Trabajo Práctico: PULPADO KRAFT

TEMPERATURA (oC)
A = 43.2 T
f (min) r´(T)
B = 16113 ( C)
o
(K)
0.0 120.0 393.2 0.0
CICLO TERMICO TEORICO
15.0 180.0 120.0 393.2 9.2
f 1= 15 min 17.0 125.3 398.5 15.8
f2= 35 min 19.0 130.6 403.8 26.9
f3= 101 min 21.0 160.0 135.9 409.1 45.1
23.0 141.2 414.4 74.7
TV = 120 oC 25.0 146.5 419.7 122.1
140.0
TD = 173 C o
27.0 151.8 425.0 197.1
29.0 157.1 430.3 314.4
n= 10 31.0 120.0 162.4 435.6 495.8
Df = 2 min 33.0 167.7 440.9 773.5
35.0 173.0 446.2 1194.1
H 1-3 = 1400 101 100.0 173.0 446.2 1194.1
0.0 20.0 40.0 60.0 80.0 100.0 120.0
H 1-2 = 89 TIEMPO (min)

H 2-3 = 1311

f 3 - f2 = 66 min
 Trabajo Práctico: PULPADO KRAFT
Fecha: 10/22/2004
Comisión No: 1
CONDICIONES DE LA DIGESTION
VAPORADO:
Tiempo de venteo Øv = 30 seg.
Temperatura de vaporado Tv = 120 oC.
Tiempo de vaporado Øvap = 15 min.
Sequedad final de vaporado Sv = 0.766 g.chips s.s. / g.chips h.
DIGESTION:
Relación licor / madera RL = 5 :1
Carga de álcali activo C= 20 %
Sulfidez s= 23 %
Temperatura máxima Tr = 173 oC.
Tiempo hasta temperatura Øh = 20 min.
Factor H consigna Hc = 1400 h.
Tiempo a temperatura Øa = 66 min.
Tiempo total de digestión Øt = 101 min.

CALCULO DE MATERIALES A AGREGAR

Humedad de chips.
Muestra (1) (2)
Tara 327.96 g. 327.59 g.
Tara + MH 377.16 g. 394.34 g.
Tara + MS 372.3 g. 387.77 g.
MH 49.2 g. 66.75 g.
MS 44.34 g. 60.18 g.
Sequedad 0.9012 0.9016
Masa chips secos al aire Msa = 1151.56 g.
Sequedad inicial So = 0.901 g.chips s.s. / g.chips h.
Masa chips secos secos Mss = 1038.0 g.
Concentración licor blanco Clb = 139.3 g.NaOH / L
Sulfidez licor blanco S= 23 %
Masa inicial álcali activo MoAA(NaOH) = 207.6 g. NaOH
Volumen licor blanco Vlb = 1490 mL
Volumen agua vaporado Vv = 317 mL
Volumen total de licor Vt = 5190 mL
Volumen agua a agregar Va = 3383 mL
Mss = Msa*So Vv = Mss*[(1/Sv)-1]
MoAA(NaOH) = Mss*C/100 Vt = Mss*RL
Vlb = MoAA(NaOH)*1000/Clb Va = Vt-Vlb-Vv
 Trabajo Práctico: PULPADO KRAFT
Fecha: 10/2/2000
Comisión No: 2
CONTROL DEL AVANCE DE LA DIGESTION
CALCULO DEL FACTOR H
Factor H consigna Hc = 1400 horas

