 -32114.0 3914.8
0.950 101.611 0.883 110.0 -32521.9 3783.9 -3.5E+04
0.0 0.1 0.2
1.000 104.153 1.000 0.0 -32875.3 3558.1
Fracc
F racción m olar del m eta nol en el v apor, y 1

140.0
Diagrama Txy del sistema etanol(1)-tolueno(2) a
120
kPa
130.0
Temperatura, ° C

T vs x1 T vs y1 Column H Column H Curva de equilibrio del sistema eta

1.0 120 kPa
120.0
0.9

0.8
110.0
0.7

0.6

100.0 0.5

0.4

90.0 0.3

0.2

0.1
80.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
0.0
 0.6

100.0 0.5

0.4

90.0 0.3

0.2

0.1
80.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
Fracción molar del metanol en el líquido, x1 Fracción molar del metanol en el líquido,
N LA LEY DE RAOUT MODIFICADA POR EL MODELO DE WILSON: y(i) = [P(i)sg(i)/P]x(i)

T(i)s (K) y(i) Cp(i)/R ¶lnP(i)s/¶T K(i)

82.517 0.5782 8.948 0.03685 6.13

116.670 0.4218 12.922 0.03230 0.47
CpmG = 88.329 (hvap) (hG - h0) = 5564.8 (SG - S0) =
CpmL = 104.319 35858.71 (hL - h0) = -28843.1 (SL - S0) =
g1 g2 P*s (kPa) Tcalc DT
4.3212 1.0259 172.945 92.273 -21.177
4.5938 1.0286 160.484 90.227 -2.045
4.6216 1.0289 159.282 90.023 -0.204
4.6244 1.0289 159.163 90.003 -0.020 TB (K) = 363.00
4.6247 1.0289 159.151 90.001 -0.002
4.6247 1.0289 159.149 90.001 0.000 hE = 443.4

Diagrama hxy del sistema etanol(1)-tolueno(2) a 120

kPa
1.0E+04
Entalpía molar (kJ/kmol)

(hL - h0) vs x1 (hG - h0) vs y1

5.0E+03
Linea de operación Línea de enlace
0.0E+00

-5.0E+03

-1.0E+04

-1.5E+04

-2.0E+04

-2.5E+04

-3.0E+04

-3.5E+04
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Fracción molar del metanol en el líquido, x1
Entalpía molar en exceso (kJ/kmol)

Diagrama hEx del sistema etanol(1)-tolue

kPa
8.0E+02

va de equilibrio del sistema etanol(1)-tolueno(2) a 7.0E+02

kPa
6.0E+02

5.0E+02

4.0E+02

3.0E+02

2.0E+02

1.0E+02
 4.0E+02

3.0E+02

2.0E+02

1.0E+02

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 0.0E+00
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
Fracción molar del metanol en el líquido, x1
Fracción molar del metanol en el líquido, x1
 20.98
-72.26

x del sistema etanol(1)-tolueno(2) a 120

 0.4 0.5 0.6 0.7 0.8 0.9 1.0
r del metanol en el líquido, x1
ANÁLISIS DE UN PLATO DE SEPARACIÓN DE UNA COLUMNA DE DESTILACIÓN BASADO EN LA LEY DE RAOUT MODIFICA
P (kPa) = 120.00 T0 (K) = 300
v(i)
x(i) a (kcal/kmol) A(i) B(i) C(i)
(cm3/mol) (i,j)
Etanol (1) 0.0547 58.68 1,556.450 16.8958 3795.17 230.918
Tolueno (2) 0.9453 106.85 210.52 13.9320 3056.96 217.625
x= 0.0547 0.9453
y= 0.4933 0.5067
T (° C) s
P1 (kPa)(*) s
P2 (kPa) L12 L21 Q1 Q2
114.803 371.756 113.993 0.2416 0.4179 0.2830 0.9682
97.264 206.767 68.303 0.2195 0.4125 0.2622 0.9679
95.266 192.624 64.197 0.2170 0.4119 0.2598 0.9678
95.031 191.017 63.727 0.2167 0.4118 0.2596 0.9678
95.004 190.828 63.672 0.2167 0.4118 0.2595 0.9678
95.000 190.806 63.666 0.2167 0.4118 0.2595 0.9678
x1 = 0.0547 y1 = 0.4933
T vs x1 T (° C) T vs y1 hE vs x1 (hL - h0) vs x1 (hG - h0) vs y1
0.000 132.448 0.000 0.0 -21425.3 8994.0
Diagram
0.050 113.302 0.390 308.6 -23670.2 6043.4 kPa
1.0E+04

