Cálculo de entalpía ulilizando un polinomio en función de la temperatura.

COMPUESTO FÓRMULA A B C D E
Ciclohexanol 𝐶_6 𝐻_12 𝑂 17.124 3.3700E-01 2.8176E-04 -4.2713E-07 1.3215E-10

Capacidad calorífica a presión constante

Cp J/(molK) T K

Entalpía del vapor por componente

𝑑𝐻=𝐶_𝑝 𝑑𝑇

∫24_(𝐻_𝑟𝑒𝑓)^𝐻▒ 〖𝑑𝐻 = 〗 ∫ _(𝑇_𝑟𝑒𝑓)^𝑇▒ 〖𝐶 _𝑝

𝑑𝑇 〗

𝐻−𝐻_𝑟𝑒𝑓=∫_(𝑇_𝑟𝑒𝑓)^𝑇▒[𝐴+𝐵𝑇+𝐶𝑇^2+𝐷𝑇^3+𝐸𝑇^4
]𝑑𝑇

∆𝐻=𝐴|𝑇|_(𝑇_𝑟𝑒𝑓)^𝑇+𝐵/2 |𝑇^2 |_(𝑇_𝑟𝑒𝑓)^𝑇+𝐶/3 |𝑇^3 |_(𝑇_𝑟𝑒𝑓)^𝑇+𝐷/4 |𝑇^4 |

_(𝑇_𝑟𝑒𝑓)^𝑇+𝐸/5 |𝑇^5 |_(𝑇_𝑟𝑒𝑓)^𝑇

∆𝐻=𝐴[𝑇_𝑟𝑒𝑓−𝑇]
+𝐵/2[𝑇_𝑟𝑒𝑓^2−𝑇^2]+𝐶/3[𝑇_𝑟𝑒𝑓^3−𝑇^3]+𝐷/4[𝑇_𝑟𝑒𝑓^4−𝑇^4]+𝐸/5[𝑇_𝑟𝑒𝑓^5−𝑇^5]

298.15 [𝑇_𝑟𝑒𝑓−𝑇] [𝑇_𝑟𝑒𝑓^2−𝑇^2][𝑇_𝑟𝑒𝑓^3−𝑇^3][𝑇_𝑟𝑒𝑓^4−𝑇^4] [𝑇_𝑟𝑒𝑓^5−𝑇^5]

200 98.15 48893.4225 18503573.9 6302040564 2.035993E+12
250 48.15 26393.4225 10878573.9 3995790564 1.379431E+12
300 -1.85 -1106.5775 -496426.082 -197959436.2 -74006605914
350 -51.85 -33606.5775 -16371426 -7104209436 -2.89619E+12
400 -101.85 -71106.5775 -37496426 -17697959436 -7.88401E+12
450 -151.85 -113606.578 -64621426 -33104209436 -1.60968E+13
500 -201.85 -161106.578 -98496426 -54597959436 -2.8894E+13
550 -251.85 -213606.578 -139871426 -83604209436 -4.79724E+13
600 -301.85 -271106.578 -189496426 -1.21698E+11 -7.5404E+13
650 -351.85 -333606.578 -248121426 -1.70604E+11 -1.13673E+14
700 -401.85 -401106.578 -316496426 -2.32198E+11 -1.65714E+14
750 -451.85 -473606.578 -395371426 -3.08504E+11 -2.34949E+14
 800 -501.85 -551106.578 -485496426 -4.01698E+11 -3.25324E+14
850 -551.85 -633606.578 -587621426 -5.14104E+11 -4.41349E+14
900 -601.85 -721106.578 -702496426 -6.48198E+11 -5.88134E+14
950 -651.85 -813606.578 -830871426 -8.06604E+11 -7.71425E+14
1000 -701.85 -911106.578 -973496426 -9.92098E+11 -9.97644E+14
1050 -751.85 -1013606.58-1131121426 -1.2076E+12 -1.27393E+15
1100 -801.85 -1121106.58-1304496426 -1.4562E+12 -1.60815E+15
1150 -851.85 -1233606.58-1494371426 -1.7411E+12 -2.009E+15
1200 -901.85 -1351106.58-1701496426 -2.0657E+12 -2.48596E+15
1250 -951.85 -1473606.58-1926621426 -2.4335E+12 -3.0494E+15
1300 -1001.85 -1601106.58-2170496426 -2.8482E+12 -3.71057E+15
1350 -1051.85 -1733606.58-2433871426 -3.3136E+12 -4.48168E+15
1400 -1101.85 -1871106.58-2717496426 -3.8337E+12 -5.37588E+15
1450 -1151.85 -2013606.58-3022121426 -4.4126E+12 -6.40738E+15
1500 -1201.85 -2161106.58-3348496426 -5.0546E+12 -7.59139E+15
𝐵/2[𝑇_𝑟𝑒𝑓^2− 𝐶/3[𝑇_𝑟𝑒𝑓^3− 𝐷/4[𝑇_𝑟𝑒𝑓^4− 𝐸/5[𝑇_𝑟𝑒𝑓^5−
298.15 𝐴[𝑇_𝑟𝑒𝑓−𝑇] 𝑇^2] 𝑇^3] 𝑇^4] 𝑇^5]

