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Termodinámica 605

B 1 Calores específicos y constantes de gases a baja presión

Para cada sustancia, la constante específica de gas se calculó a partir de R = 1 545.32/M pie 'Ibt/lb' °R
Y se da también su conversión a unidades SI. Valores instantáneos de Cp a la temperatura normal de 25°C
(o bien 77°F) se obtuvieron de la infor.!!laQión publicada. y de dichos valores se determinaron los demás,
como sigue: cp = CjM, Cv = Cp - R, R = 1.986 Btu/lbmol·oR, k = CjCv' Cv = cp - R.
NOTAS. Un cierto número de valores ha sido actualizado, principalmente con datos de JANAFI022J, pero
en la mayoría de los casos la variación no tiene importancia técnicamente: (a) Valores a 37.8°C (o bien,
100°F) tomados de Gas Tables de Keenan y Kaye. (b) El calor específico de todos los gases monoatómicos
se considera C = 4.97 Btu/lbmol- ° R. (c) Valores tomados de Rossini y cols.10.1.0.21.
(d) Valores provenientes
de McBride y cols. [0231.(e) De JANAFI022J.
Todas las masas moleculares se basaron en el valor de 32 para el O2, pero no difieren mucho de los
obtenidos con base en 12 para el C12.
Los valores de cp' Cv en kcal/kg' K son igu..ales a los expresados en Btu/lb' ° R; asimismo, el valor de M
en kg/kgmol es igual al expresado en Ib/lbmol.

M cp cF cp Cv R R
Gas kglkgmol keallkg'K keal/kg'K kJ/kg'K kJ/kg'K K = c/c, Ibf'pie/lb"R J/kg·K

Argón (A) (b) 39.95 0.1244 0.0747 0.5215 0.3132 1.666 38.68 208.17 ;
Helio (He) (b) 4.003 1.241 0.745 5.2028 3.1233 1.666 386.04 2077.67
Mercurio (Hg) (b) 200.61 0.0248 0.0148 0.1039 0.0624 1.666 7.703 41.45
Neón (Ne) (b) 20.183 0.246 0.1476 1.0313 0.6188 1.666 76.57 412.10
Xenón (Xe) (b) 131.30 0.0378 0.0227 0.1585 0.0952 1.666 11.77 63.34
Aire (a) 28.970 0.24 0.1714 1.0062 0.7186 1.4 63.342 287.08
Monóxido de carbono (CO) 28.01 0.2487 0.1778 1,0426 0.7454 1.399 65.170 296.92
-l Cloro (CI,) 70.914 0.1144 0.0864 0.4796 0.3622 1,324 " 21.791 117.28
Flúor (F,) (d) 38.00 0.197 0.1447 0.8259 0,6066 1.36 40.67 218.88
Hidrógeno (H,) 2.016 3.419 2.434 14.3338 10.2043 1.40 766.54 4125.52
Hldroxilo (OH) (e) 17.008 0.421 0.3031 1.7650 1.2708 1.383 90.858 488.99
Oxido nítrico (NO) 30.008 0.2378 0.1716 0.9969 0.7194 1.386 51.497 277.15
Nitrógeno (N,) 28.016 0.2484 0.1775 1.0414 0.7442 1.399 55.158 296.86
Oxígeno (O,) (e) 32 0.2194 0.1573 0.9198 0.6595 1.395 48.291 259.90
Dióxido de carbono (CO,) 44.010 0.2016 0.1565 0.9452 0.6561 1.268 35.11 188.96
Sulluro de hidrógeno (H,S) (e) 34.086 0.2397 0.1799 1.0049 0.7542 1.321 45.33 243.96
Dióxido de nitrógeno (NO,) (e) 46.008 0.1921 0.1489 0.8054 0.6242 1.29 33.59 180.78
Oxido nitroso (N,O) (e) 44.016 0.2097 0.1646 0.8791 0.6901 1.274 35.11 188.96
Ozono (0,) (e) 46 0.1954 0.154 0.8192 0.6456 1.269 32.194 173.27
Dióxido de azufre (SO,) (e) 64.07 0.1487 0.1177 0.6234 0.4934 1.263 24.12 129.81
Vapor de agua (H,O) (a) 18.016 0.4454 0.3352 1.8673 1.4053 1.329 85.77 461.61
Acetileno (C,H,) (e) 26.036 0.4048 0.3285 1.6971 1.3772 1.232 59.35 319.42
Amoniaeo (NH,) (e) 17.032 0.499 0.382 2.0920 1.6015 1.304 90.73 488.31
n-Butano (C.H,,) 58.120 0.4007 0.3685 1.6799 1.5365 1.093 26.59 143.11
Cianógeno (C,N,) (e) 52.038 0.261 0.2228 1.0942 0.9341 1.172 29.7 159.84
Etano (C,H,) 30.068 0.4186 0.3526 1.7549 1.4782 1.187 51.39 276.58
Etíleno (C,H.) (e) 28.052 0.3654 0.2946 1.5319 1.2351 1.240 55.09 296.49
Hidrazina (N,H.) (e) 32.048 0.393 0.33 1.6476 1.3834 1.195 48.22 259.52
Peróxido de hidrógeno (C,H,) (e) 34.016 0.303 0.2446 1.2703 1.0225 1.239 45.43 244.50
Metano (CH.) (e) 16.043 0.5099 0.3861 2.1377 1.6187 1.321 96.33 518.45
Metanol (CH.O) (e) 32.042 0.336 0.274 1.4086 1.1487 1.226 48.23 259.57
n-Octano (C,H ••) 114.224 0.3952 0.3778 1.6568 1.5839 1.046 13.53 72.82
Propano (C,H,) 44.094 0.3985 0.3535 1.6707 1.4820 1.127 35.05 188.64

!
