METODO DE MC CABE-THIELE

DATOS
P 14.7 PSI
F 700 LB/H
q 0.99999

FRACCIONES MOLARES DE CADA CORRIENTE

COMPONENTE N° zF yD xB
Benceno 113 0.45 0.92 0.05
Tolueno 125 0.55 0.08 0.95

Constantes criticas y de Antoine

COMPONENTE Pc A1 A2 A3
N° PSIA
Benceno 113 714.2 5.658375 5307.813 379.456
Tolueno 125 587.8 5.944251 5836.287 374.745

CALCULO DEL INCREMENTO DE LA TEMPERATURA

∆TT 30.5 °C
N 15
∆T 2.1785714286 °C

T T Ps-BENCENO Ps-TOLUENO x-BENCENO

N° °C °F PSIA PSIA
1 80.1 176.18 14.53933686235 5.62388877893 1.018020758591
2 82.278571429 180.1014285714 15.54600824856 6.061120778048 0.910804608785
3 84.457142857 184.0228571429 16.60689784704 6.525484402543 0.810850149383
4 86.635714286 187.9442857143 17.72400445426 7.018199650203 0.717535999432
5 88.814285714 191.8657142857 18.89935847712 7.540516665216 0.630300470184
6 90.992857143 195.7871428571 20.13502106135 8.093715510564 0.548635234076
7 93.171428571 199.7085714286 21.43308319446 8.679105910742 0.472079725039
8 95.35 203.63 22.79566478502 9.298026965495 0.400216179063
9 97.528571429 207.5514285714 24.22491371991 9.951846835332 0.332665236075
10 99.707142857 211.4728571429 25.72300490141 10.64196239961 0.269082034608
11 101.88571429 215.3942857143 27.29213926558 11.36979888796 0.209152739676
12 104.06428571 219.3157142857 28.93454278386 12.13680948604 0.152591451984
13 106.24285714 223.2371428571 30.6524654493 12.94447491625 0.099137453257
14 108.42142857 227.1585714286 32.44818024925 13.79430299454 0.048552748208
15 110.6 231.08 34.32398212592 14.68782816416 0.000619868629
DOMO 84.280316776 183.7045701969 16.51872039471 6.486753216369 0.818707501492
FONDO 108.3574255 227.0433658932 32.39429433497 13.76872090466 0.050000022755
ALIMENTACION 93.82637658 200.8874778449 21.83583860578 8.861586560581 0.450000001471

CALCULO DEL NUMERO DE ETAPAS MINIMAS

COMPOSICION EN EL DOMO
x y 1
0.92 0
0.9

0.8

0.7
 1

0.92 0.92 0.9

0.8
COMPOSICION EN EL FONDO
x y 0.7
0.05 0
0.05 0.05 0.6

Y-BEN
RECTA DE 45 0.5
x y
0.4
0 0
1 1
0.3

0.2

0.1

0
0 0.1 0.2 0.3

CALCULO DEL REFLIJO MINIMO

DATOS
q 0.99999
xF 0.45 1
f(x) = − 0.2034766
R² = 0.999999998
RECTA DE ALIMENTACION 0.9
x y
0.45 0.45 Recta alim. Fobj 0.8
0.44999781562 0.6684362192 0.668436219195 2.569533163E-23
0.7

0.6
Y-BEN

0.5
RECTA DE RECTIFICACIÓN
x y 0.4
0.92 0.92
0.449997815616 0.6684362192 0.3

Calculo de reflujo minimo Pág.357 0.2

(L/V)min 0.5352395992 𝑅_𝑚𝑖𝑛=(𝐿⁄𝑉)_𝑚𝑖𝑛/(1−(𝐿⁄𝑉)_𝑚𝑖𝑛 )
Rmin 1.1516463071 0.1

Pág.361 0
0 0.1

CALCULO DEL REFLUJO REAL Y NUMERO DE ETAPAS REALES

Reflujo real
1
Rreal 1.7274694607 RreAL=1.5Rmin
0.9
Pendienre de la recta de rectificación
(L/V) 0.6333597811 0.8
(𝐿⁄𝑉)=𝑅/(𝑅+1)
0.7
RECTA DE RECTIFICACIÓN
x y
0.6
0.92 0.92 Recta. Alim Fobj
0.44999827678 0.6223198114 0.622319811446 1.243785595E-23

Y-BEN
0.5

𝑦=𝑚(𝑥−𝑥_1 )+𝑦_1 0.4

0.3

RECTA DE AGOTAMIENTO
0.2
x y
0.05 0.05 0.1
0.449998276785 0.6223198114
0
0 0.1
Pendiente de la recta de agotamiento
Lt/Vt 1.4308056926
 DES.AVA
CAMPOS SANTOS LUIS ADRIAN
EQ 3

Pebull
°C
80.1 CLAVE LIGERO LK
110.6 CLAVE PESADO HK
EC 3-6 EC 3-7
PAG 101 PAG 105

PAG 784 EC 3-5 EC 3-8

PAG 101 PAG 105

y-BENCENO x-TOLUENO y-TOLUENO k-BENCENO k-TOLUENO VOLATILIDAD

α
1.00689434 -0.01802075859 -0.00689434 0.98907053 0.38257747 2.58528172122
0.96322285 0.08919539121 0.036777146 1.05755158 0.41232114 2.56487353046
0.91603439 0.18914985062 0.083965605 1.12972094 0.4439105 2.54492951367
0.86514362 0.28246400057 0.134856378 1.20571459 0.47742855 2.52543463248
0.81035881 0.36969952982 0.189641188 1.28567064 0.51296032 2.50637447223
0.75148177 0.45136476592 0.248518232 1.36972932 0.55059289 2.48773521074
0.68830776 0.52792027496 0.311692243 1.45803287 0.59041537 2.46950358884
0.62062543 0.59978382094 0.379374567 1.5507255 0.63251884 2.45166688262
0.54821678 0.66733476393 0.451783222 1.64795331 0.67699638 2.43421287734
0.47085704 0.73091796539 0.52914296 1.74986428 0.72394302 2.41712984274
0.38831467 0.79084726032 0.611685327 1.85660811 0.77345571 2.40040650978
0.30035129 0.84740854802 0.699648715 1.96833624 0.8256333 2.38403204871
0.20672159 0.90086254674 0.793278411 2.08520173 0.88057652 2.36799604832
0.10717336 0.95144725179 0.892826645 2.2073592 0.93838796 2.35228849635
0.00144737 0.99938013137 0.998552629 2.33496477 0.99917198 2.33689976096
0.92000002 0.18129249851 0.079999979 1.12372248 0.44127573 2.5465313453
0.11018472 0.94999997725 0.889815275 2.20369349 0.93664768 2.35274536824
0.66844404 0.54999999853 0.331555959 1.4854312 0.60282902 2.4641003568
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X-BEN

1
f(x) = − 0.203476634403753 x⁶ + 0.930942556194623 x⁵ − 1.96252542356448 x⁴ + 2.66760953897442 x³ − 2.76756443635044 x² + 2.335021368297
R² = 0.999999998675012
0.9 f(x) = 0.535239599235756 x + 0.427579568703105
R² = 1