200 1680.7206 8238.54169 1737.85566 -672.9476465 53.811305406

250 824.5206 4447.29169 1021.71566 -426.6805059 36.458358531
300 -31.6794 -186.458309 -46.6243376 21.1386035 -1.955994594
350 -887.8794 -5662.70831 -1537.60434 758.60524412 -76.54641022
400 -1744.0794 -11981.4583 -3521.66434 1889.8323535 -208.3742946
450 -2600.2794 -19142.7083 -6069.24434 3534.9502441 -425.438929
500 -3456.4794 -27146.4583 -9250.78434 5830.1066035 -763.6685946
550 -4312.6794 -35992.7083 -13136.7243 8927.4664941 -1267.911698
600 -5168.8794 -45681.4583 -17797.5043 12995.212354 -1992.927895
650 -6025.0794 -56212.7083 -23303.5643 18217.543994 -3004.379216
700 -6881.2794 -67586.4583 -29725.3443 24794.678604 -4379.821195
750 -7737.4794 -79802.7083 -37133.2843 32942.850744 -6209.693985
800 -8593.6794 -92861.4583 -45597.8243 42894.312354 -8598.313495
850 -9449.8794 -106762.708 -55189.4043 54897.332744 -11664.8625
900 -10306.0794 -121506.458 -65978.4643 69216.198603 -15544.38179
950 -11162.2794 -137092.708 -78035.4443 86131.213994 -20388.76127
1000 -12018.4794 -153521.458 -91430.7843 105938.70035 -26367.73109
1050 -12874.6794 -170792.708 -106234.924 128950.99649 -33669.85279
1100 -13730.8794 -188906.458 -122518.304 155496.4586 -42503.51039
1150 -14587.0794 -207862.708 -140351.364 185919.46024 -53097.90156
1200 -15443.2794 -227661.458 -159804.544 220580.39235 -65704.02869
1250 -16299.4794 -248302.708 -180948.284 259855.66324 -80595.69008
1300 -17155.6794 -269786.458 -203853.024 304137.6986 -98070.47099
1350 -18011.8794 -292112.708 -228589.204 353834.94149 -118450.7348
1400 -18868.0794 -315281.458 -255227.264 409371.85235 -142084.6143
1450 -19724.2794 -339292.708 -283837.644 471188.90899 -169347.0024
1500 -20580.4794 -364146.458 -314490.784 539742.6066 -200640.5436

∆𝐻=𝐴[𝑇_𝑟𝑒𝑓−𝑇]
298.15 +𝐵/2[𝑇_𝑟𝑒𝑓^2−𝑇^2]+𝐶/3[𝑇_𝑟𝑒𝑓^3−𝑇^3]+𝐷/4[𝑇_𝑟𝑒𝑓^4−𝑇^4]+𝐸/5[𝑇_𝑟𝑒𝑓^5−𝑇^5]
 ∆𝐻=𝐴[𝑇_𝑟𝑒𝑓−𝑇]
+𝐵/2[𝑇_𝑟𝑒𝑓^2−𝑇^2]+𝐶/3[𝑇_𝑟𝑒𝑓^3−𝑇^3]+𝐷/4[𝑇_𝑟𝑒𝑓^4−𝑇^4]+𝐸/5[𝑇_𝑟𝑒𝑓^5−𝑇^5]