í
---- _--
.•

°R2300
2150
2100
2200
2080
2020
2000
2040
1980
606 °R
Btu/lb
Btu/lb
T-R
703.35
688.90
674.49
761.
790.68
526.97v,
546.54
574.69
532.55
588.82
617.22
776.05
521.
717.83
504.71
510.26
102.34
112.67
116.12
105.78
28.59
27.17
650.4
281.4
87.27
85.20
601.
941.
212.1
876.4
39.64v,
1940
1920
1900
1880
1412.87
0.4518
1.13314
Btu/lb
85.97
422.59
438.83
390.40
499.17
477.09
488.12
428.00
444.26
395.74
660.12
0.70160
0.75042
0.71323
0.71886
0.70747
0.74030
310.09
0.66321
133.47
314.13
0.75536
0.78326
0.74540
0.76964
119.58
0.64159
1291.00
136.97
140.47
204.02
53.63
47.34
2.585
2.419
57.20
50.35
75.25
330.40
473.3
2.125
400.5
1.02244
702.0
1.02767
814.8
1.
0.3019
308.1
174.00
4.527
3.890
3.777
6.465
17.
18.514
0.98919
513.5
16.205
1.04288
1.09332
0.93205
1.03788
0.97732
4.819
141.
4.670
109.08
1.04779
1.16905
13.118
11.172
15.518
114.03
104.30
181.
1800
1840
1700
1740
1500
1600
1620
460.63
482.60
449.71
455.17
433.41
358.63
369.17
374.47
938.40
493.64
603.00
471.
417.20
385.08
406.45
411.
401.
560.59
645.78
631.
379.771780
1520
1580
746.88
732.331803
45
39
1050.12
515.82 700
0.72979
294.03
0.77880
814.06
931.39
0.73509
0.72438
0.67002
0.68942
0.69558
302.04
278.13
298.02
0.64902
0.65621
266.34
290.04
0.3363
0.77126
0.76019
0.76496
151.
143.98
123.04
306.06
274.20
147.50
161.
154.57
0.67665
126.51
129.99
282.09
158.12
109.21
22.30
21.
23.40
25.82
371.79
33.52
31.
24.58
94.30
65.38
256.6
30.12
44.57
42.01
4.130
35.41
350.98
37.44
380.18
355.12
61.10
80.96
91.
2.266
756.7
2.961
233.5
20.293
1.03282
2.765
375.98
3.667
359.28
367.61
334.50
342.73
326.32
70.07
338.61
346.85
6.251
318.18
322.24
88.62
1.01712
3.176
474.40
435.7
1.01172
3.410
0.99497
485.31
399.17
507.25
4.008
463.54
496.26
540.40
573.84
585.04
452.70
1.3184
431.16
367.6
562.66
4.258
188.54
441.
5.134
5.847
5.302
5.658
135.64
0.91788
6.045
8.890
6.924
64.70
1.00064
518.26
1.9956
0.95222
1.00623
1.7646
1.8756
1.4775
1.2469
0.92926
1.5662
0.97123
167.07
4.390
420.46
19.377
556.3
529.31
0.7087
388.60
11
160.37
336.8
5.476
0.92645
196.16
0.94026
384.39
153.87
0.89074
6.690
7.424
74.93
78.36
81.
8.569
95.53
90.751.6617
409.78
16.9324
9
0.96501
14.868
12.095
0.98331
12.593
14.253
7.168
124.47
119.16
9.226
7.691
71.
147.59
61.
86.82
65.00
99.69
82.83
50.34
75.29
55.86
58.78
71.
1680
466.12
363.891560
1640
1460
1480
60
82
09
48
.622
262.44
270.26
286.0627
76
02
68
53
0.68312
258.54
0.4858
0.4061
92.04
363.43
95.47
98.90
68.11
551. 77
52
0.92076
0.90908
4.974
0.88116
0.88439
0.85767
8.263
61.29
0.95868
0.94564
13.670
0.93756
0.94296
0.92362
0.90308
0.90609
0.91203
0.91497
0.88758
0.89387
0.85416
0.87462
7.971
1.3951 7.761
0.20959
0.08310
0.11047
68.30
95.24
90.95
1540
1820
1720 51
]6
3.446
3.806
91
83
73
0.93481
0.89697
0.90003
0.86456
0.87130
9.948
0.86113
0.86794
9.578
78.99
53.04
",
0.87791 u698.48
Btu/lb-
0.7913
7.149
6.573
5.051
2.005
2.801
1.3860
5.52;;
6.0J·;
2.514
4.193
4.607
0.5760
0.9182
1.5742
1.3593
1.2147
8.411
2.249
1.0590
521829.3u1.28268
20120h1.25769
Btu/lb-
0.60950
174.90
28974
110.88
102.12
0.80050
0.79628
0.80876
3280
5521
8837
0.82848
0.81280
0.84341
3000
4500
5000
6000
1.20129
0.57255
0.61793
146.34
0.55172
0.56235
240.6
215.33
0.60078
0.58233
0.59173
158.58
270.1
346.6
193.65
0.52890
0.62607
0.63395
0.78767
0.80466
0.79201
0.81680
0.83229
0.83975
0.82075
0.83604
9.102
9.834
0.6776
1.7800 6500
4000
0.54058
131.78
120.70
144.32
0.59945
0.51663
305.0
0.50369
396.6
10.336
10.743
0.82464
3.111
p.. 250.79
209.05
254.66
172.43
179.66
190.58
176.04
197.94
1239.86
1392.87
1702
165.26
168.83
216.53
244.05
231.