Entalpía molar (kJ/kmol)

0.100 106.718 0.500 508.8 -24617.2 5238.6
0.150 103.685 0.549 638.0 -25231.5 4891.1 5.0E+03
(hL
0.200 102.038 0.577 719.7 -25735.3 4704.4 Line
0.250 101.040 0.595 767.8 -26198.8 4589.3 0.0E+00
0.300 100.383 0.608 791.3 -26648.4 4510.5
0.350 99.918 0.619 795.9 -27094.8 4451.7 -5.0E+03
0.400 99.571 0.628 785.6 -27542.8 4404.3
0.450 99.299 0.637 763.2 -27994.1 4363.4 -1.0E+04
0.500 99.082 0.645 730.7 -28449.4 4325.8
0.550 98.908 0.654 689.6 -28908.3 4289.5 -1.5E+04
0.600 98.777 0.665 640.8 -29370.4 4252.9
0.650 98.695 0.677 585.2 -29834.8 4214.5 -2.0E+04
0.700 98.677 0.691 523.0 -30300.0 4172.8
0.750 98.751 0.709 454.5 -30764.3 4125.9 -2.5E+04
0.800 98.966 0.733 379.6 -31224.9 4071.1
0.850 99.400 0.766 297.8 -31677.3 4003.8 -3.0E+04
0.900 100.196 0.812 208.4 -32114.0 3914.8
0.950 101.611 0.883 110.0 -32521.9 3783.9 -3.5E+04
0.0 0.1 0.2
1.000 104.153 1.000 0.0 -32875.3 3558.1
Fracc
F racción m olar del m etanol en el v apor, y 1

140.0
Diagrama Txy del sistema etanol(1)-tolueno(2) a
120
kPa
130.0
Temperatura, ° C

T vs x1 T vs y1 Column H Column H Curva de equilibrio del sistema eta

1.0 120 kPa
120.0
0.9

0.8
110.0
0.7

0.6

100.0 0.5

0.4

90.0 0.3

0.2

0.1
80.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
0.0
 0.6

100.0 0.5

0.4

90.0 0.3

0.2

0.1
80.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
Fracción molar del metanol en el líquido, x1 Fracción molar del metanol en el líquido,
EN LA LEY DE RAOUT MODIFICADA POR EL MODELO DE WILSON: y(i) = [P(i)sg(i)/P]x(i)

T(i)s (K) y(i) Cp(i)/R ¶lnP(i)s/¶T K(i)

82.517 0.4933 8.948 0.03573 9.02

116.670 0.5067 12.922 0.03128 0.54
CpmG = 91.136 (hvap) (hG - h0) = 6197.3 (SG - S0) =
CpmL = 105.627 35490.55 (hL - h0) = -28007.5 (SL - S0) =
g1 g2 P*s (kPa) Tcalc DT
5.2646 1.0093 206.767 97.264 -17.538
5.6251 1.0102 192.624 95.266 -1.998
5.6691 1.0103 191.017 95.031 -0.235
5.6743 1.0103 190.828 95.004 -0.028 TB (K) = 368.00
5.6749 1.0103 190.806 95.000 -0.003
5.6750 1.0103 190.803 95.000 0.000 hE = 300.4

Diagrama hxy del sistema etanol(1)-tolueno(2) a 120

kPa
1.0E+04
Entalpía molar (kJ/kmol)

(hL - h0) vs x1 (hG - h0) vs y1

5.0E+03
Linea de operación Línea de enlace
0.0E+00

-5.0E+03

-1.0E+04

-1.5E+04

-2.0E+04

-2.5E+04

-3.0E+04

-3.5E+04
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Fracción molar del metanol en el líquido, x1
Entalpía molar en exceso (kJ/kmol)

