PROPIEDADES A PARTIR DE LA ECUACIN DE REDLICH KWONG

Compuesto

Temp.critica

Pres. critica

Volumen lquido

Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano

16.043
30.07
44.097
58.124
58.124
72.151
72.151
86.178
100.205
114.232
28.054
40.065
42.081
54.092
54.092
56.108
56.108
56.108
56.108
128.259
142.286

Tc, Rankine
343.9
550
665.9
734.7
765.3
829.8
845.6
914.2
972.3
1024.9
509.5
721.7
657.2
834.7
765
755.3
779.7
752.2
770.7
1071
1114

Pc, psia
673.1
709.8
617.4
529.1
550.7
483
489.5
440
396.9
362.1
742.2
747.2
667
578.1
628
583
610
580
595
331
306

vL, cm3/mol
52
68
84
105.5
101.4
117.4
116.1
131.6
147.5
163.5
61
61.6
79
83.7
88
95.6
91.2
95.4
93.8
179.6
196

C
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25

pie3/lbmol
0.83295574
1.08924982
1.34554389
1.68993906
1.6242637
1.88055777
1.85973388
2.10801877
2.362711
2.61900508
0.97712116
0.98673219
1.26545199
1.34073838
1.40961741
1.5313571
1.46087623
1.52815342
1.50252401
2.87690099
3.13960242

F
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77

z
0.0802337
0.1262563
0.1657524
0.2141499
0.2081385
0.2461386
0.2445736
0.2825341
0.3212004
0.360204
0.1102848
0.1244168
0.155274
0.1757458
0.1806139
0.1955352
0.1881382
0.1949075
0.1929028
0.3993878
0.4393971

Constantes de Antoine
A1
5.14135
5.383894
5.353418
5.611805
5.741624
5.49978
5.853654
6.039243
5.98627
6.4141
5.27791
2.443058
5.44467
6.184923
5.69864
5.58272
5.456285
5.616762
5.487073
6.22189
6.33557

A2
1742.638
2847.921
3371.084
3870.419
4126.385
4221.154
4598.287
5085.758
5278.902
5947.491
2568.994
1832.002
3375.447
4644.865
4105.731
3941.014
3977.563
3953.678
3984.406
5924.61
6213.998

Constante de equilibrio

yi Pi sat
0.42748TCi2.5
viL 0.08664TCi
sat

K i P, T
exp

(
P

P
)

2.5

xi
P
RT
PCiT
PCiT

Presin de vapor de Antoine

Volumen de lquido puro, ec Cavett

Entalpa de vapor puro

Psi
A2

Ln
A1

Pci
A3 t (
F)

viL zi (5.7 3
T

T
)
Tci

H
C P0 dT
V
i

T0

1.0695Tci
RP

0.8664Tci

1.5

Pci
T

Entalpa de lquido puro

T

A2 RT 2
H iL
CP0 dT
( A3 459.67 T ) 2
T
0

P
RTP

0.08664Tci
0.4278Tci2.5
0.08664Tci
1.0695Tci2.5
si
si

2.5
2.5
P
P

T
T
T
T

ci
ci

A2 PsiT
3T

viL

P
( P Psi )

si
i

( A3 459.67 T )
Tci

Calor especfico de gas ideal

CP0 c1 c2t c3t 2 c4t 3 c5t 4

t
F , CP0

Btu / lbmol
F

Clculo del punto de burbuja

Constantes para Calor especfico gas ideal

A3
452.974
434.898
414.488
409.949
409.5179
387.287
394.4148
382.794
359.5259
360.26
433.9156
317.5695
418.4319
419.7079
409.9979
404.741
394.4956
405.9166
400.0702
330.96
317.6512

c1
8.245223
11.51606
15.58683
20.41853
20.79783
24.94637
25.64627
30.17847
34.96845
39.77987
9.326018
12.6505
13.63267
17.15982
16.47292
17.96141
16.54537
18.93086
18.84267
44.6198
49.42138

c2
0.003806333
0.0140309
0.02504953
0.03462286
0.03143287
0.04446726
0.0389176
0.05199263
0.0608752
0.06930903
0.01393934
0.01928835
0.02106998
0.026213
0.03392027
0.03297022
0.02966393
0.03101008
0.02761259
0.07738344
0.08602711

c3
8.864745E-006
8.54034E-006
1.404258E-005
1.415619E-005
1.928511E-005
7.054883E-006
2.397294E-005
3.048799E-006
1.213345E-006
-3.57634E-005
1.010831E-006
-6.45283E-006
2.49845E-006
-5.93782E-006
-1.39251E-005
-6.05339E-006
5.471621E-006
-0.00000493
3.097447E-006
2.963375E-006
2.049705E-006

c4
-7.46115E-009
-1.10608E-008
-3.52626E-008
-4.24613E-008
-4.58865E-008
-3.34417E-008
-5.84262E-008
-2.76400E-008
-2.93693E-008
-3.45609E-008
-7.51655E-009
-1.67465E-009
-1.14686E-008
-2.36130E-009
-4.78632E-009
-5.69808E-009
-1.88313E-008
-0.000000006
-1.33756E-008
-4.13472E-008
-4.41541E-008

Compuesto
c5
1.822959E-012
3.162199E-012
1.864467E-011
2.296993E-011
2.380972E-011
1.774503E-011
3.079918E-011
1.346731E-011
1.454746E-011
1.749419E-011
3.615367E-012
1.813724E-012
5.247386E-012
1.011447E-012
5.611304E-012
2.826942E-012
8.437562E-012
3.200886E-012
5.631517E-012
2.114216E-011
2.256651E-011

Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano

Composicin de
mezcla
zFi
0.0000
0.0000
0.3000
0.0000
0.1000
0.0000
0.1500
0.4500
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1.0000

Ingrese la presin y la temperatura

P, psia =
35
T, F =
62.19
1.0789E-005
Ps
psia
3907.128581
502.5365268
110.7083275
39.85932288
27.25016278
9.860527872
7.216950868
2.007594282
0.57826718
0.169899624
819.9208759
69.0810075
137.603736
18.28312976
31.37649382
33.47028347
23.57326159
34.24991299
25.95160535
0.047568553
0.013564384

el punto de burbuja

Clculo del punto de rocio

presin y la temperatura
se corrige el valor del metano
por un factor de 1,7
si

111.632245
14.3581865
3.16309507
1.1388378
0.77857608
0.28172937
0.2061986
0.05735984
0.01652192
0.00485427
23.4263107
1.97374307
3.93153532
0.52237514
0.89647125
0.95629381
0.67352176
0.97856894
0.74147444
0.0013591
0.00038755

0.000223888
0.000686754
0.001273464
0.001900063
0.002021599
0.002821741
0.002918707
0.003946219
0.005103292
0.006381253
0.000542463
0.001286725
0.001140641
0.00239251
0.001771025
0.001847825
0.00191214
0.001838383
0.001904264
0.007792494
0.009300843

0.0001469
0.0001927
0.00023832
0.00029949
0.00028791
0.00033349
0.00032983
0.00037401
0.00041932
0.00046493
0.00017278
0.00017485
0.00022412
0.00023777
0.00024986
0.00027142
0.00025898
0.00027085
0.00026634
0.00051081
0.00055756

-8.482E-005
-0.00012864
-0.00017906
-0.00023053
-0.00023072
-0.00028523
-0.0002868
-0.00034495
-0.00040671
-0.00046991
-0.00011397
-0.00016036
-0.00016358
-0.00023971
-0.00020224
-0.00021509
-0.00021221
-0.00021531
-0.00021505
-0.00053719
-0.00060441

0.3304491013
0.7039609264
0.904025217
0.9904775513
1.0162407789
1.0748168942
1.0857663369
1.1401434307
1.1925554075
1.2486788342
0.6237820628
0.9566221441
0.8840469962
1.0407719877
1.0066116486
1.0029170743
1.0226363407
1.0014216149
1.0178521621
1.3118584332
1.3823215039

K
62.710917659
10.107602256
2.8595177079
1.127993272
0.7912207614
0.3028074841
0.2238834945
0.0653984409
0.0197033043
0.0060614304
14.6129124374
1.8881263288
3.4756619856
0.5436734087
0.9023984049
0.9590833936
0.6887678279
0.9799600908
0.7547113604
0.0017829488
0.000535724

zFi ( Ki )
0
0
0.8578553124
0
0.0791220761
0
0.0335825242
0.0294292984
0
0
0
0
0
0
0
0
0
0
0
0
0
0.9999892111
1.0788896E-005

Ingrese la presin y la temperatura

P, psia =
35
se corrige el valor del meta
T, F =
168.93
3.0898E-005
Ps
psia
6982.362588###
1383.584886###
403.7406144###
180.7154519 5
136.9023206 4
59.78501036 2
48.64577521 1
18.32156987 1
7.247518482 0
2.90712005 0
2050.999881###
199.0805925 6
493.0780514###
104.9831763 3
155.9015162 4
160.9496463 5
122.7484951 4
164.3492091 5
130.7341491 4
1.187892791 0
0.490869638 0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0###
0###
0###
0###
0###
0###
0###
0###
0###
0###
0###
0###
0###
0###
0###
0###
0###
0###
0###
0###
0###

0
1
1
1
1
1
1
1
1
1
0
1
1
1
1
1
1
1
1
1
1

se corrige el valor del metano

por un factor de 1,7
si
K
zFi / Ki
82.6513887
0
20.2683934
0
8.39838417 0.035721157
4.29455863
0
3.41574941 0.0292761523
1.63255384
0
1.35463316 0.1107310856
0.54591609 0.8243025033
0.22649733
0
0.09449808
0
26.1752914
0
4.96523345
0
9.86543009
0
2.69856111
0
3.87008811
0
3.94382886
0
3.14247045
0
4.01388526
0
3.31387995
0
0.04004118
0
0.0171448
0
1.0000308983
-3.08983E-005

