van laar x1 vs y1

1.2

0.8

0.6
y1

0.4

0.2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1

datos experimental es datos teoricos Column K

 wilson x1 vs y1
1.2

0.8

0.6
y1

0.4

0.2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1

datos experi mentales datos te ori cos Col umn K

 margules x1 vs y1
1.2

0.8

0.6
y1

0.4

0.2

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1

va lore s experimenta les datos teoricos Col umn K

 margules x1,y1-T
100

98

96

94

92

datos experi menta l es

datos experi menta l es y1-t
90
datos te oricos x1-t
T

datos te oricos y1-t

88

86

84

82

80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1,y1
 van laar x1,y1-T
100

98

96

94

92

datos experi menta l es x1-t

datos experi menta l es y1-t
90
datos te oricos x1-t
T

datos te oricos y1-t

88

86

84

82

80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1,y1
 wilson x1,y1-T
100

98

96

94

92

datos experi menta l es x1-t

datos experi menta l es y1-t
90
datos te oricos x1-t
T

datos te oricos y1-t

88

86

84

82

80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x1,y1
 TERMODINAMICA DE LOS PROCESOS QUIMICOS II
SISTEMA EN EQUILIBRIO DE LIQUIDO VAPOR

MARTICORENA BORJA Lizbet Milagros 2014201052A

INGENIERIA QUIMICA AMBIENTAL

PRESION 760
T(°C) x1+x2 1
0.7 x1 x2 Pvp1
varianza 0.6 80.1005 0.0001 0.9999 429.2
varianza 0.05 80.7005 0.05 0.95 437.792227
constantes de antoine 81.3005 0.1 0.9 446.520845
nheptano 81.9005 0.15 0.85 455.387387
A 6.9024 82.5005 0.2 0.8 464.393392
B 1268.115 83.1005 0.25 0.75 473.540409
C 216.9 83.7005 0.3 0.7 482.829995
benceno 84.3005 0.35 0.65 492.263716
A 6.90565 84.9005 0.4 0.6 501.843144
B 1211.033 85.5005 0.45 0.55 511.56986
C 220.79 86.1005 0.5 0.5 521.445455
PARAMETROS DE MARGULES 86.7005 0.55 0.45 531.471526
A12 0.2088 87.3005 0.6 0.4 541.649678
A21 0.0953 87.9005 0.65 0.35 551.981524
PARAMETROS DE VAN LAAR 88.5005 0.7 0.3 562.468687
A12 0.2361 89.1005 0.75 0.25 573.112796
A21 0.1072 89.7005 0.8 0.2 583.915486
PARAMETROS DE WILSON 90.3005 0.85 0.15 594.878404
λ12-λ11 364.63 97.03 0.9 0.1 729.317569
λ21-λ22 73.63 97.73 0.95 0.05 744.567133
VVPLUMEN MOLAR 98.43 0.9999 0.0001 760.065721
benzeno
373.15 98.537
348.15 95.4 T(K) Vm (benzeno) vm(n-heptano) ᴧ12
323.15 92.263 353.2505 96.04001074 250.80327419 0.37664738
n-heptano 353.8505 96.11529874 252.76670219 0.37402514
373.15 163.619 354.4505 96.19058674 254.73013019 0.3714433
348.15 157.961 355.0505 96.26587474 256.69355819 0.36890094
323.15 152.303 355.6505 96.34116274 258.65698619 0.36639716
356.2505 96.41645074 260.62041419 0.36393109
t 348.15 356.8505 96.49173874 262.58384219 0.36150188
r 62.4 357.4505 96.56702674 264.54727019 0.35910871
ᴧ12 0.59389436 358.0505 96.64231474 266.51069819 0.35675078
ᴧ21 1.65017334 358.6505 96.71760274 268.47412619 0.35442733
359.2505 96.79289074 270.43755419 0.3521376
359.8505 96.86817874 272.40098219 0.34988085
360.4505 96.94346674 274.36441019 0.3476564
361.0505 97.01875474 276.32783819 0.34546353
361.6505 97.09404274 278.29126619 0.34330159
362.2505 97.16933074 280.25469419 0.34116993
362.8505 97.24461874 282.21812219 0.33906792
363.4505 97.31990674 284.18155019 0.33699493
370.18 98.1643244 306.2030314 0.3155649
370.88 98.2521604 308.4936974 0.31351134
371.58 98.3399964 310.7843634 0.31148803
 CESOS QUIMICOS II
ILIBRIO DE LIQUIDO VAPOR N-HEPTANO(1) - BENZENO(2) ISOBARICO

