Datos tension superficial y ngulo de contacto 1950

H.W. Fox & W.A. Zisman (1950). The spreading of liquids on low energy surfaces. I.
520 polytetrafluoroethylene.
H. W. FOX Journal
AND of W.
Colloid Science 5 [6] 514-531.
A. ZISMAN
.
TABLE I
Surface Energy Relations of FOUT Homologous Series of Liquids and
Polytetrajhoroethylene at 20C.
=

hrc Ref. B YLV
Compound c If cpd YLY cos 9 WA WO WA--w, c
YLV

ym?s/cm deg. pes/cm ~rgs/cm.! rgs/cm. W&WCTl&.!

n-Alkanes
Hexadecane @. 27.6 (19) 46 19.2 46.8 55.2 - 8.4 0.85
Tetradecane a 26.7 (19) 44 19.2 45.9 53.4 - 7.5 0.86
Dodecane a 25.4 (22) 42 18.9 44.3 50.8 - 6.5 0.87
Undecane, a 24.7 (22) 39 19.2 43.9 49.4 - 5.5 0.89
Decane a 23.9 (22) 35 19.6 43.5 47.8 - 4.3 0.91
Nonane b 22.9 19.4 42.3 45.8 - 3.5
(22) 32 0.92
Octane a 21.8 (22) 26 19.6 41.4 43.6 - 2.2 0.95
Heptane a 20.3 (22) 21 19.1 37.4 40.6 - 1.2 0.97
Hexane a 18.4 (19) 12 18.0 36.4 36.8 - 0.4 0.99
Pentane a 16.0 32.0 > 0.0
(22) Spread1 >32.0 1.0
Di(n-alkyl)ethers
Octyl B 27.7 (20) 49 18.2 45.9 55.4 - 9.5 0.83
Heptyl f 27.0 (20) 47 18.4 45.4 54.0 - 8.6 0.84
Amy1 a 24.9 (20) 40 19.1 44.0 49.8 - 5.4 0.88
Butyl a 22.8 (20) 31 19.5 42.3 45.6 - 3.3 0.93
Propyl a 20.5 19.4 41.0 - 1.1
(20) 19 39.9 0.97
Isopropyl a 17.8 (20) Spread; >35.6 35.6 > 0.0 1.0
n-Alkylbenzenes
Hexyl d 30.0 (25) 52 18.5 48.5 60.0 -10.5 0.81
Butyl 0 29.2 (25) 49 19.2 48.4 58.4 - 10.0 0.83
Propyl c 29.0 (25) 49 19.0 48.0 58.0 - 10.0 0.83
Ethyl c 29.0 ( (25) 48 19.4 48.4 58.0 - 9.6 0.84
Methyl E 28.5 (24) 43 20.9 49.4 57.0 - 7.6 0.87
Benzene c 28.9 (24) 46 20.1 49.0 57.8 - 8.8 0.85
Linear polymethyl-
siloxanes
Heptadecamer (13) 19.9 (13) 30 17.2 37.1 39.8 - 2.7 0.93
Dodecamer (13) 19.6 (13) 29 17.2 36.8 39.2 - 2.4 0.94
Nonamer (13) 19.2 (13) 26 17.3 36.5 38.4 - 1.9 0.95
Heptamer (13) 18.6 (13) 24 17.0 35.6 37.2 - 1.6 0.96
Hexamer (13) 18.5 (13) 19 17.5 36.0 36.9 - 0.9 0.97
Pentamer (13) 18.1 (13) 15 17.5 35.6 36.2 - 0.6 0.98
Tetramer (13) 17.6 (13) 8 17.4 35.0 35.2 - 0.2 0.99
Trimer (13) 17.0 (13) Spread; - >34.0 34.0 > 0.0 1.0