0.8

0.7

0.6
Y-BEN

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

X-BEN
 1

0.9

0.8

0.7

0.6
Y-BEN

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

X-BEN
 DES.AVA MC: CARLOS VALDIVIESO RODRIGUEZ
CAMPOS SANTOS LUIS ADRIAN TORRES OTERO DENISSE
CLASE 33 APUNTE 5/6/2021

N° X1 X2 Y1 Y2
1 0.92 0.8187708504 0.92 0.92
2 0.81877085036 0.6427857726 0.8187708504 0.8187708504
 3 0.64278577256 0.422852431 0.6427857726 0.6427857726
4 0.42285243103 0.2332138254 0.422852431 0.422852431
5 0.23321382539 0.1137751861 0.2332138254 0.2332138254
6 0.11377518609 0.0516395118 0.1137751861 0.1137751861
7 0.05163951177 0.0224587418 0.0516395118 0.0516395118
8
9
10

Nmin 7

0.9 1

2.76756443635044 x² + 2.3350213682978 x + 1.14089841147804E-05

6 x + 0.427579568703105

6 0.7 0.8 0.9 1

 N° x1 x2 y1 y2
1 0.92 0.8187708504 0.92 0.92
2 0.81877085036 0.701779829 0.8558855279 0.8558855279
3 0.70177982898 0.589198482 0.7817881202 0.7817881202
4 0.58919848197 0.4978761341 0.7104836229 0.7104836229
5 0.49787613413 0.4331729632 0.6526437207 0.6526437207
6 0.43317296316 0.3784949295 0.5982460569 0.5982460569
7 0.37849492951 0.3085117655 0.5200124151 0.5200124151
8 0.30851176545 0.2310850192 0.4198801056 0.4198801056
9 0.23108501924 0.1579548702 0.3090974764 0.3090974764
10 0.15795487023 0.0980596876 0.2044624429 0.2044624429
11 0.09805968756 0.0540757297 0.1187640745 0.1187640745
12 0.05407572968 0.0243567304 0.0558315772 0.0558315772
13
14
15
16
17
18
0.7 0.8 0.9 1

Nreal 12
 X3 X4 Y3 Y4 ETAPA EVALUACION
0.8187708504 0.81877085036 0.92 0.81877085 1 CONTINUA
0.6427857726 0.64278577256 0.8187708504 0.642785773 2 CONTINUA
 0.422852431 0.42285243103 0.6427857726 0.422852431 3 CONTINUA
0.2332138254 0.23321382539 0.422852431 0.233213825 4 CONTINUA
0.1137751861 0.11377518609 0.2332138254 0.113775186 5 CONTINUA
0.0516395118 0.05163951177 0.1137751861 0.051639512 6 CONTINUA
0.0224587418 0.0224587418 0.0516395118 0.022458742 7 ULTIMA ETAPA
 x3 x4 y3 y4 ETAPA Cond. Etapa
0.8187708504 0.81877085036 0.92 0.855885528 1 CONTINUA
0.701779829 0.70177982898 0.8558855279 0.78178812 2 CONTINUA
0.589198482 0.58919848197 0.7817881202 0.710483623 3 CONTINUA
0.4978761341 0.49787613413 0.7104836229 0.652643721 4 CONTINUA
0.4331729632 0.43317296316 0.6526437207 0.598246057 5 CONTINUA
0.3784949295 0.37849492951 0.5982460569 0.520012415 6 CONTINUA
0.3085117655 0.30851176545 0.5200124151 0.419880106 7 CONTINUA
0.2310850192 0.23108501924 0.4198801056 0.309097476 8 CONTINUA
0.1579548702 0.15795487023 0.3090974764 0.204462443 9 CONTINUA
0.0980596876 0.09805968756 0.2044624429 0.118764075 10 CONTINUA
0.0540757297 0.05407572968 0.1187640745 0.055831577 11 CONTINUA
0.0243567304 0.02435673043 0.0558315772 0.013309464 12 ULTIMA ETAPA
1.2

1
f(x) = 1.078839500391 x⁶ − 2.345614297246 x⁵ + 2.255973964779 x⁴ − 0.807796180795 x³ + 0.4034644831631 x² + 0.415090596991 x
R² = 0.999999881144301

0.8

0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1
 ZONA
RECTIFICACION
RECTIFICACION
RECTIFICACION
RECTIFICACION
AGOTAMIENTO
AGOTAMIENTO
AGOTAMIENTO
AGOTAMIENTO
AGOTAMIENTO
AGOTAMIENTO
AGOTAMIENTO
AGOTAMIENTO
DATOS
p 14.7 psi
F 700 lb/h
q 0.99999

FRACCIONES MOLARES DE CADA CORRIENTE

COMPOMENTE NO. Zf yd Xb
BENCENO 113 0.45 0.92 0.05
TOLUENO 125 0.55 0.08 0.95

CONSTANTES CRITICAS DE ANTOINE

COMPOMENTE Pc A1 A2 A3
NO. psia
BENCENO 113 714.2 5.658375 5307.813 379.456
TOLUENO 125 587.8 5.944251 5836.287 374.745

CALCULO DE INCREMENTO DE TEMPERATURA

DTT 30.5 °C
N 15
DTT 2.17857142857 °C

T T Ps-BENCENO Ps-TOLUENNO x-BEN

NO °C °F psia psia
1 80.1 176.18 14.539336862 5.62388877893 1.01802076
2 82.2785714286 180.101428571429 15.546008249 6.06112077805 0.91080461
3 84.4571428571 184.022857142857 16.606897847 6.52548440254 0.81085015
4 86.6357142857 187.944285714286 17.724004454 7.0181996502 0.717536
5 88.8142857143 191.865714285714 18.899358477 7.54051666522 0.63030047
6 90.9928571429 195.787142857143 20.135021061 8.09371551056 0.54863523
7 93.1714285714 199.708571428571 21.433083194 8.67910591074 0.47207973
8 95.35 203.63 22.795664785 9.29802696549 0.40021618
9 97.5285714286 207.551428571429 24.22491372 9.95184683533 0.33266524
10 99.7071428571 211.472857142857 25.723004901 10.6419623996 0.26908203
11 101.885714286 215.394285714286 27.292139266 11.369798888 0.20915274
12 104.064285714 219.315714285714 28.934542784 12.136809486 0.15259145
13 106.242857143 223.237142857143 30.652465449 12.9444749162 0.09913745
14 108.421428571 227.158571428571 32.448180249 13.7943029945 0.04855275
15 110.6 231.08 34.323982126 14.6878281642 0.00061987
DOMO 84.2803167761 183.704570196949 16.518720395 6.48675321637 0.8187075
FONDO 108.357425056 227.043365100607 32.394293965 13.7687207288 0.05000003
ALIMENTACION 93.826384045 200.887491281079 21.83584323 8.86158865775 0.44999975