Diagrama hEx del sistema etanol(1)-tolue

kPa
8.0E+02

va de equilibrio del sistema etanol(1)-tolueno(2) a 7.0E+02

kPa
6.0E+02

5.0E+02

4.0E+02

3.0E+02

2.0E+02

1.0E+02
 4.0E+02

3.0E+02

2.0E+02

1.0E+02

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 0.0E+00
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
Fracción molar del metanol en el líquido, x1
Fracción molar del metanol en el líquido, x1
 22.87
-69.90

x del sistema etanol(1)-tolueno(2) a 400

 0.4 0.5 0.6 0.7 0.8 0.9 1.0
r del metanol en el líquido, x1
 UN PLATO DE SEPARACIÓN DE UNA COLUMNA DE DESTILACIÓN BASADO EN LA LEY DE RAOUT MODIFICADA POR EL MOD
P (kPa) = 120.00 T0 (K) = 300
v(i)
x(i) a (kcal/kmol) A(i) B(i) C(i)
(cm3/mol) (i,j)
Etanol (1) 0.0685 58.68 1,556.450 16.8958 3795.17 230.918
Tolueno (2) 0.9315 106.85 210.52 13.9320 3056.96 217.625
x= 0.0685 0.9315
y= 0.5311 0.4689
T (° C) s
P1 (kPa)(*) s
P2 (kPa) L12 L21 Q1 Q2
114.331 366.220 112.512 0.2410 0.4178 0.2930 0.9601
95.147 191.807 63.958 0.2169 0.4118 0.2705 0.9597
93.086 178.119 59.943 0.2143 0.4112 0.2681 0.9597
92.857 176.653 59.511 0.2140 0.4111 0.2678 0.9597
92.832 176.491 59.463 0.2140 0.4111 0.2678 0.9597
92.829 176.472 59.458 0.2140 0.4111 0.2678 0.9597
x1 = 0.0685 y1 = 0.5311
T vs x1 T (° C) T vs y1 hE vs x1 (hL - h0) vs x1 (hG - h0) vs y1
0.000 58.704 0.000 0.0 -29975.7 2704.1
Diagram
0.050 46.804 0.383 278.2 -31473.2 1392.0 kPa

Entalpía molar (kJ/kmol)

0.100 43.746 0.466 429.1 -31968.1 1122.5
0.150 42.534 0.500 514.7 -32288.9 1020.8 0.0E+00 (hL
0.200 41.933 0.518 562.6 -32568.0 970.6 Line
0.250 41.587 0.530 586.7 -32838.0 941.5 -5.0E+03
0.300 41.366 0.539 594.5 -33108.1 922.2
0.350 41.211 0.546 590.5 -33381.4 908.2 -1.0E+04
0.400 41.097 0.553 577.6 -33658.3 879.2
0.450 41.012 0.560 557.7 -33938.6 888.0 -1.5E+04
0.500 40.951 0.567 531.9 -34221.8 880.2
0.550 40.916 0.575 501.0 -34507.1 873.5 -2.0E+04
0.600 40.912 0.585 465.6 -34793.8 868.0
0.650 40.952 0.596 425.9 -35080.6 864.1 -2.5E+04
0.700 41.053 0.611 381.9 -35366.3 862.3
0.750 41.247 0.630 333.5 -35648.6 863.5 -3.0E+04
0.800 41.584 0.656 280.4 -35924.5 869.2
0.850 42.152 0.692 221.9 -36188.5 881.4 -3.5E+04
0.900 43.107 0.747 156.9 -36431.3 902.3 0.0 0.1 0.2
0.950 44.751 0.836 83.9 -36634.5 932.4 -4.0E+04
1.000 47.736 1.000 0.0 -36759.4 956.3
Fracc
F racción m olar del m etanol en el v apor, y 1

65.0
Diagrama Txy del sistema Etanol(1)-Tolueno(2) a
120
kPa
60.0
Temperatura, ° C

T vs x1 T vs y1 Column H Column H Curva de equilibrio del sistema Eta

55.0 1.0 120 kPa
0.9
50.0 0.8

0.7
45.0
0.6

0.5
40.0
0.4

0.3
35.0
0.2

0.1
30.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
0.0
 0.6

0.5
40.0
0.4

0.3
35.0
0.2

0.1
30.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
Fracción molar del metanol en el líquido, x1 Fracción molar del metanol en el líquido,
EY DE RAOUT MODIFICADA POR EL MODELO DE WILSON: y(i) = [P(i)sg(i)/P]x(i)

T(i)s (K) y(i) Cp(i)/R ¶lnP(i)s/¶T K(i)

