Construcción del Diagrama X-Y ; T vs X-Y y Entalpia vs Concen

Tabla 1: Cálculo de los coeficientes de actividad ƴ1 y ƴ2 usando el metodo de van laar.

X1 (Etanol) X2 (Agua) g1 g2

0 1 5.36 1.00 Constante de Van Laar

0.1 0.9 3.20 1.03 A12
0.2 0.8 2.21 1.09 A21
0.3 0.7 1.70 1.19
0.4 0.6 1.41 1.32
0.5 0.5 1.24 1.47
0.6 0.4 1.13 1.64
0.7 0.3 1.06 1.83
0.8 0.2 1.02 2.04 PM(g/mol)
0.9 0.1 1.01 2.27 Cpliq Cal/(gmol°C)
1 0 1.00 2.52 Treferencia °C
λo vap(cal/gmol)

Tabla 2: Cálculo de las variables de Temperatura (T), P° etanol y P°H20 a la P=667 mmHg

P⁰etanol P⁰agua
T(ºC) Pt(mmHg)
(mmHg) (mmHg)
96.41 1,494.60 667 667 Constantes
83.23 920.87 404 667
79.91 809.77 353 667 Etanol
78.43 763.97 333 667 Agua
77.46 735.14 320 667
76.68 712.63 309 667
76.01 693.75 301 667
75.50 679.66 295 667
75.13 669.59 290 667
74.96 665.00 288 667
75.05 667.43 289 667

Tabla 3: Datos para la construccion del diagrama T vs. X-Y y Y vs. X del equilibrio etanol-agua a P=6

T(ºC) X1 (Etanol) Y1 (Etanol)

96.41 0.00 0.00
83.23 0.10 0.44
79.91 0.20 0.54
78.43 0.30 0.58
77.46 0.40 0.62
76.68 0.50 0.66
76.01 0.60 0.70
 75.50 0.70 0.76
75.13 0.80 0.82
74.96 0.90 0.90
75.05 1.00 1.00

Tabla 3: Datos para la construccion del diagrama T vs. X-Y y Y vs. X del equilibrio etanol-agua a P=6

T(ºC) X1 (Etanol) Y1 (Etanol) PM(g/gmol) Cpliq(Cal/gmol °C) Hliq(cal/g)

96.41 0.00 0.00 18.00 7.9971 42.83
83.23 0.10 0.44 20.81 8.6599 34.64
79.91 0.20 0.54 23.61 9.3226 31.55
78.43 0.30 0.58 26.42 9.9854 29.64
77.46 0.40 0.62 29.23 10.6481 28.22
76.68 0.50 0.66 32.04 11.3109 27.07
76.01 0.60 0.70 34.84 11.9736 26.12
75.50 0.70 0.76 37.65 12.6364 25.34
75.13 0.80 0.82 40.46 13.2991 24.70
74.96 0.90 0.90 43.26 13.9619 24.19
75.05 1.00 1.00 46.07 14.6246 23.82

Etalpía vs. Composición

800.00

600.00
lpía (cal/g)

400.00
 Etalpía vs. Composición
800.00

600.00

Entalpía (cal/g)
400.00

200.00

Figura
0.00 3: Diagrama de Entalpía vs. Composición del s
0.00 0.20 0.40 0.60 0.80 1.00
Composicion Peso Etanol
 y Entalpia vs Concentración del Sistema.

odo de van laar.

Constante de Van Laar Ln ƴ1 = A12*( A21*X2 /(X1*A12+A21*X2))2

1.6798 Ln ƴ2= A21*( X1*A12/(X1*A12 +A21*X2))2
0.9227

Agua Etanol
18 46.07
7.9971 14.6246
0
9717.00 9260.00

la P=667 mmHg

Constantes de Antoine
A B C P[=] mmHg Log (P*)= A – B/(T+C)
8.1122 1592.864 226.184 T[=] °C
8.07131 1730.63 233.426
P= Pºi*X1* ƴ1 + Pº2*X2*

equilibrio etanol-agua a P=667 mmHg

0 0
0.1 0.1 0.1
0.2 0.2
0.3 0.3
0.4 0.4
0.5 0.5
0.6 0.6
0.7 0.7
0.8 0.8
 0.9 0.9
1 1

equilibrio etanol-agua a P=667 mmHg

Hv(cal/g) Hv*(cal/g)
582.67 582.67
422.61 499.45
388.01 439.17
371.06 392.23
357.69 354.42
343.92 323.27
328.24 297.14
309.23 274.94
286.50 255.85
258.82 239.29
224.60 224.82

vs. Composición

HLíq
Hvapor
Equilibrio
vs. Composición

HLíq
Hvapor
Equilibrio

lpía vs. Composición del sistema etanol-agua

0.60 0.80 1.00 1.20
on Peso Etanol
A12+A21*X2))2

12
+A21*X2))2

og (P*)= A – B/(T+C)

