Equilibrio líquido-vapor 105

T (°C) x y 100
100 0.001 0
95
91.7 0.01 0.253
86.6 0.02 0.425 90
75.7 0.05 0.624 85
66.6 0.1 0.755
80
63.4 0.15 0.798

T °C
75
62.2 0.2 0.815
61 0.3 0.83 70
60.4 0.4 0.839 65
60 0.5 0.849
60
59.5 0.6 0.859
58.9 0.7 0.874 55
58.2 0.8 0.898 50
57.5 0.9 0.935 0.0 0.1 0.2 0.3
57 0.95 0.963
56.5 1 1
1
Referencia
x y 0.9

0 0 0.8
0.1 0.1
0.7
0.2 0.2
0.3 0.3 0.6
y* acetona

0.4 0.4
0.5
0.5 0.5
0.6 0.6 0.4
0.7 0.7 0.3
0.8 0.8
0.9 0.9 0.2

1 1 0.1

0
Línea que choca 0 0.1 0.2 0.3
x y
0.4 0
0.4 75
0.4 75 PM acetona 58.08
0 75 PM agua 18.01

T (K) T (°C) x y DeltaH sln Cp L sln PM mezcla líquida

373 100 0.001 0 0 4.187 18.0224338657886
364.7 91.7 0.01 0.253 4.179 18.1351160641686
359.6 86.6 0.02 0.425 -188.4 4.162 18.2619826601907
348.7 75.7 0.05 0.624 -447.3 4.124 18.6534608971673
339.6 66.6 0.1 0.755 -668.7 4.02 19.3446045161171
336.4 63.4 0.15 0.798 -770 3.894 20.088934981131
335.2 62.2 0.2 0.815 -786 3.81 20.89283745456
334 61 0.3 0.83 -719 3.559 22.7104539829349
333.4 60.4 0.4 0.839 -509 3.35 24.8744601921431
333 60 0.5 0.849 -350.1 3.14 27.4943041135497
332.5 59.5 0.6 0.859 -252.6 2.931 30.730971267407
331.9 58.9 0.7 0.874 2.763 34.8313675868269
331.2 58.2 0.8 0.898 2.554 40.1944666461728
330.5 57.5 0.9 0.935 2.387 47.5096879683881
330 57 0.95 0.963 2.303 52.2657606115872
329.5 56.5 1 1 58.08

T (°C) Cp A kJ/kg °C lamda A kJ/kg

20 2.22 1013
37.8 2.26 976
65.6 2.34 917
93.3 2.43 863
100 850
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x, y* acetona

2.45
f(x) = 9.277419445
2.4 R² = 0.9998534124
2.35
2.3
2.25
2.2
2.15
2.1
10 20 30

1050

1000 f(x) = 0.0016

R² = 0.99993
950
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
900
x acetona
850

800
Cp L Agua kJ/kg °C 1.884
lamba Agua kJ/kg 2260 T ref 15 750
10 20 30

PM mezcla vapor h líquido H vapor Cp L Acetona Lamda Acetona kJ/kg

18.01 7545.993059606 43586.7214 2.4491 850.38
21.8183319987427 6949.635807949 47805.587810985 2.41984001 866.285373
25.4814720982211 6393.751800626 50674.499417197 2.40247604 876.174732
31.6244612459911 5376.064266412 53816.582077031 2.36693441 897.607293
37.5899364469592 4510.469656309 55851.906360856 2.33890004 915.809932
40.0710691867267 4189.548232568 56524.626636719 2.32939604 922.277772
41.1447452006946 4165.226405657 56794.231436107 2.32587956 924.712188
42.1410448031778 4211.416849241 57029.301840522 2.322389 927.1515
42.7623259135769 4524.098275278 57173.917971833 2.32065344 928.372992
43.474481277875 4829.826894993 57341.68477756 2.3195 929.188
44.2107585544637 5106.712368694 57507.104689499 2.31806225 930.207525
45.3631538821154 5668.481143038 57759.343574125 2.31634289 931.432077
47.3373839329434 5974.618066794 58169.919050794 2.31434516 932.862268
50.741869213735 6520.823447881 58812.870401413 2.31235625 934.294125
53.6624840516319 6860.978661244 59300.667610339 2.310941 935.3179
58.08 0 59949.48080418 2.30953025 936.342525
 Regresión cpL acetona
2.45
f(x) = 9.2774194451378E-06 x² + 0.00182745939191244 x + 2.17908491062433
2.4 R² = 0.999853412481328
2.35
2.3
2.25
2.2
2.15
2.1
10 20 30 40 50 60 70 80 90 100 110

Regresión lamda acetona

1050

1000 f(x) = 0.00166284930371838 x² − 2.24215888696626 x + 1057.55827633787

R² = 0.999937722941867
950

900

850

800

750
10 20 30 40 50 60 70 80 90 100 110

60000

50000

40000
 60000

50000

40000

h kJ/kmol
30000

20000

10000

0
0 0.2 0.4 0.6 0.8 1 1.2

x, y