82.517 0.5311 8.948 0.03621 7.76

116.670 0.4689 12.922 0.03172 0.50
CpmG = 89.886 (hvap) (hG - h0) = 5917.1 (SG - S0) =
CpmL = 105.171 35633.08 (hL - h0) = -28353.8 (SL - S0) =
g1 g2 P*s (kPa) Tcalc DT
4.8971 1.0143 191.807 95.147 -19.184
5.2307 1.0157 178.119 93.086 -2.061
5.2690 1.0159 176.653 92.857 -0.228
5.2732 1.0159 176.491 92.832 -0.025 TB (K) = 365.83
5.2737 1.0159 176.472 92.829 -0.003
5.2738 1.0159 176.470 92.829 0.000 hE = 356.0

Diagrama hxy del sistema Etanol(1)-Tolueno(2) a 120

kPa
Entalpía molar (kJ/kmol)

0.0E+00 (hL - h0) vs x1 (hG - h0) vs y1

Linea de operación Línea de enlace
-5.0E+03

-1.0E+04

-1.5E+04

-2.0E+04

-2.5E+04

-3.0E+04

-3.5E+04
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
-4.0E+04

Fracción molar del metanol en el líquido, x1

Entalpía molar en exceso (kJ/kmol)

Diagrama hEx del sistema Etanol(1)-Tolue

kPa
6.0E+02

va de equilibrio del sistema Etanol(1)-Tolueno(2) a

kPa 5.0E+02

4.0E+02

3.0E+02

2.0E+02

1.0E+02
 3.0E+02

2.0E+02

1.0E+02

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 0.0E+00
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
Fracción molar del metanol en el líquido, x1
Fracción molar del metanol en el líquido, x1
 F L0 G2

P (kPa) 120.0 120.0 120.0

T (° C) 92.50 90.00 95.00
22.06 T (K) 365.50 363.00 368.00
-70.86 zF (%) 7.09% 9.43% 49.33%
Condición pto burbuja pto burbuja pto rocío
Cpm (kJ/kmol-K) 105.09 104.319 91.136
(hGI - h0) (kJ/kmol) 6883.37 6572.08 6197.27
hvap (kJ/kmol) 35656.57 35858.71 0
hE (kJ/kmol) 365.21 443.42 0
(h - h0) (kJ/kmol) -28408.0 -28843.2 6197.3
F (kmol/s) 1.00 1.50 1.20
(s - s0) (kJ/kmol-k) -71.01 -72.26 22.87

Balance de materia: F + L0 + G2 = G1 + L1 3.70

zF = 0.217
G/F = (zF - xL1)/(yG1 - xL1) = 0.3218
G (kmol/s) = 1.19
Balance de energía: Q = [L1*(hL - h0) + G1*(hG - h0)] - [F*(hF - h0) + L0*(hL0 - h0) + G2*(hG2
Q (kJ/s) = 0.00
Balance de entropía: Sgen = [L1*(sL - s0) + G1*(sG - s0)] - [F*(sF - s0) + L0*(sL0 - s0) + G2*(sG2
Sgen(kJ/s-k)= 0.44
Balance de exergía: фdest= T0*Sgen
фdest= 132.72

x del sistema Etanol(1)-Tolueno(2) a 120

 0.4 0.5 0.6 0.7 0.8 0.9 1.0
ar del metanol en el líquido, x1
 G1 L1

120.00 120.00
92.829 92.829
365.83 365.83
0.5311 0.0685
pto rocío pto burbuja
89.886 105.171
5917.1 6923.3
0 35633.08
0 356.0
5917.1 -28407.99
1.19 2.51
22.06 -70.86

kmol/s

F*(hF - h0) + L0*(hL0 - h0) + G2*(hG2 - h0)]

- [F*(sF - s0) + L0*(sL0 - s0) + G2*(sG2 - s0)]