212.78
205.33
227.83
23'l.25
246.93
201.
235.43
243.08
194.25
186.93
183.29
1088. 29
1858.44
63 26
220.28
0.85062
0.84704 Apéndice B
7.13
6.31
Propiedades
129.9{)
2500
2400
2450
2250
2060
1960
1860
1760
1660
2750
2950
2850
2900
2700
2650
2600 del aire a bajas presiones (para 1 lb)
cf>

Reproducida de Keenan y Kaye, Gas Tables, con autorización de los autores y el editor, John Wiley.
cf>
TOR
7597.6
ii

6965.7
7385.3
7174.7
8026.8
6758.3
7811.4
8462.2
9575.8
9802.6
8682.1
72.616
72.175
56.536
55.831
71.
56.070
55.589
56.765
73.462
54.582
54.839
73.870
58.072
57.212
58.281
57.861
57.432
74.267
70.282
25219.4
69.771
28849.0
2.594
70.776
2.905
0.8637
5.010
1.6206
33771.6
1.4347
26422.4
1.1177
4.505
3.628
2407.3
4030.2
4235.8
2108.2
2256.6
2874.7
3534.7
4417.2
4600.9
4786.8
4056.8
5165.2
5748.4
5946.8
2716.4
3035.7
3199.4
3706.2
5552.0v,
56.305
55.093
;p
6349.1
6552.9
8243.8
9350.3
9126.2
8903.4
55.343
71.255
57.647ii1480
p,
48.947
2.057
24023.8
27632.5
32533.3
5.563
1.8276
3880.3 2122
37512.9
5827
3972
330039086.7
19330.1
54.051
51.
26840
36261.9
5285
35014.7
9692
2525
4799
6433
7875
7112
42553.0
43821.
3620
41287.9
40026.1
46367.3
3303
4363
10.351
12.820
1288.2
2800
1948.0
1396.8
3100
3500
3700
260029187.1
4200
3800
20488.-8
18182.4
73.045
56.990
2.3115297.6
22836.5
23780
52.9345466.9
6877.8
6160.1
6696.2
3.872
6516.1
7618.1
7245.3
7431.1
2.276
7060.9
8187.0
8572.3
722
5984.4
4.664
8.410
8379.0
1.0172
0.14833
0.4355
53.780
0.03385
0.05062
50.408
0.2051
0.12541
0.3252
66.327
0.5019
51.032
39070
67.557
0.6615
54.319
0.02738
0.02196
0.013705
0.04153
0.06131
77000
49.329
50.058
50820
30340
52.343
44500
50.750
39838
52.641
0.7568
16756
68.139
53.225
0.017440
89050
0.17474
65.676
13393
93.08
53.82
41.52
30071.7
69.245
3.249
31299.9
1.2677
4
6147.0
2560.5
3365.7
5357.6
4974.9 2759
20.06
8729
2313
3017
38767.7
45092.9
47644.6
1515.9
48924.7
15.981
1189
1646.5
1790.1
1098.6
1015.6
3400
2700
3000
3200
3600
4000
21657.92900
17046.9
34390
0.37696.871
820
Termodinámica
5637.7
5810.3
6337.4
7806.4
4800.1
7996.2
0.14471
21120
53.503
52.038
12004
0.10560
10777
70.42
1100 14282
44310
2963.8
4318.6
726
082
5129.9
939.9
0.2558
806.7
0.2048
0.4305
0.3303
0.3766
0.2904
0.6533
O.
870.4
5.646
2.705
1.1865
0.7548
1.6311
046
0.8749
0.2258
3.229
1.3887
1.9229
0.07386
66830
49.698
0.2399
66.953
68.702
0.5769
18796
14968
0.08852
32.32
25.36
2200
1600
1620
4100
3900
0.2797
58190 748.1
56692344
4841
13344.7
52740
37080
30910
21200
6.834
25660
87080
73930
11633
17445
36227.9
31982.8
41965.2
46314.0
44860.6
210022352.7
200021018.7
2500
2400
230025056.3
1560
1580
1680
1700
1660
1900
1500
1540
1520
1800
1640
1460
1420
1380
1440
2713.3
2080.4
2452.2
2201.
3409.4
3123.7
2847.7
3704.0
4161.
4637.9
4007.2
3265.4
2984.4
4477.3
1961.
1621.
1732.1
3555.6
408 52162.0
6082
3828
7593
9425
4
1391.
3007
1813.1
5380
530068479.1
59.477
58.485
59.283
4300
4600
76.119
27801.2
26424.0
15576.7
16590.2
19697.8
14328.
14576.0
15074.7
15325.3
16845.5
17101.4
18391.
16335.7
14080.8
14824.9
13834.5
13589.1
13101.
8
7
9
1057.9
15200 2460
47.289
47.728
163.89
320.0
46.353
48.148
46.832
438.7
797.0
48.555
25.43
21.33
27.72
23.30
32.86
35.74
45.74
30.1969676.5
38.8:1
79.20
53.70
58.13
166170
120480
196920
103360
O
5
'0.98374964.2
.1
2581.62550
6.170
30581.2
34806.6
40523.6
37654.7
43411.
49231.4
2325.6
3854.6
1512.4
1845.633391.5
4933 60.229
60.593
58.689
59.088
58.889
60.412
59.858
59.
