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PROCESO DE
TRANSFORMACIN
DE LA BIOMASA EN
ENERGA.
(Etanol y
Bioetanol)
PROCESO DE TRANSFORMACIN DE LA
BIOMASA EN ENERGA.
(Etanol y
Bioetanol)
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metanol
etanol
1-propanol
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Saturated
ethanol
Unsaturated
1-propanol
Fig. 2 Alcohols
according to their
Aromatic alkyl group
bensol
Fig. 3 Alcohols
according
to the position of
Tertiary
Primary
Secondary
their OH
2-methyl1-propane 2-propanol
2-propanol group on the carbon
atom
Fig. 4 Alcohols
according
Mono-hydroxyl Poly-hydroxyl
to the number of
propane-threeol
ethanol
Procesos Bioqumicos. Etanol y Bioetanol. OH groups in
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LA BIOMASA COMO FUENTE DE ENERGA
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Fig. 6 Gasoline
engine full throttle
exhaust emissions
using ethanol fuel
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The
typical
continuous
distillation apparatus for the
production
of
high-quality
hydrous ethanol is composed of a
mash column, a concentration
column, an extraction column, a
rectification column, a refining
column, an impurity column. A
dehydration column, dehydrate
recovery column, and dehydrate
separator are necessary for the
production of anhydrous ethanol.
The
distillation
apparatus
Fig. 9 Simple distillation
necessary for the production of
(Mathewson,
1980)
Procesos Bioqumicos. Etanol yapparatus
Bioetanol.
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LA BIOMASA COMO FUENTE DE ENERGA
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Extraction column
Many kinds of ingredients (mainly aldehydes) other than
methanol can be separated from the top of the extraction
column (fig. 8 number 2). In general, volatile components
with higher boiling points have lower volatility than those
with lower boiling points. For example, methanol with a
boiling point of 64.7C is more volatile than ethanol with a
boiling point of 78.3C. However, the relative volatility of
ethanol and methanol is reversed at low ethanol
concentration, and the relative volatility of ethanol becomes
higher than that of methanol at a water concentration of
more than 70 mol. %. The relative volatility of higher
alcohols (components of fusel oil) becomes higher than that
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Rectification Column
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Dehydration Column
To make anhydrous ethanol, there are three dehydration
processes that use solid dehydrant, liquid dehydrant, and
azeotropic distillation. The most common process is
azenopropic distillation.
An azeotropic mixture is formed when an ethanolwater
solution is mixed with a third component, such as cyclohexane, that is insoluble (or slightly soluble) in ethanol
water or that dissolves in either ethanol or water. The
boiling point of the mixture as a whole (62.1 C) is lower
than that of each component; ethanol, water, and cyclohexane having boiling points of 78.3, 100, and 80.7 C,
Bioqumicos. Etanol
y Bioetanol.
Oliva
respectively. An Procesos
azeotropic
mixture
containing DenycycloLA BIOMASA COMO FUENTE DE ENERGA
Vacuum column
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5. Alcohols as a fuel
The very first cars ever made on an assembly line the Ford
Model T, were built to run on ethanol. Henry Ford designed
the famed Model T Ford to run on alcohol. He said it was
the fuel of the future. There are more stills in this country
than filling stations, Henry Ford wisely pointed out, as
early as 1908. The oil companies thought otherwise,
however, but the oil crisis of the early 1970s gave ethanol
fuel a new lease of life.
The question is if alcohol is such a great fuel (and fuel
additive), then why isn't everyone using it? The truth is,
most petroleum companies have used it, at some point in
their history, and many
continue to use ethanol as anDenyoctane
Procesos Bioqumicos. Etanol y Bioetanol.
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LA BIOMASA COMO FUENTE DE ENERGA
So, the big five oil companies (at that time they were Shell,
Arco, Standard Oil, Texaco, and Mobil) all started building
big commercial distillation plants in the deep South,
including Texas, but mostly around Mississippi and
Louisiana (this was because it was easy to bring in the large
quantities of grain) as well as imported molasses from
Caribbean sugar cane, and sugar beet pulp from all the
Southern sugar beet farms. This wasn't the first time ethanol
was used, either. During World War Two, ethanol was
produced in very large quantities, and many new plants in
the Midwest were built to supply the US Navy & Air force
planes with aviation fuel, which was anywhere from 20 %
ethanol to pure 100% alcohol.
