Especificar Datos

Constantes

T:

500

P:

20

bar

R:

0.08314

a
17.8831366289
b
0.0829327439

bar-L/mol-K

Componente
43

Tc/K

Pc/bar

0.281

466.7

36.4

ECUACIN DE VAN DER WALLS : P ( bar ) = (R * T (K) / ( V(L/mol) -b ) ) - a/V 2

ECUACIN DE REDLICH KWONG : P ( bar ) = (R * T (K) / ( V(L/mol) -b ) ) - a/V 2

ECUACIN DE SOAVE : P ( bar ) = (R * T (K) / ( V(L/mol) -b ) ) - a/V2

ECUACIN DE PENG ROBINSON : P ( bar ) = (R * T (K) / ( V(L/mol) -b ) ) - a/V 2

Ing. Msc. Ali Epifanio Daz Cama

CONDICIONES DE OPERACIN:

COMPORTAMIENTO PVT
DE FLUIDOS
PUROS
T (K)
P(barr)
V(lt/mol)
500

Seleccionar Ecuacin

20

120

Gas

ideal

COMPONENTE

Van

Der Walls

Eter dietilico

Redlich

Tc/K

0.281

466.7

Tc/K

466.7

36.4

Tc/K

466.7

36.4

Tc/K

466.7

36.4

Tc/K

Kwong

100

Soave
Peng

Robinson

COMPONENTE
Eter dietilico

80

Mostrar resultado

ol) -b ) ) - a/V 2

1.7059881707

5
L/mol

COMPONENTE

60

Eter dietilico

f( V )
40
COMPONENTE
Eter dietilico

20

mol) -b ) ) - a/V 2
COMPONENTE
Eter dietilico

mol) -b ) ) - a/V 2

0
0

466.7

36.4

-20
COMPONENTE
Eter dietilico

COMPONENTE
Eter dietilico

COMPONENTE
Eter dietilico

COMPONENTE
Eter dietilico

Tc/K

466.7

36.4

Tc/K

466.7

36.4

Tc/K

466.7

36.4

Tc/K

466.7

36.4

VDW

ECUACIN:

OS PUROS R

V0

Eter dietilico

0.08314

2.0785

Pc/bar

36.4

17.44930

0.13325

f(V)

f'(V)

5.1920190221 16.478824 1.7634278 0.1786703

V
1.76342782
Pc/bar

0.263

17.44930

0.13325

f(V)

f'(V)

0.1810405989 15.2367019 1.7515459 0.0067837

6
7

V
1.75154594
Pc/bar

0.263

17.44930

0.13325

f(V)

f'(V)

0.0003495268 15.1776884 1.7515229 1.31E-005

V
1.75152291

Pc/bar

0.263

17.44930

0.13325

f(V)

f'(V)

1.329113E-009 15.177573 1.7515229 5.00E-011

V
1.75152291
Pc/bar

0.263

17.44930

0.13325

f(V)

f'(V)

0 15.177573 1.7515229

1.75152291

Pc/bar

0.263

17.44930

f(V)

0.13325

f'(V)

0 15.177573 1.7515229

V
1.75152291

Pc/bar

0.263

17.44930

0.13325

f(V)

f'(V)

0 15.177573 1.7515229

V
1.75152291
Pc/bar

0.263

17.44930

0.13325

f(V)

f'(V)

0 15.177573 1.7515229

V
1.75152291
Pc/bar

0.263

17.44930

0.13325

-1
1
2
3
4
5

f(V)

f'(V)

0 15.177573 1.7515229

1.75152291

f(V)
-86.6388429
-9.07834096
4.69836012
22.267906
40.9768562
60.1766218
79.632133
99.237717