60.044
4400
4700
5000
5100
4500
4900
9.219
7.560
8.35360.772
79.793
78.398
78.994
77.135
78.091
75.404
75.765
76.803
75.033
78.698
74.655
79.284
76.464
77.
79.569
23699.0
15829.0
16081.9
5 114.84
594.5
230.5
62.87
42.16
50695.1
47771.0
4800668
67.95
49.58
73.39 53632.1
58059.7
57954.0
54070.6
52780.5
55363.0
58992.5
66984.0
234900
141090 64000.0
55105.1
62511.3
65490.9
59541.1
56581.
779 O 251800
10769.2
10360.5
10974.8
11388.9
11181.4
61.
11597.2
12227.3
62.624
12651.6
12864.8
10564.5
60.949
61.124
11806.4
13725.4
63.403
15924.7
62.939
62.138
63.555
63.250
61.
62.464
63.095
64.292
64.999
639
974
808
56657.5
50207.5
51492.7
9755.0
8962.1
9555.3
9955.9
14816.9
12016.5
62.302
12439.0
13293.7
62.783
13078.9
469
298
61024.9
10157.7
9158.8
8766.6
13509.2
9356.5281900
450.4
599.3
694.3
557.5
644.8
319
483.2
518.9
420.
365.9
299.0
230.3
12441O
218100
102250
162480
139640
188530
392.0
342.0
262.2
279.97
168.21
119640
245.6 607
Dióxido
p, de carbono a bajas presiones (por Ibmol)
780
e, Gas Tables, con autorización de los autores y el editor, John Wiley.
¡¡
$rE¡¡
-
608 TOR
5709.4
5427.4
5146.4
6419.0
2081.9
5850.7
7862.9
8156.1
8450.8
9344.6
9494.8
2359.9
4866.0
6704.9
6848.4
2916.0
3194.0
4307.4
3333.0
5568.2
5286.8
6134.2
6276.4
6561.7
3611.2
3750.3
3889.5
3055.0
4168.0
4726.2
5992
3729.5
2220.9
2776.9
5006.1
2498.8
2637.9
3472.1
4028.7
4446.9
4586.5 v,
877i.
h8075.4
p,
11794.7
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13.476
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carbono a bajas presiones (por Ibmol) Apéndice B

Reproducida de Keenan y Kaye, Gas Tables, con autorización de los autores y el editor, John Wiley.
h
¡¡~
2710.2
2978.1
4214.3
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4900
5000
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43.514
44.748
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37.028
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35.659
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35.520
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15619.3
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36.560
32.829
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33.031
31.194
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31.232
32.407
34.134
32.187
35.087
1467.7
164.89
125.25
132.55
148.07
33.603
33.784
33.226
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35.235
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34.466
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118.26
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39.264
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a bajas presiones (por Ibmol) 609
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4.461
3163
41.695
0.3003
0.4263
0.5862
6198
43.337
44.034
1556.4
4379.4
4480.8
4889.3
3.106
5.729
6.206
8.410
3.411
6.711
9.043
3975.7
4076.3
3275.2
3374.9
4331 2.148
0.16458
2181.3
2280.6
0.5017
0.2485
0.3594
7570
0.7852
2379.9
2578.6
5Q95.1
1471.2
1186.7
7.246
1318.7
1855.6
7.812
3474.8
2.077
1.8645
1.6679
1486.2
1684.8
1.1676
1.0083
1.0281
1972.8
1.4868
1.3200
51.653
51.413
51.771
50.6515000
4000
4500
3500
3600
5380
1560
1460
1420
1600
1520
3800
1620
1440
1640
35.46
68.02
76.69
32.14
43.5:1
54.07
119.37
110.02
664.6
24.27
6143.4
875.3
101.
114.61
496.4
575.6
105.58
31.
26.59
5720.1
6250.1
29.45
842.1
18.681
12.533
5302.2
5615.2
6464.5
568.0
2
5825.4
523.4
10324.0
9615.5
10443.2
244.1
9033.4
464.6
7226.7
446.9
221.
9498.
59.442
207.8
7447.6
48.865
7670.1
50.241
49.193
50.380
50.516
502.8
49.955
20.98
47.977
11.939
19.774
17.530
15.479
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534 727
6680.4
81.
93.07
85.41
097
89.17
97.11
42.46
56.87
78.26
74.87
32.80
51.
34.57
59.60
46.90
8.738
6.789
38.36
49.25
44.64
7
3·~8
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52.444
42.962
52.867
3684
2.307
0.9003
1250.4
1127.2
1071.6
5.281
1019.8
3989
0.2035
0.6805
1648.3
1392.2
1747.85
0.13130
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430.1 60.54
6357.2
6037.0
5931.
5510.5
617.5
971.0
291
882.4
5198.5
672.8
734.6
5406.2
804.1
6788.9
6897.8
887
702.8
592.0 O
09
9
6572.3
545.1
8
3100
3000 4
925.2
644.5
3200
768.4
Nitrógeno
54.385.
<1>
3300
4>
2500
2600
2700
2800
2200
2300
2100
3900
3400
2900
2400
4 59
772298
64
29
8
70
6141
8504
320.5
214.4
201.
54.208
53.656
54.729
54.559
54.896
30150.5
23386.0
62.123
32752.1
63.73563
O260.8
228.
a bajas presiones (por Ibmol) Apéndice B
Reproducida de Keenan y Kaye, Gas Tables, con autorización de los autores y el editor, John Wiley.
T"R
612 ;;
62:l1.
11441.