PROPIEDADES A PARTIR DE LA ECUACIN DE REDLICH KWONG

Compuesto

Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano

16.043
30.07
44.097
58.124
58.124
72.151
72.151
86.178
100.205
114.232
28.054
40.065
42.081
54.092
54.092
56.108
56.108
56.108
56.108
128.259
142.286

Temp.critica
Tc, Rankine
343.9
550
665.9
734.7
765.3
829.8
845.6
914.2
972.3
1024.9
509.5
721.7
657.2
834.7
765
755.3
779.7
752.2
770.7
1071
1114

K i P, T

Constante de equilibrio

Pres. critica
Pc, psia
673.1
709.8
617.4
529.1
550.7
483
489.5
440
396.9
362.1
742.2
747.2
667
578.1
628
583
610
580
595
331
306

Volumen lquido
vL, cm3/mol
52
68
84
105.5
101.4
117.4
116.1
131.6
147.5
163.5
61
61.6
79
83.7
88
95.6
91.2
95.4
93.8
179.6
196

C
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25

yi
P sat
0.42748TCi2.5
viL
0.08664TCi
sat

i exp

(
P

P
)

2.5

xi
P
RT
PCiT
PCiT

Psi
A2

Ln

Pci
A3 t (
F)

Presin de vapor de Antoine

Volumen de lquido puro, ec Cavett

viL zi (5.7 3

T
)
Tci

1.0687TCI2.5
RP

h
C dT
0.08664Tci

1.5

P
T

ci
T

Entalpa de vapor puro

V
i

0
P

Entalpa de lquido puro

A2
hiL
C Pi0 dT RT 2

(T A3 459.67) 2

T0

Calor especfico de gas ideal

CP0 c1 c2t c3t 2 c4t 3 c5t 4

t

F , CP0

Btu / lbmol
F

sat

Pi

Ci

P
0.08664TCi 0.42748TCi2.5

2.5

T
T

CP0 c1 c2t c3t 2 c4t 3 c5t 4

t

F , CP0

Btu / lbmol
F

pie3/lbmol
0.832955743
1.089249818
1.345543893
1.689939056
1.624263699
1.880557774
1.859733881
2.108018766
2.362711003
2.619005077
0.97712116
0.986732188
1.265451995
1.340738379
1.409617412
1.531357097
1.460876227
1.528153421
1.502524014
2.87690099
3.139602417

F
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77

z
0.0802337
0.1262563
0.1657524
0.2141499
0.2081385
0.2461386
0.2445736
0.2825341
0.3212004
0.360204
0.1102848
0.1244168
0.155274
0.1757458
0.1806139
0.1955352
0.1881382
0.1949075
0.1929028
0.3993878
0.4393971

Constantes de Antoine
A1
A2
5.14135
1742.638
5.383894
2847.921
5.353418
3371.084
5.611805
3870.419
5.741624
4126.385
5.49978
4221.154
5.853654
4598.287
6.039243
5085.758
5.98627
5278.902
6.4141
5947.491
5.27791
2568.994
2.443058
1832.002
5.44467
3375.447
6.184923
4644.865
5.69864
4105.731
5.58272
3941.014
5.456285
3977.563
5.616762
3953.678
5.487073
3984.406
6.22189
5924.61
6.33557
6213.998

A3
452.974
434.898
414.488
409.949
409.5179
387.287
394.4148
382.794
359.5259
360.26
433.9156
317.5695
418.4319
419.7079
409.9979
404.741
394.4956
405.9166
400.0702
330.96
317.6512

Constantes para Calor especfico gas i

c1
8.245223
11.51606
15.58683
20.41853
20.79783
24.94637
25.64627
30.17847
34.96845
39.77987
9.326018
12.6505
13.63267
17.15982
16.47292
17.96141
16.54537
18.93086
18.84267
44.6198
49.42138

viL
0.08664TCi
sat

(
P

P
)
i

RT
PCiT

1.0687TCI2.5

T 1.5

sat
sat
sat

2.5

0.08664TCi 1.0687TCi2.5
P
viL
viL
0.08664
T
0.42748
T
Pi
( P Pi )
3

Ci
Ci
i

2.5

2
3.5

T
T
T
T
RT
TCi
T

RT
PCi

onstantes para Calor especfico gas ideal

c2
c3
0.003806333 8.864745E-006
0.0140309
8.54034E-006
0.02504953 1.404258E-005
0.03462286 1.415619E-005
0.03143287
1.928511E-005
0.04446726 7.054883E-006
0.0389176
2.397294E-005
0.05199263 3.048799E-006
0.0608752
1.213345E-006
0.06930903 -3.576344E-005
0.01393934 1.010831E-006
0.01928835 -6.452827E-006
0.02106998
2.49845E-006
0.026213
-5.937819E-006
0.03392027 -1.392511E-005
0.03297022
-6.05339E-006
0.02966393 5.471621E-006
0.03101008
-0.00000493
0.02761259 3.097447E-006
0.07738344 2.963375E-006
0.08602711
2.049705E-006

sat

viL
Pi )
3

T
TCi
T

Compuesto
c4
-7.461153E-009
-1.106078E-008
-3.526261E-008
-4.246126E-008
-4.588652E-008
-3.344167E-008
-5.842615E-008
-2.763996E-008
-2.93693E-008
-3.45609E-008
-7.516552E-009
-1.674653E-009
-1.146863E-008
-2.361299E-009
-4.786315E-009
-5.69808E-009
-1.883127E-008
-0.000000006
-1.337556E-008
-4.134716E-008
-4.415409E-008

c5
1.822959E-012
3.162199E-012
1.864467E-011
2.296993E-011
2.380972E-011
1.774503E-011
3.079918E-011
1.346731E-011
1.454746E-011
1.749419E-011
3.615367E-012
1.813724E-012
5.247386E-012
1.011447E-012
5.611304E-012
2.826942E-012
8.437562E-012
3.200886E-012
5.631517E-012
2.114216E-011
2.256651E-011

Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano

PROPIEDADES DE LA CORRIENTE DE ALIMENTACIN

F lbmol=
P, psia =
T, F=
Composicin de
mezcla
zFi
0.0000
0.0000
0.3000
0.0000
0.1000
0.0000
0.1500
0.4500
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1.0000

1000
35
50
Ps
psia
3599.59189
435.127887
91.9551446
32.0755849
21.6066424
7.58934277
5.47505641
1.45503164
0.39839077
0.11182031
719.64941
58.8677853
114.61933
14.2368343
24.9191665
26.6930896
18.5646118
27.3265173
20.5483346
0.02936999
0.0078855

se corrige el valor del metano

por un factor de 1,7
si

103
12
2.6
0.9
0.6
0.2
0.2
0
0
0
21
1.7
3.3
0.4
0.7
0.8
0.5
0.8
0.6
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

Entalpa en Btu/lbmo

K
zK
z/K Hvideal
HV
0 ### 0.34 60.1107375
0
0 417.3769 -18 399.41
0
0 0.73 9.05344531
0
0 593.6804 -59.89 533.79
0
0 0.92 2.42455182 0.7274 0.124 811.1846 -113 697.97
0
0 1.01 0.9220486
0
0
1064.73 -170 894.48
0
0 1.03 0.63580513 0.0636 0.157 1079.916 -182 898.25
0
0 1.09 0.23568736
0
0 1303.145 -255 1048.2
0
0 1.1 0.17161844 0.0257 0.874 1331.87 -264 1067.9
0
0 1.15 0.04788476 0.0215 9.398
1574 -358 1215.5
0
0 1.21 0.01373279
0
0 1824.522 -465 1359.5
0
0 1.27 0.00404494
0
0 2074.087 -583 1491.3
0
0 0.65 13.3187598
0
0 483.7557 -46.86 436.9
0
0 0.97 1.62748942
0
0 656.3641 -115 541.22
0
0 0.9 2.95977748
0
0 708.0575 -101 606.77
0
0 1.05 0.42874788
0
0 890.5062 -216 674.29
0
0 1.02 0.72593485
0
0
865.459 -159 706.31
0
0 1.02 0.77554095
0
0 939.0223 -166 773.12
0
0 1.03 0.54881678
0
0 864.5475 -172 692.5
0
0 1.02 0.79286529
0
0
985.091 -165 820.09
0
0 1.03 0.60493251
0
0 976.7578 -171 805.55
0
0 1.33 0.00111928
0
0 2327.779 -713 1614.7
0
0 1.41 0.00031764
0
0 2578.621 -852 1726.2
0.8382 10.55 Entalpia como vapor =

CLCULOS EN EL SEPA
Ingrese la presin y la temperatura
en el separador flash
P, psia =
35
T, F =
144.26

Entalpa en Btu/lbmol

0
0
209.39086312
0
89.824611376
0
160.18524223
546.99675013
0
0
0
0
0
0
0
0
0
0
0
0
0
1006.3974669

-277.9
4095.6
7019.2
8811.8
9606.7
11131
11810
13928
16211
18225
3077.8
6430.7
6783.7
10474
9534.4
9307.4
9990.8
9279.6
9720.6
21066
23727

1848
744.57
297.45
156.03
112.15
55.274
41.293
14.902
5.2927
1.862
963.48
193.66
331.71
87.948
113.31
126.53
91.259
128.83
100.52
0.5983
0.192