METODO APROXIMADO PARA LA SEPACION POR DESTILACION DE MEZCLAS MULTICOMPONENTES

CALCULO DE LAS ETAPAS MINIMAS CON LA ECUACION DE FENSKE

a DOMO 2.5465313453 VOLATILIDA MEDIA

a FONDO 2.35274537138 2.44772135581826

COMPOMENTE yD xB
BENCENO 0.92 0.05
TOLUENO 0.08 0.95
11.5 19

Nmin 6.01769612202 6

BALANCE GENERAL DE LA COLUMNA

METODO DE LA MATRIZ INVERSA

F=D+B
FxF=DyD+BxB

D B IND
1 1 700
0.92 0.05 315

-0.05747126437 1.14942528736 D 321.83908046 Lbmol/h

1.057471264368 -1.1494252874 B 378.1609195 Lbmol/h

CALCULO DE LA RELACION DE REFLUJO MINIMO

SUPONER UN VALOR DEL FACTOR

0 1.48543118733

CONDICION TERMICA DE ALIMENTACION

q 1 LIQUIDO SATURADO

CON LAS CONDICIONES DE LA ALIMENTACION

COMPONETE a Zf LADO 1 LADO 2
BENCENO 2.46410029542 0.45 1.1330133175
TOLUENO 1 0.55 -1.133013318
0 0 0

CON LAS CONDICIONES DEL DESTILADO

COMPONETE a yD LADO 1
BENCENO 2.5465313453 0.92 2.207905465
TOLUENO 1 0.08 -0.164801937
 2.0431035279

REFLUJO MINIMO
Rmin 1.04310352789

RELACION DEL REFLUJO REAL Y EL NUMERO DE ETAPAS REALES

Rreal 1.56465529183 RreaL=1.5Rmin
X 0.203361351
Y 0.45759966
S 11.90559663
12

Rreal
X 1.56465529183
Y 0.44900931
S 11.889758974 12

CON LAS CONDICIONES DE ALIMENTACION

COMPONETE ALIMENTACION DOMO FONDO S
BENCENO 0.45 0.92 0.05 12
TOLUENO 0.55 0.08 0.95

CALCULADO REDONDEO
NR/NS 0.88773492
NS 6.35682471774 7 ETAPAS RN LA ZONA DE AGOTAMIENTO
NR 5.64317528226 5 ETAPAS EN LA ZONA DE RECTIFICACION
12

ECUACION DE FENSKE

VOLATILIDADES
aD 2.5465313453
aB 2.35274537138
aF 2.46410029542

PARTES DE LA ECUACION DE FENSKE

P1 P2 P3 S
NUMERADOR 2.04444444444 6.875 0.381616659 12
DENOMINADOR 9 1.72727273 0.3988037035

CALCULADO REDONDEO
NR/NS 0.92063322237
NS 6.24793940887 7 ESTAPAS EN LA ZONA DE AGOTAMIENTO
NR/NS 5.75206059113 5 ETAPAS EN LA ZONA DE RECTIFICACION
RESUMEN
CALCULO 1 CALCULO 2 REDONDEO
N min 6.01769612202 6 ETAPAS MINIMAS
Rmin 1.04310352789 REFLUJO MINIMO
Rreal 1.56465529183 REFLUJO REAL
S 11.90559663 11.8897589739711 ETAPAS REALES
Salim 5.64317528226 5.75206059113498 5 ETAPAS DE ALIMENTACION
D 321.83908046 lbmol/h FLUHO MOLAR DEL DESTILADO
B 378.1609195 lbmol/h FLUJO MOLAR DE LOS FONDOS
 DES.AVA MC: CARLOS VALDIVIESO RODRIGUEZ
CAMPOS SANTOS LUIS ADRIAN TORRES OTERO DENISSE
EQ 3 CLASE 33 APUNTE 5/6/2021

Pebull
°C
80.1
110.6

Y-BEN X-TOL Y-TOL K-BEN K-TOL VOLATILIDAD

1.00689434 -0.01802076 -0.00689434 0.98907053 0.38257747 2.585281721222

0.96322285 0.08919539 0.03677715 1.05755158 0.41232114 2.564873530464
0.91603439 0.18914985 0.08396561 1.12972094 0.4439105 2.544929513672
0.86514362 0.282464 0.13485638 1.20571459 0.47742855 2.525434632476
0.81035881 0.36969953 0.18964119 1.28567064 0.51296032 2.506374472229
0.75148177 0.45136477 0.24851823 1.36972932 0.55059289 2.487735210741
0.68830776 0.52792027 0.31169224 1.45803287 0.59041537 2.469503588835
0.62062543 0.59978382 0.37937457 1.5507255 0.63251884 2.451666882621
0.54821678 0.66733476 0.45178322 1.64795331 0.67699638 2.434212877343
0.47085704 0.73091797 0.52914296 1.74986428 0.72394302 2.41712984274
0.38831467 0.79084726 0.61168533 1.85660811 0.77345571 2.400406509782
0.30035129 0.84740855 0.69964871 1.96833624 0.8256333 2.384032048714
0.20672159 0.90086255 0.79327841 2.08520173 0.88057652 2.367996048324
0.10717336 0.95144725 0.89282664 2.2073592 0.93838796 2.352288496352
0.00144737 0.99938013 0.99855263 2.33496477 0.99917198 2.336899760965
0.92000002 0.1812925 0.07999998 1.12372248 0.44127573 2.5465313453
0.11018475 0.94999997 0.88981525 2.20369347 0.93664767 2.35274537138
0.66844381 0.55000025 0.33155619 1.48543151 0.60282916 2.464100295425
 D

B
EL DESTILADO
LOS FONDOS
 DES.AVA MC: CARLOS VALDIVIESO RODRIGUEZ
CAMPOS SANTOS LUIS ADRIAN TORRES OTERO DENISSE
EQ 3 CLASE 33 APUNTE 5/6/2021

DATO
Rmin 1.06166891
Rreal 1.59250337
 DES.AVA MC: CARLOS VALDIVIESO RODRIGUEZ
CAMPOS SANTOS LUIS ADRIAN TORRES OTERO DENISSE
EQ 3 CLASE 33 APUNTE 5/6/2021
 DES.AVA MC: CARLOS VALDIVIESO RODRIGUEZ
CAMPOS SANTOS LUIS ADRIAN TORRES OTERO DENISSE
EQ 3 CLASE 33 APUNTE
ALDIVIESO RODRIGUEZ
TORRES OTERO DENISSE
5/6/2021
 DES.AVA MC: CARLOS VALDIVIESO RODRIGUEZ
CAMPOS SANTOS LUIS ADRIAN TORRES OTERO DENISSE
EQ 3 CLASE 33 APUNTE 5/6/2021
 K
Stage # 1 178.72 F 14.70 psia
Vap lbmol/h Liq lbmol/h Y/X Y X
Benzene 0 637.2868 0 #DIV/0! 0.92000112
Toluene 0 55.41541 0 #DIV/0! 0.07999889
Total lbmol/h 0 692.7022

Stage # 2 182.67 F 14.70 psia

Vap lbmol/h Liq lbmol/h Y/X Y X
Benzene 933.37872 559.47986 1.11917 0.92000108 0.82204086
Toluene 81.16216 121.11879 0.44954 0.0799989 0.17795921
Total lbmol/h 1014.5409 680.5986

Stage # 3 187.86 F 14.70 psia

Vap lbmol/h Liq lbmol/h Y/X Y X
Benzene 855.57178 469.29114 1.21483 0.85349157 0.70255836
Toluene 146.86554 198.68344 0.49256 0.14650845 0.29744161
Total lbmol/h 1002.4373 667.9746

Stage # 4 193.55 F 14.70 psia

Vap lbmol/h Liq lbmol/h Y/X Y X
Benzene 765.38312 383.25186 1.3266 0.77326009 0.58288928
Toluene 224.43018 274.25186 0.5436 0.22673991 0.41711075
Total lbmol/h 989.8133 657.5037

Stage # 5 198.69 F 14.70 psia

Vap lbmol/h Liq lbmol/h Y/X Y X
Benzene 679.34381 654.33942 1.43401 0.69367344 0.48373145
Toluene 299.9986 698.35211 0.59335 0.30632657 0.51626857
Total lbmol/h 979.3424 1352.6915

Stage # 6 201.20 F 14.70 psia

Vap lbmol/h Liq lbmol/h Y/X Y X
Benzene 635.4314 589.82086 1.48896 0.65203863 0.43791407
Toluene 339.09885 757.06635 0.61905 0.34796132 0.56208593
Total lbmol/h 974.5303 1346.8872