 ANÁLISIS DE UNA EXPANSIÓN ISENTÁLPICA A TRAVÉS DE UNA VÁLVULA BASADO EN LA LEY DE RAOUT MODIFICADA POR EL MODELO D
P (kPa) = 500.00 T0 (K) = 300
a(i,j)
x(i) v(i) (cm3/mol) A(i) B(i) C(i) T(i)s (K)
(kcal/kmol)
Etanol (1) 0.2500 58.68 1,556.450 16.8958 3795.17 230.918 124.395
Tolueno (2) 0.7500 106.85 210.52 13.9320 3056.96 217.625 178.488
x= 0.2500 0.7500
y= 0.7084 0.2916
T (° C) s
P1 (kPa)(*) s
P (kPa)
2 L12 L21 Q1 Q2 g1
164.965 1493.986 380.629 0.3045 0.4312 0.4783 0.8578 2.3113
132.271 630.323 180.411 0.2636 0.4228 0.4477 0.8557 2.3980
130.108 592.061 170.866 0.2608 0.4223 0.4456 0.8556 2.4040
129.956 589.458 170.213 0.2606 0.4222 0.4455 0.8556 2.4044
129.946 589.276 170.168 0.2606 0.4222 0.4455 0.8556 2.4044
129.945 589.263 170.164 0.2606 0.4222 0.4455 0.8556 2.4044
x1 = 0.2500 y1 = 0.7084
T vs x1 T (° C) T vs y1 hE vs x1 (hL - h0) vs x1 (hG - h0) vs y1
hxy del siste
0.000 132.448 0.000 0.0 -21425.3 8994.0
Etanol(1)-To
0.050 113.302 0.390 308.6 -23670.2 6043.4
1.0E+04 kPa
0.100 106.718 0.500 508.8 -24617.2 5238.6

Entalpía molar (kJ/kmol)

0.150 103.685 0.549 638.0 -25231.5 4891.1
5.0E+03 (hL - h0) vs x
0.200 102.038 0.577 719.7 -25735.3 4704.4 Linea de ope
0.250 101.040 0.595 767.8 -26198.8 4589.3
0.0E+00
0.300 100.383 0.608 791.3 -26648.4 4510.5
0.350 99.918 0.619 795.9 -27094.8 4451.7 -5.0E+03
0.400 99.571 0.628 785.6 -27542.8 4404.3
0.450 99.299 0.637 763.2 -27994.1 4363.4 -1.0E+04
0.500 99.082 0.645 730.7 -28449.4 4325.8
0.550 98.908 0.654 689.6 -28908.3 4289.5 -1.5E+04
0.600 98.777 0.665 640.8 -29370.4 4252.9
0.650 98.695 0.677 585.2 -29834.8 4214.5 -2.0E+04
0.700 98.677 0.691 523.0 -30300.0 4172.8
0.750 98.751 0.709 454.5 -30764.3 4125.9 -2.5E+04
0.800 98.966 0.733 379.6 -31224.9 4071.1
0.850 99.400 0.766 297.8 -31677.3 4003.8 -3.0E+04
0.900 100.196 0.812 208.4 -32114.0 3914.8
0.950 101.611 0.883 110.0 -32521.9 3783.9 -3.5E+04
0.0 0.1 0.2 0.3
1.000 104.153 1.000 0.0 -32875.3 3558.1
Fracción mol
Fracción m olar del m etanol en el vapor, y1

Txy Etanol(1)-Tolueno(2) a 500

140.0 kPa

T vs x1 T vs y1 Column H Column H
130.0
Curva de equilibrio etanol(1)-tolueno(2
Temperatura, ° C

1.0

0.9
120.0
0.8
 140.0 kPa

Fracción m olar del m etanol en

T vs x1 T vs y1 Column H Column H
130.0
Curva de equilibrio etanol(1)-tolueno(2
Temperatura, ° C 1.0

0.9
120.0
0.8

0.7
110.0
0.6

0.5
100.0
0.4

0.3
90.0
0.2

0.1
80.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Fracción molar del metanol en el líquido, x1 Fracción molar del metanol en el líquido, x1
UT MODIFICADA POR EL MODELO DE WILSON: y(i) = [P(i)sg(i)/P]x(i)

y(i) Cp(i)/R ¶lnP(i)s/¶T K(i)

0.7084 8.948 0.02914 2.83

0.2916 12.922 0.02530 0.39
CpmG = 84.028 (hvap) (hG - h0) = 8650.2 (SG - S0) = 16.43
CpmL = 99.174 35454.65 (hL - h0) = -24449.3 (SL - S0) = -61.74
g2 s
P* (kPa) Tcalc DT
1.1274 630.323 132.271 -32.694
1.1413 592.061 130.108 -2.164
1.1423 589.458 129.956 -0.151
1.1424 589.276 129.946 -0.011 TB (K) = 402.95
1.1424 589.263 129.945 -0.001
1.1424 589.262 129.945 0.000 hE = 795.9

hxy del sistema e

Etanol(1)-Tolueno(2) a 500
1.0E+04 kPa
Entalpía molar (kJ/kmol)