4282
6066
4122.0
6895
6728
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7230
5738
5902
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3482.7
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10714.5
11258.7
5087.8
5412
7568.4
7062.9
11076.6
8422.4
9116.4
9291.4
9998.0
8078
50.693
8942.0
51.
9467.1
51.478
52.768
52.
52.070
52
50
8768.2
9643.4
62.526
63.557
62
8844.6
12174
16879
1600:l
14296.6
13467.
1330:1.3
18676
49.665
49.298
15141.9
13140
49.48:1
50.019
48.721
12977
46
47.219
45.415
45.124
47.89:1
44.508
22680
45.079
48.316
15.507
19.536
22
11.219
U.:127
31690
11217
1:l.220
14585
16.766
61.426
61.043
60
20527
60.248
57.605
30452
1035·l.9
3642.3
6:\96
2686.0
3004.4
3802.0
4764.7
7908.2
5250.0
8595.0
51.925
8250.4
50.528
51.630
9820.4
52.212
51.777
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64.528
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18.106
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6.627
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40.439
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4309.0
0.7381
7851
4185.3
5831.6
2249.8
0.3237
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5701.7
89.15
325·~5.
1580
1380
611
4:37.7
393
21472.2
57.119
56
56.411
59.414
19595
25364.8
24375
27373.0
2:1396.6
26:l64.0
34.67
7
8.680
28.14
37.10
3816.8
7987
2.120
2979
9.469
5
4808
44.182
2848.8
32.37
4682.7
4672
3191.9
7029
4557.6
3210
3330.7
3876
0.6337
1851.7
0.5412
5572.4
l:l89.0
4934.2
4.082
6.038
2331
2728.8
0.3870
41.889
2608.9
0.4592
3.314
1.4696
1.1305
1
0.7217
1.6662
:15,n
1719
1489.6
5187.8
5:115.3
1599.4
5H:l.6
1996.3
0.]4479
1771
3
42.320
2489.1
1.2914
59.61
40.7:l
49.15
92
72.69
33.89
23.78
31~95
2500
14.3947'70
7437.4
3
210
4.353
887
5.OO~
450
665
:180
6
8801
19
16.95:1
10.481
:l900
2100
2900
12.263
3:l00
1620
1740
2000
1520
1540
2800
5:l80
1640
1800
1820
1600
1960
1560
1160
1920
1480
18·10
1860
1780
1980
6357
6757.5
6623.5
1440
6490.0
7027.5
6892.2
6·l8.1
7163.5
488
631
903
994.8
854
876.7
7300.1
·1I49
827'L
577
'~94
354
462.1
545
8¡¡5.1
82:1.8
171
729.6
8·1I5
7575
7713
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8.988
6.668
221
O.
0.6443
876
7.730
1.7543
945
491
984
67
673
976
683
4
9
515
I:l2
5 '7
319
39.68
650
617
514
499:1
12·l9:l.81U.83
8700.9
8968.
50.191
50.360
46150
38010
21.
45.696
46.235
46.741
44.821
26690
46.492
48.106
48.520
10.313
12.187
12756
19436
16780
58.077
58.980
58.5:l5
24.39
26
36949
3939.3
42.728
6317
5696
2526
4062.1
2010.8
43.841
2130.2
43.487
3451.
5153
3573
4250
0.8548
2741
8805
3089.4
9914
2969.1
1296.6
6093.0
2156
0.11515
0.17982
2369.4
0.2209
0.2686
0.9853
1211.
5962.0
5060.8
0.06975
1891.3
0.09033
1133.3
1061.
3163.8
4926.196
20.04
2400
:1200
:1800
2200
2300
2700
:l000
3100
3700
4000
4500
5000
1680
1720
1880
1900
1500
3400
3500
1700
1760
1660
1940
:1600
6224.8
1420
325
933.4
687.6
516
8557
9133.8
9279.4
9425.77992.5
7852.7
48.916
45.970133.73
05
O
7
43.117
41.435
<P 2600
40.952 21
89 7
3
9760
796
976
2
1
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46
2
8
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9
47
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28:l86
2713
7935
13305
6
2:l839.
11025
129H
4
6354.3
4720
6697
1
22735.4
27231.2
O
5633
392·~0
2
9
26088.
5
9368
6
13685.7
1484·1.3
17032.4
17235
13115.6
12738.8
12926.8
16628
31918.2
3276
15828.7
1:1877.
15·l33.0
15630.6
lH94.9
18466.9
1835
12178.8
3940
1218.4
12364.8
11993.4
583:18
16027.6
17439.
3125.20
217.1
228
206
195
157.71
1--
119.54
149.33
126.45
2·l0
396.0
632
185
:l10.0
101
984.8
502
53.037
53.428
53.808
51.
48.34
53.168
89.
58.53
56.
55.991
68
67.
66
275.1
261.
249.4 O6
21645.7
373.2
336.4
29552.8
30nO.
37998.9
20570.6
24957
36765
40489
46835
14261.
16227.2
14455.4
14069.2
16427.5
1499.4
12551.
33116.0
H:123.
5:1327.4
14649.5
15039
19510.8
16830
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11808.8
106.67
100.69
112.93
141.35
166.51
791.