1.08235294

0.39515279

0.01563869

-0.28881095

-0.28568316
0.89570078
2.28370259

PROPIEDADES DE LAS ESPECIES PURAS

numerCOMPUESTO
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43

1,3-Butadieno
1-Butanol
1-Buteno
1-Hexanol
1-Hexeno
1-Propanol
2-Propanol
Acetaldehido
Acetato de etilo
Acetato de metilo
Acetileno
Acetona
Acetonitrilo
Acido Actico
Acido Benzoico
Acido n-butirico
Acido ntrico
Acido sulfrico
Agua
Amoniaco
Argn
Benceno
Bifenilo
Cianuro de hidrgeno
Ciclohexano
Ciclohexeno
Ciclopentano
cis-2-Buteno
Cloro
Clorobenceno
Cloroformo
Cloruro de etilo
Cloruro de hidrgeno
Cloruro de metilo
Cumeno
Diclorometano
Dixido de azufre
Dixido de carbono
Disulfuro de carbono
Estireno
Etano
Etanol
Eter dietilico

M MOLAR
54.092
74.123
56.108
102.177
84.161
60.096
60.096
44.053
88.106
74.079
26.038
58.08
41.053
60.053
122.123
88.106
63.013
98.08 ...
18.015
17.031
39.948
78.114
154.211
27.026
84.161
82.145
70.134
56.108
70.905
112.558
119.377
64.514
36.461
50.488
120.194
84.932
64.065
44.01
76.143
104.152
30.07
46.069
74.123

Tc/K

0.19
0.594
0.191
0.579
0.28
0.622
0.668
0.291
0.366
0.331
0.187
0.307
0.338
0.467
0.603
0.681
0.714
0.345
0.253
0
0.21
0.365
0.41
0.21
0.212
0.196
0.205
0.069
0.25
0.222
0.19
0.132
0.153
0.326
0.199
0.245
0.234
0.111
0.297
0.1
0.645
0.281

425.2
563.1
420
611.4
504
536.8
508.3
466
523.3
506.6
308.3
508.2
545.5
592
751
615.7
520
924
647.1
405.7
150.9
562.2
798.3
456.7
553.6
560.4
511.8
435.6
417.2
632.4
536.4
460.4
324.7
416.3
631.1
510
430.8
304.2
552
636
305.3
513.9
466.7

Pc/bar
42.77
44.23
40.43
35.1
31.4
51.75
47.62
55.5
38.8
47.5
61.39
47.01
48.3
57.86
44.7
40.64
68.9
64
220.55
112.8
48.98
48.98
38.5
53.9
40.73
43.5
45.02
42.43
77.1
45.2
54.72
52.7
83.1
66.8
32.09
60.8
78.84
73.83
79
38.4
48.72
61.48
36.4

44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87

Eter metil t-butilico

Etilamina
Etilbenceno
Etilenglicol
Etileno
Fenol
Formaldehido
Helio 4
Hidrgeno
Isobutano
Isobutileno
Isoctano
Kriptn
Metano
Metanol
Metil etil cetona
Metilamina
Metilciclohexano
Metilciclopentano
Monxido de carbono
m-Xileno
Naftaleno
n-Butano
n-Decano
n-Heptano
n-Hexano
Nitrgeno
Nitrometano
n-Nonano
n-Octano
n-Pentano
Oxido ntrico(NO)
Oxido nitroso(N2
Oxgeno
o-Xileno
Propano
Propileno
p-Xileno
Sulfuro de hidrgeno
Tetracloruro de carbono
Tolueno
trans-2-Buteno
Trixido de azufre
Xenon

88.15
45.084
106.167
62.068
28.054
94.113
30.026
4.003
2.016
58.123
56.108
114.231
83.8
16.043
32.042
72.107
31.057
98.188
84.161
28.01
106.167
128.174
58.123
142.285
100.204
86.177
28.014
61.04
128.258
114.231
72.15
30.006
44.013
31.999
106.167
44.097
42.081
106.167
34.082
153.822
92.144
56.108
80.064
165.03

0.266
0.285
0.303
0.487
0.087
0.444
0.282
-0.39
-0.216
0.181
0.194
0.302
0
0.012
0.564
0.323
0.281
0.235
0.23
0.048
0.326
0.302
0.2
0.492
0.35
0.301
0.038
0.348
0.444
0.4
0.252
0.583
0.141
0.022
0.31
0.152
0.14
0.322
0.094
0.193
0.262
0.218
0.424
0

