Table E.10. (continued) ‘Appendix E, Parameters and Correlations on Components A B Press, Temp, 1 2 mmHg °C Eel oan |-Propanol continued) 04508 07564. 15 2Propancl 04638 0.6723. 760 05455 0.7716 $00 1-Botanol Benzene 0.5865 03594 760 Toluene 05430 03881760 Butyl cellosove Ethyleyclohexane 0584 03784 400 r-Octane 06967 03318 400 ‘Carbon tetrachloride ‘Acetone 03301 0.3889 760 Benzene 0.0309 0.0360 760 2-Propanol 04918 0.7868 760 Cellosoive Ethylbenzene 04402 03762760 n-Hexane 0.6629 0.7205. 760 Hexene-t 0.4367 05860760 r-Octane o61s8 0.7507 760 Chloroform Acetone =0.2709 0.3045 760 Benzene 00556-00858 760 2,3-Dimethylbutane 01736 02790760 Ethyl acetate 02868 0.4478 760 Methanol 0.4104 0.8263 760 Methyl scetate 02249-03343 760 MethyLethyl Ketone 0.2990 -0:3486 760, Cyelohesane Benzene 0.1645 0.1466 760 Ethanol 0.7811 1.1031 760 Methyl acetate 05799 05317760 2-Propanol 05322 1.0162 760 06156 L01s8 500 Toluene 00702 0.2578 760 Cyclopentane Benzene 01302 0.1658 760 2,3-Dimethylbutane ‘Acetone 006358 0.6345 760 Chloroform 02790 0.1736 760 Methanol 11276 1.8408 760 L4Dioxane n-Hexane 05260 0.4850 760 Hexene-1 03578 0.3757 760 Ethanol ‘Acetone 02879 0.2574 760 % Benzene 0.7969 08804760 Cyclohexane 1103107811760 Ethyl acetate 0397203311760 ; 0.4833 (O15 40 040930382 | 60 n-Heptane 1.0832 1.0208 760 n-Hexane 12008 08422760 Methanol 0.0088 0.0254 760 Methyleyclopentane 1.2330 0.732760 Toluene 07067 0.8932 756 ‘Water 0.7292 04104760 Ethyl acetate Chlorotorm 0.4478 -0.2868 760 Ethanol 03311 03972760 04151 0.4833, 4o 0.3842 0.4093, 60 Methanol 04470 04227760 04278 0.8741 40 0.5399 0.4476 50 0.4736 0.4768 © 1-Propanol 02051 0.2893 760. 03444 0.3913, 40 02762 03002 60 2-Propanol 02113 0.1964 760 03747 0.4608 40612 Appendix E. Parameters and Correlations Table E.10. (continued) Components A 8 Press, ‘Temp., i 2 mmHg °C Ethyl acetate (continued) 2-Propanol (continued) 03039 0.3261 60 Ethylbeazene Collosolve 03762 0.4402 760 Bithyleyclohexane 0.0821 0.0628 400 Hexylene glycol 03719 0.8383 400 Octane 0.0890 0.0902 760 Ethyleyelohexane Buty! cllosolve Os784 0.5814 400 Bthylbenzene 0.0628 0.0821 400 Hexylene glyeo! 0470 1.1219 400 n-Heeptane Benzene 0.2135 0.0985 760 0.2361 0.1072. 5 Ethanol 1.0208 1.0832 760 -Propanol o7n9 0.7550. 5 n-Hexane Benzene 0.2063 0.1457 760 Collosotve 0.7206 0.6629 760 14-Dioxane 0.4850 0.5260 760 Ethanol 08422 1.2008 760 Hexene-1 00393 © 0114 760 “Methyleyclopentane 0.0023 0.0226 760 1-Propanal 0.8734 0.5982 760 1,2,3-Triehloropropane 04520 0.7257 760 Hexene-1 Collosolve 05860 © 0.4367 760 1,4-Dioxane 0375703578760 n-Hexane 00114 0.0393 760 1,2,3-Trichloropropane 0349 04372760 Hexylene glycol Ethylbenzene 08383 03719400 Ethyleyelohexane 11219 0.470400, Methanol ‘Acetone 02801 02635760 02878 = 02763. 