Stage # 7 204.80 F 14.70 psia

Vap lbmol/h Liq lbmol/h Y/X Y X
Benzene 570.91284 502.97623 1.57027 0.58934398 0.37531268
Toluene 397.81308 837.17621 0.65738 0.41065593 0.62468727
Total lbmol/h 968.726 1340.1525

Stage # 8 209.43 F 14.70 psia

Vap lbmol/h Liq lbmol/h Y/X Y X
Benzene 484.06821 399.65292 1.67942 0.50319406 0.2996237
Toluene 477.92288 934.19659 0.70934 0.49680593 0.70037631
Total lbmol/h 961.9911 1333.8495

Stage # 9 214.62 F 14.70 psia

Vap lbmol/h Liq lbmol/h Y/X Y X
Benzene 380.74487 292.85492 1.80859 0.39839863 0.22028152
Toluene 574.9433 1036.60266 0.77156 0.60160134 0.77971854
Total lbmol/h 955.6882 1329.4575

Stage # 10 219.68 F 14.70 psia

Vap lbmol/h Liq lbmol/h Y/X Y X
Benzene 273.94684 196.96565 1.94092 0.28797221 0.14836878
Toluene 677.3493 1130.57544 0.83608 0.71202783 0.85163122
Total lbmol/h 951.2961 1327.5411

Stage # 11 223.96 F 14.70 psia

Vap lbmol/h Liq lbmol/h Y/X Y X
Benzene 178.05757 120.96377 2.05828 0.1875515 0.09112033
Toluene 771.32202 1206.5531 0.8939 0.81244849 0.90887972
Total lbmol/h 949.3796 1327.5168

Stage # 12 227.18 F 14.70 psia

Vap lbmol/h Liq lbmol/h Y/X Y X
Benzene 102.05569 18.90807 2.15 0.10749999 0.04999999
Toluene 847.29968 359.25339 0.93947 0.89250008 0.94999991
Total lbmol/h 949.3553 378.1615
 DES.AVA MC: CARLOS VALDIVIESO RODRIGUEZ
CAMPOS SANTOS LUIS ADRIAN TORRES OTERO DENISSE
EQ 3 CLASE 33 APUNTE 5/6/2021
CONDENSADOR
TE TS DT ZONA T
COMPONENTE °F °F °F °C
AGUA 90 140 93.7045702 DOMO 84.2803168
MEZCLA 183.70457 183.7045702 43.7045702 FONDO 108.357425
ALIMENTACION 93.826377
MEDIA LOGARITMICA DE TEMPERATURA
MLDT 65.656634 °F

REHERVIDOR
TE TS
COMPONENTE °F °F
VAPOR 292.7
MEZCLA 227.043365

MEDIA LOGARITMICA DE TEMPERATURA

MLDT 65.6566349 °F

1 2 3 DOMO 5

Rmin Smin Eficiencia T.DES v

°F ft/s
1.1516463071 6 0.7 183.70457019695 2.5
°C m/s
84.280316776083 0.762
K
357.43031677608

1 2 3 4 5

No: R X Y S Sreal

1 1.1574045387 0.002669055 0.85832283 48.408101813601 69.1544312

2 1.16 0.00386745 0.81599272 37.041974094121 52.9171058
3 1.17 0.008457923 0.73093557 25.016073847017 35.7372484
4 1.18 0.013006281 0.69269823 21.778912094962 31.1127316
5 1.19 0.017513102 0.67066486 20.254943913922 28.9356342
6 1.2 0.021978951 0.65593953 19.345260701589 27.6360867
7 1.21 0.026404386 0.64502419 18.719653747947 26.7423625
8 1.22 0.030789952 0.63629213 18.246215550433 26.0660222
9 1.23 0.035136185 0.62890057 17.862869045933 25.5183844
 10 1.24 0.039443613 0.62237838 17.53707411052 25.052963
11 1.25 0.043712752 0.61644683 17.2504032505 24.6434332
12 1.26 0.047944112 0.61093356 16.991785551595 24.2739794
13 1.27 0.052138191 0.60572808 16.754244454253 23.9346349
14 1.28 0.056295479 0.60075746 16.533201920662 23.6188599
15 1.29 0.06041646 0.59597229 16.325544446801 23.3222064
16 1.3 0.064501606 0.59133834 16.129084210148 23.0415489
17 1.4 0.103480705 0.55015298 14.560845609589 20.801208
18 1.5 0.139341477 0.51510652 13.436160282774 19.1945147
19 1.6 0.172443728 0.48461629 12.582113436617 17.9744478
20 1.7 0.20309396 0.45782762 11.911022950469 17.0157471
21 1.8 0.23155489 0.43408894 11.369434797129 16.2420497
22 1.9 0.258052998 0.41288811 10.922769885525 15.603957
23 2 0.282784564 0.39382032 10.54773117359 15.0681874
24 2.1 0.305920546 0.37656313 10.228081604574 14.6115451
25 2.2 0.327610529 0.36085722 9.9521693591675 14.2173848
26 2.3 0.347985968 0.34649179 9.7114185849056 13.8734551
27 2.4 0.367162851 0.33329375 9.4993766245177 13.570538
28 2.5 0.385243912 0.32111955 9.3110937510599 13.3015625
29 2.6 0.40232047 0.30984901 9.1427080966668 13.0610116
30 2.7 0.418473971 0.29938072 8.9911609640945 12.8445157
31 2.8 0.433777288 0.28962838 8.8539972046203 12.6485674
32 2.9 0.448295819 0.28051804 8.7292224389882 12.4703178
33 3 0.462088423 0.27198595 8.6151990927778 12.3074273
33 1.2043154108 0.023893633 0.65088271 19.050567983046 27.2150971

3000
COSTO DEL PLATO
f(x) =2500
8.99002153288E-14 x³ + 35.999999999
D D Costo R² = 1
pulg Ft Dol/plato 2000
60 5 1200
Costo en dol

70 5.8333333333 1500 1500

80 6.6666666667 1850
90 7.5 2250 1000

100 8.3333333333 2700

500

0
4.5 5 5.5 6

16000

14000 f(x) = 3.41541274758787E-21

R² = 1
12000

10000
DOL

8000
 16000

14000 f(x) = 3.41541274758787E-21

COSTO DEL CONDENSADOR R² = 1
12000
AREA COSTO
FT2 DOLARES 10000

COSTO DOL
800 9750
8000
1000 11250
1200 12600 6000

1400 13800 4000

1600 14850
2000

0
700 800 900 1000 1100
A

35000
COSTO DEL HERVIDOR
1000 17250 30000
f(x) = − 1.953125E-07 x³ − 0.000284598214286 x
1400 21150 R² = 0.999973108962484
25000
1800 24600
2200 27750 20000

COSTO
2600 30300
15000

10000

5000

0
800 1000 1200 1400 1600
ARE
 DES.AVA MC: CARLOS VALDIVIESO RODRIGUEZ
CAMPOS SANTOS LUIS ADRIAN
TS EQ 3 CLASE 33 APUNTE
°F
183.70457
227.043365
200.88748

9 10
6 7 8 λ CONDENSADOR 11

CALOR
LATENTE DE
P FC-EQ INST FC-FIJO-ANUAL LA MEZCLA U DT
atm Btu/lbmol btu/h*ft^2*°F °F
1 0.6 0.15 13700 100 50