HL
537.36 -235.47 -1454.62
79.332 -26.007 -4299.83
13.979 -4.0141 -6515.43
-0.9024 0.2414 -7902.39
-3.9739 1.0314 -8636.04
-9.4237 2.3022 -9875.99
-10.04 2.4179 -10512.3
-12.939 2.9354 -12359.2
-14.968 3.2365 -14380.3
-16.737 3.4718 -16139.3
121.66 -41.961 -3637.27
4.2995 -1.165 -5971.18
18.376 -5.3263 -6420.38
-5.0895 1.2378 -9668.04
-2.5958 0.6739 -8780.35
-2.3234 0.6089 -8493.21
-4.3867 1.1229 -9214.23
-2.1417 0.563 -8421.77
-3.9668 1.0242 -8841.4
-18.435 3.6925 -18723.6
-20.137 3.908 -21132.3
Entalpa como liquido =

0
0
-1954.629
0
-863.6038
0
-1576.842
-5561.639
0
0
0
0
0
0
0
0
0
0
0
0
0
-9956.714

Ps
psia
6219.196276
1131.760867
312.8280133
134.1959712
99.63151812
42.0363466
33.47314466
11.9008733
4.443716995
1.678005165
1710.006321
162.8052402
383.2593391
74.33819389
113.699818
118.2012152
88.8432103
120.7342769
95.18303299
0.642055486
0.248169636

CLCULOS EN EL SEPARADOR

esin y la temperatura
se corrige el valor del metano
por un factor de 1,7
si

177.7
0
32.34
0
8.938
0
3.834
0
2.847
0
1.201
0
0.956
0
0.34
0
0.127
0
0.048
0
48.86
0
4.652
0
10.95
0
2.124
0
3.249
0
3.377
0
2.538
0
3.45
0
2.72
0
0.018 0.01
0.007 0.01

K
0 ### 0 78.4998974941
0 0 1 17.8697829192
0 0 1 6.8749116988
0 0 1 3.3405064526
0 0 1 2.589795071
0 0 1 1.1841589553
0 0 1 0.9594089561
0 0 1 0.3625418569
0 0 1 0.1415779527
0 0 1 0.0555844691
0 ### 0 23.5547932807
0 0 1 4.139706928
0 0 1 8.1360073222
0 0 1 1.9891396353
0 0 1 2.9374053408
0 0 1 3.0206156418
0 0 1 2.3570113778
0 0 1 3.0767923874
0 0 1 2.503444041
0 0 1 0.0220842166
0 0 1 0.0088660074

zFi ( Ki )
0
0
2.0624735096
0
0.2589795071
0
0.1439113434
0.1631438356
0
0
0
0
0
0
0
0
0
0
0
0
0
2.6285081957

Ingrese V/F
V/F = 0.600096512

zFi / Ki
0
0
0.0436369241
0
0.0386130938
0
0.1563462578
1.2412359881
0
0
0
0
0
0
0
0
0
0
0
0
0
1.4798322638

0
0
0.5055779364
0
0.0661941525
0
0.0002596398
0.4796154341
0
0
0
0
0
0
0
0
0
0
0
0
0
-1.051647163

gi
0
0
0.389452668
0
0.081359789
0
-0.00624067
-0.46457179
0
0
0
0
0
0
0
0
0
0
0
0
0
5.1459E-014

Nuevo V/F = 0.6000965117

G1=

xi
0
0
0.066290812
0
0.051176274
0
0.153745004
0.728787909
0
0
0
0
0
0
0
0
0
0
0
0
0
1
5.1459E-014

yi
0
0
0.45574348
0
0.13253606
0
0.14750433
0.26421612
0
0
0
0
0
0
0
0
0
0
0
0
0
1

Hv ideal
1237.14871 -13.2386
1814.69346 -45.3821
2519.6761 -86.3119
3315.70049 -130.111
3341.99724 -138.962
4065.12715 -195.298
4122.73623 -202.308
4894.78065 -275.083
5676.19998 -357.17
6420.52439 -448.014
1490.65969 -35.3987
2019.04936 -87.9573
2187.21619 -77.1935
2742.04914 -165.667
2714.95654 -121.733
2927.54433 -126.864
2699.04443 -131.656
3048.09318 -126.168
3007.28751 -130.979
7240.81661 -548.424
8022.23357 -655.914
HV

HV i
1223.91
1769.311
2433.364
3185.59
3203.036
3869.829
3920.428
4619.698
5319.03
5972.51
1455.261
1931.092
2110.023
2576.382
2593.223
2800.68
2567.388
2921.925
2876.309
6692.392
7366.319
Btu/lbmol

yi (HVi)
0
0
1108.98985767
0
424.517728024
0
578.2801581138
1220.59857286
0
0
0
0
0
0
0
0
0
0
0
0
0
3332.38631666

###
2387
5513
7429
8330
9912
###
###
###
###
1421
5300
5200
9272
8277
7974
8716
7942
8470
###
###

2352
1467
771
499
396
235
193
93.5
45.3
21.5
1729
409
845
352
395
428
334
435
356
10.1
4.65

RESULTADOS
F, lbmol/h =
1000
P psia =
35
T,F =
50
HF Btu/lbmol = -9956.71368
Compuesto
HLi
932 -484.08 -305.7428949
217 -84.471 -2173.244642
68.2 -23.202 -3809.888965
30.6 -9.7008 -4633.573196
19.2 -5.8975 -5396.991596
2.42 -0.7003 -6082.897421
-0.52 0.1482 -6757.615123
-8.91 2.3951 -8022.249473
-13 3.3867 -9194.274827
-16 3.9292 -10396.34112
298 -121.64 -1836.048335
23 -7.3923 -3706.190264
80.4 -27.606 -3911.142146
9.64 -2.7789 -6888.830703
20.3 -6.234 -5971.427209
23.3 -7.2267 -5490.972795
14.4 -4.359 -6361.65093
23.9 -7.4534 -5345.220063
16.5 -5.054 -5829.996505
-18 4.2987 -11702.10687
-20 4.5989 -13040.2715
HL Btu/lbmol =

xi (HLi)
0
0
-252.56063406
0
-276.19792326
0
-1038.9495671
-5846.5184175
0
0
0
0
0
0
0
0
0
0
0
0
0
-7414.2265419

Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano

Fase vapor
lbmol/h
0
0
273.4900729
0
79.53442932
0
88.51683641
158.555173
0
0
0
0
0
0
0
0
0
0
0
0
0
Totales= 600.0965117

T
Fase lquida
lbmol/h
0
0
26.5099271
0
20.4655707
0
61.4831636
291.444827
0
0
0
0
0
0
0
0
0
0
0
1999753.40415
0
-2964975.0574
0
-9956713.6811
399.903488 Balance de energa Q Btu/h= 8991492.02781

137
140
145
150
160
163.15

V/F

Q/F
0
0.07808
0.226
0.3964
0.8258
1

2865
3659.8
5163.26
6898.7
11289.4
13071.1

1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
135 137 139 141 143 145 147 149 151 153 155 157 159 161 163 165

3000
2000

5000
4000

7000
6000

9000
8000

11000
13000
10000
12000
14000

57 159 161 163 165

000
13000
12000
14000

PROPIEDADES A PARTIR DE LA ECUACIN DE REDLICH KWONG

Compuesto

Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano

16.043
30.07
44.097
58.124
58.124
72.151
72.151
86.178
100.205
114.232
28.054
40.065
42.081
54.092
54.092
56.108
56.108
56.108
56.108
128.259
142.286

Temp.critica
Tc, Rankine
343.9
550
665.9
734.7
765.3
829.8
845.6
914.2
972.3
1024.9
509.5
721.7
657.2
834.7
765
755.3
779.7
752.2
770.7
1071
1114

K i P, T

Constante de equilibrio

Pres. critica
Pc, psia
673.1
709.8
617.4
529.1
550.7
483
489.5
440
396.9
362.1
742.2
747.2
667
578.1
628
583
610
580
595
331
306

Volumen lquido
vL, cm3/mol
52
68
84
105.5
101.4
117.4
116.1
131.6
147.5
163.5
61
61.6
79
83.7
88
95.6
91.2
95.4
93.8
179.6
196

C
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25

yi
P sat
0.42748TCi2.5
viL
0.08664TCi
sat

i exp

(
P

P
)

2.5

xi
P
RT
PCiT
PCiT

Psi
A2

Ln

Pci
A3 t (
F)

Presin de vapor de Antoine

Volumen de lquido puro, ec Cavett

viL zi (5.7 3

T
)
Tci

1.0687TCI2.5
RP

h
C dT

0.08664
T

ci

Pci
T 1.5

T
T

Entalpa de vapor puro

V
i

0
P

Entalpa de lquido puro

A2
hiL
C Pi0 dT RT 2

(T A3 459.67) 2

T0

Calor especfico de gas ideal

CP0 c1 c2t c3t 2 c4t 3 c5t 4

t

F , CP0

Btu / lbmol
F

sat

Pi

Ci

0.08664TCi 0.42748TCi2.5

2.5

T
T

CP0 c1 c2t c3t 2 c4t 3 c5t 4

t

F , CP0

Btu / lbmol
F

pie3/lbmol
0.832955743
1.089249818
1.345543893
1.689939056
1.624263699
1.880557774
1.859733881
2.108018766
2.362711003
2.619005077
0.97712116
0.986732188
1.265451995
1.340738379
1.409617412
1.531357097
1.460876227
1.528153421
1.502524014
2.87690099
3.139602417

F
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77

z
0.0802337
0.1262563
0.1657524
0.2141499
0.2081385
0.2461386
0.2445736
0.2825341
0.3212004
0.360204
0.1102848
0.1244168
0.155274
0.1757458
0.1806139
0.1955352
0.1881382
0.1949075
0.1929028
0.3993878
0.4393971

