06/04/2018, preliminary report N°6

PRELIMINARY REPORT 6
SOLID-LIQUID PHASE DIAGRAM AND EUTECTIC POINT
LABORATORIO DE PROPIEDADES TERMODINÁMICAS Y DE TRANSPORTE
Universidad Nacional de Colombia - Sede Bogotá
Facultad de Ingeniería Química y Ambiental
10 de Abril de 2018

Andrés David Galindo Alfonso, 1014284903, adgalindoa@unal.edu.co

Dayanna Catherin Galvis Guiral, 1033799538, dcgalvisg@unal.edu.co
Andrés Felipe Sánchez Caro, 1233888415, afsanchezca@unal.edu.co
Grupo N° 4

ABSTRAC
The eutectic point, is the temperature of congelation, when a mixture of liquids A and B, with
fusion points different is cools, coming to precipitate a solid of A and B, this solid stay in
equilibrium with the phase liquid of the mixture. This temperature is the lowest temperature
of the congelation temperatures, with a specific composition. In the practice we going to
determinate this temperature for a mixture liquid Urea-Naphthalene using the Diagrams of
temperature vs time, and analyze the phenomena from the point of view ideal and not ideal
too, we going to use the Gibbs rules and another criterions of equilibrium to analyze the
experiment.

INTRODUCCION

El punto eutéctico es la temperatura de congelación a la cual cuando se enfría una mezcla

liquida A y B con distinto punto de fusión, empieza a precipitarse un sólido de A y B que
estará en equilibrio con la mezcla liquida. La temperatura del eutéctico será la menor de las
temperaturas de congelación, a una composición especifica. En la práctica se determinara la
temperatura del eutéctico para una mezcla liquida Urea-Naftaleno por medio de diagramas
de enfriamiento (temperatura vs Tiempo), se analizara el fenómeno de manera ideal y no
ideal, teniendo en cuenta la regla de las fases de Gibbs y los criterios de equilibrio.
1.1 Objectives

1.1.1. General objective

Study the equilibrium Solid- Liquid of a system of liquids (Urea-Naphthalene) with different
fusion points, with a simple eutectic point, to build a diagram of equilibrium of the mixture
used.

1.1.2. Specific Objectives

• Do the experiment for different compositions of mixture, to build the diagram of
phases for the equilibrium solid- liquids of a mixture of liquids don’t miscible.
• Determinate the temperature of the simple eutectic point of the mixture of liquids
used in the experiment.
• Determinate the effect of the temperature in an equilibrium solid-liquid of a mixture
of liquids don’t miscible.
• Compare the experimental resulted with the resulted reports in the literature.
• Compare the error when assume that the system is comported of ideal form or not,
with the resulted in the literature.

1.2 Theoretical bases

Eutectic point
The eutectic point in a mixture is the composition and temperature on the same level in a
specific pressure where all components in the mixture crystallize simultaneously from the
liquid and the melting point being the lowest possible. To find this point, cooling curves are
built.

The eutectic point follows the Gibbs phases rules, the phase rule allows one to determine the
number of degrees of freedom (L) or variance of a chemical system. This is useful for
interpreting phase diagrams. where
𝐿 = 𝐶 − 𝐹 + 2 (𝐼)
In this point has a 3 phases, 2 components so the degree of freedom is 1. For example for
one specific pressure the eutectic point has already a composition and temperature definite.

Binary mixture
In that mixture found in solution two different substances, Exist two principals types of
binary mixtures: isomorphic, are mixtures where both components are soluble as much in
liquid phase like in solid phase forming a solid solution, for that reason this type of mixture
is not a eutectic mixture. In the other hand, the no isomorphic mixtures are where the solid
species are immiscible for that reason in that mixture do not form an intermediate solids.
Thermal analysis method
If the cooling temperature of the system is plotted on a temperature versus time diagram
starting with the mixture in the liquid state, a cooling curve is obtained which is used to obtain
the phase diagram of two-component systems which is the basis of thermal analysis method,
figure 2.