FLUJO MOLAR DEL DESTILADO

D 321.83908045977 lbmol/h 145.98375126437 Kmol/h
Ccolum=Sreal*Cstplato

6 7 8 9 10 11

D(R+1) D(R+1) Dc Dc Cst-PLATO Cst-Columna

Kmol/h Lbmol/h m ft Dol
314.946008 694.337093 2.061271666512 6.76262008 $ 1,893.51 $ 130,944.64
315.324903 695.172414 2.06251119826 6.76668674 $ 1,895.37 $ 100,297.45
316.78474 698.390805 2.0672800166449 6.78233228 $ 1,902.53 $ 67,991.23
318.244578 701.609195 2.07203785957 6.79794181 $ 1,909.69 $ 59,415.80
319.704415 704.827586 2.076784802469 6.81351558 $ 1,916.86 $ 55,465.51
321.164253 708.045977 2.081520919914 6.82905383 $ 1,924.02 $ 53,172.48
322.62409 711.264368 2.086246285631 6.84455681 $ 1,931.19 $ 51,644.58
324.083928 714.482759 2.090960972516 6.86002476 $ 1,938.36 $ 50,525.26
325.543765 717.701149 2.09566505264 6.8754579 $ 1,945.53 $ 49,646.67
 327.003603 720.91954 2.100358597271 6.89085649 $ 1,952.69 $ 48,920.79
328.46344 724.137931 2.10504167688 6.90622073 $ 1,959.87 $ 48,297.81
329.923278 727.356322 2.109714361158 6.92155088 $ 1,967.04 $ 47,747.81
331.383115 730.574713 2.114376719023 6.93684714 $ 1,974.21 $ 47,251.97
332.842953 733.793103 2.119028818639 6.95210975 $ 1,981.38 $ 46,798.00
334.30279 737.011494 2.123670727418 6.96733892 $ 1,988.56 $ 46,377.54
335.762628 740.229885 2.128302512043 6.98253488 $ 1,995.73 $ 45,984.77
350.361003 772.413793 2.174077695368 7.1327141 $ 2,067.54 $ 43,007.34
364.959378 804.597701 2.218908756174 7.27979585 $ 2,139.44 $ 41,065.54
379.557753 836.781609 2.262851809322 7.42396422 $ 2,211.43 $ 39,749.23
394.156128 868.965517 2.305957621832 7.56538577 $ 2,283.50 $ 38,855.47
408.754504 901.149425 2.348272300312 7.70421176 $ 2,355.65 $ 38,260.57
423.352879 933.333333 2.389837868798 7.84058008 $ 2,427.87 $ 37,884.40
437.951254 965.517241 2.430692757604 7.9746168 $ 2,500.16 $ 37,672.94
452.549629 997.701149 2.470872219399 8.10643758 $ 2,572.52 $ 37,588.53
467.148004 1029.88506 2.51040868532 8.23614881 $ 2,644.94 $ 37,604.20
481.746379 1062.06897 2.5493320713585 8.36384866 $ 2,717.43 $ 37,700.11
496.344754 1094.25287 2.58767004326 8.48962788 $ 2,789.97 $ 37,861.36
510.943129 1126.43678 2.625448246589 8.61357061 $ 2,862.56 $ 38,076.55
525.541505 1158.62069 2.662690507409 8.73575502 $ 2,935.21 $ 38,336.82
540.13988 1190.8046 2.699419008041 8.85625388 $ 3,007.91 $ 38,635.13
554.738255 1222.98851 2.735654441574 8.97513509 $ 3,080.66 $ 38,965.88
569.33663 1255.17241 2.771416148187 9.0924621 $ 3,153.45 $ 39,324.52
583.935005 1287.35632 2.80672223584 9.20829431 $ 3,226.29 $ 39,707.30
321.794233 709.434845 2.083561423845 6.83574832 $ 1,927.12 $ 52,446.65

000

8.99002153288E-14 x³ + 35.999999999998 x² − 29.999999999986 x + 449.999999999967

500
1

000

500

000

500

0
4.5 5 5.5 6 6.5 7 7.5 8 8.5 9
D Ft

000

000 f(x) = 3.41541274758787E-21 x³ − 0.001875 x² + 10.875 x + 2249.99999999999

R² = 1
000

000

000
000

000 f(x) = 3.41541274758787E-21 x³ − 0.001875 x² + 10.875 x + 2249.99999999999

R² = 1
000

000

000

000

000

000

0
700 800 900 1000 1100 1200 1300 1400 1500 1600 1700
AREA FT2

0
.953125E-07 x³ − 0.000284598214286 x² + 11.2042410714285 x + 6532.09821428576
9973108962484
0

0
800 1000 1200 1400 1600 1800 2000 2200 2400 2600 2800
AREA ft2
RLOS VALDIVIESO RODRIGUEZ
TORRES OTERO DENISSE
APUNTE 5/6/2021

14 15 16
12 13 MEZCLA ALIMENTACION REHERVIDOR 17

CP-AGUA COSTO-AGUA CP F U CST-VAPOR

Btu/lbmol°F Btu/lbol°F lbol/h Btu/h*ft^2*°F DOL/Lb
1 5.4E-06 40 700 80 0.00075

FLUJO MOLAR DEL FONDO

D 378.1609195 lbmol/h 171.530907717
=Sreal*Cstplato
Copcolum=Ceq*(1+Iinst)
12 13 14 15 16 17
CONDENSADOR HERVIDOR
Cst-op-año-columna Qcond A CST-COND CST-OP-COND Qherv
Dol/año Btu/h ft2 DOLARES DOL/año Btu/h
$ 31,426.71 9512418.172739 1448.812952 $ 14,070.11 $ 3,376.83 9686858.239
$ 24,071.39 9523862.068966 1450.555944 $ 14,079.58 $ 3,379.10 9698302.136
$ 16,317.89 9567954.022989 1457.271480 $ 14,116.00 $ 3,387.84 9742394.090
$ 14,259.79 9612045.977011 1463.987017 $ 14,152.25 $ 3,396.54 9786486.044
$ 13,311.72 9656137.931034 1470.702554 $ 14,188.33 $ 3,405.20 9830577.998
$ 12,761.40 9700229.885057 1477.418091 $ 14,224.24 $ 3,413.82 9874669.952
$ 12,394.70 9744321.83908 1484.133628 $ 14,259.98 $ 3,422.40 9918761.906
$ 12,126.06 9788413.793103 1490.849164 $ 14,295.55 $ 3,430.93 9962853.860
$ 11,915.20 9832505.747126 1497.564701 $ 14,330.95 $ 3,439.43 10006945.814
$ 11,740.99 9876597.701149 1504.280238 $ 14,366.19 $ 3,447.88 10051037.768
$ 11,591.47 9920689.655172 1510.995775 $ 14,401.25 $ 3,456.30 10095129.722
$ 11,459.47 9964781.609195 1517.711311 $ 14,436.15 $ 3,464.68 10139221.676
$ 11,340.47 10008873.56322 1524.426848 $ 14,470.87 $ 3,473.01 10183313.630
$ 11,231.52 10052965.51724 1531.142385 $ 14,505.43 $ 3,481.30 10227405.584
$ 11,130.61 10097057.47126 1537.857922 $ 14,539.82 $ 3,489.56 10271497.538
$ 11,036.34 10141149.42529 1544.573459 $ 14,574.04 $ 3,497.77 10315589.492
$ 10,321.76 10582068.96552 1611.728826 $ 14,906.92 $ 3,577.66 10756509.032
$ 9,855.73 11022988.50575 1678.884194 $ 15,222.89 $ 3,653.49 11197428.572
$ 9,539.82 11463908.04598 1746.039562 $ 15,521.95 $ 3,725.27 11638348.113
$ 9,325.31 11904827.58621 1813.194930 $ 15,804.10 $ 3,792.98 12079267.653
$ 9,182.54 12345747.12644 1880.350297 $ 16,069.34 $ 3,856.64 12520187.193
$ 9,092.26 12786666.66667 1947.505665 $ 16,317.66 $ 3,916.24 12961106.733
$ 9,041.51 13227586.2069 2014.661033 $ 16,549.08 $ 3,971.78 13402026.274
$ 9,021.25 13668505.74713 2081.816401 $ 16,763.58 $ 4,023.26 13842945.814
$ 9,025.01 14109425.28736 2148.971768 $ 16,961.17 $ 4,070.68 14283865.354
$ 9,048.03 14550344.82759 2216.127136 $ 17,141.85 $ 4,114.04 14724784.894
$ 9,086.73 14991264.36782 2283.282504 $ 17,305.61 $ 4,153.35 15165704.435
$ 9,138.37 15432183.90805 2350.437872 $ 17,452.47 $ 4,188.59 15606623.975
$ 9,200.84 15873103.44828 2417.593239 $ 17,582.41 $ 4,219.78 16047543.515
$ 9,272.43 16314022.98851 2484.748607 $ 17,695.44 $ 4,246.90 16488463.055
$ 9,351.81 16754942.52874 2551.903975 $ 17,791.55 $ 4,269.97 16929382.595
$ 9,437.88 17195862.06897 2619.059343 $ 17,870.76 $ 4,288.98 17370302.136
$ 9,529.75 17636781.6092 2686.214710 $ 17,933.05 $ 4,303.93 17811221.676
$ 12,587.20 9719257.374705 1480.316121 $ 14,239.68 $ 3,417.52 9893697.441
 18
19

