SEMANA 2: Cálculo de la rapidez de difusion del am

Ejercicio 4.1 Solución:

Especies Amoniaco (A)
Datos: Pt = 206.8 kPa
Para (A) %V(A)1 = 0.10
rNH3= 0.2900nm
rNH3 -
(ξ/k)NH3=558.3 K
(ξ/k)NH
K*T
Hallando DNH3-N2: ƒ(K*T/ξNH

DNH3-N2
rNH3= 0.2900nm
rNH3 -
(ξ/k)NH
K*T
ƒ(K*T/ξNH
Hallando DNH3-H2:

DNH3-H
ƴB'=1-0.667=0.333

Hallando D(A,m):

D(A,m)=
Ṗ(A)1=%V(A)1*Pt= 0.10*206.8kPa=20
Ṗ(A)2=%V(A)2*Pt= 0.005*206.8kPa=10
Hallando Ṗ(B,m):

Ṗ(B,m
Finalmente se halla la rapidez de difu

NA=2.724E-5 Kmol/m^
de la rapidez de difusion del amoniaco
Solución:
Amoniaco (A) Nitrogeno (B) Hidrogeno (C)
T = 54°C + 273 = 327K Z = 0.0005 m
%V(A)1 = 0.10 %V(A)2= 0.05
rN2= 0.3798nm MA=34 kg/kmol MB=28kg/kmol
rNH3 - N2= 0.3349nm
(ξ/k)NH3=558.3 K (ξ/k)N2=71.4 K
(ξ/k)NH3-N2=199.656 k
K*T/ξAB= 1.6378
ƒ(K*T/ξNH3-N2)=ƒ(1.6378)=5.8

DNH3-N2=0.1145E-5 m^2/s
rH2= 0.2827nm MA=34 kg/kmol MC=2kg/kmol
rNH3 - H2= 0.2864nm
(ξ/k)NH3-H2=182.566 k
K*T/ξAB= 1.791
ƒ(K*T/ξNH3-N2)=ƒ(1.791)=0.38

DNH3-H2=6.026E-5 m^2/s
ƴB'=1-0.667=0.333 ƴC'=2/(2+1)=0.667

D(A,m)=0.3312E-5 m^2/s
Ṗ(A)1=%V(A)1*Pt= 0.10*206.8kPa=20.68kPa Ṗ(B)1=186.12kPa
Ṗ(A)2=%V(A)2*Pt= 0.005*206.8kPa=10.34kPa Ṗ(B)2=196.46kPa

Ṗ(B,m)=191.243kPa
Finalmente se halla la rapidez de difusion del amoniaco

NA=2.724E-5 Kmol/m^2*s
a) Calcule la difusividad efectiva

SOLUCION

Placa de arcilla CAo=

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