a) Pure substance b) Solution

Figure 2. Temperature Vs. time

The figure 2(a) has a 3 regions with different gradients, The first region represent the liquid
phase of component A who is cooling. The phase II shows the equilibrium between liquid
and solid phases where the temperature is equal until region III, that temperature is the fusion
temperature (𝑇𝑓𝐴 ). In the region III represent the cooling of the solid. The gradients I and III
are different because a liquid cools with a different speed from that a solid. In the other hand,
in the figure 2(b) has also 3 regions, the region IV is the solution phase cooling, the phase V
represent the equilibrium between solution and solid A, that region does not have a gradient
zero, because in that region the temperature changes because the solid A is in constant
precipitation and concentration in the solution decreases; in the same time the B component
concentration increases in the solution and fusion temperature of this component decreases.
When begin the region VI there is a simultaneous precipitation of two solids separates in
different phases, in that point found the eutectic point where the solution composition
the maximum allowed for this binary system has changed. When doing this procedure with
different composition can graph a binary phase diagram (Figure 3.)
 Figure 3. Binary phase diagram

2 . EQUIPMENTS Y METHODS
2.1 Equipments

• Beaker
• Test Tube
• Tweezers
• Heating machine
• Analytical balance
• Termocouple
• Tow
• Watch glass
• Spatula
• Thermometer

2.2 Reagents

• Urea
• Naphthalene
• Diphenylamine
• Phenol
2.3 Precedence
3. CALCULUS

3.1 Mathematical expression

• Fusion heat calculus

For the fusion heat calculus, based on equilibrium solid-liquid:

f S  f L (II)

𝜇𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛 = 𝜇𝑠𝑜𝑙𝑖𝑑 (III)

Where the chemical potential are equals. For an ideal solution the chemical potential are
defined like:

𝜇𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛 = 𝜇 ° + 𝑅𝑇 (IV)
Replacing IV in III:

𝜇𝑠𝑜𝑙𝑢𝑡𝑖𝑜𝑛 = 𝜇 ° + 𝑅𝑇 = 𝜇𝑠𝑜𝑙𝑖𝑑 (V)

Assuming constant pressure, we can obtain:

𝜇𝑠𝑜𝑙𝑖𝑑𝐴 (𝑃, 𝑇𝑓 ) − 𝜇𝑙𝑖𝑞𝑢𝑖𝑑𝐴 (𝑃, 𝑇𝑓 )

𝐿𝑛(𝑋) = (VI)
𝑅 𝑇𝑓

𝛥𝐺𝑚,𝑓 (𝑃, 𝑇𝑓 )
𝐿𝑛(𝑋) = (VII)
𝑅 𝑇𝑓
Derivate respect x:

1 1 𝜕[𝛥𝐺⁄𝑇] 𝜕𝑇
=− ( ) (VIII)
𝑋𝐴 𝑅 𝜕𝑇 𝜕𝑋

Obtain the Gibbs-Helmholtz equation:

1 1 ∆H 𝜕𝑇
= ( 2) (IX)
𝑋𝐴 𝑅 𝑇 𝜕𝑋
Integrate:
𝑋𝐴 𝑇
𝑑𝑋 1 ∆H
∫ = ∫ ( 2 ) 𝑑𝑇 (X)
1 𝑋𝐴 𝑇𝑓 𝑅 𝑇
 ~ ~
 H f  1   H f  1 
Ln( X )     (XI)
R T  R  T f 

~ ~
 H f 2  1   H f 2  1 
Ln(1  X )     (XII)
R T  R  T f 2 
Where:

X: Component A composition.
𝑇𝑓 : Component A Fusion temperature
𝑇𝑓2 : Component B Fusion temperature
∆𝐻𝑓 : Component A Fusion heat
∆𝐻𝑓2 : Component B Fusion heat

With that equation, graph 1/T Vs Ln (X) for each component where the gradient is:

Hf
m (XIII)
R

• Eutectic Point

Matching the next equation can be calculate the composition for which the eutectic point of
the mixture is established:

2
R * TA
T  TA  ln X A (XIV)
H fA

2
R * TB
T  TB  ln(1  X A ) (XV)
H fB
Then is possible determinate the solution eutectic temperature

3.2 Calculation sample

3.2.1 Construction of the cooling curves.

With the time and temperature data taken for each of the tests the respective thermograms
are made, from which the solidification point of the binary mixture will be determined. As it
will be noticed in the graphs, in the majority of cases a "break point" is presented, this is the
temperature goes down and in an instant of time it increases suddenly (formation of the first
solid), then it continues in descent until it gives the formation of the second solid, this is seen
in the instant in which the temperature increases again, unlike the first case this increase is
slight and in some cases almost imperceptible.
 Graph. Theoretical Diagram ESL Phenol-Urea system