5.0E+03 (hL - h0) vs x1 (hG - h0) vs y1

Linea de operación Línea de enlace
0.0E+00

-5.0E+03

-1.0E+04

-1.5E+04

-2.0E+04

-2.5E+04

-3.0E+04

-3.5E+04
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

Fracción molar del metanol en el líquido, x1

hEx del sistema etanol(1)-tolueno(2) a 500

ntalpía molar en exceso (kJ/kmol)

kPa
8.0E+02

ibrio etanol(1)-tolueno(2) a 500 kPa

7.0E+02

6.0E+02
 kPa

Entalpía molar en exceso (kJ/kmol

8.0E+02

ibrio etanol(1)-tolueno(2) a 500 kPa

7.0E+02

6.0E+02

5.0E+02

4.0E+02

3.0E+02

2.0E+02

1.0E+02

0.4 0.5 0.6 0.7 0.8 0.9 1.0 0.0E+00

0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
molar del metanol en el líquido, x1
Fracción molar del metanol en el líquido, x1
o(2) a 500
9 1.0
 ANÁLISIS DE UNA EXPANSIÓN ISENTÁLPICA A TRAVÉS DE UNA VÁLVULA BASADO EN LA LEY DE RAOUT MODIFICADA POR EL MODELO D
P (kPa) = 50.00 T0 (K) = 300
a(i,j)
x(i) v(i) (cm3/mol) A(i) B(i) C(i) T(i)s (K)
(kcal/kmol)
Etanol (1) 0.1412 58.68 1,556.450 16.8958 3795.17 230.918 61.383
Tolueno (2) 0.8588 106.85 210.52 13.9320 3056.96 217.625 87.462
x= 0.1412 0.8588
y= 0.6096 0.3904
T (° C) s
P1 (kPa)(*) s
P (kPa)
2 L12 L21 Q1 Q2 g1
83.780 125.975 44.240 0.2027 0.4081 0.3152 0.9164 3.7592
65.068 58.773 22.608 0.1795 0.4014 0.2953 0.9155 3.9162
63.643 55.238 21.403 0.1777 0.4009 0.2938 0.9154 3.9284
63.531 54.968 21.310 0.1776 0.4009 0.2937 0.9154 3.9294
63.523 54.947 21.303 0.1776 0.4009 0.2937 0.9154 3.9295
63.522 54.946 21.302 0.1776 0.4009 0.2937 0.9154 3.9295
x1 = 0.1412 y1 = 0.6096
T vs x1 T (° C) T vs y1 hE vs x1 (hL - h0) vs x1 (hG - h0) vs y1
hxy Etanol(
0.000 58.704 0.000 0.0 -29975.7 2704.1
kPa
0.050 46.804 0.383 278.2 -31473.2 1392.0
0.100 43.746 0.466 429.1 -31968.1 1122.5

Entalpía molar (kJ/kmol)

0.150 42.534 0.500 514.7 -32288.9 1020.8 0.0E+00
0.200 41.933 0.518 562.6 -32568.0 970.6
0.250 41.587 0.530 586.7 -32838.0 941.5 -5.0E+03
0.300 41.366 0.539 594.5 -33108.1 922.2
0.350 41.211 0.546 590.5 -33381.4 908.2 -1.0E+04 (hL - h0) vs x1
Línea de enlace
0.400 41.097 0.553 577.6 -33658.3 879.2
0.450 41.012 0.560 557.7 -33938.6 888.0 -1.5E+04
0.500 40.951 0.567 531.9 -34221.8 880.2
0.550 40.916 0.575 501.0 -34507.1 873.5 -2.0E+04
0.600 40.912 0.585 465.6 -34793.8 868.0
0.650 40.952 0.596 425.9 -35080.6 864.1 -2.5E+04
0.700 41.053 0.611 381.9 -35366.3 862.3
0.750 41.247 0.630 333.5 -35648.6 863.5 -3.0E+04
0.800 41.584 0.656 280.4 -35924.5 869.2
0.850 42.152 0.692 221.9 -36188.5 881.4 -3.5E+04
0.900 43.107 0.747 156.9 -36431.3 902.3 0.0 0.1 0.2 0.3
0.950 44.751 0.836 83.9 -36634.5 932.4 -4.0E+04

