6.

- Determinar temperatura de burbuja y roció para un gas compuesto de 30% propano,

50% isobutano, 20% n-butano a 100 psia (lb/ft2).
componente xi A B C
C3 H8 0.30 6.80398 803.81 246.99
iC 4 H 10 0.50 6.91048 946.35 246.68
nC 4 H 10 0.20 6.80896 935.86 238.73

B
T= −C
A−log P
803.81
Teb propano= −246.99=13.11214378
6.80398−log P
946.35
Tebisobutano= −246.68=49.34458631
6.91048−log P
935.86
Teb n−butano= −238.73=63.61453761
6.80896−log P
Tsup=∑ xi(Teb)

Tsup=0.30 ( 13.1121 )+ 0.50 ( 49.3445 ) +0.20 ( 63.6145 )=41.3287

B
log P= A− 1.−Tsup=41.3287 ℃
C+T
803.81
propano log P=6.80398− = 4.016058
246.99+41.3287
P=10376.67374
Ki=2.006508497
946.35
isobutano log P=6.91048− = 3.62464176
246.68+ 41.3287
P=4213.487987
Ki=0.814750481
935.86
n−butano log P=6.80896− = 3.467303412
238.73+41.3287
P=2932.941573
Ki=0.567134742

∑ Kixi=1.0
∑ Kixi=2.0065 ( 0.30 )+ 0.8147 ( 0.50 ) +0.5671 ( 0.20 )=1.12272
 B
log P= A− 2.−Tsup =38 ℃
C+T
803.81
propano log P=6.80398− = 3.983495071
246.99+38
P=9627.09086
Ki=1.861563743
946.35
isobutano log P=6.91048− = 3.586221183
246.68+ 38
P=3856.74729
Ki=0.74576848
935.86
n−butano log P=6.80896− = 3.427107653
238.73+38
P=2673.669076
Ki=0.516999941

∑ Kixi=1.0
∑ Kixi=1.8615 ( 0.30 )+ 0.7457 ( 0.50 ) +0.5169 ( 0.20 )=1.03468
Interpolación
Xi T ℃
1.12272−−−−41.3287
1.03468−−−−−38
1.0−−−−−−−x
= 36.6887
B
log P= A− 3.−Tsup=36.68℃
C+T
803.81
propano log P=6.80398− = 3.970370524
246.99+36.68
P=9340.508591
Ki=1.806148128
946.35
isobutano log P=6.91048− = 3.570735501
246.68+ 36.68
 P=3721.649808
Ki=0.719645
935.86
n−butano log P=6.80896− = 3.410898927
238.73+36.68
P=2575.721644
Ki=0.498060119

∑ Kixi=1.0
∑ Kixi=1.8061 ( 0.30 )+ 0.7196 ( 0.50 )+ 0.4980 ( 0.20 )=1.00123
PUNTO DE ROCIO
B
log P= A− 1.−Tsup=40 ℃
C+T
803.81
propano log P=6.80398− = 4.003150703
246.99+40
P=10072.81141
Ki=1.94775
946.35
isobutano log P=6.91048− = 3.609412608
246.68+ 40
P=4068.2966
Ki=0.786675181
935.86
n−butano log P=6.80896− = 3.451373805
238.73+40
P=2827.312449
Ki=0.546709
yi
∑ xi = ki
0.30 0.50 0.20
∑ Kixi= 1.94778 + 0.78667 + 0.5467 =1.1555

B
log P= A− 2.−Tsup=45 ℃
C+T
803.81
propano log P=6.80398− = 4.051111751
246.99+45
 P=11248.9439
Ki=2.175176
946.35
isobutano log P=6.91048− = 3.665999748
246.68+ 45
P=4634.466508
Ki=0.896153878
935.86
n−butano log P=6.80896− = 3.51054249
238.73+45
P=3239.981201
Ki=0.626506139
yi
∑ xi = ki =1.0 =
0.30 0.50 0.20
∑ Kixi= 2.1751 + 0.8961 + 0.6265 =1.0151
Interpolación
Xi T ℃
1.1555−−−−40
1.0151−−−−45
1.0−−−−−−x
= 45.5377
B
log P= A− 3.−Tsup=45.5377 ℃
C+T
803.81
propano log P=6.80398− = 4.056099513
246.99+45.5377
P=11378.87989
Ki=2.200302308
946.35
isobutano log P=6.91048− = 3.671884469
246.68+ 45.5377
P=4697.691244
Ki=0.90837947
 935.86
n−butano log P=6.80896− = 3.516692358
238.73+45.5377
P=3286.187639
Ki=0.63544095
yi
∑ xi = ki
0.30 0.50 0.20
∑ Kixi= 2.2003 + 0.9083 + 0.6354 =1.00153

