60000

50000

40000
Series1
Series2
Series3

30000

Series4
Series5
Series6
Series7

20000

Series8
Series9
10000

0
Fraccin Molar
Yi

P. Critica
(psia)
Molar Weight, MW Aparente
(lb/bl-mol)
(lb/lb-mol)

T. Critica (R)

Cond. Critica

a mezcla
Van der Walls

b mezcla

Yi
Fraccin
Molar
H2S
CO2
C1
C2
C3
iC4
nC4
TOTAL

0.033
0.079
0.655
0.105
0.054
0.028
0.046
1.000

Molar
Weight,
(lb/blmol)
34.082
44.010
16.043
30.070
44.097
58.123
58.123

MW
Aparente
(lb/lbmol)

Cond. Critica
P. Critica
(psia)

T. Critica
(R)

1.125 1300.000
3.477 1069.500
10.508 667.000
3.157 707.800
2.381 615.000
1.627 527.900
2.674 548.800
24.949

672.400
547.730
343.340
550.070
665.920
734.410
765.510

Van der Walls

a
16898.851
13630.048
8587.526
20771.625
35035.968
49644.440
51883.917

b
0.694
0.687
0.691
1.043
1.453
1.866
1.871

Van der Walls

a mezcla
4.290
9.223
60.698
15.133
10.108
6.239
10.478
116.168
13495.074

b
mezcla
0.023
0.054
0.452
0.109
0.078
0.052
0.086
0.856

Yi
% Molar

Fraccin
Molar

H2S
CO2
C1
C2
C3
iC4
nC4
TOTAL

3.300
7.900
65.500
10.500
5.400
2.800
4.600
100

T=
P=

579.67 R
800 psia

0.033
0.079
0.655
0.105
0.054
0.028
0.046
1.000

Molar
Weight,
(lb/blmol)
34.082
44.010
16.043
30.070
44.097
58.123
58.123

MW
Aparente
(lb/lbmol)

Cond. Critica
P. Critica T. Critica
(psia)
(R)

1.125 1300.000
3.477 1069.500
10.508 667.000
3.157 707.800
2.381 615.000
1.627 527.900
2.674 548.800
24.949

672.400
547.730
343.340
550.070
665.920
734.410
765.510

Peng Robinson

0.095
0.267
0.011
0.097
0.152
0.185
0.198

0.518
0.767
0.391
0.522
0.602
0.651
0.670

1.076
0.956
0.779
0.972
1.082
1.151
1.181

a
19698.640
14128.643
7254.783
21893.110
41098.692
61906.412
66433.142

b
0.432
0.428
0.430
0.649
0.904
1.162
1.165

a mezcla
4.632
9.390
55.790
15.536
10.947
6.967
11.856
115.118
13252.145

b
mezcla
0.014
0.034
0.282
0.068
0.049
0.033
0.054
0.533

Correlaciones Generalizadas de R

Fracciones de petroleo, C6+, C7+, Cn+

Datos 1
Tb =
=
PM =

657.67 R
0.753
135 lb/lbmol

Datos 2 (opcional)
PM =
=
Tb =

130 lb/lbmol
0.72
R

PM
Tc, R
Pc, psia
Vc, ft3/lb

a
581.96
10.6443
6162000
0.0006233

b
0.97476
0.81067
-0.4844
0.7506

Factor de Caracterizacion de Watson

Kw =

11.548911

Tc, R
Pc, psia
Vc, ft3/lb
Tb, R

a
544.2
45203
0.01206
6.77857

b
0.2998
-0.8063
0.20378
0.401673

Resultados 1
PM
Tc
Pc
Vc

96.727
993.143
488.227
0.061
0.278

lb/lbmol
R
psia
ft3/lb

laciones Generalizadas de Riazi y Daubert

c
d
6.51274 0.00054308
0.53691 -0.00051747
4.0846
-0.004725
-1.2028 -0.0014679
c
d
1.0555 -0.00013478
1.6015 -0.0018078
-1.3036
-0.002657
-1.58262 0.00377409

