Metodo de Pitzer - lee kessler

Ecuaciones sacadas de " Inenieria de gas natural: Características y comportamiento"

Nota: los valores del factor acentrico, presion y temperatura critica se determinaron mediante la ta

Metodo de Stewart-Burkhardt-Voo (SBV) utilizado para el calculo de propiedadess seudocri

Po (lpca) To (F) To (R)

1792 290 749.67

FRACCION TEMPERATURA PRESION FACTOR

Componente MOLAR CRITICA CRITICA ACENTRICO
(Yi) Tci (R) Pci (lpca) (ω)

C1 0.7887 343 666.4 0.011

C2 0.062 549.57 706.5 0.098
C3 0.0458 665.694 616 0.149
iC4 0.0221 734.65 527.9 0.177
nC4 0.0264 765.21 550.6 0.197
iC5 0.014 828.77 490.4 0.226
nC5 0.0068 845.46 488.6 0.251
CO2 0.0006 547.57 1071 0.224
N2 8E-05 227.16 493.1 0.037
C6 0.0329 913.6 436.9 0.3047
0.99938

valores seudocriticos seudocriticos corregidos valores seudoreducidos

Tsc Psc T´SC P´sc Tsr
439.9075664 686.448785 439.887296016 686.41715459 1.7042319858
 J K ωh
0.640845429 16.7902577 0.03556216
 HERNANDEZ JIMENEZ CESAR IVAN

cterísticas y comportamiento"

e determinaron mediante la tabla 2.164 del libro "Manual del ingeniero quimico- perry". Pg 2-134

lo de propiedadess seudocriticas Factor de compresibilidad

Los valores de Tsc y Psc se ajustan usando la

Yi*(Tci/Pci) √Pci Tci/√Pci Yi*(Tci/√pci) (Yi*√(Tci/Pci))^2 YI*ω

0.405948529412 25.81472448 13.286990541 10.47944944 0.56583708357358 0.0086757

0.04822836518 26.58006772 20.676019557 1.28191321252 0.05468234304772 0.006076
0.049494781169 24.819347292 26.821575611 1.22842816297 0.04761156348549 0.0068242
0.030755379807 22.976074512 31.974565525 0.7066378981 0.02607093964033 0.0039117
0.036690054486 23.464867355 32.610881128 0.86092726177 0.03112261940182 0.0052008
0.023659828711 22.144976857 37.424739947 0.52394635925 0.01819993411959 0.003164
0.011766532951 22.104298225 38.248669621 0.26009095342 0.00894496640959 0.0017068
0.000306761905 32.726136344 16.731886534 0.01003913192 0.00042901881411 0.0001344
3.68541878E-05 22.205855084 10.229734417 0.00081837875 5.429857294E-05 2.96E-06
0.068797070268 20.902152999 43.708416068 1.43800688863 0.04757545177726 0.01002463
0.675684158077 16.7902576873 0.80052821884245

lores seudoreducidos Z⁰ Z´

Psr 0.89 0.02

2.610657364877
 FP valor del factor de compresibilidad
0.0202704239 Z = Z⁰ + ωh*Z´
0.8907112432

ρg=𝑃𝑀𝑎/𝑍𝑅𝑇= (𝑝𝑠𝑖𝑎)(𝑙𝑏
e Tsc y Psc se ajustan usando la ecuacion de Wichert y Aziz

PESO PESO/MOL GRAVEDAD ESPECIFICA

√(Tci/Pci) MOLECULAR Yi*Mi %w DE CADA COMPONENTE
(Mi) (Ma) (GE)

0.717430054 16.043 12.6531141 53.34196176717 0.553884928101642

0.881973275 30.07 1.86434 7.859531828691 1.03816741183173
1.0395537879 44.097 2.0196426 8.514243806001 1.52244989556181
1.1796805267 58.123 1.2845183 5.41516700998 2.00669785426988
1.1788870986 58.123 1.5344472 6.468796790202 2.00669785426988
1.2999952943 72.15 1.0101 4.258296823627 2.49098033799997
1.3154362367 72.15 0.49062 2.068315600047 2.49098033799997
0.7150313568 44.01 0.026406 0.111320251386 1.51944621864696
0.6787321618 28.014 0.00224112 0.009447930084 0.967183966579779
1.4460623641 86.18 2.835322 11.95291819281 2.97536639679608
23.72075132

DENSIDAD (ρ) - (Lb/ft^3) VOLUMEN (V) - ft^3

5.932025 Lb/ft^3 3.99876096 ft^3

 𝑉=𝑀𝑎/("ρ" g) = (lb/lb-mol)/(lb/ft^3 )=

=𝑃𝑀𝑎/𝑍𝑅𝑇= (𝑝𝑠𝑖𝑎)(𝑙𝑏/𝑙𝑏𝑚𝑜𝑙)/(0.774((𝑝𝑠𝑖𝑎∗𝑓𝑡Þ^3)/𝑙𝑏𝑚𝑜𝑙𝑅)(⁰𝑅))=
GRAVEDAD ESPECIFICA Valores de R unidades
DE LA MEZCLA
(Yi*GE)
8.3143 J/mol*K
0.436849042793765 8.3143 Pa*m^3/mol*K
0.064366379533567 1.9871 Cal/mol*K
0.069728205216731 1.9858 BTU/Lbmol*⁰R
0.044348022579364 0.08205 atm*L/mol*K
0.052976823352725 82.05 atm*cm^3/mol*K
0.034873724732 10.7314 psia*ft^3/Lbmol*⁰R
0.0169386662984
0.000911667731188
7.73747173263823E-05
0.097889554454591
0.818959461409657
𝑜𝑙𝑅)(⁰𝑅))=