Constantes de Antoine
A1
A2
5.14135
1742.638
5.383894
2847.921
5.353418
3371.084
5.611805
3870.419
5.741624
4126.385
5.49978
4221.154
5.853654
4598.287
6.039243
5085.758
5.98627
5278.902
6.4141
5947.491
5.27791
2568.994
2.443058
1832.002
5.44467
3375.447
6.184923
4644.865
5.69864
4105.731
5.58272
3941.014
5.456285
3977.563
5.616762
3953.678
5.487073
3984.406
6.22189
5924.61
6.33557
6213.998

A3
452.974
434.898
414.488
409.949
409.5179
387.287
394.4148
382.794
359.5259
360.26
433.9156
317.5695
418.4319
419.7079
409.9979
404.741
394.4956
405.9166
400.0702
330.96
317.6512

Constantes para Calor especfico gas i

c1
8.245223
11.51606
15.58683
20.41853
20.79783
24.94637
25.64627
30.17847
34.96845
39.77987
9.326018
12.6505
13.63267
17.15982
16.47292
17.96141
16.54537
18.93086
18.84267
44.6198
49.42138

viL
0.08664TCi
sat

(
P

P
)
i

RT
PCiT

1.0687TCI2.5

T 1.5

sat
sat

2.5

0.08664TCi 1.0687TCi2.5
Pi sat
P
viL
viL
0.08664
T
0.42748
T
( P Pi )
3

Ci
Ci
i

2.5

2
3.5

PCi
T
T
T
T
RT
TCi
T
RT
PCi

sat

onstantes para Calor especfico gas ideal

c2
c3
0.003806333 8.864745E-006
0.0140309
8.54034E-006
0.02504953 1.404258E-005
0.03462286 1.415619E-005
0.03143287
1.928511E-005
0.04446726 7.054883E-006
0.0389176
2.397294E-005
0.05199263 3.048799E-006
0.0608752
1.213345E-006
0.06930903 -3.576344E-005
0.01393934 1.010831E-006
0.01928835 -6.452827E-006
0.02106998
2.49845E-006
0.026213
-5.937819E-006
0.03392027 -1.392511E-005
0.03297022
-6.05339E-006
0.02966393 5.471621E-006
0.03101008
-0.00000493
0.02761259 3.097447E-006
0.07738344 2.963375E-006
0.08602711
2.049705E-006

sat

viL
Pi )
3

RT
TCi
T

Compuesto
c4
-7.461153E-009
-1.106078E-008
-3.526261E-008
-4.246126E-008
-4.588652E-008
-3.344167E-008
-5.842615E-008
-2.763996E-008
-2.93693E-008
-3.45609E-008
-7.516552E-009
-1.674653E-009
-1.146863E-008
-2.361299E-009
-4.786315E-009
-5.69808E-009
-1.883127E-008
-0.000000006
-1.337556E-008
-4.134716E-008
-4.415409E-008

c5
1.822959E-012
3.162199E-012
1.864467E-011
2.296993E-011
2.380972E-011
1.774503E-011
3.079918E-011
1.346731E-011
1.454746E-011
1.749419E-011
3.615367E-012
1.813724E-012
5.247386E-012
1.011447E-012
5.611304E-012
2.826942E-012
8.437562E-012
3.200886E-012
5.631517E-012
2.114216E-011
2.256651E-011

Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano

PROPIEDADES DE LA CORRIENTE DE ALIMENTACIN

F lbmol=
P, psia =
T, F=
Composicin de
mezcla
zFi
0
0
0.3
0
0.1
0
0.15
0.45
0
0
0
0
0
0
0
0
0
0
0
0
0
1

1000
35
300
Ps
psia
11371.9344
3208.68669
1165.32314
620.978515
511.350546
254.177657
227.061864
107.508103
52.7660713
27.0643928
4390.21915
442.712204
1406.8474
441.796866
577.346926
577.530923
465.203587
589.348684
485.023141
13.9317978
7.37771441

se corrige el valor del metano

por un factor de 1,7
si

325 ###
92
0
33
0
18
0
15
0
7.3
0
6.5
0
3.1
0
1.5
0
0.8
0
125
0
13
0
40
0
13
0
16
0
17
0
13
0
17
0
14
0
0.4
0
0.2
0

Entalpa en Btu/lbmo

K
zK
z/K Hvideal
HV
0 ### 0.18 100.127411
0
0 2710.412 -8.488 2701.9
0 ### 0.35 31.8920709
0
0
4142.21 -30.81 4111.4
0
0 0.53 17.6681655 5.3004 0.017 5867.316 -59.29 5808
0
0 0.62 11.0617434
0
0 7736.173 -89.79 7646.4
0
0 0.66 9.68265868 0.9683 0.01 7746.045 -96.06 7650
0
0 0.78 5.63365433
0
0 9489.336 -135 9353.9
0
0 0.79 5.15137416 0.7727 0.029 9557.585 -140 9417.2
0
0 0.89 2.73708581 1.2317 0.164 11371.22 -191 11180
0
0 0.96 1.45410499
0
0 13188.44 -249 12940
0
0 1.02 0.78890794
0
0 14669.51 -313 14357
0 ### 0.31 38.4458597
0
0 3420.709 -23.89 3396.8
0
0 0.81 10.1977614
0
0 4602.541 -60.65 4541.9
0
0 0.5 20.0114818
0
0 5039.762 -53 4986.8
0
0 0.68 8.56663579
0
0 6269.801 -115 6154.9
0
0 0.67 11.006206
0
0
6336 -84.15 6251.8
0
0 0.65 10.7834715
0
0 6807.438 -87.65 6719.8
0
0 0.71 9.41657634
0
0
6313.7 -91.08 6222.6
0
0 0.65 10.9281771
0
0 7019.672 -87.16 6932.5
0
0 0.7 9.65954784
0
0 6898.896 -90.57 6808.3
0
0 1.07 0.42458003
0
0 16821.41 -383 16438
0
0 1.11 0.23308927
0
0 18637.64 -459 18179
8.2731 0.221 Entalpia como vapor =

Ingrese la presin y la tem

en el separador flash
P, psia =
T, F =

Entalpa en Btu/lbmol

0
0
1742.4081855
0
764.99832693
0
1412.5820283
5030.9462731
0
0
0
0
0
0
0
0
0
0
0
0
0
8950.9348138

-2512.9987
-408.49574
2625.60521
4343.28072
5295.57127
7218.55733
7964.02147
10370.0976
12423.0951
14575.7988
-1050.2851
4219.786
2135.38915
5953.92918
5316.5274
4978.61712
5932.04235
4916.32522
5696.26883
16336.8352
18176.461

2757.71579
2824.45098
1974.00111
1593.08179
1403.47012
983.44371
910.656816
587.737975
375.204314
241.724009
2996.30359
767.186283
2129.90742
1450.31783
1388.12562
1446.341
1210.58393
1467.58591
1255.0936
152.478892
96.6575476

HL
2076.377 -1116.2578 1505.575
730.4182 -307.4672 1303.304
316.4988 -118.74019 1069.951
204.5394 -72.083171 1667.354
159.3285 -54.675377 942.351
84.38179 -27.437655 1230.391
73.02587 -23.443912 633.3247
31.08087 -9.4571553 391.7634
8.500301 -2.4769178 384.1135
-4.194224 1.17704084 -144.993
904.8451 -397.85595 967.7016
83.20676 -29.663372 -437.975
361.631 -136.78902 549.6238
111.6106 -36.147361 -1209.91
157.435 -54.039508 -472.052
171.2508 -59.275394 270.5042
129.2421 -43.809459 -914.359
174.6682 -60.620948 521.7139
139.1689 -47.537058 -144.098
-12.1974 3.31571478 340.9799
-17.40927 4.59807383 377.3292
Entalpa como liquido =

0
0
320.9852
0
94.2351
0
94.9987
176.2935
0
0
0
0
0
0
0
0
0
0
0
0
0
686.5125

CLCULOS EN EL SEPARADOR
Ingrese la presin y la temperatura
en el separador flash
35
144.26
Ps
psia
6219.196276 178
1131.760867 32
312.8280133 8.9
134.1959712 3.8
99.63151812 2.8
42.0363466 1.2
33.47314466 1
11.9008733 0.3
4.443716995 0.1
1.678005165 0
1710.006321 49
162.8052402 4.7
383.2593391 11
74.33819389 2.1
113.699818 3.2
118.2012152 3.4
88.8432103 2.5
120.7342769 3.4
95.18303299 2.7
0.642055486 0
0.248169636 0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

se corrige el valor del metano

por un factor de 1,7
si

K
0 ### 0 78.4998974941
0 0 1 17.8697829192
0 0 1 6.8749116988
0 0 1 3.3405064526
0 0 1 2.589795071
0 0 1 1.1841589553
0 0 1 0.9594089561
0 0 1 0.3625418569
0 0 1 0.1415779527
0 0 1 0.0555844691
0 ### 0 23.5547932807
0 0 1 4.139706928
0 0 1 8.1360073222
0 0 1 1.9891396353
0 0 1 2.9374053408
0 0 1 3.0206156418
0 0 1 2.3570113778
0 0 1 3.0767923874
0 0 1 2.503444041
0 0 1 0.0220842166
0 0 1 0.0088660074

zFi ( Ki )
0
0
2.0624735096
0
0.2589795071
0
0.1439113434
0.1631438356
0
0
0
0
0
0
0
0
0
0
0
0
0
2.6285081957

