Tabla 1.

1 Valoracin del HCl

Nmero de valoracin Volumen gastado de M [gmol/L] del HCl
NaOH
1 6.9ml 0.0207
2 6.7ml 0.0201
3 6.8ml 0.0204
0.0204M
Moralidad promedio

MHCl-valorar = .1.1

Corrida 1

(6.9)(0.03 )

MHCl-valorar = = 0.0207
(10)

Tabla 1.2. Datos experimentales

Experimento T(min) Vol.HCl (ml) Concentracin de
gastado en la NaOH (M)=CA
titulacin
1 0 5.5 0.01122
2 3 5.4 0.011016
3 6 4.5 0.00918
4 9 4.3 0.008772
5 12 4 0.00816
6 15 3.5 0.00714
7 18 3.3 0.006732
8 21 3.2 0.006528-
9 24 3 0.00612
10 27 2.5 0.0051

MNaOH = .1.2

(5.5)(0.0204)
MNaOH = = 0.01122
(10)

SECUENCIA DE CALCULOS.
METODO DIFERENCIAL
CORRIDA 1
= ( )
 1 = (0.011016 0.01122) = 0.000204
= 3
0 + 1
=
2
0.011016 + 0.01122
1 = = 0.011118
2
1 = ln
1 = ln(0.011118) =-4.4991

= ln

0.000204
= ln = 9.596
3

Tabla 1.3 Resultados del mtodo diferencial

t CA=CNaOH - = ln A y=ln


Ec.1.2
0 0.01122 - - - - -
3 0.011016 0.000204 3 0.011118 -4.4991 -9.5960
6 0.00918 0.001836 3 0.010098 -4.5954 -7.3987
9 0.008772 0.000408 3 0.008976 -4.7132 -8.9028
12 0.00816 0.000612 3 0.008466 -4.7716 -8.4973
15 0.00714 0.00102 3 0.00765 -4.8730 -7.9865
18 0.006732 0.000408 3 0.006936 -4.97103 -8.9028
21 0.006528 0.000204 3 0.00663 -5.0161 -9.5960
24 0.00612 0.000408 3 0.006324 -5.0634 -8.9028
27 0.0051 0.00102 3 0.00561 -5.1832 -7.9865

m=n De la regresin lineal: Por lo tanto:

k=eb m=-0.07344 n=-0.07344

b=-8.9976 k=1.237*10-4
Por ello el modelo cintico resultante es:

-rA=1.237*10-4CA-0.07344

METODO INTEGRAL
Corrida 1
-rA=KCAn

=

Con n=0

= 0 = (1)

= =
1
=
0

1 0.011016
= = 0.000068
3 0.01122

Tabla 1.4 Resultados del mtodo integral.

Valores de k a los diferentes valores n propuestos.
t CNaOH=CA n=0
Ec.1.2
0 0.01122
3 0.011016 0.000068
6 0.00918 0.00034
9 0.008772 0.000272
12 0.00816 0.000255
15 0.00714 0.000272
18 0.006732 0.00024
21 0.006528- 0.00022
24 0.00612 0.00021
27 0.0051 0.00022
 K =2.3543*10-4

Con base a las tendencias encontradas se concluye que:

n=0

k=2.3543*10-4

As el modelo cintico resultante es:

-rA=2.3543*10-4