Calor
latente del
vapor T-OP
btu/lbmol h/año
915.5 8500

Kmol/h

18 19 20 21 22 23 24
AGUA DE ENFRIAMIENTO VAPOR
A CST-OP.HERV CST-OP-HERV MASA CST-ANUAL MASA CST-ANUAL
ft2 DOL DOL/Año Lb/h DOL/año Lb/h DOL/año
1844.22686 $ 25,002.19 $ 6,000.53 190248.363 $ 8,732.40 10580.9484 $ 67,453.55
1846.4056 $ 25,019.96 $ 6,004.79 190477.241 $ 8,742.91 10593.4485 $ 67,533.23
1854.80002 $ 25,088.33 $ 6,021.20 191359.08 $ 8,783.38 10641.6101 $ 67,840.26
1863.19444 $ 25,156.50 $ 6,037.56 192240.92 $ 8,823.86 10689.7718 $ 68,147.29
1871.58886 $ 25,224.48 $ 6,053.88 193122.759 $ 8,864.33 10737.9334 $ 68,454.33
1879.98328 $ 25,292.27 $ 6,070.14 194004.598 $ 8,904.81 10786.095 $ 68,761.36
1888.3777 $ 25,359.85 $ 6,086.36 194886.437 $ 8,945.29 10834.2566 $ 69,068.39
1896.77213 $ 25,427.25 $ 6,102.54 195768.276 $ 8,985.76 10882.4182 $ 69,375.42
1905.16655 $ 25,494.44 $ 6,118.67 196650.115 $ 9,026.24 10930.5798 $ 69,682.45
1913.56097 $ 25,561.44 $ 6,134.75 197531.954 $ 9,066.72 10978.7414 $ 69,989.48
1921.95539 $ 25,628.24 $ 6,150.78 198413.793 $ 9,107.19 11026.903 $ 70,296.51
1930.34981 $ 25,694.84 $ 6,166.76 199295.632 $ 9,147.67 11075.0646 $ 70,603.54
1938.74423 $ 25,761.24 $ 6,182.70 200177.471 $ 9,188.15 11123.2262 $ 70,910.57
1947.13865 $ 25,827.45 $ 6,198.59 201059.31 $ 9,228.62 11171.3879 $ 71,217.60
1955.53307 $ 25,893.45 $ 6,214.43 201941.149 $ 9,269.10 11219.5495 $ 71,524.63
1963.92749 $ 25,959.25 $ 6,230.22 202822.989 $ 9,309.58 11267.7111 $ 71,831.66
2047.8717 $ 26,606.00 $ 6,385.44 211641.379 $ 9,714.34 11749.3272 $ 74,901.96
2131.81591 $ 27,231.83 $ 6,535.64 220459.77 $ 10,119.10 12230.9433 $ 77,972.26
2215.76012 $ 27,836.04 $ 6,680.65 229278.161 $ 10,523.87 12712.5594 $ 81,042.57
2299.70433 $ 28,417.95 $ 6,820.31 238096.552 $ 10,928.63 13194.1755 $ 84,112.87
2383.64854 $ 28,976.86 $ 6,954.45 246914.943 $ 11,333.40 13675.7916 $ 87,183.17
2467.59275 $ 29,512.07 $ 7,082.90 255733.333 $ 11,738.16 14157.4077 $ 90,253.47
2551.53696 $ 30,022.89 $ 7,205.49 264551.724 $ 12,142.92 14639.0238 $ 93,323.78
2635.48117 $ 30,508.64 $ 7,322.07 273370.115 $ 12,547.69 15120.6399 $ 96,394.08
2719.42538 $ 30,968.60 $ 7,432.47 282188.506 $ 12,952.45 15602.256 $ 99,464.38
2803.36959 $ 31,402.11 $ 7,536.51 291006.897 $ 13,357.22 16083.8721 $ 102,534.68
2887.3138 $ 31,808.45 $ 7,634.03 299825.287 $ 13,761.98 16565.4882 $ 105,604.99
2971.25801 $ 32,186.93 $ 7,724.86 308643.678 $ 14,166.74 17047.1043 $ 108,675.29
3055.20222 $ 32,536.87 $ 7,808.85 317462.069 $ 14,571.51 17528.7204 $ 111,745.59
3139.14643 $ 32,857.57 $ 7,885.82 326280.46 $ 14,976.27 18010.3365 $ 114,815.90
3223.09064 $ 33,148.34 $ 7,955.60 335098.851 $ 15,381.04 18491.9526 $ 117,886.20
3307.03485 $ 33,408.48 $ 8,018.04 343917.241 $ 15,785.80 18973.5687 $ 120,956.50
3390.97906 $ 33,637.30 $ 8,072.95 352735.632 $ 16,190.57 19455.1848 $ 124,026.80
1883.60582 $ 25,321.46 $ 6,077.15 194385.147 $ 8,922.28 10806.8787 $ 68,893.85
 25

COSTO TOTAL DE OPERACIÓN

DOL/año
$ 116,990.01
$ 109,731.42
$ 102,350.58
$ 100,665.05
$ 100,089.46
$ 99,911.52
$ 99,917.13
$ 100,020.71
$ 100,181.98
$ 100,379.81
$ 100,602.25
$ 100,842.12 $170,000.00
$ 101,094.90
$ 101,357.63 $160,000.00
$ 101,628.32
$150,000.00