Ingrese V/F
V/F =

zFi / Ki
0
0
0.0436369241
0
0.0386130938
0
0.1563462578
1.2412359881
0
0
0
0
0
0
0
0
0
0
0
0
0
1.4798322638

0
0
0.50557336
0
0.06619378
0
0.00025964
0.47961889
0
0
0
0
0
0
0
0
0
0
0
0
0
-1.05164566

Nuevo V/F= 0.60009651

0.6001

gi
0
0
0.389450905
0
0.081359558
0
-0.00624067
-0.46457346
0
0
0
0
0
0
0
0
0
0
0
0
0
-3.668E-006

xi
0
0
0.0662905121
0
0.0511761292
0
0.1537450267
0.7287905334
0
0
0
0
0
0
0
0
0
0
0
0
0
1.0000022015

G1= -3.66850E-006

yi
0
0
0.45574142
0
0.13253569
0
0.14750436
0.26421707
0
0
0
0
0
0
0
0
0
0
0
0
0
0.99999853

Hv ideal
1237.14871 -13.2386
1814.69346 -45.3821
2519.6761 -86.3119
3315.70049 -130.111
3341.99724 -138.962
4065.12715 -195.298
4122.73623 -202.308
4894.78065 -275.083
5676.19998 -357.17
6420.52439 -448.014
1490.65969 -35.3987
2019.04936 -87.9573
2187.21619 -77.1935
2742.04914 -165.667
2714.95654 -121.733
2927.54433 -126.864
2699.04443 -131.656
3048.09318 -126.168
3007.28751 -130.979
7240.81661 -548.424
8022.23357 -655.914
HV

HV i
1223.91
1769.311
2433.364
3185.59
3203.036
3869.829
3920.428
4619.698
5319.03
5972.51
1455.261
1931.092
2110.023
2576.382
2593.223
2800.68
2567.388
2921.925
2876.309
6692.392
7366.319
Btu/lbmol

yi (HVi)
0
0
1108.98483566
0
424.516523202
0
578.28024204
1220.60296861
0
0
0
0
0
0
0
0
0
0
0
0
0
3332.38456951

RESULTADOS
F, lbmol/h =
1000
P psia =
35
T,F =
300
HF Btu/lbmol = 8950.934814
Compuesto
-1258
2387
5513
7429
8330
9912
###
###
###
###
1421
5300
5200
9272
8277
7974
8716
7942
8470
###
###

2352
1467
771
499
396
235
193
93.5
45.3
21.5
1729
409
845
352
395
428
334
435
356
10.1
4.65

HLi
1133 -484.1 -506.1288
252.4 -84.47 -2208.212
77.79 -23.2 -3819.494
34.62 -9.701 -4637.589
21.62 -5.898 -5399.433
2.709
-0.7 -6083.187
-0.581 0.1482 -6757.554
-9.902 2.3951 -8021.258
-14.62 3.3867 -9192.873
-17.61 3.9292 -10394.71
348 -121.6 -1886.404
26.08 -7.392 -3709.25
91.8 -27.61 -3922.57
10.79 -2.779 -6889.981
22.85 -6.234 -5974.008
26.26 -7.227 -5493.964
16.18 -4.359 -6363.455
27.01 -7.453 -5348.305
18.61 -5.054 -5832.089
-19.89 4.2987 -11700.33
-21.9 4.5989 -13038.37
HL Btu/lbmol =

xi (HLi)
0
0
-253.19619433
0
-276.32207663
0
-1038.940288
-5845.8168904
0
0
0
0
0
0
0
0
0
0
0
0
0
-7414.2754494

Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano

Fase vapor
lbmol/h
0
0
273.4904242
0
79.53466592
0
88.5173638
158.5566657
0
0
0
0
0
0
0
0
0
0
0
0
0
Totales= 600.0991196

T
Fase lquida
lbmol/h
0
0
26.5095758
0
20.4653341
0
61.4826362
291.443334
0
0
0
0
0
0
0
0
0
0
0
1999761.04645
0
-2964975.2795
0
8950934.81377
399.90088 Balance de energa Q Btu/h= -9916149.0468

137
139
145
150
155
160
161
163.14

V/F

Q/F
0
0.05111
0.22597
0.3964
0.59291
0.82588
0.87844
1

2859
3380
5157
6894
8902
11287
11825
13069

1
0.9
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
135 137 139 141 143 145 147 149 151 153 155 157 159 161 163 165

3000
2000

5000
4000

7000
6000

9000
8000

11000
13000
10000
12000
14000

57 159 161 163 165

000
13000
12000
14000

PROPIEDADES A PARTIR DE LA ECUACIN DE REDLICH KWONG

Compuesto

Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano

16.043
30.07
44.097
58.124
58.124
72.151
72.151
86.178
100.205
114.232
28.054
40.065
42.081
54.092
54.092
56.108
56.108
56.108
56.108
128.259
142.286

Temp.critica
Tc, Rankine
343.9
550
665.9
734.7
765.3
829.8
845.6
914.2
972.3
1024.9
509.5
721.7
657.2
834.7
765
755.3
779.7
752.2
770.7
1071
1114

K i P, T

Constante de equilibrio

Pres. critica
Pc, psia
673.1
709.8
617.4
529.1
550.7
483
489.5
440
396.9
362.1
742.2
747.2
667
578.1
628
583
610
580
595
331
306

Volumen lquido
vL, cm3/mol
52
68
84
105.5
101.4
117.4
116.1
131.6
147.5
163.5
61
61.6
79
83.7
88
95.6
91.2
95.4
93.8
179.6
196

pie3/lbmol
0.83295574
1.08924982
1.34554389
1.68993906
1.6242637
1.88055777
1.85973388
2.10801877
2.362711
2.61900508
0.97712116
0.98673219
1.26545199
1.34073838
1.40961741
1.5313571
1.46087623
1.52815342
1.50252401
2.87690099
3.13960242

yi
P sat
0.42748TCi2.5
viL 0.08664TCi
sat

i exp

(
P

P
)

2.5

xi
P
RT
PCiT
PCiT

Presin de vapor de Antoine

Psi
A2

Ln

Pci
A3 t (
F)

Volumen de lquido puro, ec Cavett

viL zi (5.7 3

Entalpa de vapor puro

C
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25

T
)
Tci

1.0687TCi2.5
RP

h
C dT
0.08664Tci

1.5

P
T

ci
T
T

V
i

0
P

Entalpa de lquido puro

Calor especfico de gas ideal

A2

h
C Pi dT RT

(T A3 459.67) 2

T0

L
i

CP0 c1 c2t c3t 2 c4t 3 c5t 4

t
F , CP0

Btu / lbmol
F

sat

Pi

Ci

0.08664TCi 0.42748TCi2.5

T 2.5
T

CP0 c1 c2t c3t 2 c4t 3 c5t 4

t
F , CP0

Btu / lbmol
F

F
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77

z
0.0802337
0.1262563
0.1657524
0.2141499
0.2081385
0.2461386
0.2445736
0.2825341
0.3212004
0.360204
0.1102848
0.1244168
0.155274
0.1757458
0.1806139
0.1955352
0.1881382
0.1949075
0.1929028
0.3993878
0.4393971

Constantes de Antoine
A1
A2
5.14135
1742.638
5.383894
2847.921
5.353418
3371.084
5.611805
3870.419
5.741624
4126.385
5.49978
4221.154
5.853654
4598.287
6.039243
5085.758
5.98627
5278.902
6.4141
5947.491
5.27791
2568.994
2.443058
1832.002
5.44467
3375.447
6.184923
4644.865
5.69864
4105.731
5.58272
3941.014
5.456285
3977.563
5.616762
3953.678
5.487073
3984.406
6.22189
5924.61
6.33557
6213.998

A3
452.974
434.898
414.488
409.949
409.5179
387.287
394.4148
382.794
359.5259
360.26
433.9156
317.5695
418.4319
419.7079
409.9979
404.741
394.4956
405.9166
400.0702
330.96
317.6512

Constantes para Calor especfico gas ideal

c1
c2
c3
8.245223 0.003806333 8.864745E-006
11.51606
0.0140309
8.54034E-006
15.58683
0.02504953 1.404258E-005
20.41853
0.03462286 1.415619E-005
20.79783
0.03143287 1.928511E-005
24.94637
0.04446726 7.054883E-006
25.64627
0.0389176 2.397294E-005
30.17847
0.05199263 3.048799E-006
34.96845
0.0608752 1.213345E-006
39.77987
0.06930903 -3.57634E-005
9.326018
0.01393934 1.010831E-006
12.6505
0.01928835 -6.45283E-006
13.63267
0.02106998 2.49845E-006
17.15982
0.026213
-5.93782E-006
16.47292
0.03392027 -1.39251E-005
17.96141
0.03297022 -6.05339E-006
16.54537
0.02966393 5.471621E-006
18.93086
0.03101008
-0.00000493
18.84267
0.02761259 3.097447E-006
44.6198
0.07738344 2.963375E-006
49.42138
0.08602711 2.049705E-006

4TCi
sat

(
P

P
)
i

sat
sat
sat

0.08664TCi 1.0687TCi2.5
Pi v iL
v iL
8664TCi 0.42748TCi2.5
Pi
( P Pi )
3

RT
PCi

T
T 2.5
T2
T 3.5
RT
TCi
T

PROPIEDADES DE LA CORR
-2368.97

ico gas ideal

c4
-7.46115E-009
-1.10608E-008
-3.52626E-008
-4.24613E-008
-4.58865E-008
-3.34417E-008
-5.84262E-008
-2.76400E-008
-2.93693E-008
-3.45609E-008
-7.51655E-009
-1.67465E-009
-1.14686E-008
-2.36130E-009
-4.78632E-009
-5.69808E-009
-1.88313E-008
-0.000000006
-1.33756E-008
-4.13472E-008
-4.41541E-008