94.99
45.29O
43
55
36
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58
4
06
2
8
6
5:lO7
53.299
53.932
53.682
79
84.43
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54.055
54.94
62.30
66.28
70.47
42.41
55.777
289.1
319.7
304. 371
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3
5
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7
1 I12016.3
11701.2
8 53
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53.556 2
9
4
8 12815
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11544.7
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47654.7
43398.0
10620.2
89600
54.418
54.177
54.770
55.3:19
55.44'1
56.203
12333.9
11079.4
10772
11858.4
10167
10017.6
37899.5
27530
10925.6
11233.8
10468.6
10317.6
54970
54.298
54.653
54.5356
55.884
55.559
55.668
54.999
55.226
56.097
54.886
55.113
142.83
7 1:10.78
105.43
156.20
149.36
11001
196.47
3 226.4
237.6
215.9
171.03
119.89
136.66
205.9
179
163
187.53
45
04 Apéndice B
p,
p,14pO
Vapor de agua a bajas presiones (por Ibmol)
11624.8

Reproducida de Keenan y Kaye, Gas Tables, con autorización de los autores y el editor, John Wiley.
TOR
v,
q,
v,
TOR ii
ti
;.
ph20239.6
Termodinámica
4050.4
23456.6
26991.
3746.8
3768.0
3486.7
3627.4
12143.8
4901.
23018.5
22581.
24335.5
25217.8
14580.3
6340.3
5761.7
14087.2
5330.2
4759.3
13434.3
19550.1
17419.8
15574.0
18694.1
16998.0
18268.
8112.
53.422
58.048
58.869
59.026
58.710
59.180
53.312
58.384
57.152
58.548
49.329
20842.8
10250.6
26102.9
6050.5
2784.7
10875.6
3909.2
5187.0
20410.6
21709.8
4333.5
4475.2
12786.4
4617.5
5473.8
5617.5
12625.3
11984.1
13109.4
5044.2
10095.0
19979.7
15740.5
6778.3
16577
17843.2
14251.
5905.7
14415.7
11824.6
12464.3
10718.7
11506.8
13760.3
11190.7
11348.6
13597.0
13271.7
19121.4
16157.9
14910.3
15241.
15407.6
9631.
9785.5
60.734
8715.0
8563.4
8412.5
7515.6
7812.9
7962.3
52.858
51.
7367.2
59.481
53.088
53.201
60.196
52.257
52.741
52.132
58.217
50.624
50.919
52.006
50.773
50.319
59.331
52.973
59.916
52.380
59.628
60.469
56.494
56.771
56.964
50.473
57.338
56.574
57.520 ,21.
3000
2680.4
55.747
47.777
11888.3
56.002
47.558
172.25
14156.8
B486.1
13176.4
13501.
54.750
12208.2
108.20
119.01
131.
2522
6970.3
7084.7
671.2.5
1.998
140.22
1268.3
6856.3
7430.7
1460.4
2950
2800
2850
3300
3200
221-15.3
10406.2
14745.3
6631.7
6195.2
6485.9
6925.1
2644.9
3065.2
3205.7
3346.2
4191. 1480
44.591
49.839
48.783
48.591
34.20
26.80
25.17
23.61
50.002
22.14
56.333
4447.6
50.162
20.723
4553.0
4342.6
49.50244.65
39.43
23.51
32.94
37.10
47.58
453.7
71.28
31.
54.20
316.2
46'.318
280.1
269.2
222.1
3924.8
4028.8
3000.4
3102.3
3306.8
55.573
45.815
46.091
46.861
3614.4
56.086
36.28
56.169
14816.5
10813.3
10938.6
14.685
10.916
4658.9
19.385
55.
12529.8
10438.4
10563.1
4133.3
1990.3
10280
44.249
10066.6
10314.1
10190.2
47.101
8847.2
8014.6
54.654
54.844
55.032
8369.1
55.124
55.215
55.306
38.45
43.10
16149.4
16822.4
11570.2
11316.7
13.662
1I443.4
10.101
11064.3
56.252
18.1I6
10688.0
12852.3
54.057
54.260
8727.3
178.46
166.33
150.00
145.01
155.21
15481.
151-18.
15814.8
13828.7
53.745
54.160 7
5628.4
6.134
45.60
111.66
4765.0
4978.9
5410.6
43.890
2731
2336
9697.1
1.3469
4279
0.6654
7096
1.0457
5131
4644
4218
3514
1750.2
4.233
1018.6
1096.8
1121.
0.4754
1.3738
1.7709
1.5632
1.2017
3845
13923.6
2925.0
11033.1
12303.9
12947.8
10562.4
11665.6
15075.8
9477.6
8262.1
8866.6
9018.8
9171.
9939.9
7219.7
7664.1
9324.1
7072.1
57.875
52.622
52.502
57.699 O
17160.2
7199.4
17499.
18179.3
18863.1
6292.2
115.27
101.66
5738.1
7.932
9.334
8.611
126.98
122.91
3223
2963
6341
4.660
3.124
6404.1
195·l9.5
1190.6
1265.3
104.87
7.294
1346.3
135.62
1635.4
1914.6
2250
2700
2750
2500
2150
2550
2000
2020
2400
2060
3100
3400
2100
2040
1920
1620
1700
1860
1580
1600
1740
1840
1780
2900
1460
1880
1520
1720
1820
1980
1500
1660
48.968
2594.7
2797.1
49.672
45.528
49.150
2393.0
2191.4
2493.8
2695.6
2898.6
46..
3717.5
4237.6
55.918
291.
2292.2
239.6
55.660
44.917
230.6
46.357
206.2
47.333
3820.9
48.195
48.396
55.396
55.485
3511.6
40.73
32.21
28.52
30.32
16.909
56.414
11.779
7663.0
1890.3
214.0
7779.6
2090.9
249.0
8607.5
3204.2
7896.8
8250.7
258.8
45.229
8488.2
3408.9
47.989
12.69434.94
877
66.46
41.94
26.23
95.6122
08
·194.9
184.33
260.2
235.7
98.58
208.76
217.45
620.
