Calculos para diagramas T vs X-Y y X vs Y no ideales para Metanol (1)-Agua(2)

Pman (Hg) 183.93 Patm (Hg) 585 PTOT (Hg) 768.93

(g/mol) (cal/g°C) (cal/mol°C) (cal/g) VanLaar (cal/mol) A B C (°C)

Compuesto PM Cp Az A12_21 l Ctes. de Antoine (mm Hg y °C) p.e.
Metanol (1) 32.04 0.605 19.3842 0.9014 8415 8.0724 1574.99 238.8 64.870
Agua (2) 18.015 0.999 17.9970 0.5559 9718 7.96681 1669.21 228 100.525

Ec. Antoine Ec. Van Laar Raoult m

(°C) (mm Hg) (-) (-) (-) (mm Hg) (-) (-) (cal °C/mol)
Ti P1 i
0
P2 i
0
X1_supuesta g1 g2 P X1_calculada y1 hl Hv K1
64.890 769.526 185.2286 0.998600 1.00000 1.74184 768.90089 0.998665 0.999478 1258 9673 #REF!
65.000 772.8605 186.1434 0.991200 1.00003 1.73301 768.91860 0.991225 0.996334 1259 9679 #REF!
66.000 803.7296 194.6368 0.924500 1.00207 1.65511 768.91153 0.924538 0.968408 1272 9733 #REF!
67.000 835.6176 203.4562 0.859500 1.00759 1.58209 768.88836 0.859580 0.941181 1286 9785 #REF!
68.000 868.5504 212.6116 0.796400 1.01686 1.51406 768.91565 0.796426 0.914763 1299 9836 #REF!
69.000 902.5545 222.1132 0.735100 1.03025 1.45081 768.90015 0.735149 0.888981 1312 9887 #REF!
70.000 937.6565 231.9712 0.675800 1.04811 1.39242 768.86857 0.675893 0.863804 1325 9936 #REF!
71.000 973.8839 242.1965 0.618800 1.07071 1.33902 768.87959 0.618870 0.839213 1339 9985 #REF!
72.000 1011.264 252.7998 0.564200 1.09839 1.29052 768.86692 0.564280 0.815083 1352 10033 #REF!
73.000 1049.826 263.7921 0.512300 1.13128 1.24694 768.85040 0.512393 0.791350 1366 10081 #REF!
74.000 1089.597 275.1849 0.463500 1.16927 1.20835 768.91081 0.463520 0.767987 1379 10128 #REF!
75.000 1130.606 286.9896 0.417700 1.21244 1.17437 768.83494 0.417792 0.744739 1393 10175 #REF!
76.000 1172.884 299.2179 0.375400 1.26010 1.14502 768.81709 0.375499 0.721658 1407 10222 #REF!
77.000 1216.46 311.8820 0.336700 1.31154 1.11998 768.87661 0.336743 0.698661 1422 10268 #REF!
78.000 1261.365 324.9940 0.301400 1.36623 1.09876 768.87288 0.301442 0.675545 1436 10315 #REF!
79.000 1307.628 338.5664 0.269400 1.42337 1.08094 768.79713 0.269489 0.652212 1451 10361 #REF!
80.000 1355.283 352.6119 0.240700 1.48177 1.06617 768.83214 0.240760 0.628715 1466 10408 #REF!
81.000 1404.359 367.1435 0.214900 1.54094 1.05394 768.84064 0.214950 0.604871 1482 10456 #REF!
82.000 1454.89 382.1744 0.191700 1.60033 1.04382 768.78290 0.191776 0.580574 1498 10503 #REF!
83.000 1506.908 397.7180 0.170900 1.65922 1.03550 768.75530 0.170984 0.555835 1513 10551 #REF!
84.000 1560.446 413.7881 0.152200 1.71730 1.02866 768.72248 0.152292 0.530566 1529 10600 #REF!
85.000 1615.538 430.3985 0.135400 1.77408 1.02306 768.77192 0.135465 0.504790 1546 10650 #REF!
86.000 1672.218 447.5634 0.120200 1.82960 1.01845 768.78232 0.120257 0.478354 1562 10700 #REF!
87.000 1730.52 465.2974 0.106400 1.88375 1.01466 768.73646 0.106469 0.451194 1579 10750 #REF!
88.000 1790.479 483.6151 0.093900 1.93614 1.01157 768.79033 0.093947 0.423413 1595 10802 #REF!
89.000 1852.13 502.5315 0.082500 1.98693 1.00904 768.84570 0.082527 0.394883 1612 10854 #REF!
90.000 1915.51 522.0618 0.072000 2.03643 1.00697 768.70548 0.072067 0.365364 1629 10907 #REF!
91.000 1980.655 542.2215 0.062400 2.08413 1.00529 768.65869 0.062476 0.335108 1646 10961 #REF!
92.000 2047.6 563.0264 0.053600 2.13004 1.00394 768.72291 0.053655 0.304108 1663 11016 #REF!
93.000 2116.385 584.4924 0.045500 2.17426 1.00287 768.86863 0.045515 0.272312 1680 11072 #REF!
94.000 2187.046 606.6358 0.037900 2.21756 1.00201 768.62647 0.037972 0.239143 1697 11129 #REF!
95.000 2259.622 629.4731 0.030900 2.25907 1.00134 768.57572 0.030979 0.205228 1714 11187 #REF!
96.000 2334.15 653.0212 0.024400 2.29908 1.00084 768.56551 0.024477 0.170369 1731 11246 #REF!
97.000 2410.671 677.2971 0.018400 2.33732 1.00048 768.83145 0.018420 0.134847 1748 11306 #REF!
 98.000 2489.224 702.3182 0.012700 2.37487 1.00023 768.63671 0.012756 0.097676 1765 11368 #REF!
99.000 2569.848 728.1021 0.007400 2.41089 1.00008 768.61900 0.007457 0.059649 1783 11430 #REF!
100.000 2652.584 754.6666 0.002400 2.44589 1.00001 768.43272 0.002487 0.020263 1800 11494 #REF!
100.500 2694.757 768.2473 0.000100 2.46233 1.00000 768.83398 0.000116 0.000863 1809 11526 #REF!