200 11037.9816125694
250 5903.3058063194
300 -245.579437430604
350 -7406.1332124306
400 -15565.7439874306
450 -24702.7207311806
500 -34787.2840374306
550 -45782.5572499306
600 -57645.5575874306
650 -70328.1872686806
700 -83778.2246374306
750 -97940.3152874306
800 -112756.963187431
850 -128169.521806181
900 -144119.185237431
950 -160547.979324931
1000 -177399.752787431
1050 -194621.168343681
1100 -212162.693837431
1150 -229979.593362431
1200 -248032.918387431
1250 -266290.498881181
1300 -284727.934437431
1350 -303329.585399931
1400 -322089.563987431
1450 -341012.725418681
1500 -360115.659037431
 Tmin Tmax
200 1500

𝑇_(𝑟𝑒𝑓 ) [𝐾] 298.15 𝑇_(𝑟𝑒𝑓 ) [𝐾] 350

T ∆𝐻 T ∆𝐻
200 11037.981613 200 18444.1148
250 5903.3058063 250 13309.439
300 -245.5794374 300 7160.55378
350 -7406.133212 350 0
400 -15565.74399 400 -8159.61078
450 -24702.72073 450 -17296.5875
500 -34787.28404 500 -27381.1508
550 -45782.55725 550 -38376.424
600 -57645.55759 600 -50239.4244
650 -70328.18727 650 -62922.0541
700 -83778.22464 700 -76372.0914
750 -97940.31529 750 -90534.1821
4 |𝑇^4 | 800 -112756.9632 800 -105350.83
850 -128169.5218 850 -120763.389
900 -144119.1852 900 -136713.052
5−𝑇^5] 950 -160547.9793 950 -153141.846
1000 -177399.7528 1000 -169993.62
1050 -194621.1683 1050 -187215.035
1100 -212162.6938 1100 -204756.561
1150 -229979.5934 1150 -222573.46
1200 -248032.9184 1200 -240626.785
1250 -266290.4989 1250 -258884.366
1300 -284727.9344 1300 -277321.801
1350 -303329.5854 1350 -295923.452
1400 -322089.564 1400 -314683.431
1450 -341012.7254 1450 -333606.592
1500 -360115.659 1500 -352709.526