Compuesto
c5
1.822959E-012
3.162199E-012
1.864467E-011
2.296993E-011
2.380972E-011
1.774503E-011
3.079918E-011
1.346731E-011
1.454746E-011
1.749419E-011
3.615367E-012
1.813724E-012
5.247386E-012
1.011447E-012
5.611304E-012
2.826942E-012
8.437562E-012
3.200886E-012
5.631517E-012
2.114216E-011
2.256651E-011

Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano

F lbmol=
P, psia =
T, F=
Composicin de
mezcla
zFi
0
0
0.3
0
0.1
0
0.15
0.45
0
0
0
0
0
0
0
0
0
0
0
0
0
1

1000
200
150
Ps
psia
6394.36467
###
1187.7158 6
332.620774 2
144.155194 1
107.546204 1
45.7583162 0
36.6255214 0
13.2046447 0
5.00048545 0
1.91595374 0
1786.35157 9
170.929726 1
407.192879 2
80.7700163 0
122.669062 1
127.31518 1
96.0340075 0
130.03344 1
102.738239 1
0.74505851 0
0.29272499 0

se corrige el valor del metano

por un factor de 1,7
si

0###
0###
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0###
0###
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0

K
14.4115103
3.51967141
1.47129831
0.77759666
0.61375428
0.30983997
0.25501988
0.10958075
0.04931609
0.02261151
4.53847383
0.87708945
1.71267952
0.49040182
0.67563551
0.7002313
0.55228925
0.71228442
0.58547493
0.01065647
0.00513044

DADES DE LA CORRIENTE DE ALIMENTACIN

ge el valor del metano

Entalpa en Btu/lbmol

zK
0
0
0.4414
0
0.0614
0
0.0383
0.0493
0
0
0
0
0
0
0
0
0
0
0
0
0
0.5903

z/K
0
0
0.204
0
0.163
0
0.588
4.107
0
0
0
0
0
0
0
0
0
0
0
0
0
5.062

Hvideal
HV
1288.661 -74.34 1214.3
1893.513 -255 1638.2
2631.45 -486 2145.7
3463.187 -732 2730.8
3489.544 -782 2707.3
4246.186 -1099 3146.8
4304.806 -1139 3165.9
5111.824 -1549 3563.1
5927.982 -2011 3917
6702.365 -2523 4179.7
1555.961 -199 1356.9
2107.125 -495 1612.1
2283.377 -434 1849
2861.906 -933 1929.3
2836.355 -685 2151.1
3057.638 -714 2343.5
2819.425 -741 2078.3
3182.231 -710 2472.1
3138.919 -737 2401.6
7561.956 -3088 4473.8
8378.072 -3694 4684.6
Entalpia como vapor =

z(HV)
0
0
643.7133
0
270.7339
0
474.8829
1603.384
0
0
0
0
0
0
0
0
0
0
0
0
0
2992.714

-1310.9019
2280.87333
5412.13447
7331.177
8237.40903
9828.00511
10607.7281
12758.0596
14755.9408
16730.7583
1322.31973
5245.81657
5093.60706
9179.17755
8185.8862
7879.36161
8627.92748
7846.29935
8381.82277
18841.6627
20946.687

2376.641
1516.1
807.8343
527.8539
420.6158
251.5409
208.5677
102.2534
50.28052
24.1663
1778.272
423.1053
884.4499
376.6438
420.2808
454.5764
355.8543
461.731
378.7332
11.50419
5.40591

HL
1014.08 -489.481 -301.676
208.427 -76.7956 -2035.09
34.3839 -11.1809 -3611.72
-18.137 5.51321 -4383.22
-28.828 8.51647 -5148.17
-55.569 15.4961 -5793.29
-58.181 16.0045 -6469.31
-75.26 19.5528 -7692.78
-87.931 21.8184 -8812.13
-98.892 23.5793 -9977.25
300.968 -116.301 -1729.3
-5.5151 1.69741 -3557.98
50.5386 -16.5802 -3728.64
-30.621 8.50265 -6671.8
-20.927 6.18383 -5755.07
-21.375 6.37329 -5261.3
-29.143 8.49679 -6143.71
-20.535 6.14045 -5111.41
-28.049 8.24536 -5601.83
-109.17 25.1668 -11207.2
-119.3 26.6796 -12481.4
Entalpa como liquido =

CLCULOS EN EL SEPARADOR
Ingrese la presin y la temperatura
en el separador flash
P, psia =
75
T, F = 132.5505304

z(HL)
0
0
-1083.5166
0
-514.81688
0
-970.39701
-3461.7519
0
0
0
0
0
0
0
0
0
0
0
0
0
-6030.4824

Ps
psia
5866.679561
1022.554371
274.9281959
115.418352
84.81893698
35.15109386
27.68974508
9.557837674
3.463034664
1.268082581
1559.943686
146.8425534
337.3856329
62.42694478
96.90082124
101.08313
75.40297208
103.2673749
81.03473486
0.468588018
0.174899853

78
14
3.7
1.5
1.1
0.5
0.4
0.1
0
0
21
2
4.5
0.8
1.3
1.3
1
1.4
1.1
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

se corrige el valor del metano

por un factor de 1,7
si

K
0 ### 0 35.9920757943
0 0 1 7.9846960682
0 0 1 3.0082146279
0 0 1 1.4509948141
0 0 1 1.114023499
0 0 1 0.5097761348
0 0 1 0.4092104622
0 0 1 0.1541949688
0 0 1 0.060346342
0 0 1 0.0238376346
0 0 1 10.5922400677
0 0 1 1.8278893819
0 0 1 3.5591717797
0 0 1 0.8508680832
0 0 1 1.2546249773
0 0 1 1.2992724503
0 0 1 1.0047885125
0 0 1 1.3235635381
0 0 1 1.0711044739
0 0 2 0.0095330982
0 0 2 0.0038647418

zFi ( Ki )
0
0
0.9024643884
0
0.1114023499
0
0.0613815693
0.0693877359
0
0
0
0
0
0
0
0
0
0
0
0
0
1.1446360435

zFi / Ki
0
0
0.0997269268
0
0.0897647133
0
0.366559543
2.9183831589
0
0
0
0
0
0
0
0
0
0
0
0
0
3.474434342

Ingrese V/F
V/F =

0.102358888

0
0
0.832462818
0
0.00127031
0
0.059311364
0.385840564
0
0
0
0
0
0
0
0
0
0
0
0
0
-1.278885057

gi
0
0
0.499738777
0
0.011270805
0
-0.09432234
-0.41668724
0
0
0
0
0
0
0
0
0
0
0
0
0
1.1102E-016

Nuevo V/F= 0.102358888

xi
0
0
0.248847295
0
0.098846333
0
0.15965473
0.492651642
0
0
0
0
0
0
0
0
0
0
0
0
0
1

yi
0
0
0.74858607
0
0.11011714
0
0.06533239
0.0759644
0
0
0
0
0
0
0
0
0
0
0
0
0
1

Hv ideal
1132.6673553
1655.5208644
2294.4305811
3018.5430221
3044.5200015
3700.3325616
3755.6638969
4457.2620764
5168.6587973
5851.4235712
1358.8574537
1841.1515461
1993.2110434
2500.0363571
2470.344444
2665.3161395
2456.5532379
2777.4467423
2741.5959423
6593.4604282
7304.9312675

G1= 1.11022E-016
d(G1)/d -1.278885057
Guardar
Guardar
Guardar
Guardar
Guardar
Guardar
Guardar
Calcula
Ingresar
Calcula
Guardar
Guardar
Calcula
Calcula

HV i
-29.410551571 1103.256804
-100.44396282 1555.076902
-190.8816152 2103.548966
-287.65277855 2730.890244
-307.18472493 2737.335277
-431.63006931 3268.702492
-447.10255933 3308.561338
-607.83189441 3849.430182
-789.1172962 4379.541501
-989.73264235 4861.690929
-78.379325633 1280.478128
-194.46920948 1646.682337
-170.7239919 1822.487052
-366.1377513 2133.898606
-269.1004535 2201.24399
-280.45282355 2384.863316
-291.02034367 2165.532894
-278.91679395 2498.529948
-289.53288865 2452.063054
-1211.4662519 5381.994176
-1448.8220672 5856.1092
HV Btu/lbmol =

V/F antiguo
T antiguo
G1 antiguo=
G2 antiguo=
Hv=
Hl=

0.102379989
132.5533861
1.1102E-016
5.4745E-005
2384.770881
-6989.93449

d(G1)/d
d(G2)/d

-1.27888549
1.554553145

delta T=
T=
G1=
G2=
d(G1)/dT =
d(G2)/dT =

0.1
132.6505304
0.000945128
0.000822875
0.009451284
0.007681308

yi (HVi)
0
-1147.0195252
0
2604.8088384
1574.68745715 5716.5155097
0
7625.290554
301.427525597 8513.9606145
0
10078.73304
216.156206272 10844.772206
292.419671714 12973.730101
0
14996.111682
0
16965.450034
0
1624.2630812
0
5416.3841328
0
5415.0209881
0
9454.4083053
0
8457.4283285
0
8162.4665131
0
8893.1601307
0
8131.2506537
0
8644.5654944
0
19166.8213
0
21340.689791
2384.69086074

2300.56376
1369.45884
699.716508
442.672128
347.401091
202.296921
165.068745
77.4607811
36.4365407
16.7341696
1630.23112
380.751404
767.997627
304.758149
347.680733
377.987323
292.583985
384.040068
312.829612
7.56904759
3.37865023