Tabla de Xw y 1/(Y-X) para 2 etapas, Yd=0.84, Rcte

refujo 2 et yd xw 1/y-x Aparcial
2.25 0.2584615 0.84 0.8131 37.238547 0.54630
2.25 0.2553846 0.83 0.7970 30.267117 3.33403
2.25 0.2307692 0.75 0.6218 7.8000035 2.12052
2.25 0.2215385 0.72 0.54 5.5555556 1.72009
2.25 0.2092308 0.68 0.4 3.5714286 0.98687
2.25 0.2 0.65 0.1983 2.21372 0.24463
2.25 0.1846154 0.6 0.08 1.9230769 0.0696
2.25 0.1692308 0.55 0.0443 1.977457 0.0491
2.25 0.1384615 0.45 0.0215 2.3337223 0.0217
2.25 0.1076923 0.35 0.0133111 2.9701012 0.0180
2.25 0.0769231 0.25 0.0082586 4.1366513 0.0449
2.25 0.0307692 0.1 0.002 10.204082 0.0153
2.25 0.0153846 0.05 0.001 20.408163 #REF!
2.25 0 0 0 #DIV/0! #REF!
Metanol (1)-Agua(2) @ 760 mm de Hg 768.9 mmHg = 1.0 atm = 1.02515285 bar = 1.045

NOMENCLATURA DE COLOR

(cal /mol) Celdas dato (llenar)

hli Hvi y Constantes de los componentes de la mz
1257.4588 9672.4588 y Titulos generales del proceso de cálculo
1809.14588 11527.146 y Variables calculadas

volatilidad Referencia
K2 a 1/(y-x) p/graficar
#REF! 2.38511 1139.3 1.000000 Diagrama T vs x-y (mz metanol-agua) @ 80
#REF! 2.39587 194.8 0.971236
#REF! 2.50010 22.8 0.905008 105
#REF! 2.61571 12.2 0.840529
#REF! 2.74363 8.4 0.777868 100
#REF! 2.88556 6.5 0.717135
#REF! 3.0425942 5.3 0.658485
95
#REF! 3.21532 4.5 0.602117
#REF! 3.40471 4.0 0.548273
90
#REF! 3.61059 3.6 0.497220
Temperatura, T (°C)

#REF! 3.83143 3.3 0.449223

85
#REF! 4.06727 3.1 0.404513
#REF! 4.31381 2.9 0.363253
#REF! 4.56750 2.8 0.325505 80
#REF! 4.82599 2.7 0.291227
#REF! 5.08577 2.6 0.260278 75
#REF! 5.34176 2.6 0.232443
#REF! 5.59259 2.6 0.207460 70
#REF! 5.8365014 2.6 0.185047
#REF! 6.07108 2.6 0.164923
65
#REF! 6.29569 2.6 0.146824
#REF! 6.50905 2.7 0.130505
#REF! 6.71202 2.8 0.115751 60
0.0 0.1 0.2 0.3 0.4 0.5 0.6
#REF! 6.90472 2.9 0.102371
#REF! 7.08614 3.0 0.090197 Fracción molar x, y
#REF! 7.25740 3.2 0.079085
#REF! 7.42021 3.4 0.068912
1
Di agrama x vs y (mz M etanol -
#REF! 7.57296 3.7 0.059569
#REF! 7.71608 4.0 0.050964
#REF! 7.85028 4.4 0.043016 0.9
#REF! 7.97875 5.0 0.035656
#REF! 8.09849 5.7 0.028823
0.8
#REF! 8.21085 6.9 0.022464
#REF! 8.31508 8.6 0.016533
0.7
va por, y

0.6
 0.8

#REF! 8.41528 11.8 0.010989 0.7

#REF! 8.50860 19.1 0.005797
#REF! 8.59700 56.0 0.000926

Fracci ón mola r del va por, y

0.6
#REF! 8.63704 1310.5 0.000000

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0

Fracci ón mol a
 Kg/cm2

mz metanol-agua) @ 805 mm de Hg

l i qui do Vapor

0.4 0.5 0.6 0.7 0.8 0.9 1.0

Fracción molar x, y

y (mz M etanol - agua) @ 8 0 5 mm de Hg

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Fracci ón mol ar del l íqui do, x