Milagros 2014201052A

mmHg
ȣ1 ȣ2
Pvp2 margules van laar wilson margules van laar wilson margules
760.01186 1.61709505 1.72185282 0.53470239 1.00000001 1.00000001 0.99999999 9.132331E-05
774.159117 1.50729627 1.54738107 0.59237484 1.00179158 1.00266698 0.99715654 0.043413328
788.511949 1.4149497 1.4203329 0.64590642 1.00692239 1.00958655 0.98948245 0.083132175
803.072392 1.33738632 1.32566567 0.69493604 1.01504577 1.01952401 0.97807752 0.120203064
817.842495 1.27226037 1.25370625 0.73941335 1.02583143 1.031613 0.9638292 0.155481397
832.824312 1.21766585 1.19814761 0.77941513 1.03895533 1.04523169 0.94745068 0.189675652
848.019906 1.17204153 1.15473212 0.81510477 1.05409074 1.05992554 0.92951334 0.223380318
863.431348 1.13409745 1.12049874 0.84670151 1.07090051 1.07535726 0.91047372 0.257100341
879.060717 1.10275745 1.09333449 0.8744576 1.08903039 1.09127359 0.89069566 0.291269087
894.910101 1.07711389 1.07169735 0.89864169 1.10810362 1.10748259 0.87046829 0.32626125
910.981592 1.05639175 1.05443965 0.91952698 1.12771667 1.12383782 0.85002055 0.36240176
927.277294 1.03991987 1.04069235 0.93738305 1.14743641 1.14022699 0.82953294 0.399971433
943.799316 1.02710774 1.02978719 0.95247031 1.16679887 1.15656385 0.80914694 0.439209927
960.549775 1.01742669 1.02120327 0.96503653 1.1853098 1.17278215 0.78897263 0.480316417
977.530795 1.01039456 1.0145296 0.97531475 1.20244716 1.18883113 0.76909478 0.523448305
994.74451 1.00556321 1.00943832 0.98352228 1.21766585 1.20467213 0.74957783 0.568718232
1012.19306 1.00250835 1.00566536 0.98986035 1.23040475 1.22027603 0.73046981 0.616189634
1029.87858 1.0008215 1.00299609 0.99451432 1.2400962 1.23562121 0.71180558 0.665871093
1245.12592 1.00010362 1.00125472 0.99749898 1.24617777 1.25069201 0.66794812 0.863755037
1269.36738 0.99996057 1.00029618 0.99939912 1.24810644 1.26547753 0.64964729 0.930672218
1293.97138 1 1 1 1.24538502 1.27994193 0.63195648 0.999986466

ᴧ21 datos experimentales

2.60273721 benceno(1)+n-heptano(2) n-heptano(1)+benceno(2)
2.62107303 x1 y1 x1 y1 t(°c)
2.63938032 0.1 0.188 0.9 0.812 94.5
2.65765916 0.3 0.458 0.7 0.542 89
2.67590961 0.5 0.64 0.5 0.36 85
2.69413173 0.7 0.782 0.3 0.218 82.2
2.71232559 0.9 0.918 0.1 0.082 80.5
2.73049125
2.74862879 x y
2.76673826 0 0
2.78481973 1 1
2.80287327
2.82089893
2.83889678
2.8568669
2.87480933
2.89272414
2.91061141
3.1093633
3.12984236
3.15028504
y1 y2 y1+y2
van laar wilson margules van laar wilson margules van laar wilson
9.723937E-05 3.019661E-05 0.99991561 0.99991562 0.99991559 1.00000693 1.00001285 0.99994579
0.044567856 0.017061651 0.9694326 0.97027973 0.96494728 1.01284593 1.01484759 0.98200893
0.083448453 0.037948774 0.94022803 0.94271572 0.92394324 1.02336021 1.02616418 0.96189201
0.119149623 0.062460218 0.91168677 0.91570901 0.87848289 1.03188984 1.03485864 0.94094311
0.153213921 0.090362809 0.88312477 0.88810205 0.82974787 1.03860617 1.04131597 0.92011068
0.186635299 0.121409395 0.85388216 0.85904049 0.7786776 1.04355781 1.04567579 0.90008699
0.220081303 0.155351461 0.82331968 0.82787707 0.72601588 1.04669999 1.04795837 0.88136734
0.254017508 0.191947567 0.79081828 0.79410942 0.67234935 1.04791862 1.04812693 0.86429692
0.28878022 0.230968711 0.75578198 0.75733874 0.61813861 1.04705106 1.04611896 0.84910732
0.324620563 0.272201449 0.71764371 0.71724151 0.56374339 1.04390496 1.04186207 0.83594484
0.361732082 0.315449451 0.67587443 0.67354971 0.50944281 1.03827619 1.03528179 0.82489226
0.400268544 0.360533973 0.6299951 0.6260368 0.45545155 1.02996653 1.02630534 0.81598552
0.44035571 0.407293606 0.57959157 0.57450746 0.4019328 1.01880149 1.01486317 0.80922641
0.482099303 0.455583574 0.5243318 0.51879009 0.34900871 1.00464822 1.0008894 0.80459228
0.525590515 0.505274746 0.46398518 0.4587312 0.29676862 0.98743349 0.98432171 0.80204336
0.570909887 0.556252505 0.3984429 0.39419111 0.2452758 0.96716113 0.965101 0.8015283
0.618130081 0.608415563 0.32773872 0.32504077 0.19457275 0.94392836 0.94317085 0.80298832
0.667317905 0.661674771 0.25206879 0.25115917 0.14468552 0.91793988 0.91847708 0.8063603
0.864749199 0.861505498 0.20416424 0.20490382 0.10943152 1.06791928 1.06965302 0.97093701
0.930984573 0.930149672 0.10423063 0.10568131 0.0542527 1.03490285 1.03666588 0.98440237
0.999986468 0.999986464 0.00021204 0.00021792 0.0001076 1.0001985 1.00020439 1.00009406