Determine los datos de equilibrio

Sistema Tb(°C) A B C Parametros de Wilson (Tablas)

Metanol 64.7 8.08097 1582.271 239.726 A12(cal/mol) A21(cal/mol)
Benceno 80.1 6.87987 1196.76 219.161 1734.42 183.04

P(atm) 1
R 1.98721

T(°C) x1 x2 Ps1(mmHg) Ps2(mmHg) D12 D21

58.846336 0.3 0.7 604.663645 375.916605 0.15820877113 0.345130407825
 MODELO DE WILSON
arametros de Wilson (Tablas)
∆_12=(𝑉_2^𝐿)/(𝑉_1^𝐿 ) exp⁡(−𝐴_12/𝑅𝑇)
∆_21=(𝑉_1^𝐿)/(𝑉_2^𝐿 ) exp⁡(−𝐴_21/𝑅𝑇
VL1(cm3/mol) VL2(cm3/mol)
40.73 89.41
ln⁡(𝛾_1 )=−ln⁡(𝑥_1+𝑥_2 ∆_12 )+𝑥_2 (∆_12/(𝑥_1+𝑥_2 ∆_12 )−∆_21/(𝑥_

ln⁡(𝛾_2 )=−ln⁡(𝑥_2+𝑥_1 ∆_21 )−𝑥_1 (∆_12/(𝑥_1+𝑥_2 ∆_12 )−∆_21/(𝑥

y1 y2 K1 K2 y1 y2 åyi
2.36019150850654 1.261158879181 1.8777921 0.62380337 0.56333763 0.43666236 1.000
MODELO DE WILSON

_1^𝐿)/(𝑉_2^𝐿 ) exp⁡(−𝐴_21/𝑅𝑇)

12/(𝑥_1+𝑥_2 ∆_12 )−∆_21/(𝑥_2+𝑥_1 ∆_21 ))

_12/(𝑥_1+𝑥_2 ∆_12 )−∆_21/(𝑥_2+𝑥_1 ∆_21 ))