3.2.2 Determination of Crystallization Point

With the thermograms made it is easy to identify the point at which the formation of the solid
begins, this is therefore the point of crystallization; for each of the tests the molar fraction of
phenol is calculated, and the crystallization point is also tabulated, this is the point at which
the temperature increases suddenly, since the first trace of solid appears.

The molar fraction is calculated by knowing the mass of each component added in each test,
it is necessary in every equilibrium to determine the percentage in the mixture:

mi
M
xi  N i
mi

i 1 M i

0,1
60,06 g / mol
x ph   0,15
0,9 0,1

94,11 60,06 g / mol
For this case it is 1 - Phenol and 2 - Urea; considering that the mass of Urea (m2) must be the
difference between the total required mass of the mixture (m) and that of Phenol (m1),
substituting in previous equation and clearing the mass of urea we obtain:

x1  m  M1
m1 
M 2  x1  M1  M 2 

0,15  1g  60,06 g / mol

m Ph 
94,11g / mol  0,15  94,11g / mol  60,06 g / mol 

For example, for a molar phenol fraction of 0.70 and a sample mass of 1 g (where M1 =
94.11 g / gmol and M2 = 60.06 g / gmol), the required phenol mass is calculated:

g
0.70  1g  94,11
gmol
m1   0,78 g
 g 
 0.70  94,11  60,06 
g
gmol 
60,06
gmol 

With the above data we obtain the experimental graph for the solid-liquid equilibrium, additionally
we have a theoretical equilibrium diagram from which the experimental error for each of the trials
was calculated. In this way, the theoretical temperature is calculated and then the error is
calculated using the equation:

 Ttheorical  Texp erimental 

% Error    *100
 T theoricl 

 40,05  40 
% Error    *100  0,12
 40,05 

3,1.3 Determination of Fusion Heat

The heat of fusion of urea is obtained by the equation:

~
H f 1  1 
Ln(1  X )     1 
R  T T f 1 

Likewise, the heat of fusion of phenol is obtained by an analogous expression:

~
H f 2  1 
Ln( X )     1 
R  T T f 2 

In such a way that for urea values of composition are taken corresponding to the first zone
(mixture rich in urea) with its corresponding pair of temperature, with them it is plotted ln
(1-X) vs 1 / T, this graph will approach a straight line where:

1 H f 1
Intercept b *
Tf1 R
Hf1
Pending m
R

Con R=1.9872 cal/molK, this gives the heat of fusion of urea

Analogously, the heat of fusion of phenol is obtained, only that on this occasion,
compositions close to unity are taken (mixture rich in phenol) and plot ln (X) vs 1 / T
obtaining approximately a straight line with the following characteristics:

1 H f 2
b *
Tf 2 R
Hf 2
m
R

For Example:

X T (K) Ln(1-X) 1/T

0.065 402 -0.067 2.49x10-3

0.2 363 -0.223 2.75x10-3
0.39 372 -0.494 2.69x10-3
0.5 363 -0.693 2.75x10-3
Table. Determination of the Urea Fusion Point
 Ln(1-X) vs 1/T y = -2059,7x + 5,0047
R2 = 0,9615
0
0,00245 0,0025 0,00255 0,0026 0,00265 0,0027 0,00275 0,0028
-0,1

-0,2

-0,3
Ln(1-X)

-0,4

-0,5

-0,6

-0,7

-0,8
1/T

Graphic. Ln x vs 1/T of Urea

CORRELATING R2 m ΔHf11 ΔHtheoric Error (%)

y = -2059.7x + 5.0047 0.9615 -2059.7 4093.04 3532.53 15.87

To determine the melting point, the following relationships will be used:

2
R *Tf 2
T  Tf 2  ln X
H f 2
2
R *Tf 1
T  Tf 1  ln(1  X )
H f 1

Where the subscript 1 refers to phenol and 2 to urea

We have a system of two equations with two unknowns (T and X) whose solution will give
us the coordinates of the eutectic point.