Factor H acumulado Hac = 1389 horas

Ø T nec. T leída r'(T) D Hi S (D Hi) Øf
(min) (oC) (oC) (h) (h) (min)
0.0 120.0 87.8 0 0 0 -
0.5 120.0 110.1 0 0 0 -
1.00 120.0 116.9 0 0 0 -
1.50 120.0 118.3 0 0 0 -
2.00 120.0 118.7 0 0 0 -
2.50 120.0 118.6 0 0 0 -
3.00 120.0 118.6 0 0 0 -
3.50 120.0 118.6 0 0 0 -
4.00 120.0 118.8 0 0 0 -
4.50 120.0 118.9 0 0 0 -
5.00 120.0 118.9 0 0 0 -
5.50 120.0 118.9 0 0 0 -
6.00 120.0 118.8 0 0 0 -
6.50 120.0 118.8 0 0 0 -
7.00 120.0 118.7 0 0 0 -
7.50 120.0 119.0 0 0 0 -
8.00 120.0 119.2 0 0 0 -
8.50 120.0 118.6 0 0 0 -
9.00 120.0 118.7 0 0 0 -
9.50 120.0 118.8 8.0 0.0 0 10553
10.00 120.0 119.1 8.2 0.1 0.10 10225
10.50 120.0 119.1 8.2 0.1 0.17 10225
11.00 120.0 119.4 8.5 0.1 0.24 9908
11.25 120.0 118.8 8.0 0.0 0.27 10551
11.50 120.0 116.2 6.0 0.0 0.30 13886
11.75 120.0 112.4 4.0 0.0 0.32 20886
12.00 120.0 109.6 3.0 0.0 0.34 28362
12.25 120.0 107.9 2.5 0.0 0.35 34227
12.50 120.0 107.1 2.2 0.0 0.36 37414
12.75 120.0 107.2 2.3 0.0 0.37 36999
13.00 120.0 96.9 0.7 0.0 0.37 120418
13.25 120.0 78.9 0.1 0.0 0.38 1117808
13.50 120.0 91.9 0.4 0.0 0.38 218733
13.75 120.0 85.3 0.2 0.0 0.38 493361
14.00 120.0 91.4 0.4 0.0 0.38 232395
14.25 120.0 95.7 0.6 0.0 0.38 138759
14.50 120.0 98.3 0.8 0.0 0.38 102178
14.75 120.0 100.1 1.0 0.0 0.39 82877
15.25 121.3 103.0 1.4 0.0 0.40 59398
15.75 122.7 103.2 1.4 0.0 0.41 58059
16.25 124.0 102.5 1.3 0.0 0.42 62885
16.75 125.3 102.3 1.3 0.0 0.43 64339
17.25 126.6 102.5 1.3 0.0 0.44 62884
17.75 128.0 103.8 1.5 0.0 0.46 54230
18.25 129.3 106.5 2.1 0.0 0.47 40004
18.75 130.6 110.2 3.2 0.0 0.49 26549
19.25 131.9 114.6 5.1 0.0 0.53 16472
19.75 133.3 119.8 8.8 0.1 0.59 9500
20.25 134.6 125.1 15.3 0.1 0.69 5502
20.75 135.9 128.6 21.7 0.2 0.84 3866
21.25 137.2 130.7 26.8 0.2 1.04 3137
21.75 138.6 132.6 32.3 0.2 1.29 2602
22.25 139.9 134.9 40.4 0.3 1.59 2079
22.75 141.2 137.2 50.4 0.4 1.97 1666
23.25 142.5 139.4 62.1 0.5 2.44 1350
23.75 143.9 141.3 74.3 0.6 3.00 1128
24.25 145.2 143.4 90.4 0.7 3.69 927
24.75 146.5 145.4 108.7 0.8 4.52 770
25.25 147.8 147.6 133.0 1.0 5.53 629
25.75 149.2 149.9 163.8 1.2 6.76 510
26.25 150.5 152.0 197.8 1.5 8.27 422
26.75 151.8 153.6 228.0 1.8 10.05 366
27.25 153.1 156.0 281.6 2.1 12.17 296
27.75 154.5 158.3 344.1 2.6 14.78 242
28.25 155.8 160.6 419.5 3.2 17.96 198
28.75 157.1 162.4 489.1 3.8 21.74 169
29.25 158.4 164.0 560.1 4.4 26.11 147
29.75 159.8 165.4 630.1 5.0 31.07 130
30.25 161.1 166.4 685.1 5.5 36.55 119
30.75 162.4 167.2 732.3 5.9 42.46 111
31.25 163.7 167.9 776.1 6.3 48.74 104
31.75 165.1 168.5 815.6 6.6 55.38 99
32.25 166.4 169.1 857.0 7.0 62.35 94
32.75 167.7 169.5 885.8 7.3 69.61 90
33.25 169.0 169.9 915.4 7.5 77.11 87
33.75 170.4 170.0 922.9 7.7 84.77 86
34.25 171.7 170.1 930.5 7.7 92.50 84
