DIAGRAMA DE EQUILI

BENCENO-TOLUENO

DATOS DE ANTOINE PRESION TOTAL

A B C P
BENCENO 6.90565 1211.33 220.79
TOLUENO 6.95464 1344.8 219.48

T(ºC) PA P(mmHg) PB P(mmHg) XA PA* YB

80.1737851806 760 292.9504284523 1 760 1

85 879.7042303024 345.0877499539 0.7760932655 682.7325288063 0.8983322747
90 1018.747187244 406.7115480513 0.5772350976 588.0566320995 0.7737587264
95 1174.297293117 476.8419098235 0.4059873892 476.7498922272 0.6273024898
100 1347.615375803 556.2881672584 0.2574305932 346.9174256507 0.4564702969
105 1539.992793103 645.896130069 0.1276191654 196.532594991 0.2585955197
110.627340227 1780.947602267 760 0 0 0

1
DIAGRAMA T X-Y @ 760 mmHg
Benceno-Tolueno 0.9

115 0.8

110 0.7
105
0.6
100
0.5
95
T(ºc)

0.4
90

85 0.3

80 0.2

75 0.1
70
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
fraccion mol
X-Y 1
 DATOS DE ANTOINE
A B C
METANOL 7.97328 1515.14 232.85
ETANOL 8.32109 1718.1 237.52

T(ºC) PA P(mmHg) PB P(mmHg) XA PA*

64.6757721295 760 432.21786771 1 760

67.1757721295 838.0060750099 481.227881389 0.7813597456 654.7842136
69.6757721295 922.5277102597 534.859347699 0.5807558058 535.76332379
72.1757721295 1013.9758130545 593.454640266 0.3960451233 401.58017592
74.6757721295 1112.7776060001 657.373811499 0.2253520716 250.76673873
77.1757721295 1219.3767495669 726.995008377 0.0670313069 81.73641717
78.2911594408 1269.5723930257 760 0 0

DIAGRAMA T X-Y @ 760 mmHg

Metanol-Etanol
80 1

78 0.9

76 0.8

74 0.7

72 0.6
70
T(ºc)

0.5

y
68 0.4
66 0.3
64 0.2
62 0.1
60 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0
Fraccion mol
MA DE EQUILIBRIO LIQUIDO VAPOR
METANOL-
ETANOL

PRESION TOTAL DATOS DE ANTOINE

760 mmHg A B C
BENCENO 6.90565 1211.33 220.79
TOLUENO 6.95464 1344.8 219.48

PB* α T(ºC) PA P(mmHg) PB P(mmHg) XA PA*

0 2.5942955742 104.503494 1520 636.518834 1 1520

77.267471194 2.5492189463 109.503494 1730.67198 736.032391 0.78819265 1364.10293
171.9433679 2.5048395899 114.503494 1962.92943 847.410245 0.60293876 1183.52624
283.25010777 2.4626553768 119.503494 2218.13244 971.594819 0.43994274 975.851272
413.08257435 2.4225131058 124.503494 2497.65779 1109.55821 0.29568613 738.522762
563.46740501 2.3842731384 129.503494 2802.89548 1262.30012 0.16727292 468.848501
760 2.3433521082 136.96648 3309.35588 1520 0 0

DIAGRAMA T X-Y @ 1520 mmHg D

Benceno-Tolueno 1
140
0.9

135 0.8

130 0.7

125 0.6

0.5
Y

120
T(ºc)

0.4
115
0.3
110
0.2
105 0.1

100 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2
.3 0.4 0.5 0.6 0.7 0.8 0.9 1 Fraccion mol
X-Y 1
 PRESION TOTAL DATOS DE ANTOINE
P 760 mmHg A B
METANOL 7.97328 1515.14
ETANOL 8.32109 1718.1

YB PB* α T(ºC) PA P(mmHg) PB P(mmHg)

1 1.0231815E-12 1.75837247 112.009734 3800 2544.65175

0.8615581758 105.2157864 1.74139136 114.509734 4086.99633 2757.63229
0.7049517418 224.23667621 1.72480431 117.009734 4391.09663 2985.05297
0.5283949683 358.41982408 1.70859868 119.509734 4713.02187 3227.64496
0.3299562352 509.23326127 1.6927623 122.009734 5053.50824 3486.1619
0.1075479173 678.26358283 1.67728352 124.509734 5413.30689 3761.37996
0 760 1.67048999 124.848481 5463.58668 3800

DIAGRAMA X-Y DIAGRAMA T X-Y @ 3800 mmH

Metanol-Etanol Metanol-Etanol
1 130
0.9

0.8 125
0.7

0.6 120
Axis Title

0.5
y

0.4 115
0.3

0.2 110

0.1

0 105
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.