COSTO DE OPERACIÓN DOL/Año

$ 101,905.57
$ 104,901.16 $140,000.00
$ 108,136.23
$130,000.00
$ 111,512.17
$ 114,980.11 $120,000.00
$ 118,510.19
$110,000.00
$ 122,083.03
$ 125,685.48 $100,000.00
$ 129,308.35
$90,000.00
$ 132,944.99
$ 136,590.47 $80,000.00
1 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2
$ 140,241.07
$ 143,893.86 RELACION DE REFLUJO

$ 147,546.56
$ 151,197.32
$ 154,844.62
$ 158,487.20
$ 162,124.01
$ 99,898.00 R COSTO R
1.20431541 0 1
1.20431541 $ 99,898.00 1.20431541
1.8 1.9 2 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3 3.1
ION DE REFLUJO

COSTO
$ 99,898.00
$ 99,898.00
METODO DE MC CABE-THIELE
DATOS
P 14.7
F 700
q 0.99999
psi Presion de alimentacion
lbmol/hr Flujo de la alimentacion
Condicion termica de alimentacion

FRACCIONES MOLARES DE CADA CORRIENTE

Componente No. zF yD
Benceno 113 0.45 0.92
Tolueno 125 0.55 0.08

CONSTANTES CRITICAS DE ANTOINE

Pc A1
Componente No. psia
Benceno 113 714.2 5.658375
Tolueno 125 587.8 5.944251

CONSTANTES DEL POLINOMIO DE CAPACIDADES CALORIFICAS

Componente No. 1 2
Benceno 113 16.39282 4.02E-02
Tolueno 125 21.17722 4.64E-02

CALCULO DE INCREMENTO DE TEMPERATURA

N 15
DTT 30.5 ºC
∆T 2.17857142857143 ºC

T T T
No. ºC ºF R
1 80.1 176.18 635.85
2 82.2785714285714 180.101429 639.771428571429
3 84.4571428571429 184.022857 643.692857142857
4 86.6357142857143 187.944286 647.614285714286
5 88.8142857142857 191.865714 651.535714285714
6 90.9928571428572 195.787143 655.457142857143
7 93.1714285714286 199.708571 659.378571428571
8 95.35 203.63 663.3
9 97.5285714285714 207.551429 667.221428571429
10 99.7071428571429 211.472857 671.142857142857
11 101.885714285714 215.394286 675.064285714286
 12 104.064285714286 219.315714 678.985714285714
13 106.242857142857 223.237143 682.907142857143
14 108.421428571429 227.158571 686.828571428571
15 110.6 231.08 690.75
DOMO 84.2803167760825 183.70457 643.374570196949
FONDO 108.357425055893 227.043365 686.713365100607
ALIMENTACIÓN 93.8263840450441 200.887491 660.557491281079

X-Ben y-ben HL HV
No. btu/lbmol btu/lbmol
1.0180207585914 1.00689433619252 -10283.4931 3509.06066721304
0.91080460878509 0.963222854489876 -10238.4235 3643.5306911168
0.810850149382501 0.916034394561373 -10182.459 3784.13547418818
0.717535999431728 0.865143622450117 -10116.5741 3931.3240367352
0.63030047018384 0.810358811857057 -10041.6398 4085.57177811028
0.548635234076123 0.751481768239441 -9958.43514 4247.38151382157
0.472079725039487 0.68830775654351 -9867.65753 4417.2845296159
0.40021617906301 0.62062543261635 -9769.93212 4595.8416520217
0.332665236074668 0.548216778334871 -9665.81974 4783.64433482755
0.26908203460799 0.470857040483143 -9555.82394 4981.31576095937
0.209152739676193 0.388314673402773 -9440.39727 5189.51195920878
0.152591451984203 0.30035128543458 -9319.94679 5408.92293525482
0.099137453257428 0.206721589163627 -9194.83895 5640.27381641258
0.048552748208422 0.107173355473704 -9065.40388 5884.32600953452
0.000619868629197 0.001447371411496 -8931.93925 6141.8783714833

PUNTO DE LA COMPOSICION DE LA ALIMENTACION

x,y H
0.45 0
0.45 -9838.98148029349

RECTA DE EQUILIBRIO DE LA ALIMENTACION

x,y H
0.45 -9838.98148029349
0.668443812402797 4470.02897049345

PUNTO DE LA COMPOSICION DEL DESTILADO

x,y H
0.92 3772.48383499479
0.92 20948.0425964926

PUNTO DE LA COMPOSICION DEL FONDO

x,y H
0.05 -9069.26534675281
0.05 -36040.7040988349
RECTA DE LA ALIMENTACION
x,y H
0.92 20948.0425964926
0.05 -36040.7040988349

RECTA DE EQUILIBRIO EN EL DOMO

x,y H
0.81870750149209 -10187.3837070828
0.92 3772.48383499479

RECTA DE EQUILIBRIO EN EL FONDO

x,y H
0.110184745451828 5876.96760014366
0.05 -9069.26534675281

33000
31000
29000
27000
25000
23000
21000
19000
17000
15000
13000
11000
9000
7000
5000
3000
1000
-1000 0 0.1

-3000
-5000
-7000
-9000
-11000
-13000
-15000
-17000
-19000
 -7000
-9000
-11000
-13000
-15000
-17000
-19000
-21000
-23000
-25000
-27000
-29000
-31000
-33000
-35000
-37000
-39000
-41000
-43000
-45000
-47000
limentacion R 1.987 Btu/Lbmol
imentacion
rmica de alimentacion

xB
0.05
0.95

A2 A3 Peb
ºC
5307.813 379.456 80.1 Clave Ligero
5836.287 374.745 110.6 Clave Pesado

3 4 5
6.93E-06 -4.11E-08 2.40E-11
9.96E-06 -4.63E-08 2.59E-11

EC- 3-6
Seader PAG. 101
pag.784
EC- 3-5
PAG. 101

Ps-Benceno Ps-Tolueno x-ben y-ben x-tol y-tol

psia psia
14.5393368623544 5.62388878 1.0180207585914 1.00689433619252 -0.01802076 -0.00689434
15.5460082485619 6.06112078 0.9108046087851 0.963222854489876 0.08919539 0.03677715
16.6068978470398 6.5254844 0.8108501493825 0.916034394561373 0.18914985 0.08396561
17.7240044542556 7.01819965 0.7175359994317 0.865143622450117 0.282464 0.13485638
18.8993584771153 7.54051667 0.6303004701838 0.810358811857057 0.36969953 0.18964119
20.135021061347 8.09371551 0.5486352340761 0.751481768239441 0.45136477 0.24851823
21.433083194461 8.67910591 0.4720797250395 0.68830775654351 0.52792027 0.31169224
22.7956647850161 9.29802697 0.400216179063 0.62062543261635 0.59978382 0.37937457
24.2249137199108 9.95184684 0.3326652360747 0.548216778334871 0.66733476 0.45178322
25.7230049014082 10.6419624 0.269082034608 0.470857040483143 0.73091797 0.52914296
27.2921392655824 11.3697989 0.2091527396762 0.388314673402773 0.79084726 0.61168533
28.9345427838607 12.1368095 0.1525914519842 0.30035128543458 0.84740855 0.69964871
30.6524654493043 12.9444749 0.0991374532574 0.206721589163627 0.90086255 0.79327841
32.4481802492528 13.794303 0.0485527482084 0.107173355473704 0.95144725 0.89282664
34.3239821259216 14.6878282 0.0006198686292 0.001447371411496 0.99938013 0.99855263
16.5187203947109 6.48675322 0.8187075014921 0.920000021 0.1812925 0.08
32.3942939645074 13.7687207 0.05000003 0.110184745451828 0.94999997 0.88981525
21.8358432295021 8.86158866 0.4499997521985 0.668443812402797 0.55000025 0.33155619