350 [𝑇_𝑟𝑒𝑓−𝑇] [𝑇_𝑟𝑒𝑓^2−𝑇^2][𝑇_𝑟𝑒𝑓^3−𝑇^3] [𝑇_𝑟𝑒𝑓^5−𝑇^5] 0 [𝑇_𝑟𝑒𝑓−𝑇] [𝑇_𝑟𝑒𝑓^2−𝑇^2

200 150 82500 13406250000 4.932188E+12 200 -200
250 100 60000 11100000000 4.275625E+12 250 -250
300 50 32500 6906250000 2.822188E+12 300 -300
350 0 0 0 0 350 -350
400 -50 -37500 -10593750000 -4.98781E+12 400 -400
450 -100 -80000 -26000000000 -1.32006E+13 450 -450
500 -150 -127500 -47493750000 -2.59978E+13 500 -500
550 -200 -180000 -76500000000 -4.50763E+13 550 -550
600 -250 -237500 -1.14594E+11 -7.25078E+13 600 -600
650 -300 -300000 -1.635E+11 -1.10777E+14 650 -650
700 -350 -367500 -2.25094E+11 -1.62818E+14 700 -700
750 -400 -440000 -3.014E+11 -2.32053E+14 750 -750
 800 -450 -517500 -3.94594E+11 -3.22428E+14 800 -800
850 -500 -600000 -5.07E+11 -4.38453E+14 850 -850
900 -550 -687500 -6.41094E+11 -5.85238E+14 900 -900
950 -600 -780000 -7.995E+11 -7.68529E+14 950 -950
1000 -650 -877500 -9.84994E+11 -9.94748E+14 1000 -1000
1050 -700 -980000 -1.2005E+12 -1.27103E+15 1050 -1050
1100 -750 -1087500 -1.44909E+12 -1.60526E+15 1100 -1100
1150 -800 -1200000 -1.734E+12 -2.00611E+15 1150 -1150
1200 -850 -1317500 -2.05859E+12 -2.48307E+15 1200 -1200
1250 -900 -1440000 -2.4264E+12 -3.04651E+15 1250 -1250
1300 -950 -1567500 -2.84109E+12 -3.70768E+15 1300 -1300
1350 -1000 -1700000 -3.3065E+12 -4.47878E+15 1350 -1350
1400 -1050 -1837500 -3.82659E+12 -5.37299E+15 1400 -1400
1450 -1100 -1980000 -4.4055E+12 -6.40448E+15 1450 -1450
1500 -1150 -2127500 -5.04749E+12 -7.5885E+15 1500 -1500
𝐵/2[𝑇_𝑟𝑒𝑓^2− 𝐶/3[𝑇_𝑟𝑒𝑓^3− 𝐸/5[𝑇_𝑟𝑒𝑓^5−
350 𝐴[𝑇_𝑟𝑒𝑓−𝑇] 𝑇^2] 𝑇^3] 𝑇^5] 0 𝐴[𝑇_𝑟𝑒𝑓−𝑇]

200 2568.6 13901.25 -1431.552891 130.35771563 200 -3424.8

250 1712.4 10110 -1185.28575 113.00476875 250 -4281
300 856.2 5476.25 -737.4666406 74.590415625 300 -5137.2
350 0 0 0 0 350 -5993.4
400 -856.2 -6318.75 1131.2271094 -131.8278844 400 -6849.6
450 -1712.4 -13480 2776.345 -348.8925188 450 -7705.8
500 -2568.6 -21483.75 5071.5013594 -687.1221844 500 -8562
550 -3424.8 -30330 8168.86125 -1191.365288 550 -9418.2
600 -4281 -40018.75 12236.607109 -1916.381484 600 -10274.4
650 -5137.2 -50550 17458.93875 -2927.832806 650 -11130.6
700 -5993.4 -61923.75 24036.073359 -4303.274784 700 -11986.8
750 -6849.6 -74140 32184.2455 -6133.147575 750 -12843
800 -7705.8 -87198.75 42135.707109 -8521.767084 800 -13699.2
850 -8562 -101100 54138.7275 -11588.31609 850 -14555.4
900 -9418.2 -115843.75 68457.593359 -15467.83538 900 -15411.6
950 -10274.4 -131430 85372.60875 -20312.21486 950 -16267.8
1000 -11130.6 -147858.75 105180.09511 -26291.18468 1000 -17124
1050 -11986.8 -165130 128192.39125 -33593.30638 1050 -17980.2
1100 -12843 -183243.75 154737.85336 -42426.96398 1100 -18836.4
1150 -13699.2 -202200 185160.855 -53021.35515 1150 -19692.6
1200 -14555.4 -221998.75 219821.78711 -65627.48228 1200 -20548.8
1250 -15411.6 -242640 259097.058 -80519.14367 1250 -21405
1300 -16267.8 -264123.75 303379.09336 -97993.92458 1300 -22261.2
1350 -17124 -286450 353076.33625 -118374.1884 1350 -23117.4
1400 -17980.2 -309618.75 408613.24711 -142008.0679 1400 -23973.6
1450 -18836.4 -333630 470430.30375 -169270.456 1450 -24829.8
1500 -19692.6 -358483.75 538984.00136 -200563.9972 1500 -25686

