Volumen a titular 25 Mililitros de NAOH pH experimental

Concentración HCl 0.0995 0 1.21

Concentración NaOH 0.09032 1 1.28
2 1.29
3 1.39
4 1.43
5 1.42
6 1.45
7 1.45
8 1.48
9 1.52
10 1.53
11 1.6
12 1.63
13 1.69
14 1.77
15 1.86
16 1.89
17 1.97
17.5 2.02
18 2.09
18.5 2.15
19 2.19
19.5 2.36
20 2.49
20.5 2.7
21 3.14
21.5 9.31
22 10.5
22.1 10.52
22.2 10.63
22.3 10.67
22.4 10.73
22.5 10.79
22.6 10.83
22.7 10.86
22.8 10.91
22.9 10.96
23 11.02
23.5 11.17
24 11.28
24.5 11.38
25 11.46
25.5 11.53
27 11.66
28 11.7
29 11.74
30 11.79
31 11.83
32 11.86
33 11.91
[H+] [OH-] pH teórico pOH teórico Primera derivada Segunda derivada
0.0995 1.0 13.0 0.07 -0.06
0.0922 1.0 13.0 0.01 0.09
0.0854 1.1 12.9 0.1 -0.06
0.0792 1.1 12.9 0.04 -0.05
0.0733 1.1 12.9 -0.01 0.04
0.0679 1.2 12.8 0.03 -0.03
0.0628 1.2 12.8 0 0.03
0.0580 1.2 12.8 0.03 0.01
0.0535 1.3 12.7 0.04 -0.03
0.0493 1.3 12.7 0.01 0.06
0.0453 1.3 12.7 0.07 -0.04
0.0415 1.4 12.6 0.03 0.03
0.0379 1.4 12.6 0.06 0.02
0.0346 1.5 12.5 0.08 0.01
0.0314 1.5 12.5 0.09 -0.06
0.0283 1.5 12.5 0.03 0.05
0.0254 1.6 12.4 0.08 0.02
0.0227 1.6 12.4 0.1 0.08
0.0213 1.7 12.3 0.14 -0.04
0.0200 1.7 12.3 0.12 -0.08
0.0188 1.7 12.3 0.08 0.52
0.0175 1.8 12.2 0.34 -0.16
0.0163 1.8 12.2 0.26 0.32
0.0151 1.8 12.2 0.42 0.92
0.0140 1.9 12.1 0.88 22.92
0.0128 1.9 12.1 12.34 -19.92
0.0117 1.9 12.1 2.38 -4.36
0.0106 2.0 12.0 0.2 9
0.0104 2.0 12.0 1.1 -7
0.0102 2.0 12.0 0.4 2
0.0100 2.0 12.0 0.6 -3.90798504668063E-13
0.0098 2.0 12.0 0.6 -2
0.0096 2.0 12.0 0.4 -1
0.0094 2.0 12.0 0.3 2
0.0092 2.0 12.0 0.5 1.77635683940023E-13
0.0090 2.0 12.0 0.5 1
0.0088 2.1 11.9 0.6 -3
0.0085 2.1 11.9 0.3 -0.16
0.0075 2.1 11.9 0.22 -0.04
0.0065 2.2 11.8 0.2 -0.08
0.0055 2.3 11.7 0.16 -0.04
0.0046 2.3 11.7 0.14 -0.1066666667
0.0037 2.4 11.6 0.0866666667 -0.0311111111
0.0009 3.0 11.0 0.04 1.77635683940025E-15
0.0008 10.89 3.1066 0.04 0.01
0.0024 11.39 2.6125 0.05 -0.01
0.0040 11.61 2.3938 0.04 -0.01
0.0056 11.75 2.2534 0.03 0.02
0.0071 11.85 2.1509 0.05 0.3109090909
0.0085 11.93 2.0705 0.3609090909 0.0109366391
Primera derivada teórica Segunda derivada teórica
0.0331 -1.0166
-0.9835 -1.0055
-1.9890 -1.0027
-2.9917 -1.0016
-3.9933 -1.0011
-4.9943 -1.0007
-5.9951 -1.0005
-6.9956 -1.0004
30
-7.9960 -1.0003 Segunda derivada vs Vo
-8.9963 -1.0002 Segunda deri va da experi mental
-9.9966 -1.0002
20
-10.9968 -1.0001
-11.9969 -1.0001
-12.9970 -1.0001
-13.9970 -1.0000
10
-14.9971 -1.0000
Segunda derivada
-15.9971 -1.0014
-16.9985 -1.0000
0
-17.4985 -1.0000
0 5 10 15
-17.9985 -0.9999
-18.4984 -0.9999
-18.9984 -0.9999
-10
-19.4984 -0.9999
-19.9983 -0.9999
-20.4983 -0.9998
-20.9982 -20
-0.9998
-21.4981 -1.0030
-21.9996 -1.0000
-22.0996 -1.0000
-30 Volumen
-22.1996 -0.9999
-22.2996 -0.9999
-22.3996 -0.9999
-22.4996 -0.9999
-22.5996 -0.9999
-22.6996 -0.9999
-22.7996 -0.9999
-22.8995 -0.9810
-22.9977 -0.9995
-23.4974 -0.9994
-23.9971 -0.9992
-24.4967 -0.9988
-24.9961 -0.9641
-25.4782 -0.8273
-26.7191 -1.2639
-27.9830 -1.0097
-28.9927 -1.0028
-29.9955 -1.0013
-30.9968 -1.0008
-31.9976 #DIV/0!
#DIV/0! #DIV/0!
 Segunda derivada vs Volumen de NaOH
Segunda deri va da experi mental Segunda deri va da teóri ca

10 15 20 25 30 35

Volumen de NaOH
 Curva de titulación ácido- base
14
13.5
13
12.5
12
11.5
11
10.5
10
9.5
9
8.5
8
7.5
7
pH

6.5
6
5.5
5
4.5
4
3.5
3
2.5
2
1.5
1
0.5
0
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 2

Volumen NaOH mL
ulación ácido- base

20

Pri mera deri vada

10 experi mental
Pri mera deri vada teóri ca

0
0 5

-10

pH
-20

-30

-40

15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34

Volumen NaOH mL
 Gráfico primera derivada

Pri mera deri vada

experi mental
Pri mera deri vada teóri ca

5 10 15 20 25 30

Volumen de NaOH
30 35