P= Pºi*X1* ƴ1 + Pº2*X2* ƴ2
 densidad patron 0.3023 % peso 48.13
densidad sln 10%etanol 0.4795 % peso 10.66
densidad acumulada 0.8381
% etanol 80.4
PMetanol 46
Pmagua 18

%Barrido Reflujo Tproducto (ºC) Tproducto (K) Ttope(ºC) Ttope (K) Tfondo (ºC)
2 30:60 63 336.15 73 346.15 115.7
2 30:60 65 338.15 73 346.15 116.4
2 30:60 67 340.15 73 346.15 117.2
2 30:60 69 342.15 74 347.15 117.4
3 30:60 67 340.15 74 347.15 117.8
3 30:60 70 343.15 74 347.15 118.1
3 30:60 67 340.15 75 348.15 118.1
4 30:60 68 341.15 75 348.15 118.4
5 30:60 69 342.15 75 348.15 118.5
5 30:60 66 339.15 75 348.15 118.9
5 30:60 68 341.15 75 348.15 119
5 30:60 66 339.15 75 348.15 119.2
5 30:60 68 341.15 75 348.15 119.1
5 30:60 66 339.15 75 348.15 119
5 1:1. 66 339.15 74 347.15 119.3
5 1:1. 65 338.15 74 347.15 119.7
5 1:1. 67 340.15 73 346.15 120.5

TpromdF2% 35.5
TpromdF3% 42.6666667
TpromdF4% 47
TpromdF5% 42.3333333
Tfondo (K) Talim (ºC) Talim(K) Qalimentación (ml/min) tiempo (seg)
388.85 30 303.15 27 235
389.55 33 306.15 27 223
390.35 38 311.15 27 219
390.55 41 314.15 27 241
390.95 41 314.15 41 230
391.25 42 315.15 41 275
391.25 45 318.15 41 251
391.55 47 320.15 56 281
391.65 46 319.15 67 283
392.05 44 317.15 67 312
392.15 43 316.15 67 329
392.35 42 315.15 67 311
392.25 42 315.15 67 319
392.15 41 314.15 67 369
392.45 41 314.15 67 346
392.85 41 314.15 67 324
393.65 41 314.15 67 330
ρ dest (g/ml) ρfondo (g/ml) %ρ peso dest %ρ peso fondo Vdestilado (ml) Vfondo (ml)
0.8263 0.9929 85.115 2.34 60 65
0.8289 0.9878 84.08 5.23 60 52
0.831 0.9868 83.24 5.88 60 36
0.8323 0.9833 82.72 8.14 60 20
0.8348 0.9812 81.72 9.5 60 44
0.8357 0.9819 81.36 9.05 60 38
0.8365 0.9872 81.04 5.63 60 90
0.8472 0.9882 76.69 4.98 60 132
0.8421 0.99 78.76 3.86 60 210
0.8427 0.9844 78.53 7.43 60 300
0.8445 0.9855 77.74 6.72 60 400
0.8466 0.9877 76.94 5.3 60 420
0.8461 0.9881 77.14 5.04 60 420
0.8475 0.989 77.69 4.53 60 400
0.847 0.9898 76.77 4.08 60 360
0.8478 0.9806 76.45 3.64 60 340
0.8472 0.9903 76.69 3.8 60 320
Qdest (ml/s) Qfondo (ml/s) Xd peso Xd molar Xd molar acuml ρdest acuml Xb peso
0.2553191489 0.2765957447 0.85115 0.69112406 0.6750987648 0.0234
0.269058296 0.2331838565 0.8408 0.67390995 0.0523
0.2739726027 0.1643835616 0.8324 0.66026229 0.0588
0.2489626556 0.0829875519 0.8272 0.6519546 0.6441135046 0.0814
0.2608695652 0.1913043478 0.8172 0.63627241 0.095
0.2181818182 0.1381818182 0.8136 0.6307194 0.6282715639 0.0905
0.2390438247 0.3585657371 0.8104 0.62582372 0.0563
0.2135231317 0.4697508897 0.7669 0.56282108 0.5774117413 0.0498
0.2120141343 0.74204947 0.7876 0.59200241 0.0386
0.1923076923 0.9615384615 0.7853 0.58869047 0.5830696067 0.0743
0.1823708207 1.2158054711 0.7774 0.57744875 0.0672
0.192926045 1.3504823151 0.7694 0.56627196 0.5676594368 0.053
0.1880877743 1.3166144201 0.7714 0.56904692 0.0504
0.162601626 1.0840108401 0.7769 0.57674415 0.5703336807 0.0453
0.1734104046 1.0404624277 0.7677 0.56392321 0.0408
0.1851851852 1.049382716 0.7645 0.55952671 0.5611738956 0.0364
0.1818181818 0.9696969697 0.7669 0.56282108 0.038
 Xb molar
0.00928883
0.02113815
0.02386278
0.03351265
0.03945547
0.03747757
0.0228122
0.02009613
0.01546777
0.0304511
0.02741713
0.0214305
0.02034592
0.01822872
0.01637181
0.01456621
0.01522165
Ecuaciones de VAN LAAR. 2
� A 21 *X2 � Pi=pºi*X1*g1 Pi= Yi*P
Ln g 1 =A12 * � �
Etanol (1)- Agua (2): (X *A +A
� 1 12 21 2 � *X )
p1o * X1 * g 1
� A12 *X1
2
� Y1 
A12 1.6798 Ln g 2 =A 21 * � � P
A21 0.9227 �(X1 *A12 +A 21 *X2 ) �

antoine Constantes de Antoine

B A B C
ln( P º )  A 
T C Etanol 8.1122 1592.864 226.184
Agua 8.07131 1730.63 233.426

X1 X2 γ1 γ2 Temperatura P°1 P°2 Ptotal

0 1 5.3645 1 96.3947 1493.7978 666.9998 667
0.1 0.9 3.1967 1.02646317 83.2206 920.5370 403.4747 667
0.2 0.8 2.2107 1.09446671 79.8978 809.3814 353.0650 667
0.3 0.7 1.6990 1.19391232 78.4180 763.6093 332.3871 667
0.4 0.6 1.4089 1.3196387 77.4486 734.8111 319.4027 667
0.5 0.5 1.2351 1.46874688 76.6685 712.2997 309.2672 667
0.6 0.4 1.1283 1.63943411 76.0108 693.7705 300.9343 667
0.7 0.3 1.0629 1.83044258 75.4832 679.1992 294.3875 667
0.8 0.2 1.0248 2.04078401 75.1173 669.2446 289.9182 667
0.9 0.1 1.0056 2.26959731 74.9524 664.7984 287.9229 667
1 0 1.0000 2.51607463 75.0342 667.0009 288.9113 667

X1 X2 γ1 γ2 Temperatura P°1 P°2 Ptotal

0 1 5.36448297 1 96.3947 1493.79783 666.999789 667
0.1 0.9 3.19665877 1.02646317 83.2206 920.536993 403.474686 667
0.2 0.8 2.21074237 1.09446671 79.8978 809.381435 353.065036 667
0.3 0.7 1.69899774 1.19391232 78.418 763.609348 332.387085 667
0.4 0.6 1.40887064 1.3196387 77.4486 734.811074 319.402729 667
0.5 0.5 1.23510124 1.46874688 76.6685 712.299708 309.267211 667
0.6 0.4 1.12827028 1.63943411 76.0108 693.770539 300.934276 667
0.7 0.3 1.06289255 1.83044258 75.4832 679.199223 294.38752 667
0.8 0.2 1.0247916 2.04078401 75.1173 669.244649 289.918245 667
0.9 0.1 1.00557351 2.26959731 74.9524 664.798448 287.922903 667
1 0 1 2.51607463 75.0342 667.000927 288.911253 667
 1.2000

1.0000

0.8000
Y1 Y2
0.0000 1.0000
0.4412 0.5588 0.6000
0.5365 0.4635
0.5835 0.4165 0.4000
0.6208 0.3792
0.6595 0.3405 0.2000
0.7041 0.2959
0.7576 0.2424 0.0000
0.8226 0.1774 0 0.2 0.4 0
0.9020 0.0980
1.0000 0.0000
linea auxiliar
x
Y1 Y2 Datos de Equilibrio 0
0 0.99999968 0.1
0.44117581 0.55882566 Temperatura X1 Y1 0.2
0.53653188 0.46346978 96.3947 0 0 0.3
0.58352499 0.41647485 83.2206 0.1 0.44117581 0.4
0.62084183 0.379157 79.8978 0.2 0.53653188 0.5
0.65949195 0.34050619 78.418 0.3 0.58352499 0.6
0.70413255 0.29586921 77.4486 0.4 0.62084183 0.7
0.75763277 0.24236557 76.6685 0.5 0.65949195 0.8
0.82259226 0.17740945 76.0108 0.6 0.70413255 0.9
0.90202899 0.09797137 75.4832 0.7 0.75763277 1
1.00000139 0 75.1173 0.8 0.82259226
74.9524 0.9 0.90202899
75.0342 1 1.00000139
1.2000