The calculation will be made using the theoretical heats of fusion first and then the heats
found experimentally, well, only that of urea since for lack of data it was not possible to
calculate the heat of fusion of phenol, so heat will be used of theoretical fusion of said
compound to find the solution.

ΔHf2 Tf2 (K) ΔHf1 Tf1 (K) X T (K)

T. Calculus 3532.53 406 2728 313.8 0.715 289.70
Experimental 4090.15 406 2728 313.1 0.756 293.10

1
Fusion Heat in cal/mol
4. REFERENCES

[1] Rosalba, P. (2006). determinación del diagrama de fase solido-liquido. [online] iqcelaya.
Available at: http://www.iqcelaya.itc.mx/~roosph/PracticasFQ/R.pdf [Accessed 2 Apr.
2018].
[2] SHOEMAKEER D.P., “Experimentos de Fisicoquímica”, Editorial Uthea, México
(1968). Pág. 215 – 219
[3] ocw. (2017). experimentación en química física. [online] Available at:
https://ocw.ehu.eus/file.php/207/TEMA_3._EQUILIBRIO_DE_FASES/Practica_4_equilbr
io_solido-liquido.pdf [Accessed 2 Apr. 2018].
[4] Smith W. Fundamentos de la ciencia e ingeniería de materiales. Mc Graw Hill. Tercera
edición. 1998
 He a lt h 2
1 1
Fire
2 0
Re a c t iv it y 0
P e rs o n a l E
P ro t e c t io n

Material Safety Data Sheet

Urea MSDS

Section 1: Chemical Product and Company Identification

Product Name: Urea Contact Information:

Catalog Codes: SLU1063, SLU1132, SLU1093, SLU1162 Sciencelab.com, Inc.
14025 Smith Rd.
CAS#: 57-13-6 Houston, Texas 77396
RTECS: YR6250000 US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
TSCA: TSCA 8(b) inventory: Urea
Order Online: ScienceLab.com
CI#: Not available.
CHEMTREC (24HR Emergency Telephone), call:
Synonym: Carbamide 1-800-424-9300
Chemical Name: carbonyldiamide International CHEMTREC, call: 1-703-527-3887
Chemical Formula: (NH2)2CO or CH4N2O For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Urea 57-13-6 100

Toxicological Data on Ingredients: Urea: ORAL (LD50): Acute: 8471 mg/kg [Rat]. 11000 mg/kg [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.
TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to
blood, cardiovascular system. Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention.
Skin Contact:

p. 1
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated
clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical
attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.

Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of heat.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on
the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill:
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate
the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable
protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice

p. 2
immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as
oxidizing agents.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 23°C (73.4°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Crystals solid.)

Odor:
Almost odorless; May gradually develop slight odor of ammonia, especially in presence of moisture.
Taste: Cooling. Saline
Molecular Weight: 60.06 g/mole
Color: White.
pH (1% soln/water): Not available.
Boiling Point: Not available.
Melting Point: 132.7°C (270.9°F)
Critical Temperature: Not available.
Specific Gravity: 1.323 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: 2.07 (Air = 1)
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: The product is more soluble in water; log(oil/water) = -2.1
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility: Easily soluble in cold water, hot water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

p. 3
Instability Temperature: Not available.
Conditions of Instability: Excess heat, excess dust generation, incompatible materials.
Incompatibility with various substances: Reactive with oxidizing agents.
Corrosivity: Not available.
Special Remarks on Reactivity:
Hygroscopic. Aborbs moisture from air. Reacts violently with Gallum Perchlorate. Reacts with chlorine to form chloramines. It
also reacts with the following: sodium hypochlorite, sodium nitrate, calcium hypochlorite, NaNO2, P2Cl5, nitrosyl perchlorate,
strong oxidizing agents (permanganate, nitrate, dichromate, chloride)
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 8471 mg/kg [Rat].
Chronic Effects on Humans:
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. May cause damage to the following organs: blood,
cardiovascular system.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans:
May cause adverse reproductive effects (fetotoxicity) and genetic material (mutagenicity) based on animal studies. Passes
through the placental barrier in human and is present in breast milk.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: Causes skin irritation. Eyes: Causes eye irritation. Inhalation: Causes irritation of the
respiratory tract, nose, and throat, coughing and sneezing. May also affect blood, metabolsim and urinary system. Ingestion:
Causes digestive (gastrointestinal) tract irritation with nausea, vomiting, and diarrhea. May affect behavior (altered sleep
time, change in motor activity), cardiovascular system (heart rate), and the brain. May also affect the blood and may cause
tumorigenic effects. Chronic Potential Health Effects: Prolonged exposure may cause adverse reproductive effects. Laboratory
experiments on animals have resulted in mutagenic effects. Prolonged exposure or exposure at high concentrations may
cause eye damage.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.