226.42
845.3
82.33
062
203
415.3
62.02
944.7
329.5
511.6
192.21
88.66
651.
562.5
539.1
50.76
892.8
379.5
746
613
76.56
590.5
162.26
142.35
108.40
148.76
343.6
690.9
636.9
809.9
488.4
358.4
586.4
342
176.73
169.37
130.21
371.0
11190.4
15.768
54.459
53.851
8132.5
54.557
53.955
198.80
191.
184.93
160.66
16485.5
53.639
54.939
903083:J
9
89.61
.1
6516.6
5086.2
5519.4
4871.9
6.695
9209.6
9574.5
9820.0
6629.4
7546.5
50.91
5194.1
5301.
0.5646
0.7785
0.9050
2.515
9331.
5.118
5.609
9452.7
2167.0
3.836
2014.4
7314.8
6180.4
6069.2
5848.1
7982
0.3967
1530.6
2.246
2.807
3.467
1675.3
1057.8
1434.6
5692
1876.0
53.5312650
2600
2080
2200
2450
2350
2300
1940
1960
1560
1900
1640
1540
1680
1800
1760
8967.6
9088.3 4
6 14
200.35
29.35
801.1
685.5
943.7
760.1
286.7
426.4
466.6
390.5
57.94
479
998.9
721.2
315.3
346.2
103.43
113.55
136.18
124.45
875.2
407.9
536.3
155.39
118.90
19.06
66.37
98.64
613
53.75
56.71
81.24
94.05
69.86
73.51
85.35
77
63.01
59.80
48.19
9943.0
5958.53
5
71
445.9
303.6
.'>4.360
Productos
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p, 6
OO
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9 .21276.O
748.5
de combustión - 400% aire estequiométrico (por Ibmol) 613
Reproducida de Keenan y Kaye, Gas Tables, con autorización de los autores y el editor, John Wiley.
TOR

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1780
1760
1820
18<l0
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9933.8
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8683.6
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8222.1
9776.2
52.724
8375.5
53.316
53.430
50.370
52.601
53.200
53.543
52.222
61.
25805.6
14512.5
24895.3
27636.4
14176.1
13507.0
13340.3
13174.6
12843.8
11696.8
11372.8
32266.2
23536.7
4082.7
12186.2
2801.4
12022.7
ll050.2
2660.3
10250.7
14850.4
4947.7
5092.6
6264.9
15189.3
4226.3
15359.3
17769.3
21293.8
5676.3
5383.7
5237.9
4802.8
6561.
6710.4
15700.3
15871.
16902.5
3796.3
4514.
19962.0
4370.1
16HI.
19080.7
3226.8
62.333
7310.5
8838.6
9305.3
9461.
7461.
9119.3
7159.8
8993.7
50.528
50.83:¡
50.983
51.128
7612.7
52.093
51.692
53.654
52.845
52.477
52.351
53
214.81660
1700
1580
1600
1640
1620
1560
Productos
2518.3
46.070
e,.
;¡,
14681.4
29479.9
14008.4
22636.3
10410.0
14344.
23988.5
23086.0
21740.3
22187.5
20404.6
20848.4
6ll7.5
6413.
6859.8
5823.1
10569.3
60.218
56.694
58.974
56.978
10571.
10958.1
50.210
56.777
57.377
14898.0
15241.3
15585.8
16279.2
59.138
58.808
15932.0
13876.0
147.80
ll740.7
50.047
59.459
24.68
2621.
2708.5
4409.6
3452.4
46.851
26.34
20.170
46.300
2007.0
4194.7
43.10
4734.5
12.126
31.
2415.7
13.089
19450.8
108.35
20884.4
4284
18739.1
17678.4
9805.5
2946
55.000
1271.2
1476.8
51.
1007.2
1089.8
4953.4
5507.7
1411.7
7470.5
7590.1
2326
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4317
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7233.0
7ll5.1
7.437
1731.
7351.
1858.7
8.101
1032.4
5844.8
2900
2350
2850
3200
3100
3600
3400
22.528
28.56
250.4
86.36
32.31
352.0
H.42
89.15
387.5
39.18
206.63
58.114
60.507319.2
79.86
789.4
353.9
660.8
324.2
16.152
310.5
819.8
775.8
734.9
444.5
387.0
424.2
370.0
513.2
10314.7
177.46
57.177
58.639
8682.2
57.933
8559.1
14215.3
8805.6
8192.9
242.0
8071.
10699.6
59.921
10442.7
59.615
48.4ll
2827.3
2930.9
153.22
12533.6
12867.1
59.300
3034.8
16627.1
13201.
58.467
57.562
12201.
164.79
14556.0
58.292
49.360
48.994
48.804
49.711
ll217.6
142.63
56.612
ll609.4
ll872.1
23.10
2723.9
44.883
3980.9
ll087.8
3557.6
3662.8
4517.3
3768.4
4625.7
36.05
3347.9
46.600
ll347.9
47.094
29.94
45.500
45.791
28.09
2108.9
2313.3
21.
4087.6
4301.8
40.64
38.29
48.207
33.90
47.996
47.781
15.189
3138.9
47.330
3'243.0
22ll.0
45.198
44.553
10.366
ll.221
14.109
16.333
18.822 063
O
87
115.87
9932.421
9
I
24521.3
56.189
22330.8
124.03
55.837
104.82
56.275
55.657
128.40
55.566
101.