34.75 173.0 170.4 953.7 7.9 100.35 82
35.25 173.0 170.7 977.4 8.0 108.39 79
35.75 173.0 170.9 993.5 8.2 116.60 78
36.25 173.0 171.0 1001.7 8.3 124.92 76
36.75 173.0 171.1 1009.9 8.4 133.30 75
37.25 173.0 171.1 1009.9 8.4 141.72 75
37.75 173.0 171.0 1001.7 8.4 150.10 75
38.25 173.0 171.0 1001.7 8.3 158.45 74
38.75 173.0 171.3 1026.6 8.5 166.90 72
39.25 173.0 171.6 1052.0 8.7 175.56 70
39.75 173.0 173.6 1237.4 9.5 185.10 59
40.25 173.0 173.5 1227.4 10.3 195.37 59
40.75 173.0 173.5 1227.4 10.2 205.59 58
41.25 173.0 173.1 1188.3 10.1 215.66 60
41.75 173.0 173.6 1237.4 10.1 225.77 57
42.25 173.0 173.5 1227.4 10.3 236.04 57
42.75 173.0 173.2 1198.0 10.1 246.14 58
43.25 173.0 173.1 1188.3 9.9 256.09 58
43.75 173.0 173.6 1237.4 10.1 266.19 55
44.25 173.0 173.6 1237.4 10.3 276.50 54
44.75 173.0 173.4 1217.5 10.2 286.73 55
45.25 173.0 173.1 1188.3 10.0 296.76 56
45.75 173.0 173.4 1217.5 10.0 306.78 54
46.25 173.0 173.7 1247.4 10.3 317.05 52
46.75 173.0 173.6 1237.4 10.4 327.40 52
47.25 173.0 173.2 1198.0 10.1 337.55 53
47.75 173.0 173.4 1217.5 10.1 347.62 52
48.25 173.0 173.8 1257.5 10.3 357.93 50
48.75 173.0 173.5 1227.4 10.4 368.28 50
49.25 173.0 173.2 1198.0 10.1 378.39 51
49.75 173.0 173.6 1237.4 10.1 388.54 49
50.25 173.0 173.8 1257.5 10.4 398.93 48
50.75 173.0 173.5 1227.4 10.4 409.28 48
51.25 173.0 173.6 1237.4 10.3 419.55 48
51.75 173.0 173.7 1247.4 10.4 429.91 47
52.25 173.0 172.1 1095.7 9.8 439.67 53
52.75 173.0 173.0 1178.7 9.5 449.15 48
53.25 173.0 174.0 1278.0 10.2 459.38 44
53.75 173.0 174.0 1278.0 10.6 470.03 44
54.25 173.0 173.4 1217.5 10.4 480.43 45
54.75 173.0 173.3 1207.7 10.1 490.54 45
55.25 173.0 173.7 1247.4 10.2 500.77 43
55.75 173.0 174.0 1278.0 10.5 511.29 42
56.25 173.0 173.7 1247.4 10.5 521.81 42
56.75 173.0 173.5 1227.4 10.3 532.12 42
57.25 173.0 173.7 1247.4 10.3 542.43 41
57.75 173.0 174.0 1278.0 10.5 552.96 40
58.25 173.0 174.0 1278.0 10.6 563.61 39
58.75 173.0 173.7 1247.4 10.5 574.13 40
59.25 173.0 173.8 1257.5 10.4 584.57 39
59.75 173.0 173.9 1267.7 10.5 595.09 38
60.25 173.0 173.7 1247.4 10.5 605.57 38
60.75 173.0 173.9 1267.7 10.5 616.05 37
61.25 173.0 173.9 1267.7 10.6 626.61 37
61.75 173.0 173.8 1257.5 10.5 637.13 36
62.25 173.0 173.4 1217.5 10.3 647.44 37
62.75 173.0 173.3 1207.7 10.1 657.55 37
63.25 173.0 173.5 1227.4 10.1 667.70 36
63.75 173.0 173.4 1217.5 10.2 677.88 36
64.25 173.0 173.1 1188.3 10.0 687.91 36
64.75 173.0 173.3 1207.7 10.0 697.89 35
65.25 173.0 173.6 1237.4 10.2 708.08 34
65.75 173.0 173.5 1227.4 10.3 718.35 33
66.25 173.0 173.2 1198.0 10.1 728.45 34
66.75 173.0 173.3 1207.7 10.0 738.48 33
67.25 173.0 173.5 1227.4 10.1 748.62 32
67.75 173.0 173.3 1207.7 10.1 758.77 32
68.25 173.0 172.9 1169.2 9.9 768.67 32
68.75 173.0 173.2 1198.0 9.9 778.54 31