35 Benzene 09975 0.7518 760 Chloroform 0.8263 0.4104 760 2,3-Dimethylbutane 15408 1.1276 760 Ethanol 0.0254 0.0088 760 Ethyl acetate 0.4227 0.4470 760 Os74l 0.4278 40 04876 0.5399 50 04768 0.4736 60 Methy] acetate 0.4394 0.4262 760 2-Propanol 0.0325 -0.0329 760 Water 0.3861 02439760 Methyl acetate Benzene 0.0919 0.1292 760 Chloroform 03343-02249 760 Cyelohexane 05317 0.5799 760 Methanol 0.4262 0.4394 760 ‘Methyleyelohexane Benzene 0.1901 0.0910 760 2-Propanol 0.6886 1.0659 $00 ‘Methyleyclopentane Benzene 0.1605 0.1360 760 Ethanol 0.7332 1.2330 760 n-Hexane 0.0226 0.0023 760 Toluene 0.0717 0.2478. 760 MethyL-ethyl-ketone Chloroform 03486 © -0.2990 760 n-Octane Butyl collosolve 05318 0.6967 400, Cellosolve 0.7507 0.6158 760 Ethylbenzene 0.0902 0.0890 760 2-Propanol 08535 0.8043 400 n-Pentane Acetone 0.6364 0.7403 760 1 -Propanol Benzene 0.7703 0.3772 760 0.7564 0.4808 5Appendix E Parameters and Conelations 613 Table E.10. (continued) Componenti A B Press, Temp, 1 2 mmiig °C T-Propanol (continued) Ethyl acetate 0.2893 0.2081 760 03913 0.3444 40 0.3092 0.2762 60. n-Heptane 07580 0.79 75 n-Hexane 05952 o.R734 760 Water 1.1433 05037760 1231505305 40 11879 0.524 0 2-Propanol Acetone 0269 02186 760 0.2495 03158 55 Benzene 06723 0.4638 760 0.7716 0.5455 $00 Carbon tetrachloride 0.7868 = 0.4918 760 Cyclohexane 1.0162 05322760 10158 0.6156 500 Ethyl acetate 0.1964 = 02113760 0.460¢ 0.3747 40 03261 0.3039 60 Methanol 0.0329 00325 760 ‘Methyleyclohexane 1.0659 0.6886 500 Octane 0.8043 0.8335 400 2,2,4-Trimethylpentane 06603 0.6927 760 Toluene 1-Butanol 0.3841 05430760 Cyclohexane 0.2378 =~ 0.0702 760 Ethanol 06932 0.7067 756 Methyleyclopentane 02475 0o717 760 1,2,3-Trichloropropane n-Hexane 0.7257 0.4520. 760 Hexene-t 0437203419760 2.2,4-Trimethylpentane —_2-Propanol 06927 0.6603 760 Water Acetone 06105 0.9972 760 Acetonitrile 08207 1.0680 760 Ethanol 04104 0.7292 760 Methanol 0.2439 0.3861 760 1-Propanol 05037 1.1433 760 05305 1.2315, 40 05274 11879 60 Rule EL, [UNIFAC Group Volume and Surface-Area Parameters for Prediction of Vapor Liquid Equilibria (Gmebling, Rasmussen, & Fredenshund 1982), Copyright American Chemical Society; used with permission Main Group Subgroup No. Ry Qy Sample Group Assignment 1 CH; 1 0.9011 0.848 hexane: 2 CH, 4 CH, “CH CH; 2 0.6744 0.540 2-methylpropane: 3 CHs, 1 CH 30.4469 0.228 2,2-dimethypropane: 4CH, IC 4 0.2195 0,000 5 13454 1.176 I-hexene: 1.CHs, 3 CH, 1 CH;=CH 6 1.1167 0.867 2-hexene 2.CH3, 2 CH, 1 CH=CH 7 1.1173 0.988 2-methyl-1-butene: 2.CHy, 1 CHy, 1 CH,=C 8 0.8886 0.676 2-mothyi-2-butene: 3 CH, 1. CH=C 0.6605 0.485 2,3-dimethylbutene-2: 4.CHy, 1 C=C 05313 0.400 benzene: 6 ACH 0.3652 0.120 styrene: 1 CHy=CH, $ ACH, 1 AC 1.2663 0,968 toluene: 5 ACH, 1 ACH, 1.0396 0.660 ethylbenzene: 1 CH, $ ACH, 1 ACCH, ACCH 14 08121 0.348 cumene: 2 CH, $ ACH, 1 ACCH 5 OH 15 1.000 1.200 2-propanot 2CHs, 1 CH, 1 OH