Determinar el punto de Burbuja del siguiente sistema multicomponente

Constantes de Antoine 𝑻_𝒃 110

Benceno Tolueno Etil-benceno Presión (Kpa) 91.1925
A 13.8594 14.0098 14.0045
B 2773.78 3103.01 3279.47
C 220.07 219.79 213.2 𝑃_𝑠𝑎𝑡=𝑒^((𝐴−𝐵/
𝜶_𝒊 (𝑇+𝐶)) )
𝒙_𝒊 Compuesto 𝒌_𝒋 P° 𝜶_𝒊 𝒋
𝒋 𝒙_𝒊 𝑘_𝑗=(𝑃
0.3 Benceno 234.10942748 2.35146098 0.7054382929 _𝑖^°)/𝑃
0.4 Tolueno 1.091747 99.559137846 1 0.4 _𝑇
0.3 Etil-benceno 47.352754921 0.4756244 0.1426873191
∑24_(𝑖=1 1.248125612
𝒌_𝒋 0.80120141 )^𝑛▒ 〖𝜶 0.9159631348 1
𝟐
𝑷_𝒋 /
73.0635596 _𝒊𝒋 𝒙_𝒊 〗
𝑘
T 99.499962 _
𝜶_𝒊 𝑗
𝒙_𝒊 Compuesto 𝒌_𝒋 P° 𝜶_𝒊 𝒋
𝒋 𝒙_𝒊
0.3 Benceno 177.62473373 2.43109882 0.7293296472
0.4 Tolueno 0.80120141 73.063559566 1 0.4
0.3 Etil-benceno 33.680087447 0.4609697 0.1382909113
∑24_(𝑖=1 1.2676205585
𝒌_𝒋 0.7888796 )^𝑛▒ 〖𝜶 1.248125612
𝟑 1
𝑷_𝒋 71.939903 _𝒊𝒋 𝒙_𝒊 〗 /
T 98.9915811 𝑘
_
𝜶_𝒊 𝑗
𝒙_𝒊 Compuesto 𝒌_𝒋 P° 𝜶_𝒊 𝒋 2
𝒋 𝒙_𝒊
0.3 Benceno 175.18510051 2.43515898 0.7305476929
0.4 Tolueno 0.7888796 71.939902987 1 0.4
0.3 Etil-benceno 33.109773672 0.46024212 0.1380726369
∑24_(𝑖=1 1.2686203298
𝒌_𝒋 0.7882579 )^𝑛▒ 〖𝜶 1.2676205585 1
𝟒
𝑷_𝒋 /
71.8832088 _𝒊𝒋 𝒙_𝒊 〗
𝑘
T 98.965764 _
𝜶_𝒊 𝑗
𝒙_𝒊 Compuesto 𝒌_𝒋 P° 𝜶_𝒊 𝒋 3
𝒋 𝒙_𝒊
0.3 Benceno 175.06190048 2.43536569 0.7306097078
0.4 Tolueno 0.7882579 71.883208758 1 0.4
0.3 Etil-benceno 33.081021341 0.46020513 0.1380615386
∑24_(𝑖=1 1.2686712464
𝒌_𝒋 0.78822627 1.2686203298
)^𝑛▒ 〖𝜶 1
𝟓
𝑷_𝒋 /
71.8803238 _𝒊𝒋 𝒙_𝒊 〗
𝑘
T 98.9644498 𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑎 𝑑𝑒 𝑝𝑢𝑛𝑡𝑜 𝑑𝑒 𝑏𝑢𝑟𝑏𝑢𝑗𝑎 _
𝜶_𝒊 𝑗
𝒙_𝒊 𝒌_𝒋 𝜶_𝒊 𝒋 4
𝒋 𝒙_𝒊
 1
/
𝑘
_
𝜶_𝒊 𝑗
𝒙_𝒊 Compuesto 𝒌_𝒋 P° 𝜶_𝒊 𝒋 4
𝒋 𝒙_𝒊
0.3 Benceno 175.05563104 2.43537622 0.7306128649
0.4 Tolueno 0.78822627 71.88032381 1 0.4
0.3 Etil-benceno 33.079558306 0.46020325 0.1380609737
∑24_(𝑖=1 1.2686738386
)^𝑛▒ 〖𝜶 1.2686712464 1
_𝒊𝒋 𝒙_𝒊 〗 /
𝑘
_
𝑗
5
𝑃_𝑠𝑎𝑡=𝑒^((𝐴−𝐵/
(𝑇+𝐶)) )
𝛼_𝑖𝑗=(𝑃_𝑖
^°)/
(𝑃_𝑗^° )

𝑇=𝐵/(𝐴−𝑙𝑛𝑃_𝑠𝑎𝑡 )
−𝐶

𝑘_𝑗=(𝑃_𝑖^°)/𝑃_𝑇 〖 ∴
𝑃〗 _𝑗^°=𝑘_𝑗 𝑃_𝑇
Determinar el punto de Rocío del siguiente sistema multicomponente

