UNIVERSIDAD NACIONAL AUTNOMA DE MXICO

FACULTAD DE ESTUDIOS SUPERIORES ZARAGOZA

LABORATRIO DE ANLISIS DE FRMACOS Y MATERIAS PRIMAS I

PRCTICA ?: Valoracin potencio mtrica de un policido (cido ctrico)

ALUMNOS:

PEAFLOR CERN VALERIA MARISELA

PREZ MENDOZA MANUEL ALBERTO

RAMREZ LUIS MARIO

EQUIPO: 2

PROFESORA: ERIKA VZQUEZ

GRUPO: 2453

FECHA DE ENTREGA: JUEVES 31 DE MARZO DEL 2016

Introduccin
Objetivo
Obtener %peso aproximado de una muestra de cido ctrico.

Hiptesis
El cido ctrico al ser un policido posee 3 puntos de equivalencia siendo los
primeros 2 poco cuantificables por lo que al seguir la reaccin de neutralizacin
usando una base fuerte de manera potencio mtrica y usando su primera y segunda
derivada podemos obtener el volumen exacto en el cual se completa la
neutralizacin de los 3 equivalente de cido ctrico

Formulario
()()()
%P=( )

= ()()
= ()()()

= #
(xix)2
2 = i=1 1
= 2

CV = ( ) (100)

%error = (100)

21
1 = ( )=( )
21
21
2 = ( )=d( )
21

Sustitucin del formulario

210.4
(0.095 )(0.017)( )
3
%P= =107.77%
(0.1051 )
1er derivada. 2da derivada

3.573.57
( )= =0 ( )=0-0=0
0.50

3.63.57
( )= =0.06 ( )
10.5
3.653.60
( )= =0.1 ( )
1.51
3.733.65
( )= =0.16
21.5
3.823.73
( )= =0.18
2.52
3.903.82
( )= =0.16
32.5
4.013.90
( )= =0.22
3.53
4.114.01
( )= =0.2
43.5
4.324.21
( )= =0.22
4.54
4.434.32
( )= =0.22
55.5
4.544.43
( )= =0.22
65.5
4.664.54
( )= =0.24
6.56
4.754.66
( )= =0.18
76.5
4.884.75
( )= =0.26
7.57
4.964.88
( )= =0.16
87.5
5.064.96
( )= =0.2
8.58
5.155.06
( )= =0.18
98.5
5.255.15
( )= =0.2
9.59
5.345.25
( )= 109.5
=0.18
 5.445.34
( )= =0.2
10.510
5.555.44
( )= =0.22
1110.5
5.685.55
( )= =0.26
11.511
5.785.68
( )= =0.2
1211.5
5.885.78
( )= =0.2
12.512
5.995.88
( )= =0.22
1312.5
6.216.10
( )= =0.22
1413.5
6.326.21
( )= =0.22
14.514
6.446.32
( )= =0.24
1514.5
6.616.44
( )= =0.34
15.515
6.796.61
( )= =0.36
1615.5
7.106.79
( )= =0.62
16.516
8.907.10
( )= =3.6
1716.5
10.048.90
( )= =2.28
17.517
10.4710.04
( )= =0.86
1817.5
10.6510.47
( )= =0.36
18.518
10.7710.65
( )= =0.24
1918.5
10.8610.77
( )= =0.18
19.519
10.9010.86
( )= =0.08
2019.5
RESULTADOS.

Ph Ph 1er 2da
Volumen derivada derivada
0.5 3.57 0 0.5 0 0.03
1 3.6 0.03 0.5 0.06 0.02
1.5 3.65 0.05 0.5 0.1 0.03
2 3.73 0.08 0.5 0.16 0.01
2.5 3.82 0.09 0.5 0.18 -0.01
3 3.9 0.08 0.5 0.16 0.03
3.5 4.01 0.11 0.5 0.22 -0.01
4 4.11 0.1 0.5 0.2 -8.8818E-
16
4.5 4.21 0.1 0.5 0.2 0.01
5 4.32 0.11 0.5 0.22 -8.8818E-
16
5.5 4.43 0.11 0.5 0.22 8.88178E-
16
6 4.54 0.11 0.5 0.22 0.01
6.5 4.66 0.12 0.5 0.24 -0.03
7 4.75 0.09 0.5 0.18 0.04
7.5 4.88 0.13 0.5 0.26 -0.05
8 4.96 0.08 0.5 0.16 0.02
8.5 5.06 0.1 0.5 0.2 -0.01
9 5.15 0.09 0.5 0.18 0.01
9.5 5.25 0.1 0.5 0.2 -0.01
10 5.34 0.09 0.5 0.18 0.01
10.5 5.44 0.1 0.5 0.2 0.01
11 5.55 0.11 0.5 0.22 0.02
11.5 5.68 0.13 0.5 0.26 -0.03
12 5.78 0.1 0.5 0.2 -8.8818E-
16
12.5 5.88 0.1 0.5 0.2 0.01
13 5.99 0.11 0.5 0.22 -8.8818E-
16
13.5 6.1 0.11 0.5 0.22 8.88178E-
16
14 6.21 0.11 0.5 0.22 0
14.5 6.32 0.11 0.5 0.22 0.01
15 6.44 0.12 0.5 0.24 0.05
15.5 6.61 0.17 0.5 0.34 0.01
16 6.79 0.18 0.5 0.36 0.13
16.5 7.1 0.31 0.5 0.62 1.49
17 8.9 1.8 0.5 3.6 -0.66
17.5 10.04 1.14 0.5 2.28 -0.71
18 10.47 0.43 0.5 0.86 -0.25
18.5 10.65 0.18 0.5 0.36 -0.06
19 10.77 0.12 0.5 0.24 -0.03
19.5 10.86 0.09 0.5 0.18 -0.05
20 10.9 0.04 0.5 0.08 -0.04

Anlisis de resultados.
Conclusiones.

Bibliografa.
Skoog, D. A., West D. M.; Holler, F. J., Crouch R. "Fundamentos de Qumica
Analtica". 8 ed. Ed. Thomson-Paraninfo. Madrid. (2005).
Martn A. "Experimentacin en Qumica Analtica." Universidad de Navarra.
Pamplona. (1999).