948.15491 -444.561552
199.95179 -71.564454
51.834352 -16.3729771
13.126536 -3.87604913
3.0616786 -0.87859367
-14.356544 3.88888939
-16.848054 4.50197112
-26.366651 6.65411199
-32.258038 7.77515728
-36.810291 8.52560834
281.7285 -105.750959
13.629695 -4.07480707
64.001185 -20.3959511
-3.2290002 0.8709602
5.9265867 -1.70119103
7.6704841 -2.22161162
0.1129584 -0.03199096
8.2963197 -2.40981478
1.7403613 -0.49695164
-40.833737 9.14423794
-44.7 9.71006459
HL Btu/lbmol =

Jacobiano, J = -1.27888549 0.0094513

1.55455315 0.0076813

J-1xG = -0.31331769 0.3855144 1.110E-016

63.4096445 52.165263 5.474E-005
J-1xG = 2.11E-005
0.0028558
Nuevos
V/F= 0.1023589
T= 132.55053

RESULTADOS
F, lbmol/h =
1000
P psia =
200
T,F =
150
HF Btu/lbmol = -6030.48239
Compuesto
HLi
-524.47023675
-2447.1341528
-4157.2628112
-5058.6701474
-5819.0247889
-6570.2297451
-7241.8309713
-8574.2162666
-9839.4065442
-11102.47595
-2071.6142924
-3965.5388785
-4233.412806
-7256.7720573
-6338.9900127
-5880.5865689
-6729.2718449
-5743.7304847
-6217.0425734
-12549.240421
-14004.147238

xi (HLi)
0
0
-1034.5236036
0
-575.18926181
0
-1156.1925702
-4224.1017241
0
0
0
0
0
0
0
0
0
0
0
0
0
-6990.0071597

Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano
0.000009766

G2

0.000009766

Fase vapor
lbmol/h
0
0
76.62443768
0
11.27146774
0
6.68735036
7.775631959
0
0
0
0
0
0
0
0
0
0
0
0
0
Totales= 102.3588877

Fase lquida
lbmol/h
0
0
223.375562
0
88.7285323
0
143.31265
442.224368
0
0
0
0
0
0
0
0
0
0
0
244094.304092
0
-6274517.8016
0
-6030482.3913
897.641112 Balance de energa Q Btu/h= 58.8938422622

2500
2000
1500
1000
500
0
-500
-1000

25

26

27

28

Q/F
25
27
27.3
27.4
27.5
28
30
35

delta(BM-BE)
25
0.06201
27 -0.0089448
27.3 -0.0022255
27.4 0.0000393
27.5 0.0023307
28 0.0138228
30 -0.0519624
35 0.1963176

-559
-96.8
-24.03
0.421
24.97
149.2
670
2135

500

0.25

000

0.2

500

0.15

000

0.1

500

0.05
0

500

000

25

26

27

28

29

30

31

32

33

34

35

36

-0.05
-0.1

25

26

27

28

29

26

27

28

29

30

31

32

33

34

35

36

PROPIEDADES A PARTIR DE LA ECUACIN DE REDLICH KWONG

Compuesto

Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano

16.043
30.07
44.097
58.124
58.124
72.151
72.151
86.178
100.205
114.232
28.054
40.065
42.081
54.092
54.092
56.108
56.108
56.108
56.108
128.259
142.286

Temp.critica
Tc, Rankine
343.9
550
665.9
734.7
765.3
829.8
845.6
914.2
972.3
1024.9
509.5
721.7
657.2
834.7
765
755.3
779.7
752.2
770.7
1071
1114

K i P, T

Constante de equilibrio

Volumen lquido
vL, cm3/mol
52
68
84
105.5
101.4
117.4
116.1
131.6
147.5
163.5
61
61.6
79
83.7
88
95.6
91.2
95.4
93.8
179.6
196

C
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25
25

pie3/lbmol
0.83295574
1.08924982
1.34554389
1.68993906
1.6242637
1.88055777
1.85973388
2.10801877
2.362711
2.61900508
0.97712116
0.98673219
1.26545199
1.34073838
1.40961741
1.5313571
1.46087623
1.52815342
1.50252401
2.87690099
3.13960242

yi
P sat
0.42748TCi2.5
viL 0.08664TCi
sat

i exp

(
P

P
)

2.5

xi
P
RT
PCiT
PCiT

Psi
A2

Ln

Pci
A3 t (
F)

Presin de vapor de Antoine

Volumen de lquido puro, ec Cavett

Entalpa de vapor puro

Pres. critica
Pc, psia
673.1
709.8
617.4
529.1
550.7
483
489.5
440
396.9
362.1
742.2
747.2
667
578.1
628
583
610
580
595
331
306

viL zi (5.7 3

T
)
Tci

1.0687TCi2.5
RP

h
C dT

0.08664
T

ci

Pci
T 1.5

T
T

V
i

0
P

Entalpa de lquido puro

Calor especfico de gas ideal

A2

h
C Pi dT RT

(T A3 459.67) 2

T0

L
i

CP0 c1 c2t c3t 2 c4t 3 c5t 4

t
F , CP0

Btu / lbmol
F

sat

Pi

Ci

0.08664TCi 0.42748TCi2.5

T 2.5
T

CP0 c1 c2t c3t 2 c4t 3 c5t 4

t
F , CP0

Btu / lbmol
F

F
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77
77

z
0.0802337
0.1262563
0.1657524
0.2141499
0.2081385
0.2461386
0.2445736
0.2825341
0.3212004
0.360204
0.1102848
0.1244168
0.155274
0.1757458
0.1806139
0.1955352
0.1881382
0.1949075
0.1929028
0.3993878
0.4393971

Constantes de Antoine
A1
A2
5.14135
1742.638
5.383894
2847.921
5.353418
3371.084
5.611805
3870.419
5.741624
4126.385
5.49978
4221.154
5.853654
4598.287
6.039243
5085.758
5.98627
5278.902
6.4141
5947.491
5.27791
2568.994
2.443058
1832.002
5.44467
3375.447
6.184923
4644.865
5.69864
4105.731
5.58272
3941.014
5.456285
3977.563
5.616762
3953.678
5.487073
3984.406
6.22189
5924.61
6.33557
6213.998

A3
452.974
434.898
414.488
409.949
409.5179
387.287
394.4148
382.794
359.5259
360.26
433.9156
317.5695
418.4319
419.7079
409.9979
404.741
394.4956
405.9166
400.0702
330.96
317.6512

Constantes para Calor especfico gas ideal

c1
c2
c3
8.245223 0.003806333 8.864745E-006
11.51606
0.0140309
8.54034E-006
15.58683
0.02504953 1.404258E-005
20.41853
0.03462286 1.415619E-005
20.79783
0.03143287 1.928511E-005
24.94637
0.04446726 7.054883E-006
25.64627
0.0389176 2.397294E-005
30.17847
0.05199263 3.048799E-006
34.96845
0.0608752 1.213345E-006
39.77987
0.06930903 -3.57634E-005
9.326018
0.01393934 1.010831E-006
12.6505
0.01928835 -6.45283E-006
13.63267
0.02106998 2.49845E-006
17.15982
0.026213
-5.93782E-006
16.47292
0.03392027 -1.39251E-005
17.96141
0.03297022 -6.05339E-006
16.54537
0.02966393 5.471621E-006
18.93086
0.03101008
-0.00000493
18.84267
0.02761259 3.097447E-006
44.6198
0.07738344 2.963375E-006
49.42138
0.08602711 2.049705E-006

4TCi
sat

(
P

P
)
i

sat
sat
sat

0.08664TCi 1.0687TCi2.5
Pi v iL
v iL
8664TCi 0.42748TCi2.5
Pi
( P Pi )
3

RT
PCi

T
T 2.5
T2
T 3.5
RT
TCi
T

PROPIEDADES DE LA CORR
-2368.97

ico gas ideal

c4
-7.46115E-009
-1.10608E-008
-3.52626E-008
-4.24613E-008
-4.58865E-008
-3.34417E-008
-5.84262E-008
-2.76400E-008
-2.93693E-008
-3.45609E-008
-7.51655E-009
-1.67465E-009
-1.14686E-008
-2.36130E-009
-4.78632E-009
-5.69808E-009
-1.88313E-008
-0.000000006
-1.33756E-008
-4.13472E-008
-4.41541E-008

Compuesto
c5
1.822959E-012
3.162199E-012
1.864467E-011
2.296993E-011
2.380972E-011
1.774503E-011
3.079918E-011
1.346731E-011
1.454746E-011
1.749419E-011
3.615367E-012
1.813724E-012
5.247386E-012
1.011447E-012
5.611304E-012
2.826942E-012
8.437562E-012
3.200886E-012
5.631517E-012
2.114216E-011
2.256651E-011

Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano

F lbmol=
P, psia =
T, F=
Composicin de
mezcla
zFi
0
0
0.3
0
0.1
0
0.15
0.45
0
0
0
0
0
0
0
0
0
0
0
0
0
1

1000
35
50
Ps
psia
3599.59189
###
435.127887
###
91.9551446 3
32.0755849 1
21.6066424 1
7.58934277 0
5.47505641 0
1.45503164 0
0.39839077 0
0.11182031 0
719.64941
###
58.8677853 2
114.61933 3
14.2368343 0
24.9191665 1
26.6930896 1
18.5646118 1
27.3265173 1
20.5483346 1
0.02936999 0
0.0078855 0

se corrige el valor del metano

por un factor de 1,7
si

0###
0###
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0
0 0###
0

K
60.1107375
9.05344531
2.42455182
0.9220486
0.63580513
0.23568736
0.17161844
0.04788476
0.01373279
0.00404494
13.3187598
1.62748942
2.95977748
0.42874788
0.72593485
0.77554095
0.54881678
0.79286529
0.60493251
0.00111928
0.00031764

