𝐴=𝜋𝑟^2Equilibrio L-V por medio de K´s usando las constantes de la ecuacion de Antoine.

Cálculos de P de burbuja y de rocio.

log⁡(𝑃𝑣𝑎𝑝)=𝐴−𝐵/(𝑇+𝐶)

Name # A B C
25 methane 1 3.7687 395.744 266.681
27 methanol 1 5.20277 1580.0800 239.500
47 ethyne 1 3.67374 528.6700 228.790
55 ethene 1 3.91382 596.526 256.37
60 ethanoic acid 1 4.54456 1555.12 224.65
65 ethane 1 3.95405 663.72 256.681
66 ethanol 1 5.33675 1648.22 230.918
85 propene 1 3.95606 789.624 247.58
89 propanona 1 4.2184 1197.01 228.06
95 propane 1 3.92828 803.997 247.04
96 1-propanol 1 4.99991 1512.94 205.807
97 2-propanol 1 5.24268 1580.92 219.61
110 1,3-butadiene 1 3.9664 927.21 238.63
124 ethyl etenoate(acetate) 1 4.13361 1195.13 212.47
127 butane 1 3.93266 935.773 238.789
128 2-methylpropane 1 4.00272 947.54 248.87
166 pentane 1 3.97786 1064.84 232.014
167 2methylbutane 1 3.92023 1022.88 233.46
187 benzene 1 3.98523 1184.24 217.572
188 phenol 1 4.2696 1523.42 175.4
216 hexane 1 4.00139 1170.875 224.317
234 toluene 1 4.05043 1327.62 217.625
259 heptane 1 4.02023 1263.909 216.432
273 ethylbenzene 1 4.06861 1415.77 212.3
296 octane 1 4.05075 1356.36 209.635
394 nonane 1 4.07356 1438.03 202.694
440 water 1 5.11564 1687.537 230.17
441 cumeno 1 4.06112 1460.766 207.83
butanol 1 7.92484 1617.52 203.296

BURBUJA
Temperatura Presion
°C atm bar psia
0.960905231826 3 3.03975 44.1
Name Ki xi ki*xi
methane 64.15488126 0 0
methanol 0.014089149 0 0
ethyne 7.759698062 0 0
ethene 12.96743388 0 0
ethanoic acid 0.001475003 0 0
ethane 7.853774218 0 0
ethanol 0.005569362 0 0
propene 1.977806193 0 0
propanona 0.032279096 0 0
propane 1.59783003 0 0
1-propanol 0.001584817 0 0
2-propanol 0.003912386 0 0
1,3-butadiene 0.410762254 0 0
ethyl etenoate(acetate) 0.011250228 0 0
butane 0.352128092 0 0
2-methylpropane 0.533527504 0 0
pentane 0.084023566 0 0
2methylbutane 0.118565617 0 0
benzene 0.012115617 0 0
phenol 1.40825E-05 0 0
hexane 0.020945118 0 0
toluene 0.003118286 0 0
heptane 0.005289974 0 0
ethylbenzene 0.000885312 0 0
octane 0.001340698 0 0
nonane 0.00033854 0 0
water 0.002145777 0 0
cumeno 0.000381919 0 0
butanol 0.333392091 0 0
TOTAL 0 0
 *Introducir valores de sus composiciones
Depende qué quieran obtener, presión o temperatura de burbuja o rocío, se van
a la tecla de:
* datos (está en barra de tareas)
* análisis "y si"
* buscar objetivo
definimos la celda xi*Ki o yi/Ki, con el valor de 1 (es la condición de equilibrio,
que la sumatoria de 1), para modificar el valor de la celda que queramos
encontrar, ya sea la temperatura o presión de burbuja o rocío.

ROCÍO
Temperatura Presion
°C atm bar psia
141.5155512 3 3.03975 44.1
Name Ki yi yi/ki
methane 207.1898116 0 0
methanol 3.740328958 0 0
ethyne 57.97533618 0 0
ethene 85.45588306 0 0
ethanoic acid 0.652651634 0 0
ethane 63.73780362 0 0
ethanol 2.681458006 0 0
propene 27.78682129 0 0
propanona 3.138227784 0 0
propane 23.7819607 0 0
1-propanol 1.448984001 0 0
2-propanol 2.410376488 0 0
1,3-butadiene 11.07822193 0 0
ethyl etenoate(acetate 1.881745488 0 0
butane 9.75514314 0 0
2-methylpropane 12.3791804 0 0
pentane 4.408292883 0 0
2methylbutane 5.123117127 0 0
benzene 1.601318604 0 0
phenol 0.095442151 0 0
hexane 2.079580871 0 0
toluene 0.742905464 0 0
heptane 1.014852107 0 0
ethylbenzene 0.384005049 0 0
octane 0.507335655 0 0
nonane 0.258789887 0 0
water 1.237583548 0 0
cumeno 0.249371212 0 0
TOTAL 0 0