Ejercicio 4:

Usando la fórmula del trabajo:

𝑊1−5= 𝑊1−2 + 𝑊2−3 + 𝑊3−4 + 𝑊4−5

𝑉2 𝑉4 𝑉5
𝑊1−5= 𝑚. 𝑃1. 𝑉1. ( ) + 𝑚. 𝑃3. 𝑉3. ( ) + 𝑚. 𝑃4. 𝑉4. ( )
𝑉1 𝑉3 4
Para esto hallamos antes los volúmenes:

𝑉1 = 0.89133
𝑉2 = 𝑉3 = 0.001404
𝑉4 = 0.021659
𝑉5 = 0.06845
Reemplazamos en la fórmula:
𝑉2 𝑉4 𝑉5
𝑊1−5= 𝑚. 𝑃1. 𝑉1. ( ) + 𝑚. 𝑃3. 𝑉3. ( ) + 𝑚. 𝑃4. 𝑉4. ( )
𝑉1 𝑉3 4
0.001404 0.021659
𝑊1−5= (25)(198.67)(0.89133)𝐿𝑛 ( ) + (25)(8587.9)(0.001404)𝐿𝑛 ( )
0.89133 0.001404
0.06845
+ (25)(8587.9)(0.021659)𝐿𝑛 ( )
0.021659
𝑊1−5= − 28569,2406 + 824,7558 + 5350,8267
𝑊1−5= − 22393,6581 𝐾𝐽