1.0000

0.8000

0.6000 EQUILIBRIO L-V

AUXILIAR
0.4000

0.2000

0.0000
0 0.2 0.4 0.6 0.8 1 1.2

linea auxiliar
y Diagrama de equilibrio del sistema T vs X e Y
0
120
0.1
0.2
100
0.3
0.4
80
0.5
0.6
60 T vs X
0.7
T vs Y
0.8
40
0.9
1
20

0
0 0.2 0.4 0.6 0.8 1 1.2
 diagrama del sistema X vs Y

1.2

0.8
T vs X
T vs Y
0.6 Xvs Y
auxiliar
0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2
 Recta de Enriquecimiento

%Barrido Reflujo R m b Xd molar Y

2 30:60 0.5 0.33333333 0.46074938 0.69112406 0.69112406
2 30:60 0.5 0.33333333 0.4492733 0.67390995 0.67390995
2 30:60 0.5 0.33333333 0.44017486 0.66026229 0.66026229
2 30:60 0.5 0.33333333 0.4346364 0.6519546 0.6519546
3 30:60 0.5 0.33333333 0.4241816 0.63627241 0.63627241
3 30:60 0.5 0.33333333 0.4204796 0.6307194 0.6307194
3 30:60 0.5 0.33333333 0.41721582 0.62582372 0.62582372
4 30:60 0.5 0.33333333 0.37521405 0.56282108 0.56282108
5 30:60 0.5 0.33333333 0.39466827 0.59200241 0.59200241
5 30:60 0.5 0.33333333 0.39246031 0.58869047 0.58869047
5 30:60 0.5 0.33333333 0.38496583 0.57744875 0.57744875
5 30:60 0.5 0.33333333 0.37751464 0.56627196 0.56627196
5 30:60 0.5 0.33333333 0.37936461 0.56904692 0.56904692
5 30:60 0.5 0.33333333 0.3844961 0.57674415 0.57674415
5 1:1. 1 0.5 0.28196161 0.56392321 0.56392321
5 1:1. 1 0.5 0.27976336 0.55952671 0.55952671
5 1:1. 1 0.5 0.28141054 0.56282108 0.56282108

Tabla 10: Constantes para el agua y etanol.

Agua Etanol

Tc (K) 647.30 516.20

Tb (K) 373.20 351.50
λo vap(cal/gmol 9717.00 9260.00
T ref (K) 298.00 298.00
CTTE para Cp (líquido) T(K) PM Etanol 46.07 Kg/Kgmol
A 1.83E+01 -2.25E+02 PM Agua 18 Kg/kgmol
B 4.72E-01 4.14E-04
C -1.34E-03 -1.40E-05
CTTE para Cp (gas) T(°C)
A 3.35E+01 -9.94E-01
B 6.88E-03 6.88E-02
C 7.60E-06 -5.00E-05