1.000 47.736 1.000 0.0 -36759.4 956.3

Fracción mol
F racción m olar del m etanol en el vapor, y1

Txy del sistema Etanol(1)-Tolueno(2) a 50

65.0 kPa

60.0 T vs x1 T vs y1 Column H Column H

Curva de equilibrio Etanol(1)-Tolueno(
Temperatura, ° C

1.0
55.0
0.9

0.8
50.0
 65.0 kPa

F racción m olar del m etanol en

60.0 T vs x1 T vs y1 Column H Column H
Curva de equilibrio Etanol(1)-Tolueno(
Temperatura, ° C 1.0
55.0
0.9

0.8
50.0
0.7

45.0 0.6

0.5

40.0 0.4

0.3
35.0
0.2

0.1
30.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Fracción molar del metanol en el líquido, x1 Fracción molar del metanol en el líquido, x1
UT MODIFICADA POR EL MODELO DE WILSON: y(i) = [P(i)sg(i)/P]x(i)

y(i) Cp(i)/R ¶lnP(i)s/¶T K(i)

0.6096 8.948 0.04378 4.32

0.3904 12.922 0.03867 0.45
CpmG = 87.293 (hvap) (hG - h0) = 3188.1 (SG - S0) = 21.35
CpmL = 102.769 37091.40 (hL - h0) = -32813.9 (SL - S0) = -83.80
g2 s
P* (kPa) Tcalc DT
1.0612 58.773 65.068 -18.712 Cpm (kJ/kmol-K)
1.0665 55.238 63.643 -1.425 (hGI - h0) (kJ/kmol)
1.0669 54.968 63.531 -0.112 hvap (kJ/kmol)
1.0670 54.947 63.523 -0.009 TB (K) = 336.52
1.0670 54.946 63.522 -0.001 (h - h0) (kJ/kmol)
E
1.0670 54.946 63.522 0.000 h = 524.2
(s - s0) (kJ/kmol-k)

hxy Etanol(1)-Tolueno(2) a 50
kPa
Entalpía molar (kJ/kmol)

0.0E+00

-5.0E+03

-1.0E+04 (hL - h0) vs x1 (hG - h0) vs y1 Linea de operación

Línea de enlace

-1.5E+04

-2.0E+04

-2.5E+04

-3.0E+04

-3.5E+04

0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
-4.0E+04

Fracción molar del metanol en el líquido, x1

hEx Etanol(1)-Tolueno(2) a 50
ntalpía molar en exceso (kJ/kmol)

kPa
6.0E+02

librio Etanol(1)-Tolueno(2) a 50 kPa

5.0E+02

4.0E+02
 kPa

Entalpía molar en exceso (kJ/k

6.0E+02

librio Etanol(1)-Tolueno(2) a 50 kPa

5.0E+02

4.0E+02

3.0E+02

2.0E+02

1.0E+02

0.4 0.5 0.6 0.7 0.8 0.9 1.0 0.0E+00

0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
molar del metanol en el líquido, x1
Fracción molar del metanol en el líquido, x1
 F L G

P (kPa) 500.0 50.0 50.0

T (° C) 129.95 63.52 63.52
T (K) 402.95 336.52 336.52
zF (%) 25.00% 14.12% 60.96%
Condición pto burbuja pto burbuja pto rocío
Cpm (kJ/kmol-K) 99.17 102.769 87.293
(hGI - h0) (kJ/kmol) 10209.42 3753.33 3188.10
hvap (kJ/kmol) 35454.65 37091.40 0
hE (kJ/kmol) 795.89 524.17 0
(h - h0) (kJ/kmol) -24449.3 -32813.9 3188.1
F (kmol/s) 20.00 15.35 4.65
(s - s0) (kJ/kmol-k) -61.74 -83.80 21.35

Balance de mat F=L+G= 20.00 kmol/s

zF = 0.250
G/F = (zF - xL)/(yG - xL) = 0.2323
G (kmol/s) = 4.65
Balance de eneQ = [L*(hL - h0) + G*(hG - h0)] - F*(hF - h0)
Q (kJ/s) = 0.00
Balance de entSgen = [L*(sL - s0) + G*(sG - s0)] - F*(sF - s0)
Sgen(kJ/s-k)= 47.38
Balance de exeфdest= T0*Sgen
фdest= 14212.80

0
 0.9 1.0

x1