69.25 173.0 173.4 1217.5 10.1 788.60 30
69.75 173.0 173.4 1217.5 10.1 798.75 30
70.25 173.0 173.3 1207.7 10.1 808.85 29
70.75 173.0 173.4 1217.5 10.1 818.96 29
71.25 173.0 173.5 1227.4 10.2 829.15 28
71.75 173.0 173.3 1207.7 10.1 839.29 28
72.25 173.0 173.1 1188.3 10.0 849.28 28
72.75 173.0 173.4 1217.5 10.0 859.30 27
73.25 173.0 173.6 1237.4 10.2 869.53 26
73.75 173.0 173.0 1178.7 10.1 879.60 26
74.25 173.0 172.6 1141.1 9.7 889.26 27
74.75 173.0 173.0 1178.7 9.7 898.93 26
75.25 173.0 173.2 1198.0 9.9 908.83 25
75.75 173.0 173.3 1207.7 10.0 918.85 24
76.25 173.0 173.1 1188.3 10.0 928.84 24
76.75 173.0 173.3 1207.7 10.0 938.82 23
77.25 173.0 173.4 1217.5 10.1 948.93 22
77.75 173.0 173.4 1217.5 10.1 959.07 22
78.25 173.0 173.1 1188.3 10.0 969.10 22
78.75 173.0 173.2 1198.0 9.9 979.04 21
79.25 173.0 173.5 1227.4 10.1 989.15 20
79.75 173.0 173.3 1207.7 10.1 999.29 20
80.25 173.0 173.1 1188.3 10.0 1009.27 20
80.75 173.0 173.4 1217.5 10.0 1019.30 19
81.25 173.0 173.2 1198.0 10.1 1029.36 19
81.75 173.0 172.9 1169.2 9.9 1039.23 19
82.25 173.0 173.4 1217.5 9.9 1049.17 17
82.75 173.0 173.3 1207.7 10.1 1059.28 17
83.25 173.0 173.4 1217.5 10.1 1069.38 16
83.75 173.0 173.1 1188.3 10.0 1079.41 16
84.25 173.0 173.0 1178.7 9.9 1089.27 16
84.75 173.0 173.4 1217.5 10.0 1099.25 15
85.25 173.0 173.2 1198.0 10.1 1109.32 15
85.75 173.0 172.9 1169.2 9.9 1119.18 14
86.25 173.0 173.3 1207.7 9.9 1129.09 13
86.75 173.0 173.5 1227.4 10.1 1139.23 13
87.25 173.0 173.3 1207.7 10.1 1149.38 12
87.75 173.0 173.1 1188.3 10.0 1159.36 12
88.25 173.0 173.0 1178.7 9.9 1169.22 12
88.75 173.0 171.6 1052.0 9.3 1178.52 13
89.25 173.0 173.1 1188.3 9.3 1187.85 11
89.75 173.0 173.3 1207.7 10.0 1197.84 10
90.25 173.0 173.6 1237.4 10.2 1208.02 9
90.75 173.0 173.3 1207.7 10.2 1218.21 9
91.25 173.0 173.2 1198.0 10.0 1228.24 9
91.75 173.5 1227.4 10.1 1238.34 8
92.25 173.5 1227.4 10.2 1248.57 7
92.75 173.0 1178.7 10.0 1258.60 7
93.25 173.2 1198.0 9.9 1268.50 7
93.75 173.4 1217.5 10.1 1278.56 6
94.25 173.3 1207.7 10.1 1288.67 6
94.75 173.0 1178.7 9.9 1298.61 5
95.25 173.2 1198.0 9.9 1308.52 5
95.75 173.4 1217.5 10.1 1318.58 4
96.25 173.2 1198.0 10.1 1328.64 4
96.75 173.0 1178.7 9.9 1338.55 3
97.25 173.0 1178.7 9.8 1348.37 3
97.75 173.0 1178.7 9.8 1358.19 2
98.25 170.6 969.5 9.0 1367.14 2
98.75 169.1 857.0 7.6 1374.75 2
99.25 168.0 782.6 6.8 1381.59 1
99.75 160.2 405.3 4.9 1386.54 2
100.25 145.5 109.8 2.1 1388.68 6
100.75 130.1 25.2 0.6 1389.24 26
101.25 117.2 6.7 0.1 1389.38 95
101.75 108.1 2.5 0.0 1389.42 253
102.25 101.2 1.2 0.0 1389.43 551
102.75 89.4 0.3 0.0 1389.44 2239
103.25 78.1 0.1 0.0 1389.44 9363
103.75 70.4 0.0 0.0 1389.44 26200
104.25 62.8 0.0 0.0 1389.44 75771
104.75 60.6 0.0 0.0 1389.44 103975