Densidad %Peso Xd Xdmolar

0.9795 10.66 0.1066 0.04460749
 Agua Etanol
Ttope(ºC) Xd molar Cv λ Cv λ Hv
73 0.6911240628 34.002762 9184.47275 3.76245 203433.663 144063.704
73 0.6739099459 34.002762 9184.47275 3.76245 203433.663 140744.863
73 0.6602622858 34.002762 9184.47275 3.76245 203433.663 138113.626
74 0.6519546028 34.010760 9172.87156 3.8239 202237.346 135744.329
74 0.6362724064 34.010760 9172.87156 3.8239 202237.346 132739.851
74 0.6307194046 34.010760 9172.87156 3.8239 202237.346 131675.977
75 0.6258237232 34.018773 9161.24638 3.88525 201041.03 130002.192
75 0.5628210774 34.018773 9161.24638 3.88525 201041.03 118008.182
75 0.5920024053 34.018773 9161.24638 3.88525 201041.03 123563.522
75 0.5886904663 34.018773 9161.24638 3.88525 201041.03 122933.018
75 0.5774487472 34.018773 9161.24638 3.88525 201041.03 120792.897
75 0.5662719571 34.018773 9161.24638 3.88525 201041.03 118665.137
75 0.5690469165 34.018773 9161.24638 3.88525 201041.03 119193.415
75 0.5767441477 34.018773 9161.24638 3.88525 201041.03 120658.76
74 0.5639232138 34.010760 9172.87156 3.8239 202237.346 118878.807
74 0.5595267138 34.010760 9172.87156 3.8239 202237.346 118036.503
73 0.5628210774 34.002762 9184.47275 3.76245 203433.663 119327.189
y xd prom
0.4897493752 0.087
0.6767789653 0.682517
0.6601748572 0.660
0.6533392166 0.65610844
0.6375149376 0.640
0.6316449049 0.63349591
0.6005491488 0.550
0.5733215183 0.5943224
0.5920016035 0.592
0.5892424561 0.59034644
0.5782991648 0.580
0.5681347554 0.57186035
0.5700312777 0.572
0.5754612758 0.57289553
0.5659616069 0.568
0.5606258388 0.56172496
0.5628210774 0.56282108
 Xb molar Cplagua Cpletanol Hl Tfondo (K) ρ dest (g/ml)
0.0092888269 128.0418 -227.09749 11314.1876 388.85 0.8263
0.0211381457 127.642798 -227.10485 10981.1699 389.55 0.8289
0.0238627755 127.18519 -227.11327 10946.9655 390.35 0.831
0.033512653 127.070521 -227.11538 10644.555 390.55 0.8323
0.0394554684 126.84086 -227.1196 10474.8171 390.95 0.8348
0.0374775687 126.668333 -227.12277 10558.3875 391.25 0.8357
0.0228121989 126.668333 -227.12277 11041.4347 391.25 0.8365
0.0200961314 126.495565 -227.12594 11150.9458 391.55 0.8472
0.0154677732 126.437922 -227.127 11310.6071 391.65 0.8421
0.030451097 126.207083 -227.13123 10840.5244 392.05 0.8427
0.0274171321 126.149307 -227.13229 10947.5538 392.15 0.8445
0.0214304969 126.033673 -227.13441 11159.4129 392.35 0.8466
0.0203459165 126.091503 -227.13335 11188.9435 392.25 0.8461
0.0182287242 126.149307 -227.13229 11252.6868 392.15 0.8475
0.0163718077 125.975816 -227.13547 11334.3645 392.45 0.847
0.0145662149 125.74412 -227.13971 11421.193 392.85 0.8478
0.0152216486 125.279443 -227.1482 11451.8742 393.65 0.8472
ρfondo (g/ml) Pmprom fonfo Pmpromdtope Flumo molar tope flujo molar fondo flujo molar alim
0.9929 18.2607373723 37.3998524436 0.005640937 0.0150394756 0.0206804127
0.9878 18.5933477488 36.9166521801 0.0060412418 0.0123882486 0.0184294903
0.9868 18.6698281087 36.5335623634 0.0062318377 0.0086885481 0.0149203858
0.9833 18.9407001702 36.3003656999 0.0057082515 0.0043082705 0.010016522
0.9812 19.1075149977 35.8601664475 0.006072864 0.0098237697 0.0158966336
0.9819 19.0519953527 35.704293688 0.005106796 0.007121602 0.012228398
0.9872 18.6403384237 35.566871911 0.0056220901 0.0189897891 0.0246118792
0.9882 18.5640984092 33.7983876413 0.0053522316 0.025005676 0.0303579075
0.99 18.434180395 34.6175075165 0.0051574222 0.0398514585 0.0450088807
0.9844 18.8547622929 34.5245413883 0.0046939854 0.050201559 0.0548955444
0.9855 18.7695988975 34.2089863326 0.0045020965 0.0638360094 0.0683381059
0.9877 18.601554048 33.8952538353 0.0048187038 0.071707524 0.0765262278
0.9881 18.5711098751 33.973146946 0.0046843192 0.0700521787 0.074736498
0.989 18.5116802887 34.1892082254 0.0040306543 0.0579140685 0.0619447228
0.9898 18.4595566415 33.8293246111 0.0043417542 0.0557895149 0.0601312692
0.9806 18.4088736528 33.7059148573 0.0046579362 0.0558982972 0.0605562334
0.9903 18.4272716753 33.7983876413 0.0045575063 0.0521124845 0.0566699907
 R:0,5, Barrido 2%