∆𝐻=𝐴[𝑇_𝑟𝑒𝑓−𝑇]
350 +𝐵/2[𝑇_𝑟𝑒𝑓^2−𝑇^2]+𝐶/3[𝑇_𝑟𝑒𝑓^3−𝑇^3]+𝐷/4[𝑇_𝑟𝑒𝑓^4−𝑇^4]+𝐸/5[𝑇_𝑟𝑒𝑓^5−𝑇^5] 0 +𝐵/2[𝑇_𝑟𝑒𝑓^2−𝑇^2]+𝐶/3[𝑇_𝑟
 ∆𝐻=𝐴[𝑇_𝑟𝑒𝑓−𝑇]
+𝐵/2[𝑇_𝑟𝑒𝑓^2−𝑇^2]+𝐶/3[𝑇_𝑟𝑒𝑓^3−𝑇^3]+𝐷/4[𝑇_𝑟𝑒𝑓^4−𝑇^4]+𝐸/5[𝑇_𝑟𝑒𝑓^5−𝑇^5] +𝐵/2[𝑇_𝑟𝑒𝑓^2−𝑇^2]+𝐶/3[𝑇_𝑟

200 18444.114825 200

250 13309.43901875 250
300 7160.553775 300
350 0 350
400 -8159.610775 400
450 -17296.58751875 450
500 -27381.150825 500
550 -38376.4240375 550
600 -50239.424375 600
650 -62922.05405625 650
700 -76372.091425 700
750 -90534.182075 750
800 -105350.829975 800
850 -120763.38859375 850 -
900 -136713.052025 900
950 -153141.8461125 950
1000 -169993.619575 1000
1050 -187215.03513125 1050 -
1100 -204756.560625 1100
1150 -222573.46015 1150
1200 -240626.785175 1200
1250 -258884.36566875 1250 -
1300 -277321.801225 1300
1350 -295923.4521875 1350
1400 -314683.430775 1400
1450 -333606.59220625 1450 -
1500 -352709.525825 1500
𝑇_(𝑟𝑒𝑓 ) [𝐾] 0
T ∆𝐻
25000
200 -10753.7656
250 -15888.4414 0
200 250 300 350 400 450 500 550 600 650
300 -22037.3267
-25000
350 -29197.8804
400 -37357.4912 -50000
450 -46494.4679
-75000
500 -56579.0313
550 -67574.3045 -100000
600 -79437.3048
-125000
650 -92119.9345
700 -105569.972 -150000
750 -119732.063
-175000
800 -134548.71
850 -149961.269 -200000
900 -165910.932
950 -182339.727 -225000

1000 -199191.5 -250000

1050 -216412.916
1100 -233954.441 -275000
1150 -251771.341
-300000
1200 -269824.666
1250 -288082.246 -325000
1300 -306519.682
-350000
1350 -325121.333
1400 -343881.311 -375000
1450 -362804.473
-400000
1500 -381907.406

[𝑇_𝑟𝑒𝑓^2−𝑇^2][𝑇_𝑟𝑒𝑓^3−𝑇^3][𝑇_𝑟𝑒𝑓^4−𝑇^4] [𝑇_𝑟𝑒𝑓^5−𝑇^5]
-40000 -8000000 -1600000000-320000000000
-62500 -15625000 -3906250000-976562500000
-90000 -27000000 -8100000000 -2.43E+12
-122500 -42875000-15006250000 -5.252188E+12
-160000 -64000000-25600000000 -1.024E+13
-202500 -91125000-41006250000 -1.845281E+13
-250000 -125000000-62500000000 -3.125E+13
-302500 -166375000-91506250000 -5.032844E+13
-360000 -216000000 -1.296E+11 -7.776E+13
-422500 -274625000 -1.78506E+11 -1.160291E+14
-490000 -343000000 -2.401E+11 -1.6807E+14
-562500 -421875000 -3.16406E+11 -2.373047E+14
 -640000 -512000000 -4.096E+11 -3.2768E+14
-722500 -614125000 -5.22006E+11 -4.437053E+14
-810000 -729000000 -6.561E+11 -5.9049E+14
-902500 -857375000 -8.14506E+11 -7.737809E+14
-1000000 -1E+09 -1E+12 -1E+15
-1102500-1157625000 -1.21551E+12 -1.276282E+15
-1210000-1331000000 -1.4641E+12 -1.61051E+15
-1322500-1520875000 -1.74901E+12 -2.011357E+15
-1440000-1728000000 -2.0736E+12 -2.48832E+15
-1562500-1953125000 -2.44141E+12 -3.051758E+15
-1690000-2197000000 -2.8561E+12 -3.71293E+15
-1822500-2460375000 -3.32151E+12 -4.484033E+15
-1960000-2744000000 -3.8416E+12 -5.37824E+15
-2102500-3048625000 -4.42051E+12 -6.409734E+15
-2250000-3375000000 -5.0625E+12 -7.59375E+15
𝐵/2[𝑇_𝑟𝑒𝑓^2− 𝐶/3[𝑇_𝑟𝑒𝑓^3− 𝐷/4[𝑇_𝑟𝑒𝑓^4− 𝐸/5[𝑇_𝑟𝑒𝑓^5−
𝑇^2] 𝑇^3] 𝑇^4] 𝑇^5]

