Gas Ideal

Pv = nRT

Pv = (w/M)RT

M = wRT/(Pv)

Con v = volumen del Erlenmeyer

P = 0,851 bar*(1 atm/1,013 bar) = 0,84 atm ; T = la del termómetro; w = masa
del condensado

M_acetato_etilo = 95,6 g/mol = Mexp

Masa molar: 88.11 g/mol = Mteo

%Erel = 100*(Mteo – Mexp)/Mteo

Van der Waals

Sustancia: Etanol

(1) Calculemos a y b
Tc = 514 K, Pc = 63 bar*(1 atm/1,013 bar) = 62,1 atm.
2
L
a=
[
27∗ 0,082 atm
molK
∗514 K
=
]
atm2 L2 atm L2
=
64∗62,1atm mol 2 atm mol2
 atm L2
a=12,1
mol2
L
0,082atm ∗514 K
molK L
b= =0,085
8∗62,1 atm mol

(2) Despejamos Vm

12,1
( 0,84 +
)
V 2m
( V m −0,085 ) =0,082∗349,1 5

12,1
( 0,84 +
)(
V 2m
V m −0,085 ) =28,6

12,1
( 0,84 +
)(
V 2m
V m −0,085 ) −28,6=0

www.wolfram.com à plot (0.84+ (12.1 )/(x^2 ))(x-0.085)-28.6, x from 33 to 34

Resolviendo encontramos:
L
V m =34,4
mol

(3) Hallamos M

V erlenmeyer L
moles EtOH = =0,125 L/34,4
Vm mol

moles EtOH =3,6 x 10−3

masa EtOH 0,339 g
M EtOH = =
moles EtOH 3,6 x 10−3 moles
M EtOH =94,1 g/mol