So the petroleum companies already knew a lot about
ethanol as a fuel and as an additive, and have had this in
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They just ignored the fact that lead did not enter into the
combustion cycle at all, it just inhibited it, and ended up as
lead dust all over the cities, which started getting heavily
polluted and greyish coloured from all the lead dust landing
on the streets, of the walls of buildings, and on the hands of
little children playing outside. Well, with the oil embargo of
the 70s, they went back to ethanol, as an octane booster.
They made a marketing mistake, they decided to call it
Gasohol, and they promoted it hard and heavy. The term,
gasohol confused people though, and a very high
percentage of people weren't sure if they could put it in their
car.
At this time, ethanol started so getting popular as an
alternative fuel, that many people, from farmers organizing
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(Iso-
octane)
C8H18
114
gravity
(20C)
Compositio
n (wt. %)
Carbon
Hydrogen
Oxygen
Theoretical
air-fuel ratio
(air
kg/fuel
kg)
Net
heating
value (MJ/kg)
LA BIOMASA COMO FUENTE DE ENERGA
Ethanol mixed
Ethanol
Ethanol
Etha
nol
C2H5
OH
46
10%gasoline20%
Gasoline Gasoline
90%
80%
0.72
0.73
0.7
0.79
84
52
81
16
0
13
35
12 - 15
4
12 - 15
7
15.1
14.2
13.6
44.37
0.76
84
0.77
78
81
29.7
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Gasolin
Parameter
Heating
value in
theoretical air
fuel ratio (MJ/m3
mix)
(MJ/kg
Latent
2.94
air)
heat of
vaporization
(kJ/kg)
272
Research
Motornumber
octane
octane
Cetane value
number
Ignition point
(C)
Flash point (C)
Boiling point
(C)
LA BIOMASA COMO FUENTE DE ENERGA
e
(Isooctane)
3.55
100
100
12
275
-43
99.4
Eth
10%gasoline20%
Gasolin Gasolin
e 90%
e 80%
anol
3.5
3
2.9
8
381sp. 435sp.
862
106
89
8
420
14
78.
gr.0.783 gr.0.738
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6.2 Carburetion
The carburettor meters the flow of fuel to the cylinders and
mixes the fuel with air. Because ethanol supplies less energy
per unit of volume than does gasoline, fuel-metering jets
must be enlarged to allow the proper amount of fuel to pass.
The main modification required to run a carburetted engine
on ethanol is drilling out the jets or installing larger jets. It
is better to buy replacement jets and drill those out so you
still have the originals if you ever want to revert to gasoline.
For some carburettors used in racing, you can buy the next
size larger jet. You want to drill the jet out only 15% more
by total diameter, no more. In fact, start at only 8% and try
that first. EveryProcesos
engine
is different, accordingDenytoOliva its
Bioqumicos. Etanol y Bioetanol.
LA BIOMASA COMO FUENTE DE ENERGA
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REFERENCES
1. Saiki, T., Karaki, I., Roy, K. 1999. Biomass liquid fuels. CIGR
Handbook of Agrilultural Engineering, Volume V:
Energy&Biomass Engineering. ASAE, St. Joseph MI, 139201.
2. Hartmann, H. and A. Strehler. 1995. Die Stellung der Biomasse.
Landwirtschaftsverlag GmbH, Mnster.
3. Mathewson, S.W. 1980. The Manual for the Home and Farm
Production of Alcohol Fuel. Ten Speed Press, J.A. Diaz
Publications
(http://journeytoforever.org/biofuel_library/ethanol_manual/manu
al_ToC.html)
4. Smith, J.L. and J.P. Workman, J.P. 2004. Alcohol for Motor Fuels,
Farm Management Online Fact Sheets No. 5010, Colorado State
University Cooperative Extension
(http://www.ext.colostate.edu/pubs/farmmgt/05010.html)
LA BIOMASA COMO FUENTE DE ENERGA
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PROCESOS BIOQUMICOS.
(ETANOL Y BIOETANOL)
Deny Oliva