1.2000

1.0000

0.8000
EQUILIBRIO L-V
AUXILIAR
0.6000
ENRIQUECIMIENTO
AGOTAMIENTO
0.4000 ALIMENTACION

0.2000

0.0000
0 0.2 0.4 0.6 0.8 1 1.2

X Y
LOE 0.000 0.44620848
0.6693127243 0.66931272
LOF 0.2643726641 0
0.2856202267 0.54141523
LOA 0.0219506003 0
0.2856202267 0.54141523
 recta aliment
Xf Qdest (ml/s) Qfondo (ml/s) Talim (ºC) Talim(K) Hf q balim
0.18865563 0.25531915 0.2765957447 30 303.15 305.213856 1.08293042 2.27486637
0.22117155 0.2690583 0.2331838565 33 306.15 393.461689 1.08159222 2.710694
0.27598086 0.2739726 0.1643835616 38 311.15 382.272743 1.08307754 3.32196735
0.37168261 0.24896266 0.0829875519 41 314.15 -73.187519 1.08567356 4.33835864
0.24345767 0.26086957 0.1913043478 41 314.15 650.66355 1.08035129 3.02991598
0.26366652 0.21818182 0.1381818182 42 315.15 567.552905 1.08248872 3.19639495
0.14339008 0.23904382 0.3585657371 45 318.15 1518.76401 1.08004884 1.79128235
0.09973033 0.21352313 0.4697508897 47 320.15 2007.03307 1.0855713 1.16546469
0.06845206 0.21201413 0.74204947 46 319.15 2146.94921 1.08163403 0.83852354
0.05186619 0.19230769 0.9615384615 44 317.15 2049.73464 1.07842443 0.6613525
0.03979237 0.18237082 1.2158054711 43 316.15 2017.64509 1.08129529 0.48947945
0.03719374 0.19292605 1.3504823151 42 315.15 1919.26651 1.08595027 0.43273559
0.03709188 0.18808777 1.3166144201 42 315.15 1920.82537 1.08581236 0.43224409
0.03858361 0.16260163 1.0840108401 41 314.15 1800.29481 1.08639732 0.44658344
0.04163123 0.1734104 1.0404624277 41 314.15 1780.40577 1.08883731 0.46862322
0.04385257 0.18518519 1.049382716 41 314.15 1764.30814 1.09057691 0.48414732
0.04605636 0.18181818 0.9696969697 41 314.15 1744.76655 1.08998451 0.51182539
 R:0,5, Barrido3%

1.2000 1.2000

1.0000 1.0000

0.8000 0.8000
EQUILIBRIO L-V
AUXILIAR 0.6000
0.6000
ENRIQUECIMIENTO
AGOTAMIENTO
0.4000 0.4000
ALIMENTACION

0.2000 0.2000

0.0000 0.0000
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4

X Y
LOE 0 0.42062567 LOE
0.63093851 0.63093851
LOF 0.21683809 0 LOF
0.23802022 0.49996575
LOA 0.03324841 0 LOA
0.23802022 0.49996575
 recta alimentación
malim Xinters Yinters λpromd Calor Cond elim calor pérdido
13.0583008 0.21498018 0.53240943 143434.762 809.10646356 -143523.7
13.25607 0.24452772 0.53078254 140090.934 846.3232043465 -140803.95
13.0369483 0.29614737 0.53889065 137439.887 856.5030768749 -138176.14
12.6722131 0.38682564 0.56357828 135042.145 770.854529171 -135805.82
13.4453505 0.26342992 0.51199158 132014.47 801.705916728 -132793.12
13.1228701 0.2827995 0.5147461 130942.382 668.6960382757 -131722.96
13.4923733 0.16783125 0.47315957 129244.167 726.6223537598 -130026.89
12.6861611 0.12472276 0.4167883 117155.233 627.0419345381 -118006.94
13.2497933 0.09547444 0.42649308 122754.54 633.0969902286 -123525.22
13.751129 0.07853845 0.41863979 122119.045 573.2250132854 -122871.38
13.3008361 0.06743359 0.4074437 119961.987 540.0804425655 -120704.3
12.6346343 0.06586704 0.39947032 117817.387 567.7270937675 -118572.04
12.6533334 0.06587733 0.40132372 118349.845 554.3884576638 -119102.27
12.5744326 0.06789256 0.40712695 119826.788 482.9803562672 -120592.6
12.256532 0.06384407 0.31388364 118046.411 512.528501162 -118820.96
12.0403419 0.0661948 0.31286076 117197.603 545.8989529618 -117982.86
12.1130235 0.06830572 0.3155634 118512.011 540.119235069 -119280.51
 R:0,5, Barrido 4% R:0,5, Barr

1.2000
1.2000

1.0000
1.0000

0.8000 0.8000
EQUILIBRIO L-V
AUXILIAR 0.6000
0.6000
ENRIQUECIMIENTO
AGOTAMIENTO
0.4000 0.4000
ALIMENTACION

0.2000 0.2000

0.0000 0.0000
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4 0.6 0.8

X Y
0 0.37521405 LOE
0.56282108 0.57332152
0.09973033 0 LOF
0.12472276 0.4167883
0.02009613 0 LOA
0.12472276 0.4167883
1.2000