497.1
456.2
617.2
719.7
282.3
694.3
408
5.2
33.19
408.1
417.9
544
209.4
190.6
512.6
535.5
430.1
572.2
532.8
132.9
617.1
748.4
425.1
617.7
540.2
507.6
126.2
588.2
594.6
568.7
469.7
180.2
309.6
154.6
630.3
369.8
365.6
616.2
373.5
556.4
591.8
428.6
490.9
289.7

34.3
56.2
36.06
77
50.4
61.3
65.9
2.28
13.13
36.48
40
25.68
55.02
45.99
80.97
41.5
74.6
34.71
37.85
34.99
35.36
40.51
37.96
21.1
27.4
30.25
34
63.1
22.9
24.9
33.7
64.8
72.45
50.43
37.34
42.48
46.65
35.11
89.63
45.6
41.06
41
82.1
58.4

1
2
3
4
5

GAS IDEAL
VAN DER WALLS
REDLICH KWONG
SOAVE R K
PENG ROBINSON

1 GAS IDEAL
2 VAN DER WALLS
3 REDLICH KWONG
4 SOAVE R K
5 PENG ROBINSON

V
2.07850
1.75152
1.72636
1.74337
1.70599

V1

17.4493016 0.1332467 -84.0092973

381.96974 0.09235595 -83.9756733
### 0.09235595 -83.3625899
17.8831366 0.08293274 -86.6388429

CIES PURAS
Zc

Vc
0.267
0.26
0.277
0.263
0.265
0.254
0.248
0.221
0.255
0.257
0.271
0.233
0.184
0.211
0.246
0.232
0.231
0.147
0.229
0.542
0.291
0.271
0.295
0.197
0.273
0.272
0.273
0.273
0.265
0.265
0.293
0.275
0.249
0.276
0.261
0.265
0.269
0.274
0.275
0.256
0.279
0.24
0.263

3
-1
cm mol

220.4
275
239.3
381
354
219
220
154
286
228
113
209
173
179.7
344
291.7
145
177
55.9
72.5
74.6
259
502
139
308
291
258
233.8
124
308
239
200
81
143
427
185
122
94
160
352
145.5
167
280

Tn/K
268.7
390.8
266.9
430.6
336.3
370.4
355.4
294
350.2
330.1
189.4
329.4
354.8
391.1
522.4
436.4
356.2
610
373.2
239.7
87.3
353.2
528.2
298.9
353.9
356.1
322.4
276.9
239.1
404.9
334.3
285.4
188.2
249.1
425.6
312.9
263.1
319.4
418.3
184.6
351.4
307.6

0.273
0.307
0.263
0.246
0.281
0.243
0.223
0.302
0.305
0.282
0.275
0.266
0.288
0.286
0.224
0.249
0.321
0.269
0.272
0.299
0.259
0.269
0.274
0.247
0.261
0.266
0.289
0.223
0.252
0.256
0.27
0.251
0.274
0.288
0.263
0.276
0.289
0.26
0.284
0.272
0.264
0.275
0.255
0.286

329
207
374
191
131
229
115
57.3
64.1
262.7
238.9
468
91.2
98.6
118
267
154
368
319
93.4
376
413
255
600
428
371
89.2
173
544
486
313
58
97.4
73.4
369
200
188.4
379
98.5
276
316
237.7
127
118

328.4
289.7
409.4
470.5
169.4
455
154.1
4.2
20.4
261.4
266.3
372.4
119.8
111.4
337.9
352.8
266.8
374.1
345
81.7
412.3
272.7
447.3
371.6
34.19
77.3
374.4
424
398.8
309.2
121.4
184.7
90.2
417.6
231.1
225.5
411.5
212.8
349.8
383.8
274
317.9
165

V2

V3

V4

V5

V6

V7

-9.110694142 3.9084514123 21.3231597 39.9820751 59.1619239 78.608698

-9.223428091 4.3699807056 21.9368329 40.6606776 59.8753997 79.3435972
-9.646702805 4.1377590499 21.7771709 40.5390723 59.7772125 79.2612689
-9.078340961 4.6983601208 22.267906 40.9768562 60.1766218 79.632133

V8
98.2103732
98.9596411
98.8887629
99.237717