p. 4
 Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).

Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations:

Minnesota: Urea TSCA 8(b) inventory: Urea
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the
European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
R36/38- Irritating to eyes and skin. R40- Possible risks of irreversible effects. S24/25- Avoid contact with skin and eyes.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 1
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.
Created: 10/10/2005 08:32 PM
Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.

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 Material Safety Data Sheet

Issuing Date 06/04/10 Revision Number 0

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name Phenol, Saturated Solution

Product Code(s) 0945

UN-No 2821

Distributor
AMRESCO INC.
6681 Cochran Road
SOLON, OHIO 44139

Company Phone Number 1-800-829-2805

Emergency Telephone Number Chemtrec 1-800-424-9300

2. HAZARDS IDENTIFICATION
Emergency Overview
Highly toxic
Corrosive
Combustible
Appearance Clear, Two-Layer Physical State Liquid Odor Phenolic, Medicinal

Potential Health Effects

Acute Toxicity
Eyes Corrosive.
Skin Very toxic in contact with skin. Corrosive, causes burns. readily absorbed through skin.
Inhalation Very toxic by inhalation. corrosive ,causes burns.
Ingestion Very toxic if swallowed. Corrosive, causes burns.

Chronic Effects No known effect based on information supplied.

Aggravated Medical Conditions None known.

Environmental Hazard See Section 12 for additional Ecological Information.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No Weight %

Phenol 108-95-2 95-100

4. FIRST AID MEASURES

Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

_____________________________________________________________________________________________

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Skin Contact Wash skin with soap and water.

Inhalation Move to fresh air. If breathing becomes difficult, give oxygen.

Ingestion Clean mouth with water and afterwards drink plenty of water.

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Flammable Properties combustible liquid.

Flash Point Not determined

Suitable Extinguishing Media Dry chemical, CO2, water spray or regular foam.

Hazardous Combustion Products Carbon oxides

Explosion Data
Sensitivity to Mechanical Impact Not sensitive.
Sensitivity to Static Discharge Not sensitive.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-
demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

NFPA Health Hazard - Flammability - Stability - Physical and Chemical

Hazards -

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Avoid contact with skin, eyes and clothing. Use personal protective equipment. Ensure
adequate ventilation
.

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up Cover with dry lime or soda ash. Pick up and transfer to properly labeled containers.
Ventilate area and wash spill site after material pickup is complete.

7. HANDLING AND STORAGE

Handling Handle in accordance with good industrial hygiene and safety practice. Light Sensitive.

Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from light.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

Phenol TWA: 5 ppm TWA: 19 mg/m3 IDLH: 250 ppm
108-95-2 TWA: 5 ppm Ceiling: 15.6 ppm
(vacated) TWA: 19 mg/m3 Ceiling: 60 mg/m3
(vacated) TWA: 5 ppm TWA: 19 mg/m3
Skin TWA: 5 ppm

Engineering Measures Showers

Eyewash stations
Ventilation systems.
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Personal Protective Equipment

Eye/Face Protection Tightly fitting safety goggles.
Skin and Body Protection Wear protective gloves/clothing.
Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Clear Two-Layer Odor Phenolic, Medicinal

Physical State Liquid
Flash Point No information available Autoignition Temperature No information available
Boiling Point/Range No information available
Flammability Limits in Air No information available
Explosion Limits No information available

Solubility No information available Evaporation Rate No information available

Vapor Density No information available.

10. STABILITY AND REACTIVITY

Stability Stable under recommended storage conditions.