r'(T) = exp (43.2-16113/T)

D Hi = [ r'n + r'( n-1)] * [Øn - Ø (n-1)] / 2
r'(170oC) = 922.9
Øa = (Hc - SDHi)*60/r'(173oC)
 NOTEBOOK
tiempo (min) T leída (ºC) T consigna (ºC)
0 114.6 120
0.5 118.3 120
1 118.6 120
1.5 118.6 120
2 118.7 120
2.5 118.6 120
3 118.9 120
3.5 119.2 120
4 119 120
Vaporado 4.5 119.2 120
5 118.7 120
5.5 118.9 120
6 118.7 120
6.5 119.3 120
7 119.5 120
7.5 118.6 120
8 118.6 120
8.5 118.9 120
9 119.3 120
9.5 119.3 120
10 119.6 120
10.5 114.1 121.3
11 108.6 122.7
vapor indirecto 11.5 107.1 124
12 78.4 125.3
12.5 90.8 126.6
13 90.3 128
13.5 98.1 129.3
14 101.6 130.6
14.5 103.1 131.9
15 103.5 133.3
15.5 102.7 134.6
16 102.1 135.9
16.5 103.1 137.2
 17 105 138.6
17.5 108.8 139.9
18 113.2 141.2
18.5 119.2 142.5
Comienza la 19 124.7 143.8
trepada 19.5 128 145.2
20 130.5 146.5
20.5 132.3 147.8
21 134.4 149.2
21.5 136.9 150.5
22 139.2 151.8
22.5 141.3 153.1
23 143.4 154.4
23.5 145.7 155.8
24 147.6 157.1
24.5 150.1 158.4
25 152.1 159.8
25.5 153.8 161.1
26 156.9 162.4
26.5 159.1 163.7
27 161.3 165.1
27.5 162.8 166.4
28 164.6 167.7
28.5 165.6 169
29 166.5 170.3
29.5 167.5 171.7
30 168.3 173
30.5 168.8 173
31 169.1 173
31.5 169.4 173
32 169.8 173
32.5 170.3 173
33 170.4 173
33.5 170.7 173
34 170.9 173
34.5 170.9 173
35 170.9 173
35.5 170.7 173
36 170.6 173
36.5 171.1 173
37 171.4 173
37.5 171.2 173
38 172.9 173
38.5 173.5 173
39 173.3 173
39.5 172.7 173
40 173 173
40.5 173.3 173
primer muestra 41 173.5 173
41.5 173 173
42 173.2 173
42.5 173.5 173
43 173.6 173
vapor directo 43.5 173.2 173
44 173.2 173
44.5 172.7 173
45 173.2 173
45.5 173.5 173
46 173.3 173
46.5 172.9 173
47 173.5 173
47.5 173.5 173
48 173.3 173
48.5 172.7 173
49 173.5 173
49.5 173.6 173
50 173.6 173
50.5 172.1 173
51 172.6 173
51.5 174 173
52 174 173
52.5 173.5 173
53 173 173
53.5 173.3 173
54 173.5 173
54.5 173.6 173
55 173.2 173
55.5 173 173
56 173.8 173
56.5 173.8 173
57 173.6 173
57.5 173.2 173
58 173.2 173
58.5 173.8 173
59 174.1 173
59.5 173.3 173
60 173.2 173
60.5 173.5 173
61 173.5 173
61.5 173.2 173
62 173 173
62.5 173 173
63 173.3 173
63.5 173.3 173
64 173.2 173
64.5 173 173
 65 173.3 173
65.5 173.6 173
66 173.2 173
66.5 172.4 173
67 172.9 173
67.5 173.3 173
68 173.3 173
68.5 173.2 173
69 172.9 173
69.5 173.2 173
70 173.5 173
70.5 173.3 173
71 173.2 173
71.5 173.3 173
72 172.6 173
72.5 173 173
73 172.6 173
73.5 172.7 173
74 173.3 173
74.5 173.5 173
75 173.3 173
75.5 172.9 173
76 173.3 173
76.5 173.5 173
77 173.2 173
77.5 173 173
78 172.7 173
78.5 173.3 173
79 173.3 173
79.5 173 173
80 172.4 173
80.5 173.2 173
81 173.2 173
81.5 173.3 173
82 172.9 173
82.5 172.9 173
83 173.3 173
83.5 173.2 173
84 172.7 173
84.5 172.7 173
85 173.2 173
85.5 173.3 173
86 173 173
86.5 172.7 173
87 172.4 173
87.5 172.4 173
88 173.2 173
88.5 173.2 173
 89 173.3 173
89.5 173.3 173
90 173.2 173
90.5 173.2 173
91 173.2 173