DADES DE LA CORRIENTE DE ALIMENTACIN

ge el valor del metano

Entalpa en Btu/lbmol

zK
0
0
0.7274
0
0.0636
0
0.0257
0.0215
0
0
0
0
0
0
0
0
0
0
0
0
0
0.8382

z/K
0
0
0.124
0
0.157
0
0.874
9.398
0
0
0
0
0
0
0
0
0
0
0
0
0
10.55

Hvideal
HV
417.3769 -18 399.41
593.6804 -59.89 533.79
811.1846 -113 697.97
1064.73 -170 894.48
1079.916 -182 898.25
1303.145 -255 1048.2
1331.87 -264 1067.9
1574 -358 1215.5
1824.522 -465 1359.5
2074.087 -583 1491.3
483.7557 -46.86 436.9
656.3641 -115 541.22
708.0575 -101 606.77
890.5062 -216 674.29
865.459 -159 706.31
939.0223 -166 773.12
864.5475 -172 692.5
985.091 -165 820.09
976.7578 -171 805.55
2327.779 -713 1614.7
2578.621 -852 1726.2
Entalpia como vapor =

z(HV)
0
0
209.3909
0
89.82461
0
160.1852
546.9968
0
0
0
0
0
0
0
0
0
0
0
0
0
1006.397

-277.85921 1847.974 537.358

4095.61121 744.5715 79.3317
7019.20035 297.4487 13.9789
8811.75928 156.026 -0.9024
9606.7462 112.1507 -3.9739
11130.9866 55.27427 -9.4237
11810.4794 41.29262 -10.04
13928.2992 14.90163 -12.939
16211.279 5.292694 -14.968
18224.8068 1.862045 -16.737
3077.84082 963.482 121.661
6430.74762 193.6592 4.29952
6783.67426 331.7105 18.3757
10474.4529 87.9476 -5.0895
9534.41826 113.3095 -2.5958
9307.42356 126.5262 -2.3234
9990.77801 91.25927 -4.3867
9279.60921 128.8293 -2.1417
9720.58469 100.5156 -3.9668
21065.5081 0.598349 -18.435
23726.9286 0.192047 -20.137
Entalpa como liquido =

-235.474
-26.0074
-4.01414
0.24135
1.03138
2.30215
2.41792
2.93539
3.23654
3.47179
-41.9612
-1.16505
-5.32633
1.23782
0.6739
0.60891
1.12289
0.56298
1.02419
3.69247
3.90796

HL
-1454.62
-4299.83
-6515.43
-7902.39
-8636.04
-9875.99
-10512.3
-12359.2
-14380.3
-16139.3
-3637.27
-5971.18
-6420.38
-9668.04
-8780.35
-8493.21
-9214.23
-8421.77
-8841.4
-18723.6
-21132.3

CLCULOS EN EL SEPARADOR
Ingrese la presin y la temperatura
en el separador flash
P, psia =
35
T, F =
144.26

z(HL)
0
0
-1954.6288
0
-863.60385
0
-1576.842
-5561.6391
0
0
0
0
0
0
0
0
0
0
0
0
0
-9956.7137

Ps
psia
6219.196276 178
1131.760867 32
312.8280133 8.9
134.1959712 3.8
99.63151812 2.8
42.0363466 1.2
33.47314466 1
11.9008733 0.3
4.443716995 0.1
1.678005165 0
1710.006321 49
162.8052402 4.7
383.2593391 11
74.33819389 2.1
113.699818 3.2
118.2012152 3.4
88.8432103 2.5
120.7342769 3.4
95.18303299 2.7
0.642055486 0
0.248169636 0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

se corrige el valor del metano

por un factor de 1,7
si

K
0 ### 0 78.4998974941
0 0 1 17.8697829192
0 0 1 6.8749116988
0 0 1 3.3405064526
0 0 1 2.589795071
0 0 1 1.1841589553
0 0 1 0.9594089561
0 0 1 0.3625418569
0 0 1 0.1415779527
0 0 1 0.0555844691
0 ### 0 23.5547932807
0 0 1 4.139706928
0 0 1 8.1360073222
0 0 1 1.9891396353
0 0 1 2.9374053408
0 0 1 3.0206156418
0 0 1 2.3570113778
0 0 1 3.0767923874
0 0 1 2.503444041
0 0 1 0.0220842166
0 0 1 0.0088660074

zFi ( Ki )
0
0
2.0624735096
0
0.2589795071
0
0.1439113434
0.1631438356
0
0
0
0
0
0
0
0
0
0
0
0
0
2.6285081957

Ingrese V/F
V/F =
0.600096512

zFi / Ki
0
0
0.0436369241
0
0.0386130938
0
0.1563462578
1.2412359881
0
0
0
0
0
0
0
0
0
0
0
0
0
1.4798322638

0
0
0.5055779
0
0.0661942
0
0.0002596
0.4796154
0
0
0
0
0
0
0
0
0
0
0
0
0
-1.051647
0.6000965

gi
0
0
0.389452668
0
0.081359789
0
-0.00624067
-0.46457179
0
0
0
0
0
0
0
0
0
0
0
0
0
5.1459E-014
G1

xi
0
0
0.0662908
0
0.0511763
0
0.153745
0.7287879
0
0
0
0
0
0
0
0
0
0
0
0
0
1

yi
0
0
0.45574348
0
0.13253606
0
0.14750433
0.26421612
0
0
0
0
0
0
0
0
0
0
0
0
0
1

Hv ideal
1237.14871
1814.69346
2519.6761
3315.70049
3341.99724
4065.12715
4122.73623
4894.78065
5676.19998
6420.52439
1490.65969
2019.04936
2187.21619
2742.04914
2714.95654
2927.54433
2699.04443
3048.09318
3007.28751
7240.81661
8022.23357

-13.2386
-45.3821
-86.3119
-130.111
-138.962
-195.298
-202.308
-275.083
-357.17
-448.014
-35.3987
-87.9573
-77.1935
-165.667
-121.733
-126.864
-131.656
-126.168
-130.979
-548.424
-655.914
HV Btu/lbmol =

HV

HV i
yi (HVi)
1223.91
0
-1258
1769.311
0
2387
2433.364 1108.98985767 5513
3185.59
0
7429
3203.036 424.517728024 8330
3869.829
0
9912
3920.428 578.2801581138 10687
4619.698 1220.59857286 12830
5319.03
0
14835
5972.51
0
16807
1455.261
0
1421
1931.092
0
5300
2110.023
0
5200
2576.382
0
9272
2593.223
0
8277
2800.68
0
7974
2567.388
0
8716
2921.925
0
7942
2876.309
0
8470
6692.392
0
18947
7366.319
0
21073
Btu/lbmol = 3332.38631666

HLi
2352 ### -484 -305.7429
1467 ### -84 -2173.245
771.5 68 -23 -3809.889
498.9 31 -9.7 -4633.573
395.6 19 -5.9 -5396.992
234.6 2 -0.7 -6082.897
193.5 -1 0.15 -6757.615
93.54 -9 2.4 -8022.249
45.35 ### 3.39 -9194.275
21.48 ### 3.93 -10396.34
1729 ### -122 -1836.048
409.1 23 -7.39 -3706.19
845.3 80 -28 -3911.142
351.9 10 -2.78 -6888.831
395.5 20 -6.23 -5971.427
428.4 23 -7.23 -5490.973
334.2 14 -4.36 -6361.651
435.2 24 -7.45 -5345.22
356.2 17 -5.05 -5829.997
10.06 ### 4.3 -11702.11
4.651 ### 4.6 -13040.27
HL Btu/lbmol =

xi (HLi)
0
0
-252.56063406
0
-276.19792326
0
-1038.9495671
-5846.5184175
0
0
0
0
0
0
0
0
0
0
0
0
0
-7414.2265419 0.9030582093
G2

RESULTADOS
F, lbmol/h =
1000
P psia =
35
T,F =
50
HF Btu/lbmol = -9956.71368
Compuesto
Metano
Etano
Propano
i-Butano
n-Butano
i-Pentano
n-Pentano
n-Hexano
n-Heptano
n-Octano
Etileno
Propadieno
Propileno
1,2-Butadieno
1,3-Butadieno
1-Buteno
cis-2 Buteno
Isobuteno
Trans-2 Buteno
n-Nonano
n-Decano

Fase vapor Fase lquida

lbmol/h
lbmol/h
0
0
0
0
273.4900729 26.5099271
0
0
79.53442932 20.4655707
0
0
88.51683641 61.4831636
158.555173 291.444827
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Totales= 600.0965117 399.903488 Balance de energa Q Btu/h=

Q/F
25
27
27.3
27.4
27.5
28
30
35

-559
-96.8
-24.03
0.421
24.97
149.2
670
2135

2500
2000
1500

1999753.40415
-2964975.0574
-9956713.6811
8991492.02781

1000
500
0
-500
-1000

25

26

27

28

29

30

31

32

33

34

35

delta(BM-BE)
25
0.06201
27 -0.0089448
27.3 -0.0022255
27.4 0.0000393
27.5 0.0023307
28 0.0138228
30 -0.0519624
35 0.1963176

0.25
0.2
0.15
0.1
0.05
0
31

32

33

34

35

36

-0.05
-0.1

25

26

27

28

29

30

31

32

33

34

35

32

33

34

35

36