g E / R T , ln (γ1), ln (γ2 ), g E /R T x1x2

El sistema metanol(1)/agua(2) a una T=333.15K, con los siguientes datos

experimentales determine : Los parámetros de Wilson y NRTL y represente
en la gráfica P-x-y

P(kPa) x1 y1 ln(γ1) ln(γ2) gE/RT gE/RT.x1.x2

M
19.953 0.000 0.000 0.6828 0.0000 0 0.6828
0.8
39.223 0.169 0.571 0.4523 0.0133 0.08732 0.6229
42.984 0.217 0.627 0.3855 0.0260 0.10393 0.6123 0.7

48.852 0.304 0.694 0.2775 0.0725 0.13482 0.6373 f

0.6 R
52.784 0.368 0.735 0.2196 0.1057 0.14762 0.6346
56.652 0.446 0.774 0.1507 0.1462 0.14823 0.5999 0.5
60.614 0.528 0.809 0.0927 0.2095 0.14782 0.5932
63.998 0.604 0.838 0.0485 0.2708 0.13645 0.5707 0.4

67.924 0.680 0.873 0.0305 0.2998 0.11656 0.5360

0.3
70.229 0.726 0.892 0.0211 0.3237 0.10417 0.5231
72.832 0.778 0.914 0.0124 0.3435 0.08603 0.4975 0.2

84.562 1.000 1.000 0.0000 0.4753 0 0.4753

0.1
MODELO MARGULES MODELO WILSON
A12 A21 Psat1(kPa) Psat2(kPa) ʌ12 ʌ21 0
0.000
0.6828 0.4753 84.5620 19.53 0.485 1.04

x1 γ1 γ2 Pcal y1cal
0.00 1.981 1.000 19.530 0.00
0.10 1.655 1.009 31.737 0.44
0.20 1.441 1.034 40.530 0.60
0.30 1.295 1.071 47.500 0.69
0.40 1.193 1.119 53.475 0.75
0.50 1.121 1.178 58.910 0.80
0.60 1.071 1.245 64.074 0.85
0.70 1.037 1.322 69.133 0.89
0.80 1.015 1.408 74.191 0.93
0.90 1.004 1.504 79.319 0.96
1.00 1.000 1.609 84.562 1.00
MODELO NRTL
Psat1(kPa) Psat2(kPa) τ12 τ21 G12 G21 MODELO WILSON, N
84.5620 19.53 -0.166 0.858 1.058 1.339
90.000
Metanol-agua T=333
P-x
PRESIÓN (kPa)

x1 γ1 γ2 Pcal y1cal 80.000

P-y
0.00 2.341 1.000 19.530 0.000 P-x
experimental
0.10 2.014 1.005 34.695 0.491 70.000 P-y
0.20 1.754 1.022 45.629 0.650 experimental
P-x NRTL
0.30 1.548 1.054 53.676 0.731 60.000
P-y NRTL
0.40 1.385 1.106 59.814 0.783
0.50 1.258 1.184 64.761 0.822 50.000

40.000

30.000
 experimental

PRE
P-x NRTL
60.000
P-y NRTL

50.000
0.60 1.161 1.297 69.044 0.853
0.70 1.089 1.463 73.037 0.883 40.000
0.80 1.039 1.707 76.974 0.913
0.90 1.010 2.075 80.905 0.950 30.000

1.00 1.000 2.646 84.562 1.000

20.000

10.000

0.000
0.00 0.10 0.20 0.30 0.4
 g E / R T , ln (γ1), ln (γ2 ), g E /R T x1x2

Metanol-agua T=333.15 K
x1-gE/RT
0.8
x1-ln(Y1)
x1-ln(Y2)
0.7
x1-gE/RTx1x2
f(x) = − 0.207505801842392 x + 0.682763216650381
Linear (x1-
0.6 R² = 0.913654179335894 gE/RTx1x2)

0.5

0.4

0.3

0.2

0.1

0
0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700 0.800 0.900 1.000

x1

MODELO WILSON, NRTL Y EXPERIMENTAL

Metanol-agua T=333.15 K
P-x
P-y
P-x
experimental
P-y
experimental
P-x NRTL
P-y NRTL
 experimental
P-x NRTL
P-y NRTL

0 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
x1-y1