Segunda muestra
 AL C AL I AC TIVO R ESID U AL (g N aOH /L)
TEM PER ATU R A (°C ) CICLO TERMICO PULPADO KRAFT
200.0 45

40
180.0

35
160.0

CICLO TERMICO DISPLAY LUMINOSO 30

140.0 CICLO TERMICO TEORICO

CICLO TERMICO NOTEBOOK

25
ALCALI ACTIVO
120.0

20

100.0
15

80.0
10

60.0
5

40.0 0
0 20 40 60 80 100 120

TIEMPO (min)
 Trabajo Práctico: PULPADO KRAFT
Fecha: 10/22/2004
Comisión No: 1
DETERMINACION DEL RENDIMIENTO (Pulpa sin depurar)
Sequedad de la pulpa centrifugada:
Muestra (1) No 557 (2) No 300
Tara 85.0689 g. 85.8409 g.
Tara + MH 106.6139 g. 103.7801 g.
Tara + MS 91.4278 g. 91.0958 g.
MH 21.545 g. 17.9392 g.
MS 6.3589 g. 5.2549 g.
Sequedad 0.2951 0.2929
Sequedad pulpa centrifugada Spc = 0.2940
Masa de chips secos secos Mss = 1038.0 g.
Masa de pulpa centrifugada Mpc = 1827.59 g.
Masa de pulpa seca seca Mpss = 537.4 g.

Rendimiento n= 51.77 %
Mss = Mpc*Spc n = Mpss*100/Mss

DETERMINACION DE RECHAZOS
La pulpa se pasó por zaranda Valley de 0.030 "= 00,762mm.
Masa pulpa sin depurar Ps/d = 1827.6 g.
Sequedad pulpa sin depu Spc = 0.2940 La pulpa se disperso en hidrapulper
Tara T= 347.0300 g.
Tara + rechazos T + MR = 371.7500 g.
Masa de rechazos MR = 24.7200 g.

Contenido de rechazos R= 4.60 %

R = MR*100/Ps/d
CALCULO DEL CONSUMO DE ALCALI.
Ø pH AA Consumo de álcali
(min) (gNaOH/L) (g AA/ (g AA/
100g mad.) 100g pulpa)
0 13.2 40 0 0
37 12.8 13.2 13.4 25.9
 98 12.6 8.2 15.9 30.7
C.I. = (MoNaOH - AAi*Vt/1000)*100/Mss
(1) No se ha tenido en cuenta la dilución por condensación de vapor directo ni los volúmenes de licor extraído.
or extraído.