C interpolada 9.

34526757361935

R1 0.34044
0.00769127644369472 R 2 0.3438 m
R3 0.35512
Promedio 0.3465 A*s

Concentración Cd Absorbancia 228,8

(μg/L) nm
xi-x promedio
4.4 0.05382 20.55017
4.4 0.05079 20.55017
4.4 0.05989 20.55017
5.4 0.10805 11.86978
5.4 0.10740 11.86978
5.4 0.10899 11.86978
7.6 0.23431 1.61113
7.6 0.24418 1.61113
7.6 0.25584 1.61113
9.8 0.33292 0.82201
9.8 0.35726 0.82201
9.8 0.38141 0.82201
12.0 0.47629 9.50240
12.0 0.51888 9.50240
12.0 0.52315 9.50240
14.1 0.60945 27.65231
14.1 0.64375 27.65231
14.1 0.67210 27.65231
xi-x promedio
PROMEDIOS 8.88513 0.31880
suma 216.02343
y0-yprome 0.02765
s y/x 0.01931014278729

Pendiente Intercepto
0.06008923535516 -0.21509664935484

n 18
Niveles (k) 6
Replicas ( r) 3

PREPARACIÓN DE CALIBRAN
 SOLUCIÓN INTERMEDIA

MRC (a) 10 mg/g

U 0.016 mg/g Delta T laboratorio
k 2.01 Vol balon 100 mL
u MRC 0.00796019900498 U (0.02/2)
Vol final 100 mL

Concentración stock mg/kgmasa a tomar masa tomada(g) (b) u (masa ) (g)

1000 10 10.8754 0.000121627933983769
u balanza 0.0001108754

Solución stock en volumen

Concentración (a) 1087.97519007603 mg/L Vol final (d)

Incertidumbre 0.91189212397376 mg/L vol corregido
Concentración (b) 1087.97519007603 mg/L U (0.04/2)
Incertidumbre 0.91189212397376 mg/L u (T)
u vol final (b)

Concentración mg/L Volumen a tomar Volumen tomado (d ) u (mL)

4 0.36765544255844 0.4 0.05
6 0.55148316383765 0.5 0.05
8 0.73531088511687 0.7 0.05
10 0.91913860639609 0.9 0.05
12 1.1029663276753 1.1 0.05
14 1.28679404895452 1.3 0.05
u interpolación 0.5799527 mg/L
 3

yi estimado yi-yiestimado
0.04641 0.00005
0.04641 0.00002
0.04641 0.00018 0.3213577719
0.11178 0.00001
0.11178 0.00002
0.11178 0.00001
0.24253 0.00007
0.24253 0.00000
0.24253 0.00018 0.0009801063
0.37328 0.00163
0.37328 0.00026
0.37328 0.00007
0.50403 0.00077
0.50403 0.00022 S x0 0.201 mg/L
0.50403 0.00037
0.63479 0.00064
0.63479 0.00008
0.63479 0.00139
yi estimado yi-yiestimado

0.00597

0.7

0.6 R² = 0.992409200383363

0.5
Respuesta (A)

0.4

0.3

0.2

0.1
PREPARACIÓN DE CALIBRANTES
0
2 4 6 8 1
Concentración (mg/
 0.2

0.1

0
2 4 6 8 1
Concentración (mg/

2 °C
99.96 mL
0.01 mL

Volumen final (mL) u (vol) mL ci (a) ci (b) ci © u*ci (a)

99.96 0.026229754097 0.10879752 100.040016 10.884105543 0.8660499025
u efecto temperatu 0.024248711306

100 mL
98.38 mL
0.02 mL
0.0238558821828077 0.0003164304 u rel volumen
0.0311304210495136 mL 0.0008381553 u rel C

ci (b) ci (c ) ci (d) u*ci (b) u*ci (c ) u*ci (d)

11.06 0.0 0.045 0.3 0.00 0.00
11.06 0.0 0.056 0.3 0.00 0.00
11.06 0.0 0.079 0.3 0.01 0.00
11.06 0.0 0.101 0.3 0.01 0.01
11.06 0.0 0.124 0.3 0.01 0.01
11.06 0.0 0.146 0.3 0.01 0.01
 n= replicas niveles curva

Cambio de incertidumbre con m

n=18
m S x0
1 0.330 3.53%
2 0.240 2.57%
3 0.201 2.15%
4 0.178 1.90%
5 0.163 1.74%
6 0.152 1.62%
7 0.143 1.54%
8 0.137 1.47%

Variación de sx0 con m (n=35)

4.00%
3.50%
3.00%
2.50%
2.00%
1.50%
1.00%
0.50%
0.00%
0 1 2 3 4 5 6 7 8 9

= 0.992409200383363

6 8 10 12 14 16
Concentración (mg/L)
6 8 10 12 14 16
Concentración (mg/L)

u*ci (b) u*ci (c) u stock (mg/L) C stock mg/L

0.0013227524 0.28548741196 0.91189212397 1087.97519007603

u stock (masa) C stock ug/L u rel volumen uc relativa u

0.34 4.352 0.125 0.12500321 0.54400157
0.34 5.440 0.1 0.10000401 0.54400943
0.34 7.616 0.07142857142857 0.07143419 0.54403038
0.34 9.792 0.05555555555556 0.05556278 0.54405832
0.34 11.968 0.04545454545455 0.04546337 0.54409325
0.34 14.144 0.03846153846154 0.03847197 0.54413515
m= Réplicas muestra

Cambio de incertidumbre con n

m=3
n S x0
6 0.227 2.4%
12 0.208 2.2%
18 0.201 2.1%
24 0.197 2.1%
32 0.194 2.1%

Variación de sx0 con n (m=3)

2.6%

2.5%

2.4%

2.3%

2.2%

2.1%
0 5 10 15 20 25 30 35