17327.0
56.360
55.473
54.705
9428.1
55.097
54.605
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2259
18030.9
16976.6
54.805
45.68
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4843.7
54.298
54.194
54.088
54.17
18.38
2517
5284.9
2.243
2967
5173.9
2.516
2730
5731.
54.504
54.401
13673.8
15019.8
13840.5
12350.0
12514.2
12678.6
11859.6
10729.3
11534.7
13009.0
10889.5
3939.4
15529.7
3084.8
3511.2
3653.7
18642.1
4658.6
3368.9
18204.9
3774.9
19520.7
5529.9
5969.9
7764.3
52.965
51.
50.6821708.2
6.234
5.690
6.815
6997.4
2154.5
4.273
6763.4
5063.6
3.136
9.564
6647.1
3233
5619.6
6185.9
1508.7
1322.6
1614.9
3.487
8.808
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3532
6531.
5772
5194
1.3620
6071.
6415.8
1.3350
8138
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1999.34O86
ll65.11
3871
4692
7223
1.
1.992
2800
2550
1520
2450
2950
2300
2650
2600
2700
2400
232.5
223.5
105163900
1540
1500
1480
202.71
26.88
30.36
288.9
20.103
240.2
230.4
220.8
68.57
260.9
44.76
36.71
63.68
467.4
6ll.3
4791
17.542
47.558
44.208
2943.0 177.82
170.09
194.13
123.27
117.53
59.21
666.6
41.
725.9
55.12
51.
185.82
162.55
155.46
135.43
129.23
929.8
112.01
13.ll4
857.2
285.3
961
627.1
338.6
297.6
867.2
973.3
918.2
488.9
273
539.0
466.0
415
595.9
555
566.6
084
405.1
10828.8
10059.5
10186.5
56.444
8436.7
8314.6
57.749
7950.4
48.610
56.529
170.97
8929.4
191.35
198.81
49.179
49.537
11478.5
184.25
158.88
13538.1
46.340 91.
63.88
96.69
83.10
78.92
87.44
67.40
9.770
57.26
595
57621
55.380
55.926
112.04
55.748
55.287
9302.6
9553.6
55.192
56.015
56.102
137.68
132.94
54.903
9679.5
9177.9
43.845
5.1833
7
543
5395.8
0.6539
9222
3.864
2.814
4255
1.1893
6441
1096.4
1.5526
1.0330
0.3878
7829.
11211.4
Pr
85
36
25.321
92.03
98.16
425.9
2ll.6
95.04
73.96
5ll.9
559.8
1460
9053.5
49.881
1905.7148.54
101.
106.70
141.
696.2
828
74.91
71.08
0.8925
0.7663
0.5539
0.4655
60.49
2100
2080
2150
2200
2020
59.769,
2000
2040
1980
1920
1940
1900 9 O
4
97
8
9
1
2
9 273
60252. de
3874.4
53.981
61.590
.6O
262.5
53.874
53.764 combustión
1880- 200% aire estequiométrico (por Ibmol) Apéndice B
:1000
2750
2500
2250
2060
1960
rr

Reproducida de Keenan
614 y Kaye, Gas Tables, con autorización de los autores y el editor, John Wiley.
Termodinámica
64.51
120.86
-169293
-101
SO
55.66
-54270
-47560
+14238
-36425
+87453
-10105
+68476
+10728
+29408
+70195
+93780-72
-19746
-122971
74.12
111.82
101.64
+132480
59.298
-127705
56.8
-32210
+22572
+41022
+61380
-3719022158
19940
-44676
+38880
-58554
-86544
-14391
67.4 +3186
-80802
-8784
+0685232
-7047
8545
+37'294
-45374
-69642
-27083
-169668
-59010
+22045
-14148
-102042
-129134
-49032
-21862
+14953
+127458
46.0317856
15728
+7452
+99711
+3762
-98344
-75186
-71
-7380
9063
+97542
+35676
+89987
+107206
-10403618216
16096
6489540
-f756
+55780
+52920
-89676
+16978
O
EntalpiaO&109370
514
O 45.767
1.359
85.50
49.15
47.21
57.080
45.106
44.48
57.03
77.9257.86
16.716
29.756
49.004
4.988
43.88
27.392
0.583
57.343
52.396
38.468
30.3
55.99
54.85
50.339
21.2
38.4
51.061
mol., M•34.016
48.004
64.34 28.016
32
17.032
0.0005488
114.224
100.198
28.01
46.068
32.042
28.052
30.008
50.49
17.008
18.016
16.042
16 -98432
1.008 -107532
26.036
78.108
44.010
44.094
30.068
58.120
34.086
12.01
48
52.038
48.008
64.07
32,048 +0453
-102640
-96530
-80712
+20934
-119448 615
aGfohfg y función de Gibbs de formación; entalpia absoluta
H,O,(g)-J
vaporización
provienen
clon (§13.29),
de a aGf
25°C.
Rossini [01,0.21,
(Btu/lbmol)
muchos= de
función
los cuales
de Gibbs
han sido
de formación
actualizados
(§13.33),
según sO(Btu/lbmol·oR)
JANAF[0221 q ue también
= entropía
es
I~.fuente de las Iluevas adiciones; se designan con -J. Se tiene que (Btu/lbmol) = entalpia
absoluta, cada una según el estado normal de 1 atm y 25°C (o bien, 77°F); ii¡1g (Btu/lbmol) = entalpia de
&1fo de forma-
Vea también en la tabla 111, pág. 156, otros valores de la entropla. Los datos originales de esta tabla
Masa

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