ESCUELA SUPERIOR DE INGENIERA QUMICA E INDUSTRIAS

EXTRACTIVAS
problema 5
termodinmica del equilibrio qumico
cruz santos Nohem Alejandra
Hernndez Ramrez Lorena
Vzquez Montenegro Liliana
Lara salas Sebastin
Ziga casco irvin
Vega Zavala Ulises

PROBLEMA 5

La corriente de gas de un quemador de azufre consiste en 15% mol de SO 2 ,

20% mol de O2 y 65 % mol de N2. La corriente de gas a presin atmosfrica y a
una temperatura de 400 C entra al convertidor cataltico donde el 86% del SO 2
se oxida a SO3. Considere una mol de gas que entra al quemador. Cunto
calor deber eliminarse del convertidor de modo que los gases producidos
salgan a 500 C ?

SO2 + O2

SO 3

Gas
15% SO2
20% O2

nSO3 = ?
Q=?

65%N2

nO2 = ?

P= 1 atm
T= 400
BaseC
de Calculo: 1 mol de gas
ENTRADA

nSO2 = 0.15 mol

nO2 = 0.20 mol
nN2 = 0.65 mol

nSO2 = ?

P= 1 atm
T= 500
C
SALIDA

nSO3 = 0.15 * (0.86) = 0.129

nSO2 = 0.15 0.129 = 0.021
nO2 = 0.20 0.129 * (0.5) = 0.1355
nN2 = 0.65

T = 500 C

Q=

H
productos

T = 400
C

H reactivos

H 298.5
A=

Hf298.15

Hprod=

A=

A= (0.15)(5.699)+(0.20)(3.639)+(0.65)(3.280)
A= 3.7146
B= (0.15)(0.801X10-3)+(0.20)(0.506)+(0.65)(0.593X10-3)
B=6.07X10-4
C=0
D=(0.15)(-1.015X10-5)+(0.20)(-0.227X10-5)+(0.65)(0.040X10-5)
D= -2X10-6
Hreac=
H reac= -1503.542
H reac= (-1503.542)(R) =(-1503.542)(8.314)
H reac=-12500.4 J/mol

Hprod=
A= (0.129)(8.060)+(0.1355)(3.639)+(0.65)(3.280)+(0.021)(5.699)
A= 3.7845
B=(0.129)(1.056x10-3)+(0.1355)(0.506x10-3)+(0.65)(0.593x10-3)+(0.021)(0.801x10-3)
B=6.09x10-4
C=0
D=(0.129)(-2.028x10-5)+(0.1355)(-0.227x10-5)+(0.65)(0.040x10-5)+(0.021)(-0.015x10-5)
D=-3x10-6

Hprod=

Hprod=1952.1
Hprod=(1952.1)(R)=(1952.1)(8.314)
Hprod=16229.8 J/mol

Hf298.15

Hf298.15= (Mi SO2)(H SO2)+(Mi O2)(H O2)+(Mi SO3)(H SO3)

Hf298.15= (-1)(-296830)+(-0.5)(0)+(1)(-395720)
Hf298.15= -98890 J/mol
Q= Hreac+H298.15(0.86)+Hprod
Q= (-12500.4)+(-98890)(0.86)+16229.8
Q= -180206 J