1.0000

0.8000
EQUILIBRIO L-V
AUXILIAR
0.6000
ENRIQUECIMIENTO
AGOTAMIENTO
0.4000 ALIMENTACION

0.2000

0.0000
0 0.2 0.4 0.6 0.8 1 1.2
 R:0,5, Barrido 5% R:1, Barrido 5%

1.2000

1.0000

0.8000
EQUILIBRIO L-V
AUXILIAR
0.6000
ENRIQUECIMIENTO
AGOTAMIENTO
ALIMENTACION 0.4000

0.2000

0.0000
0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4 0.6 0.8 1

X Y X
0 0.38557829 LOE 0
0.57836744 0.57836744 0.56209033
0.04549664 0 LOF 0.04384672
0.0735139 0.41008293 0.06611486
0.02222352 0 LOA 0.01538656
0.0735139 0.41008293 0.06611486
 R:1, Barrido 5%

EQUILIBRIO L-V
AUXILIAR
ENRIQUECIMIENTO
AGOTAMIENTO
ALIMENTACION

0.2 0.4 0.6 0.8 1 1.2

Y
0.28104517
0.56209033
0
0.3141026
0
0.3141026
Vfondo(ml) Vdest (ml) tiempo (s) Qfondo Qdest Pmpromd
64 60 235 0.27234043 0.25531915
52 60 223 0.23318386 0.2690583
36 60 219 0.16438356 0.2739726
20 60 241 0.08298755 0.24896266
44 60 230 0.19130435 0.26086957
38 60 275 0.13818182 0.21818182
90 60 251 0.35856574 0.23904382
132 60 331 0.39879154 0.18126888
210 60 283 0.74204947 0.21201413
300 60 312 0.96153846 0.19230769
400 60 329 1.21580547 0.18237082
20 60 311 0.06430868 0.19292605
420 60 319 1.31661442 0.18808777
400 60 369 1.08401084 0.16260163
350 60 346 1.01156069 0.1734104
340 60 324 1.04938272 0.18518519
320 60 330 0.96969697 0.18181818
parte 1 de la guia

120
1.2
100
1
80
0.8
60 T vs X
T vs Y
0.6
40
0.4
20
0.2
0
0 0.2 0.4 0.6 0.8 1 1.2
0
0 0.2 0.4 0.6

parte 2 de la guía

Entalpía vs. Composición

800.00

600.00
Entalpía (cal/g)

HLíq
400.00 Hvapor
Equilibrio

200.00

0.00
0.00 0.20 0.40 0.60 0.80 1.00 1.20
Composicion Peso Etanol

parte 3 de la guía

alimentación
flujo promedXf promedio barrido reflujo
0.0160117 0.26437266 2% 0.5
0.01757897 0.21683809 3% 0.5
0.03035791 0.09973033 4% 0.5
0.063575 0.04549664 5% 0.5
0.05911916 0.04384672 5% 1

parte 4 de la guía

1.2000
1.2000

1.0000
1.0000

0.8000
EQUILIBRIO L-V 0.8000
AUXILIAR
0.6000
ENRIQUECIMIENTO 0.6000
AGOTAMIENTO
0.4000 ALIMENTACION 0.4000

0.2000
0.2000

0.0000
0.0000
0 0.2 0.4 0.6 0.8 1 1.2
0 0.2 0.4

barrido reflujo nmin

2% 0.5 4
3% 0.5 4
4% 0.5 4
5% 0.5 4
5% 1 4

parte 5 de la guía

Calculo del Calor Eliminado en el condensador

barrido reflujo Calor eliminado cond

2% 0.5 820.6968184881
3% 0.5 732.3414362545
4% 0.5 627.0419345381
5% 0.5 558.583058963
5% 1 532.8488963976

parte 6 de la guía

Potencia del calentador en el rehervidor = 2,5 KW

Q rehervidor 597.514455
parte 8 de la guia

barrido calor perdido

2% -139577.4
3% -131514.32
4% -118006.94
5% -120894.64
5% -118694.78

parte 9 de la guía

Coeficiente global de transferencia de masa

Reflujo Barrido (%) Kxa (Kg/s* m^3)
0.5 0.02 0.36876191
0.5 0.03 0.33957968
0.5 0.04 0.26070961
0.5 0.05 0.27467629
1 0.05 0.25912379
1.2