33000
31000
29000
27000
25000
23000
21000
19000
17000
15000
13000
11000
9000
7000
5000
3000
1000
-1000 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7

-3000
-5000
-7000
-9000
-11000
-13000
-15000
-17000
-19000
-21000
-23000
-25000
-27000
-29000
-31000
-33000
-35000
 -23000
-25000
-27000
-29000
-31000
-33000
-35000
-37000
-39000
-41000
-43000
-45000
-47000

33000
31000
29000
27000
25000
23000
21000
19000
17000
15000
13000
11000
9000
7000
5000
3000
1000
-1000 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

-3000
-5000
-7000
-9000
-11000
-13000
-15000
-17000
-19000
 -7000
-9000
-11000
-13000
-15000
-17000
-19000
-21000
-23000
-25000
-27000
-29000
-31000
-33000
-35000
-37000
-39000
-41000
-43000
-45000
-47000
 DES.AVA MC: CARLOS VALDIVIESO RODRIGUEZ
CAMPOS SANTOS LUIS ADRIAN TORRES OTERO DENISSE
EQ 3 CLASE 33 APUNTE 5/6/2021

1
f(x) = 1.0788395003913 x⁶ − 2.3456142972457 x
R² = 0.999999881144301
0.9

0.8

0.7

0.6

0.5

0.4

0.3
EC.484 PAG176
0.2

0.1

EC- 3-7 0
0 0.1 0.2
PAG. 105
EC.460 PAG167
EC- 3-8
PAG. 105

K-BEN K-TOL VOLATILIDAD HV0-BEN HV0-TOL λ-BEN λ-TOL

ᾳ btu/lbmol btu/lbmol
0.98907053 0.38257747 2.58528172 3515.56 4458.93 13811.5391811921 15447.52468588
1.05755158 0.41232114 2.56487353 3607.98 4574.71 13787.1287642756 15418.37484011
1.12972094 0.4439105 2.54492951 3700.99 4691.18 13763.0792488775 15389.66109346
1.20571459 0.47742855 2.52543463 3794.61 4808.37 13739.3827168703 15361.37376871
1.28567064 0.51296032 2.50637447 3888.83 4926.26 13716.031479389 15333.50347194
1.36972932 0.55059289 2.48773521 3983.65 5044.86 13693.0180686157 15306.04108225
1.45803287 0.59041537 2.46950359 4079.07 5164.16 13670.3352299127 15278.97774194
1.5507255 0.63251884 2.45166688 4175.08 5284.17 13647.9759142893 15252.30484711
1.64795331 0.67699638 2.43421288 4271.69 5404.87 13625.9332711849 15226.01403867
1.74986428 0.72394302 2.41712984 4368.90 5526.28 13604.200641553 15200.09719371
1.85660811 0.77345571 2.40040651 4466.69 5648.38 13582.7715512317 15174.54641724
 1.96833624 0.8256333 2.38403205 4565.08 5771.18 13561.6397045878 15149.35403427
2.08520173 0.88057652 2.36799605 4664.05 5894.67 13540.7989784199 15124.51258224
2.2073592 0.93838796 2.3522885 4763.62 6018.85 13520.2434161094 15100.01480371
2.33496477 0.99917198 2.33689976 4863.77 6143.73 13499.9672220076 15075.85363941
1.12372248 0.44127573 2.54653135 3693.42 4681.70 13765.0179861977 15391.97564636
2.20369347 0.93664767 2.35274537 4760.68 6015.20 13520.8432999011 15100.72968225
1.48543151 0.60282916 2.4641003 4107.87 5200.17 13663.5795354108 15270.91826755

ESTIMACION DEL REFLUJO MINIMO

RECTA PARA EL REFLUJO MINIMO
x,y H
0.92 20948.04259649
0.81870750149209 -10187.38370708

PNTO VN1
y Hrecta
0.864644429471187 3932.771850084

Distancias
P1'Vn-1 17015.2707465
Vn-1Ln 14120.15555724

Reflujo minimo
(L/D)min Rmin

LOCALIZACION DEL PUNTO P'

0.6 0.7 0.8 0.9 1

REFLUJO MINIMO
(L/D) Rreal

PUNTO PARA CALCULAR LA PENDIENTE DE LA RECT

x,y H
0.81870750149209 -10187.38370708
0.854786093185314 3960.820744886

PENDIENTE
m 392149.5764655

RECTA ENTRE LR Y P'

x,y H
0.81870750149209 -10187.38370708
 0.92 29534.42668192

LOCALIZACION DEL PUNTO P"

*RECTA QUE PASA POR P' Y LA ALIMENTACION

x,y H
0.92 29534.42668192
0.45 -9838.981480293

PENDIENTE
m 83773.20885578

RECTA ENTRE LR Y P' Y P''

x,y H
0.92 29534.42668192
0.05 -43348.26502261

RECTA PARA ACOMPLETAR EL GRAFICO

DESTILADO
x,y H
0.92 3772.483834995
0.92 29534.42668192

FONDO
x,y H
0.05 -9069.2653
0.05 -43348.26502261

ETAPAS MINIMAS 6
ETAPAS REALES 12

RESUMEN
VALOR
N min 6
Rmin 1.20503422767
0.7 0.8 0.9 1 Rreal 1.807551341505
S 12
Salim 5
3913 x⁶ − 2.3456142972457 x⁵ + 2.2559739647785 x⁴ − 0.8077961807947 x³ + 0.4034644831631 x² + 0.4150905969914 x + 4.3807778945E-05
44301

.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

EC.480 PAG176 EC.481 PAG176

HV HL

3509.06066721304 -10283.49314289
3643.5306911168 -10238.42352375
3784.13547418818 -10182.45897039
3931.3240367352 -10116.5741117
4085.57177811028 -10041.63983691
4247.38151382157 -9958.435142171
4417.2845296159 -9867.657525992
4595.8416520217 -9769.932123266
4783.64433482755 -9665.819741213
4981.31576095937 -9555.823938228
5189.51195920878 -9440.397267317
 5408.92293525482 -9319.946789397
5640.27381641258 -9194.838947649
5884.32600953452 -9065.403881978
6141.8783714833 -8931.939252287
3772.48383499479 -10187.38370708
5876.96760014366 -9069.265346753
4470.02897049345 -9838.981480293

7000

Punto del destilado P1' 6000

f(x) = − 234.171285608 x⁶ + 484.420040122 x⁵ − 481.3779
Equilibrio del domo en la fase liquida LR R² = 0.999999999313913

5000
Hveq fob
3932.7718500883 1.458799205E-17 vn1
4000

3000

2000

Razon
r 1000

P1'Vn-1/Vn-1Ln 1.20503422767 0.8298519469723

0
0 0.2 0.4

Razon
r
P1'Vn/VnLn 1.807551341505 0.5532346313149

PENDIENTE DE LA RECTA QUE LLEGA A P'

LR
Vn

LR
 P' y=m(x-x1)+y1

Y LA ALIMENTACION

P'
ALIMENTACION

P' y=m(x-x1)+y1
P''

EL GRAFICO

EQUILIBRIO DEL DESTILADO

P'

EQUILIBRIO FONDOS
P''
484.420040122 x⁵ − 481.377909833 x⁴ + 136.032630546 x³ − 92.9708054449 x² − 2426.71399599 x + 6145.38581634

0.4 0.6 0.8 1 1.2

Pag. 419