-6740 -751.36 170.852 -8.4576

-10531.25 -1467.5 417.1191406 -25.810546875
-15165 -2535.84 864.93825 -64.2249
-20641.25 -4026.82 1602.404891 -138.81531563
-26960 -6010.88 2733.632 -270.6432
-34121.25 -8558.46 4378.749891 -487.70783438
-42125 -11740 6673.90625 -825.9375
-50971.25 -15625.94 9771.266141 -1330.1806031
-60660 -20286.72 13839.012 -2055.1968
-71191.25 -25792.78 19061.34364 -3066.6481219
-82565 -32214.56 25638.47825 -4442.0901
-94781.25 -39622.5 33786.65039 -6271.9628906
-107840 -48087.04 43738.112 -8660.5824
-121741.25 -57678.62 55741.13239 -11727.131409
-136485 -68467.68 70059.99825 -15606.6507
-152071.25 -80524.66 86975.01364 -20451.030178
-168500 -93920 106782.5 -26430
-185771.25 -108724.14 129794.7961 -33732.121697
-203885 -125007.52 156340.2583 -42565.7793
-222841.25 -142840.58 186763.2599 -53160.170466
-242640 -162293.76 221424.192 -65766.2976
-263281.25 -183437.5 260699.4629 -80657.958984
-284765 -206342.24 304981.4983 -98132.7399
-307091.25 -231078.42 354678.7411 -118513.00375
-330260 -257716.48 410215.652 -142146.8832
-354271.25 -286326.86 472032.7086 -169409.27127
-379125 -316980 540586.4063 -200702.8125

∆𝐻=𝐴[𝑇_𝑟𝑒𝑓−𝑇]
+𝐵/2[𝑇_𝑟𝑒𝑓^2−𝑇^2]+𝐶/3[𝑇_𝑟𝑒𝑓^3−𝑇^3]+𝐷/4[𝑇_𝑟𝑒𝑓^4−𝑇^4]+𝐸/5[𝑇_𝑟𝑒𝑓^5−𝑇^5]
 ∆𝐻=𝐴[𝑇_𝑟𝑒𝑓−𝑇]
+𝐵/2[𝑇_𝑟𝑒𝑓^2−𝑇^2]+𝐶/3[𝑇_𝑟𝑒𝑓^3−𝑇^3]+𝐷/4[𝑇_𝑟𝑒𝑓^4−𝑇^4]+𝐸/5[𝑇_𝑟𝑒𝑓^5−𝑇^5]

-10753.7656
-15888.44140625
-22037.32665
-29197.880425
-37357.4912
-46494.46794375
-56579.03125
-67574.3044625
-79437.3048
-92119.93448125
-105569.97185
-119732.0625
-134548.7104
-149961.26901875
-165910.93245
-182339.7265375
-199191.5
-216412.91555625
-233954.44105
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-269824.6656
-288082.24609375
-306519.68165
-325121.3326125
-343881.3112
-362804.47263125
-381907.40625
0 550 600 650 700 750 800 850 900 950 1000 1050 1100 1150 1200 1250 1300 1350 1
0 1250 1300 1350 1400 1450 1500

298.15
350
0