e
-9.53384
-0.54444
-4.8014
-0.26404

Correlaciones Gen

f
0.00111056
0.00035995
0.0031939
0.001095

e
f
-0.61641
0
-0.3084
0
0.5287
0.0026012
2.984036 -0.00425288

Resultados 2
Tc
Pc
Vc
Tb

1043.704
333.974
0.066
757.398
0.538

R
psia
ft3/lb
R

Resultados 1

Pc
Tc
PM

Correlaciones Generalizadas de Kesler y Lee

0.666
494.403 psia
987.179 R
96.923 lb/lbmol
0.298

Resultados 1

Pc
Tc
PM

Tb

0.713
325.661
1062.669
130.000
0.435
757.398

psia
R
lb/lbmol
R

Correlacion Generalizada de Mathews, Roland y katz

Resultados
Tb =
Psc =
Tsc =

757.398
338.517 psia
1090.088 R
0.329

ws, Roland y katz

Yi
Fraccin
Molar
N2
H2S
CO2
C1
C2
C3
iC4
nC4
iC5
nC5
C6+
TOTAL

P
T
Psc
Tsc
Pr
Tr

0.005
0.055
0.016
0.763
0.074
0.055
0.008
0.009
0.004
0.004
0.007
1.000

psia
R

MW
Aparente
(lb/lb-mol)
0.146
1.878
0.717
12.233
2.231
2.425
0.453
0.546
0.267
0.296
0.737
21.930

Cond. Pseudocritica

Psc (Yi*Pci), Tsc (Yi*Tci),

psia
R

p y/o
mezcla

2.563
71.630
17.433
508.588
52.519
33.825
4.118
5.159
1.814
2.001
2.808
702.456

1.183
37.049
8.928
261.797
40.815
36.626
5.728
7.196
3.067
3.467
6.835
412.692

0.000
0.005
0.004
0.008
0.007
0.008
0.001
0.002
0.001
0.001
0.003
0.041

Entalpia Ideal

Hi a 120F
155
145
100
292
189
162
151
161
151
158
140

Hm =
Yi*Pmi*Hi
22.579
272.298
71.736
3571.974
421.696
392.904
68.457
87.963
40.310
46.739
103.180
5099.837

Entropia ideal

si
1.660
1.460
1.180
3.150
2.040
1.620
1.380
1.340
1.260
1.260
1.260

Yi*Pmi*si Yi*LN Yi
0.242
2.742
0.846
38.533
4.552
3.929
0.626
0.732
0.336
0.373
0.929
53.839

-0.027
-0.160
-0.067
-0.207
-0.193
-0.160
-0.038
-0.044
-0.021
-0.023
-0.034
-0.972

T=
P=
zi
Fraccin
Molar
H2S
CO2
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7+
TOTAL

0.005
0.013
0.214
0.368
0.102
0.064
0.098
0.026
0.040
0.039
0.031
1.000

659.67 R
300 psia

Molar
Weight,
(lb/bl-mol)
34.082
44.010
16.043
30.070
44.097
58.123
58.123
72.150
72.150
86.177
130.000

MW
Aparente
(lb/lb-mol)
0.170
0.550
3.427
11.060
4.502
3.708
5.719
1.898
2.893
3.361
4.082
41.371

Cond. Critica
P. Critica
(psia)
1300.000
1069.500
667.000
707.800
615.000
527.900
548.800
490.400
488.100
439.500
333.974

T. Critica (R)
672.070
547.400
343.010
549.740
665.590
734.080
765.180
828.630
845.370
911.470
1043.704

V
Cond. Pseudocritica

Psc (Yi*Pci), Tsc (Yi*Tci),

psia
R

6.500
13.369
142.471
260.329
62.792
33.680
54.002
12.898
19.573
17.141
10.487
633.240

3.360
6.843
73.267
202.194
67.957
46.834
75.294
21.793
33.899
35.547
32.772
599.761