Constantes de Antoine 𝑻_𝒃 110

Benceno Tolueno Etil-benceno Presión (Kpa) 101.325
A 13.8594 14.0098 14.0045
B 2773.78 3103.01 3279.47
C 220.07 219.79 213.2 𝑃_𝑠𝑎𝑡=𝑒^((𝐴−𝐵/
(𝑇+𝐶)) )
𝒌_𝒋 𝜶_𝒊 𝒚_𝒊/𝜶
𝒚_𝒊 Compuesto P° _𝒊𝒋
𝒋 𝑘_𝑗=(𝑃
0.25 Benceno 234.10942748 2.35146098 0.1063168824 _𝑖^°)/𝑃
0.45 Tolueno 0.9825723 99.559137846 1 0.45 _𝑇
0.3 Etil-benceno 47.352754921 0.4756244 0.6307498139
∑24_(𝑖=1 1.1870666963
𝒌_𝒋 1.1870667 )^𝑛▒𝒚_𝒊/ 0.9825722955 𝑘
𝟐
𝑷_𝒋 𝜶_𝒊𝒋 _
120.279533
𝑗
T 116.762735

𝒚_𝒊 𝜶_𝒊 𝒚_𝒊/𝜶

Compuesto 𝒌_𝒋 P° _𝒊𝒋
𝒋
0.25 Benceno 277.13688409 2.30410675 0.1085019172
0.45 Tolueno 1.1870667 120.279533 1 0.45
0.3 Etil-benceno 58.299282222 0.48469828 0.6189417524
∑24_(𝑖=1 1.1774436696
𝒌_𝒋 1.17744367 )^𝑛▒𝒚_𝒊/ 1.1870666963 𝑘
𝟑
𝑷_𝒋 𝜶_𝒊𝒋 _
119.30448
T 116.465881 𝑗
2
𝒚_𝒊 𝒌_𝒋 𝜶_𝒊 𝒚_𝒊/𝜶
Compuesto P° _𝒊𝒋
𝒋
0.25 Benceno 275.131087 2.30612536 0.1084069426
0.45 Tolueno 1.17744367 119.30447982 1 0.45
0.3 Etil-benceno 57.779850194 0.48430579 0.6194433496
∑24_(𝑖=1 1.1778502922
𝒌_𝒋 1.17785029 )^𝑛▒𝒚_𝒊/ 1.1774436696
𝟒 𝑘
𝑷_𝒋 119.345681 𝜶_𝒊𝒋 _
T 116.478463 𝑗
3
𝒚_𝒊 𝒌_𝒋 𝜶_𝒊 𝒚_𝒊/𝜶
Compuesto P° _𝒊𝒋
𝒋
0.25 Benceno 275.21587784 2.3060397 0.1084109698
0.45 Tolueno 1.17785029 119.34568086 1 0.45
0.3 Etil-benceno 57.801790731 0.48432243 0.6194220595
∑24_(𝑖=1 1.1778330293
𝒌_𝒋 1.17783303 )^𝑛▒𝒚_𝒊/ 1.1778502922 𝑘
𝟓
𝑷_𝒋 𝜶_𝒊𝒋 _
119.343932
𝑗
T 116.477929 𝑇𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑎 𝑑𝑒 𝑝𝑢𝑛𝑡𝑜 𝑑𝑒 𝑟𝑜𝑐í𝑜
4
𝒚_𝒊 𝒌_𝒋 𝜶_𝒊 𝒚_𝒊/𝜶
𝒋 _𝒊𝒋
𝒚_𝒊 𝒌_𝒋 𝜶_𝒊 𝒚_𝒊/𝜶
Compuesto P° _𝒊𝒋
𝒋
0.25 Benceno 275.21227815 2.30604333 0.1084107988
0.45 Tolueno 1.17783303 119.34393169 1 0.45
0.3 Etil-benceno 57.800859243 0.48432173 0.6194229632
∑24_(𝑖=1 1.177833762
)^𝑛▒𝒚_𝒊/ 1.1778330293 𝑘
𝜶_𝒊𝒋 _
𝑗
5
𝑃_𝑠𝑎𝑡=𝑒^((𝐴−𝐵/
(𝑇+𝐶)) )
𝛼_𝑖𝑗=(𝑃_𝑖
^°)/
(𝑃_𝑗^° )

𝑇=𝐵/(𝐴−𝑙𝑛𝑃_𝑠𝑎𝑡 )
−𝐶

𝑘_𝑗=(𝑃_𝑖^°)/𝑃_𝑇 〖 ∴
𝑃〗 _𝑗^°=𝑘_𝑗 𝑃_𝑇