X Axis Title
 PRESION TOTAL DATOS DE ANTOINE
P 1520 mmHg A B
BENCENO 6.90565 1211.33
TOLUENO 6.95464 1344.8

YB PB* α Presion Tolueno

Presion Benceno
1 0 2.38798904 222.935800922 74.1217228234
0.89743614 155.897073 2.35135301
0.77863568 336.473764 2.31638624 XA XB Pa*
0.64200742 544.148728 2.28298092 0 1 0
0.48587024 781.477238 2.25103809 0.1 0.9 7.41217228
0.30845296 1051.1515 2.22046677 0.2 0.8 14.8243446
0 1520 2.17720782 0.3 0.7 22.2365168
0.4 0.6 29.6486891
0.5 0.5 37.0608614
0.6 0.4 44.4730337
DIAGRAMA X-Y 0.7 0.3 51.885206
1
0.8 0.2 59.2973783
0.9 0.1 66.7095505
0.9
1 0 74.1217228
0.8

0.7

0.6

0.5
Y

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

X
ANTOINE PRESION TOTAL
C P 3800 mmHg
232.85
237.52

XA PA* YB PB* α

1 3800 1 0 1.4933281134
0.78411005 3204.65491 0.84333024 595.345088 1.4820671867
0.57960293 2545.09248 0.66976118 1254.90752 1.4710280439
0.38532647 1816.05208 0.47790844 1983.94792 1.4602045552
0.20023532 1011.89085 0.26628707 2788.10915 1.4495908049
0.02337878 126.556514 0.03330435 3673.44349 1.4391810824
0 0 0 3800 1.4377859675

X-Y @ 3800 mmHg DIAGRAMA X-Y

nol-Etanol Metanol-Etanol
1

0.9

0.8

0.7

0.6
Axis Title

0.5

0.4

0.3

0.2

0.1

0.4 0.5 0.6 0.7 0.8 0.9 1 0

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Axis Title Axis Title
INE TEMPERATURA
C T 45 ºc
220.79
219.48

DIAGRAMA P X-Y @ 45 ºC
Benceno-Tolueno
230

210
Pb* P Y
190
222.935801 222.935801 0
200.642221 208.054393 0.03562613 170
presion (mmHg)

178.348641 193.172985 0.07674129 150

156.055061 178.291577 0.12471995
133.761481 163.41017 0.18143723 130

111.4679 148.528762 0.24951976 110

89.1743204 133.647354 0.33276404
90
66.8807403 118.765946 0.43686939
44.5871602 103.884538 0.57080081 70
22.2935801 89.0031306 0.74951915 50
0 74.1217228 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

fraccion mol

^
 45 ºC DIAGRAMA X-Y @ T=cte
no Benceno-Tolueno
1

0.9

0.8

0.7

0.6

0.5
y

0.4

0.3

0.2

0.1

0
.6 0.7 0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
l X
 DIAGRAMA DE EQUILI
BENCENO-
-335544.32
TOLUENO

DATOS DE ANTOINE PRESION TOTAL

A B C P
ACETONA 7.11714 1210.595 229.664
AGUA 7.96681 1668.21 228

Base 100 moles 70

T(ºC) PA P(mmHg) PB P(mmHg) XA YB PA*

56.1012795106 760 124.4300130191 1 1 760

80.9666666 1659.294099817 369.393869704 0.3028188702 0.6611389007 502.46556456
81 1660.892521588 369.8896130097 0.3021762262 0.660371361 501.88223438
82 1709.404068607 385.0236611493 0.2831334085 0.6368281584 483.98940037
86 1914.544052614 450.8575008484 0.2112081298 0.5320621956 404.36726869
88 2024.001556491 487.1519332544 0.1775372571 0.4728101116 359.33568479
100.000624906 2785.725296241 760 0 0 0

1
DIAGRAMA T X-Y @ 760 mmHg
0.9
Benceno-Tolueno
105 0.8

0.7
100

0.6
95
0.5
90
T(ºc)

0.4
85
0.3
80
0.2
75
0.1
 90

T(ºc)
0.4
85
0.3
80
0.2
75
0.1

70
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
fraccion mol X-Y 1

DIAGRAMA T X-Y @ 760 mmHg

Metanol-Etanol
120

110

100

90
T(ºc)

80

70

60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Fraccion mol
AMA DE EQUILIBRIO LIQUIDO VAPOR
METANOL-
ETANOL

SION TOTAL
760 mmHg

Chart Title
4

PB* α 1/(YB-XA) 3.5

0 6.1078511652 9.0072E+14 3
257.53443544 4.4919372949 2.79080128 2.5
258.11776562 4.4902383391 2.79177438
2
276.01059963 4.4397377125 2.8272967
355.63273131 4.2464504838 3.11668171 1.5
400.66431521 4.1547644961 3.38669805 1
760 3.6654280214 #DIV/0!
0.5
4.5137725019
0
0.16 0.18 0.2 0.22 0.24 0.26 0.28 0.3
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X-Y 1

DIAGRAMA X-Y DIAGRAMA T X-Y @ 3800 mmH

Metanol-Etanol Metanol-Etanol
1 12
0.9

0.8 10

0.7
8
0.6
Axis Title

0.5 6
y

0.4
4
0.3

0.2
2
0.1

0 0
0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

X Axis Title
e

0.26 0.28 0.3 0.32

X-Y @ 3800 mmHg DIAGRAMA X-Y
nol-Etanol Metanol-Etanol
1

0.9

0.8

0.7

0.6
Axis Title

0.5

0.4

0.3

0.2

0.1

0.4 0.5 0.6 0.7 0.8 0.9 1 0

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Axis Title Axis Title
^