VALORACIÓN ACIDO-BASE FUERTE ml M

50 ml de HCl 0,1 M 50 0.1

Vamos añadiendo NaOH 0,1 M

CONCENTRACIO
ml NaOH añadidos moles OH- base moles H+ ácido moles H+ netos volumen total ml N DE H+ pH
0 0 0.005 0.005 50 0.1 1
10 0.001 0.005 0.004 60 0.0666666667 1.17609126
20 0.002 0.005 0.003 70 0.0428571429 1.36797679
30 0.003 0.005 0.002 80 0.025 1.60205999
40 0.004 0.005 0.001 90 0.0111111111 1.95424251
45 0.0045 0.005 0.0005 95 0.0052631579 2.2787536
49 0.0049 0.005 0.0001 99 0.001010101 2.99563519
49.9 0.00499 0.005 0.00001 99.9 0.0001001001 3.99956549
50 0.005 0.005 0.00000001 100 0.0000001 7
50.1 0.00501 0.005 0.000000001 100.1 0.00000001 8.00043408
51 0.0051 0.005 1E-10 101 0.000000001 9.00432137
55 0.0055 0.005 2E-11 105 1.9047619E-10 9.7201593
60 0.006 0.005 1E-11 110 9.09090909E-11 10.0413927
70 0.007 0.005 5E-12 120 4.16666667E-11 10.3802112
80 0.008 0.005 3.3333333333333E-12 130 2.56410256E-11 10.5910646
90 0.009 0.005 2.5E-12 140 1.78571429E-11 10.748188
100 0.01 0.005 2E-12 150 1.33333333E-11 10.8750613
resumen

ml NaOH añadidos pH pH
0 1
12
10 1.17609126
20 1.36797679
30 1.60205999 10
40 1.95424251
45 2.2787536
49 2.99563519 8
49.9 3.99956549
pH
50 7 6
50.1 8.00043408
51 9.00432137
55 9.7201593 4
60 10.0413927
70 10.3802112
2
80 10.5910646
90 10.748188
100 10.8750613 0
0 20 40 60 80 100 120
 VALORACIÓN ACIDO-
BASE FUERTE
ml M nº moles H+
50 ml de HCl 0,1 M 50 0.1 0.005
V NaOH 0,1 M
ml NaOH añadidos moles OH- base moles H+ exceso moles OH- netos volumen total ml [H+] [OH-] pH
0 0 0.005 50 1.00E-01 1.00
10 0.001 0.004 60 6.67E-02 1.18
20 0.002 0.003 70 4.29E-02 1.37
30 0.003 0.002 80 2.50E-02 1.60
40 0.004 0.001 90 1.11E-02 1.95
45 0.0045 0.0005 95 5.26E-03 2.28
49 0.0049 0.0001 99 1.01E-03 3.00
49.9 0.00499 0.00001 99.9 1.00E-04 4.00
50 0.005 0 100 1E-07 (agua) 1E-07 (agua) 7.00
50.1 0.00501 0.00001 100.1 9.99E-05 10.00
51 0.0051 0.0001 101 9.90E-04 11.00
55 0.0055 0.0005 105 4.76E-03 11.68
60 0.006 0.001 110 9.09E-03 11.96
70 0.007 0.002 120 1.67E-02 12.22
80 0.008 0.003 130 2.31E-02 12.36
90 0.009 0.004 140 2.86E-02 12.46
100 0.01 0.005 150 3.33E-02 12.52
ml NaOH añadidos pH
0 1.00
10 1.18
20 1.37 pH
30 1.60
14.00
40 1.95
45 2.28 12.00
49 3.00
49.9 4.00 10.00
50 7.00
50.1 10.00 8.00
51 11.00
55 11.68 6.00
60 11.96
70 12.22 4.00

80 12.36
2.00
90 12.46
100 12.52
0.00
0 20 40 60 80 1
mL de NaOH 0,1 M añadidos
 pH

pH

40 60 80 100 120
mL de NaOH 0,1 M añadidos