10.- Se tiene una mezcla ideal con la siguiente composición 20% mol de n-hexano, 50%
mol de benceno y 30% mol de tolueno;
Determinar:
a) La presión del punto de roció de la mezcla a 150 °F.
b) La presión del punto de burbuja si la mezcla está a 150 °F.
c) La temperatura del punto de roció de la mezcla a 85 psia.
componente xi A B C
n-Hexano 0.2 6.86572 1152.971 225.849
Benceno 0.5 6.90565 1211.033 220.79
Tolueno 0.3 6.95464 1344.8 219.482

Conversión de 150 °F a °C = 65.555

B
log P= A−
C+T
1152.971
n−Hexano log P=6.86572− = 2.909045
225.849+65.55
P=811.0459
1211.033
benceno log P=6.90565− = 2.909045
220.79+65.55
P=474.5661785
1344.8
Toluneo log P=6.95464− = 2.2365
219.482+ 65.55
P=172.4142894
 Componente Zi P (Mmhg) Yi/Pi

N-Hexano 0.2 811.0459 2.4659¿ 10−4

Benceno 0.5 474.5661 1.0535¿ 10−3

Tolueno 0.3 172.4142 1.7399¿ 10−3

∑ 3.04008 ¿ 10−3

1 1
P= = = 328.9581 mmHg
PT 3.0399 ¿10−3

Presión que tiene la mezcla en el punto de roció.

Componente Zi P (Mmhg) Yi*Pi

N-Hexano 0.2 811.0459 162.20918

Benceno 0.5 474.5661 237.28305

Tolueno 0.3 172.4142 51.72426

∑ 451.2163

Presión de la mezcla en el punto de burbuja = 451.2163

Conversión de 85 psia a mmhg = 4,395.7614
B
T= −C
A−log P
1152.971
T n−hexano= −225.849=131.9181
6.86572−log P
1211.033
T benceno= −220.79=150.3946
6.90563−log P
1344.8
T tolueno= −219.482=186.6049
6.95464−log P
xi
T ¿∑
Te
 0.20 0.50 0.30 1
T¿ + + = =155.0783237
131.9181 150.3946 186.6046 6.448354458

B
log P= A− 1.- T sup = 155.0783
C+T

1152.971
hexano log P=6.86572− = 3.838971851
225.849+155.0783
P=6901.950678
Ki=1.570137696
1211.033
benceno log P=6.90565− = 3.68368901
220.79+155.0783
P=4827.130166
Ki=1.09813288
1344.8
tolueno log P=6.95464− = 3.364298
219.482+155.0783
P=2313.645783
Ki=0.526335615
yi
∑ xi = ki
0.20 0.50 0.30
∑ Kixi= 1.5701 + 1.09813 + 0.5263 =1.15271702
B
log P= A− 2.- T sup = 150
C+T

1152.971
hexano log P=6.86572− = 3.798075813
225.849+150
P=6281.680061
Ki=1.429031171
1211.033
benceno log P=6.90565− = 3.639561378
220.79+150
P=4360.751897
 Ki=0.992035622
1344.8
log P=6.95464− = 3.314949839
219.482+150
P=2065.1416 19
Ki=0.469802937
yi
∑ xi = ki
0.20 0.50 0.30
∑ Kixi= 1.429031171 + 0.992035622 + 0.469802937 =1.282534731

B
log P= A− 3.−Tsup=160℃
C+T
1152.971
hexano log P=6.86572− = 3.877579562
225.849+160
P=7543.615803
Ki=1.716111298
1211.033
benceno log P=6.90565− = 3.725082188
220.79+160
P=5309.849212
Ki=1.20794755
1344.8
tolueno log P=6.95464− = 3.410861902
219.482+160
P=2575.502065
Ki=0.585905792
yi
∑ xi = ki
0.20 0.50 0.30
∑ Kixi= 1.7161 + 1.2079 + 0.5859 =1.042517647
Interpolación
Xi T ℃
1.1527−−−−155.0783
1.0425−−−−−160
 1.0−−−−−−x
= 161.8981
B
log P= A− 4.−Tsup=161.8981 ℃
C+T
1152.971
hexano log P=6.86572− = 3.89220711
225.849+161.8981
P=7802.020907
Ki=1.77489636
1211.033
benceno log P=6.90565− = 3.7411
220.79+161.8981
P=5509.43247
Ki=1.253351119
1344.8
tolueno log P=6.95464− = 3.4284
219.482+161.8981
P=2682.2485
Ki=0.610189749
yi
∑ xi = ki
0.20 0.50 0.30
∑ Kixi= 1.7748 + 1.2533 + 0.610189 =1.0033