0.095
0.267
0.011
0.097
0.152
0.185
0.198
0.229
0.251
0.299
0.538

Constantes de equilibrio
Wilson Ki
3.8800
11.3457
30.1022
6.2980
1.9393
0.8583
0.6537
0.3017
0.2455
0.1022
0.0091

Zi*Ki

0.890

Zi/ki

0.019
0.142
6.430
2.316
0.198
0.055
0.064
0.008
0.010
0.004
0.000
9.247
DOS FASES

0.001
0.001
0.007
0.058
0.053
0.074
0.151
0.087
0.163
0.382
3.455
4.433

Xi
0.0014
0.0012
0.0079
0.0644
0.0556
0.0730
0.1422
0.0695
0.1221
0.1941
0.2659
0.9973

0.905

0.915

0.925

0.935

0.110

Xi

Xi

Xi

Xi

Yi = Ki*Xi

0.0014
0.0012
0.0078
0.0635
0.0552
0.0732
0.1433
0.0715
0.1264
0.2080
0.3042
1.0556

0.0014
0.0012
0.0077
0.0629
0.0549
0.0733
0.1440
0.0728
0.1295
0.2185
0.3365
1.1028

0.0014
0.0012
0.0077
0.0623
0.0546
0.0734
0.1448
0.0743
0.1327
0.2300
0.3765
1.1589

0.0014
0.0012
0.0076
0.0618
0.0544
0.0735
0.1455
0.0758
0.1361
0.2429
0.4272
1.2273

0.0054
0.0139
0.2390
0.4053
0.1078
0.0627
0.0930
0.0210
0.0300
0.0198
0.0024
1.0003

zi
Fraccin
Molar
H2S
CO2
C1
C2
C3
iC4
nC4
iC5
nC5
C6
C7+
TOTAL

0.005
0.013
0.214
0.368
0.102
0.064
0.098
0.026
0.040
0.039
0.031
1.000

Molar
Weight,
(lb/bl-mol)
34.082
44.010
16.043
30.070
44.097
58.123
58.123
72.150
72.150
86.177
130.000

MW
Aparente
(lb/lb-mol)
0.170
0.550
3.427
11.060
4.502
3.708
5.719
1.898
2.893
3.361
4.082
41.371

Constantes de equilibrio
Pvi
394.670
0.000
5000.000
800.000
188.680
72.598
51.719
20.450
15.580
4.961
0.172

Ideales k =
Pvi/P
1.3156
0.0000
16.6667
2.6667
0.6289
0.2420
0.1724
0.0682
0.0519
0.0165
0.0006

V calc

0.6
V

ntes de equilibrio
Zi*Ki

Zi/ki

0.007
0.004
0.000
0.000
3.560
0.013
0.981
0.138
0.064
0.162
0.015
0.264
0.017
0.571
0.002
0.386
0.002
0.772
0.001
2.358
0.000
54.895
4.649
59.563
DOS FASES

0.565

0.580

0.590

0.600

0.610

Xi

Xi

Xi

Xi

Xi

0.0042
0.0287
0.0217
0.1894
0.1292
0.1116
0.1848
0.0555
0.0864
0.0878
0.0721
0.9715

0.0042
0.0298
0.0212
0.1870
0.1301
0.1139
0.1892
0.0572
0.0891
0.0908
0.0747
0.9872

0.0042
0.0305
0.0209
0.1854
0.1307
0.1154
0.1923
0.0584
0.0910
0.0929
0.0765
0.9983

0.0042
0.0312
0.0205
0.1839
0.1313
0.1170
0.1955
0.0597
0.0930
0.0951
0.0784
1.0099

0.0042
0.0321
0.0202
0.1824
0.1320
0.1187
0.1987
0.0609
0.0951
0.0975
0.0804
1.0222

L
0.4
Yi = Ki*Xi
0.0055
0.0000
0.3423
0.4904
0.0826
0.0283
0.0337
0.0041
0.0048
0.0016
0.0000
0.9934