0.8

0.6 Xvs Y
auxiliar
0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2
1.2000 1.2000

1.0000 1.0000

0.8000 0.8000
EQUILIBRIO L-V
AUXILIAR 0.6000
0.6000
ENRIQUECIMIENTO
AGOTAMIENTO
0.4000 0.4000
ALIMENTACION

0.2000 0.2000

0.0000 0.0000
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4 0.6 0.8
 1.2000

1.0000

0.8000
EQUILIBRIO L-V
AUXILIAR 0.6000
ENRIQUECIMIENTO
AGOTAMIENTO
0.4000
ALIMENTACION

0.2000

0.0000
0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4 0.6 0.8 1
 1.2000

1.0000

0.8000
EQUILIBRIO L-V
AUXILIAR
0.6000
ENRIQUECIMIENTO
AGOTAMIENTO
ALIMENTACION 0.4000

0.2000

0.0000
.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4 0.6 0.8 1 1.2
 EQUILIBRIO L-V
AUXILIAR
ENRIQUECIMIENTO
AGOTAMIENTO
ALIMENTACION

0.4 0.6 0.8 1 1.2

 R:0,5, Barrido 2%

1.2000
1.2000

1.0000
1.0000

0.8000
EQUILIBRIO L-V 0.8000
AUXILIAR
0.6000
ENRIQUECIMIENTO 0.6000
AGOTAMIENTO
0.4000 ALIMENTACION 0.4000

0.2000
0.2000

0.0000
0.0000
0 0.2 0.4 0.6 0.8 1 1.2
0 0.2 0.4 0

X Y
LOE 0 0.44620848
0.66931272 0.66931272
LOF 0.26437266 0
0.28562023 0.54141523
LOA 0.0219506 0
0.28562023 0.54141523
 R:0,5, Barrido3% R:0,5, Barrido 4%

1.2000 1.2000

1.0000 1.0000

0.8000 0.8000
EQUILIBRIO L-V
AUXILIAR 0.6000
0.6000
ENRIQUECIMIENTO
AGOTAMIENTO
0.4000 0.4000
ALIMENTACION

0.2000 0.2000

0.0000 0.0000
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4 0.6 0.8 1

X Y
LOE 0 0.42062567 LOE
0.63093851 0.63093851
LOF 0.21683809 0 LOF
0.23802022 0.49996575
LOA 0.03324841 0 LOA
0.23802022 0.49996575
:0,5, Barrido 4% R:0,5, Barrido 5%

1.2000

1.0000

0.8000
EQUILIBRIO L-V
AUXILIAR 0.6000
ENRIQUECIMIENTO
AGOTAMIENTO
0.4000
ALIMENTACION

0.2000

0.0000
0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4 0.6 0.8 1

X Y
0 0.37521405 LOE
0.56282108 0.57332152
0.09973033 0 LOF
0.12472276 0.4167883
0.02009613 0 LOA
0.12472276 0.4167883
 R:1, Barrido 5%

1.2000

1.0000

0.8000
EQUILIBRIO L-V
AUXILIAR
0.6000
ENRIQUECIMIENTO
AGOTAMIENTO
ALIMENTACION 0.4000

0.2000

0.0000
0.4 0.6 0.8 1 1.2 0 0.2 0.4 0.6 0.8 1 1.2

X Y X
0 0.38557829 LOE 0
0.57836744 0.57836744 0.56209033
0.04549664 0 LOF 0.04384672
0.0735139 0.41008293 0.06611486
0.02222352 0 LOA 0.01538656
0.0735139 0.41008293 0.06611486
 EQUILIBRIO L-V
AUXILIAR
ENRIQUECIMIENTO
AGOTAMIENTO
ALIMENTACION

4 0.6 0.8 1 1.2

Y
0.28104517
0.56209033
0
0.3141026
0
0.3141026
Qrehervidor 597.514455
  * D2 Área (m^2) 0.0019635
AT 
4 Z (m) 1.8
V
Q
t

Coeficiente global de transferencia de masa

Caudal Densidad G Etapas Mc Kxa (Kg/s*
Reflujo Barrido (%) promedio prom (Kg/s*m^2) Thiele m^3)
(ml/s) (g/ml)
0.5 2% 0.26182818 0.829625 0.11062857 6 0.36876191
0.5 3% 0.23936507 0.83566667 0.1018739 6 0.33957968
0.5 4% 0.18126888 0.8472 0.07821288 6 0.26070961
0.5 5% 0.19149589 0.84491667 0.08240289 6 0.27467629
1 5% 0.18013792 0.84733333 0.07773714 6 0.25912379