Incompatible Products Strong oxidizing agents. Strong acids. Strong bases.

Conditions to Avoid Protect from light.

Hazardous Decomposition Products Carbon oxides.

Hazardous Polymerization Hazardous polymerization does not occur.

11. TOXICOLOGICAL INFORMATION

Acute Toxicity

Product Information Very toxic by inhalation, in contact with skin, or if swallowed. Corrosive, causes burns.

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

Phenol 317 mg/kg ( Rat ) 525 mg/kg ( Rat ) 316 mg/m3( Rat ) 4 h
630 mg/kg ( Rabbit )

Chronic Toxicity

Target Organ Effects Kidney, Liver, Central nervous system (CNS)

12. ECOLOGICAL INFORMATION

Ecotoxicity
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Harmful to aquatic organisms.

Chemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (Water
Flea)
Phenol EC50 = 150 mg/L 96 h LC50 5 - 12 mg/L EC50 21 - 36 mg/L 30 min LC50 = 13 mg/L 48 h
Oncorhynchus mykiss 96 h EC50 = 23.28 mg/L 5 min EC50 = 23.0 mg/L 48 h
LC50= 23.88 mg/L Lepomis EC50 = 25.61 mg/L 15 min
macrochirus 96 h EC50 = 28.8 mg/L 5 min
LC50= 24 mg/L Pimephales EC50 = 31.6 mg/L 15 min
promelas 96 h
LC50= 27.8 mg/L
Brachydanio rerio 96 h
LC50= 40 mg/L Poecilia
reticulata 96 h
LC50= 8.9 mg/L
Oncorhynchus mykiss 96 h

Chemical Name Log Pow

Phenol = 1.47

13. DISPOSAL CONSIDERATIONS

Waste Disposal Method Dispose of material in accordance with all federal, state, and local regulations.

Contaminated Packaging Dispose of in accordance with all federal, state and local regulations.

Chemical Name
Phenol - 108-95-2

Chemical Name RCRA - Halogenated RCRA - P Series RCRA - F Series RCRA - K Series RCRA - U Series
Organic Compounds Wastes Wastes Wastes Wastes
Phenol - 108-95-2 U188

Chemical Name California Hazardous Waste Status

Phenol Toxic; Corrosive

14. TRANSPORT INFORMATION

DOT
Proper Shipping Name PHENOL SOLUTION
Hazard Class 6.1
UN-No 2821
Packing Group II

IATA
UN-No 2821
Proper Shipping Name PHENOL SOLUTION
Hazard Class 6.1
Packing Group II

15. REGULATORY INFORMATION

International Inventories

TSCA Complies
DSL Complies
EINECS/ELINCS Complies
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ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies

U.S. Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:

Chemical Name CAS-No Weight % SARA 313 - Threshold

Values %
Phenol 108-95-2 95-100 1.0

SARA 311/312 Hazard Categories

Acute Health Hazard Yes
Chronic Health Hazard No
Fire Hazard Yes
Sudden Release of Pressure Hazard No
Reactive Hazard No

Clean Water Act

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42).
Component CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Quantities Substances
Phenol 1000 lb X X X
108-95-2 ( 95-100 )

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product contains the following substances which are listed hazardous air pollutants (HAPS) under Section 112 of the Clean Air
Act:.

Chemical Name CAS-No Weight % HAPS data VOC Chemicals Class 1 Ozone Class 2 Ozone
Depletors Depletors
Phenol 108-95-2 95-100 Present Group III

CERCLA

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs

Phenol 1000 lb 1000 lb

U.S. State Regulations

California Proposition 65
This product does not contain any Proposition 65 chemicals.

Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island

Phenol X X X X X

International Regulations

Mexico - Grade -

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Chemical Name Carcinogen Status Exposure Limits
Phenol Mexico: TWA= 19 mg/m3
Mexico: TWA= 5 ppm
Mexico: STEL= 38 mg/m3
Mexico: STEL= 10 ppm

Canada

WHMIS Hazard Class

Not determined

Chemical Name NPRI

Phenol X

16. OTHER INFORMATION

Issuing Date 06/04/10

Revision Date

Revision Note No information available.

Disclaimer
The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guide for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered as a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
material or in any process, unless specified in the text.

End of MSDS

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