113.

8 mol/s

0.83 metanol (H3) (L)

0.17 N2 (H4)
33 c , 6 ATM, H4

170 mol/s
CONDENSADOR

0.73 metanol (H1)

0.27 N2 (H2)
76.2 C , 1 ATM

56.2 mol/s
Metanol (v) HV=0
33 C

BALANCE DE ENERGIA
Q-WS=H+EC+EP
Q=H=niHi-inniHi
Q= nHsale-Nhentra
Q=H
 Establecer los datos de referencia de propano y el N2
N2
Metanol (L,33c , 6 ATM)
Elaborando la tabla
Sustancia nin (Hi kj/mol) nsust Hs (kj/mol)
Metanol (v) 73 Hi 16.8 HS
Metanol (L) ------ -------- 56.2
N2 (L) 27 H2 27 H4

Metanol (g) 33c, 6 ATM

METANOL
76.2 C , 1 ATM

Metanol (L) 33c, 6 ATM

Para H1 que esta a 76.2 c ,1 atm, partimos de dicha de referencia

Ref----metanol(L, 33c, 6 atm)partiendo metanol (v,76.2 c, 1 atm)
Metanol(L, 33c , 6 atm)alta metanol (L, 33c, 1 atm)
alta
Metanol(L,64.5c, 1 atm)

Metanol (v, 76.2c, 1 atm)alta metanol (v, 64.5|c, 1 atm)

H1=Ha+Hb+HC+Hd
64.5 76.2
H1=VP+33 (L)dt+Hv+64.5

1
Ha=vp Vesp= metanol

volumen especifico= 0.0404 L/mol

0.1013
Ha=0.0404(1-6)atm. =-0.0204 kj/mol
1
64.5 64.5
Hb=33 =33 [0.07586 + 16.83 105 ]
16.83105
=[(0.07586(64.5-33)c)+( (64.5 33)2 )]
2

=2.389+0.109512=2.498kj/mol

Hc=Hvmetanol=35.27kj/mol propiedades fsicas para

T=64.5C,1atm
8.301105 1.87108
Hc=0.04293(76.2-64.5)+[ (76.2 64.5)2 ]- *(76.2
2 3
8.031012
64.5)3 + (76.2 64.5)4]
4

Hd=0.502281+2.841186173 1010 -9.9833877 106 -3.761828574

108
Hd=0.50226 kj/mol
H1=Ha+Hb+Hc+Hd
H1=38.249 kj/mol
Ahora calculamos H3 Metanol en la corriente superior en la salida
Metanol (L,33 c,6 atm)partiendo Metanol (L,33c,1atm)

Metanol (L,64.5c,1 atm)

Metanol (V, 64.5c,1 atm)

Metanol (V, 33c,1 atm)

Metanol (V, 33c,6 atm)

1 64.5 33 6
H3=VP6 + 33 + Hv+64.5 +Vp1

H3=(2.448+35.27-0.50226) kj/mol

N2
Ref=N2(g,25c,1 atm) N2(g,76.2c,6 atm)
76.2 2.8711012
H2=25 =29.00 103 (76.2-25)- (76.2 25)4
4

H2=0.1484 kj/mol
N2(V,25c,1 atm) N2(V,33C,6 atm)
Partiendo
N2(V,25c,1 atm) N2(V,76.2C,1 atm)

N2(V,33c,6 atm) N2(V,76.2C,6 atm)

76.2 6 33
H4=25 +Vp1 + 76.2

Por lo general el VESPECIFICO para gas es

H4=-1.30295+0.1484
H4=-1.15455 kj/mol
Q=H
H=NhOut-NhIm
H=[(16.8 37.26574)+56.20)+(270.1484)]-[(73 38.249) + (27
1.15455)]
H= -2130.934268 KW