Composición del aire 2010

COMPONENTES % MOLAR Xi XiLnXi

N2 78.084000 0.78084000 -0.193168116
O2 20.946000 0.20946000 -0.327432582
Ar 0.934000 0.00934000 -0.043650014
CO2 0.035000 0.00035000 -0.002785152
Ne 0.001818 0.00001818 -0.000198438
H2 0.000550 0.00000550 -6.66092E-05
CO 0.000010 0.00000010 -1.61181E-06
NO2 0.000030 0.00000030 -4.50585E-06
CH4 0.000179 0.00000179 -2.36876E-05
NH3 0.000300 0.00000300 -3.81507E-05
O3 0.000002 0.00000002 -3.54551E-07
N2O 0.000025 0.00000025 -3.80045E-06

∑ = −0.567373022

Hallando ∆𝐺:
𝑛

∆𝐺 = 𝑛𝑅𝑇 ∑ 𝐿𝑛𝑋𝑖
𝑖=1

𝑐𝑎𝑙
∆𝐺 = 2 (298𝐾)(−0.567373022)
𝑚𝑜𝑙 𝐾
𝑐𝑎𝑙
∆𝐺 = −338.1543211
𝑚𝑜𝑙

Hallando ∆𝑆:
𝑛

∆𝑠 = −𝑛𝑅 ∑ 𝐿𝑛𝑋𝑖
𝑖=1

𝑐𝑎𝑙
∆𝑠1 = −2 (−0.567373022)
𝑚𝑜𝑙 𝐾
𝑐𝑎𝑙
∆𝑠1 = 1.134746044
𝑚𝑜𝑙 𝐾
 Composición del aire 2015
COMPONENTES % MOLAR Xi XiLnXi
N2 78.0300000 0.780300000 -0.193574341
O2 20.9900000 0.209900000 -0.327679939
Ar 0.9400000 0.009400000 -0.043870229
CO2 0.0350000 0.000350000 -0.002785152
Ne 0.0024000 0.000024000 -0.000255299
H2 0.0005000 0.000005000 -6.10304E-05
CO 0.0000100 0.000000100 -1.61181E-06
NO2 0.0000001 0.000000001 -2.07233E-08
CH4 0.0001500 0.000001500 -2.01151E-05
NH3 0.0000001 0.000000001 -2.07233E-08
O3 0.0000020 0.000000020 -3.54551E-07
N2O 0.000025 0.000000250 -3.80045E-06

∑ = −0.568251913

Hallando ∆𝐺:
𝑛

∆𝐺 = 𝑛𝑅𝑇 ∑ 𝐿𝑛𝑋𝑖
𝑖=1

𝑐𝑎𝑙
∆𝐺 = 2 (298𝐾)(−0.568251913)
𝑚𝑜𝑙 𝐾
𝑐𝑎𝑙
∆𝐺 = −338.6781401
𝑚𝑜𝑙

Hallando ∆𝑆:
𝑛

∆𝑠 = −𝑛𝑅 ∑ 𝐿𝑛𝑋𝑖
𝑖=1

𝑐𝑎𝑙
∆𝑠2 = −2 (−0.568251913)
𝑚𝑜𝑙 𝐾
𝑐𝑎𝑙
∆𝑠2 = 1.136503826
𝑚𝑜𝑙 𝐾
 𝑇2
∆𝑠2 − ∆𝑠1 = 𝐶𝑝𝐴𝑖𝑟𝑒 𝐿𝑛
𝑇1
∆𝑆 𝑇
𝐶𝑝𝐴𝑖𝑟𝑒 𝐿𝑛 2
𝑒 = 𝑒 𝑇1
∆𝑺
𝑻𝟐 = 𝒆 𝑪𝒑𝑨𝒊𝒓𝒆
(𝑻𝟏 ) … … … ..(1)

∆𝑆 = ∆𝑠2 − ∆𝑠1 = 1.136503826 − 1.134746044

𝑐𝑎𝑙 1 𝑚𝑜𝑙 𝑎𝑖𝑟𝑒 1000𝑔 1 𝐾𝑐𝑎𝑙

∆𝑆 = 0.001757782 ∗ ∗ ∗
𝑚𝑜𝑙 𝐾 28.9 𝑔 1𝐾𝑔 1000 𝑐𝑎𝑙

𝐾𝑐𝑎𝑙
∆𝑆 = 6.082290657𝑥10−5
𝐾𝑔 °𝐶

𝐾𝑐𝑎𝑙
𝐶𝑝𝐴𝑖𝑟𝑒 = 0.237
𝐾𝑔 °𝐶
Reemplazamos en (1):
∆𝑆
𝑇2 = 𝑒 𝐶𝑝𝐴𝑖𝑟𝑒 ( 𝑇1 )

𝐾𝑐𝑎𝑙
6.082290657𝑥10−5
𝐾𝑔 °𝐶
𝐾𝑐𝑎𝑙
0.237
𝑇2 = 𝑒 𝐾𝑔 °𝐶 ( 298 𝐾)

𝑇2 = 298.076 𝐾
 Xi FRACCION
COMPONENTES % MOLAR LnXi XiLnXi
MOLAR
1 CH4 80.59 0.806 -0.21579561 -0.173909685
2 C2H6 9.8 0.098 -2.32278780 -0.227633204
3 C3H8 3.8 0.038 -3.27016912 -0.124266427
4 C8H8 3.38 0.034 -3.38729448 -0.114490553
5 C4H10 1.7 0.017 -4.07454193 -0.069267213
6 N2 0.55 0.006 -5.20300719 -0.028616540
7 CO2 0.18 0.002 -6.31996861 -0.011375944
100.00 1.000 -24.793564745 -0.749559565

Hallando ∆𝐺
𝑛

∆𝐺 = 𝑛𝑅𝑇 ∑ 𝐿𝑛𝑋𝑖
𝑖=1

𝑐𝑎𝑙
∆𝐺 = 2 (298𝐾)(−0.749559565)
𝑚𝑜𝑙 𝐾
𝑐𝑎𝑙
∆𝐺 = −446.7375
𝑚𝑜𝑙
Hallando ∆𝑆
𝑛

∆𝑆 = −𝑛𝑅 ∑ 𝐿𝑛𝑋𝑖
𝑖=1

𝑐𝑎𝑙
∆𝑆 = −2 (−0.749559565)
𝑚𝑜𝑙 𝐾
𝑐𝑎𝑙
∆𝐺 = 1.499
𝑚𝑜𝑙 𝐾