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V=
nRT
P
1lbmol1073
psi
P
V =
3
1lbmol10.73
psipie
(60 F +460)
lbmolR
=379,4 pie 3
14.71 psi
a)
V=
b)
psipie 3
1lbmol10.73
(32 F+ 460)
lbmolR
3
V=
=358.97 pie
14.71 psi
3
psipie
(80 F +460)
lbmolR
3
=377.9 pie
1lb
14.71 psi+10 oz
16 oz
1lbmol10.73
c)
d)
V=
psipie 3
(60 F +460)
lbmolR
=371.2 pie3
15.025 psia
1lbmol10.73
V=
a)
10 lb
20 lb C 2
CH 41 mol
=0.625 mol
16 lb
H 61 mol
=0.667 mol
30 lb
nC H 4 + n C2 H 6=0.625+0.667=1.292 moles
b)
P=
PV =nRT
1.29210.732(90+ 460)
=15.25 psi
500
P=15.2514.7=0.55 psi
X 1=0.33316=5.333
X 1=0.33330=10
X 1=0.33344=14.667
X 1 + X 2 + X 3=5.333+10+14.667=30
=
30
=1.036
28.97
10 lb C
O21 mol
=0.227 mol
44 lb
n=
14.750
=0.13
10.732(75+ 460)
nT =0.227+ 0.13=0.357
P=
20
0.35710.732(45+ 460)
=3869 psi
50
lb1 mol
=0.769
26 lb
n=
15.7200
=0.54 moles
10.732(85+ 460)
0.54$ 4.50
=$ 3.15
0.769
n=
14.71000
=2.63 moles
10.732(60+ 460)
2.63$ 4.50
=$ 15.41
0.769
a) Volumen aire
2
110 (3225)
pi
2
pi D h
V=
=
4
Volumen condensado
Hg2.54 cm Hg
10 mmHg
1Hg
14.7 psi
1 cm Hg
29.1
=14.3 psi
760 mmHg
3 oz
1 lb
4 2
=0.047+ 14.3 psi=14.347
16 oz
V=
16926.1414.3
=16870.69 bl
14.347
V T =16926.1416870.69=55.4 bl
t=
55.45 bl
=3.9 min
bl
1 dia
dia
20000
1440 min
b)
P=
F
A
F=PA
12
1 pie
110 pie
psi
F=14.347
4
c) Si existiera mayor cantidad de petrleo el tiempo de colapso sera
menor.
a)
Mgas
28.97
Mgas=28.970.65=18.8305
X
( 1Mmet )+(X 2Meta)=Mmezcla
X 1 + X 2 =1
X 2=1X 1
X
( 1Mmet )+( ( 1 X 1 )Meta)=Mmezcla
X 1=
MmezclaMeta
MmetMeta
X 1=
18.830530
=0.797=79.7
1630
X 1=0.797
0.791 mol CH 4
1 mol de mezcla
0.797 mol16
g
=12.64 g
mol
0.791mol C 2 H 4
1 mol de mezcla
0.209 mol30
g
=6.27 g
mol
mT =18.99 g
Metano=66.84 %Etano=333.15
P1=50 psi
P2=25 psi
V 1=50 pie s3
V 2=?
V eq =V 1+ V 2
T 1 =50 F
PV =nRT
n1=
50 pi e 350 psi
=0.4567 lbmol
pie s3psi
10.732
(510 R)
R lbmol
RT
V =
P
3
pie s psi
10.732
510 R
3
R lbmol
pie s
V =
=218.922
25 psi
lb
TeqR
pie s3
V =
=156.373
Peq
1 mol
V T =V 1+V 2
V T =50+V 2
nT =n1 +n 2
nT =0.4567+ n2
3
V eq =156.373
Vn =
2
pie s
lbmol
V2
n2
V 2=V n n2
2
V eq =
3
50+V 2
pie s
=156.373
0.4567 +n2
lbmol
50+V 2=156.373
pie s
(0.4567lbmol+n 2)
mol
62.549
pie s
n =21.41 pi e3
lbmol 2
21.41 pi e
n2 =
=0.342 mol
3
pie s
62.549
lbmol
V 2=124.9450=74.94 pie s 3
pie s3 psi
(80+ 460) R =2.484 lbmol
R lbmol
RT
10.732
n=
2.692$ 1.10
3
=$ 1.19 dolares por cada 1000 pie s a 60 F y 15.025 psi
2.484 lbmol
30,48 cm 3
cm 31 pie 3
V =4500
n=
PV
=
RT
P(psi)
300
750
1500
2500
4000
5000
6000
V ideal(pie
cubico)
0,09278
0,03711
0,01856
0,01113
0,00696
0,00557
0,00464
Z
0,963
0,917
0,862
0,841
0,914
0,993
1,083
B)
g=0,0282692
zT
P
P(psi)
300
750
1500
2500
4000
5000
6000
g(pie
cubico/SCF)
0,0562
0,0214
0,0101
0,0059
0,0040
0,0035
0,0032
c)
P(psi)
300
750
1500
2500
4000
5000
6000
Z
0,962642381
0,917346041
0,862153022
0,840583337
0,913539626
0,992839941
1,082544457
g(pie
cubico/SCF)
0,0562
0,0214
0,0101
0,0059
0,0040
0,0035
0,0032
Z y bg vs Presion
1.2
1
0.8
g(pie cubico/SCF)
0.6
0.4
0.2
0
300
750
A)
T
P
P pr=
T pc
P pc
P(psi)
Preducida
T reducida Z
0
0,000
1,699
1
1000
1,493
1,699
0,91
2000
2,985
1,699
0,88
3000
4,478
1,699
0,9
4000
5,970
1,699
0,95
5000
7,463
1,699
0,96
6000
8,955
1,699
0,9
Los valores de z a su respectiva P reducida y T reducida fueron tomados
de la Figura A-15 de la termodinamica de Cengel, quinta edicion.
B)
P(psi)
0
1000
2000
3000
4000
5000
T
Preducid reducid
a
a
Z
0,000
1,649
1
1,489
1,649
0,91
2,979
1,649
0,88
4,468
1,649
0,9
5,958
1,649
0,95
7,447
1,649
0,96
6000
8,936
1,649
0,9
Comparacion z vs Presion
1.2
1
0.8
Z
0.6
Ejercico 1,11a
0.4
Ejercico 1,10a
0.2
0
Presion (psi)
n1 =
PV
=
Z1 RT
2500 psia0,330 ft
=0,174 lbmol
3
pie s psi
0,7510.732
590 R
R lbmol
3
pie s psi
520 R
Rlbmol
=66,05 SCT
14,7 psia
0,174 lbmol10.732
V CS1=
n2 =
PV
=
RT
14,7 psia22,45 ft
=0,0591 lbmol
3
pie s psi
10.732
520 R
R lbmol
Z 2=
PV
=
n2 RT
1000 psia0,330 ft 3
=0,88
pie s3 psi
0,0591lbmol10.732
590 R
R lbmol
P1 P2
=
n1 n 2
n2=
n1
2
P1=2 P2
P2=
P 1 6000 psi
=
=300 psi
2
2
3
n=
500 psi(1 MM pi e )
PV
=
=75144.578 Lbmol
RT
pie s 3 psi
10.732
620 R
R lbmol
n producido n
total
nres
V=
nRT
=
P
pie s3 psi
( 520 R )
R lbmol
V =3138025936.8 SCF
z vs P
1.2
1
0.8
0.6
0.4
0.2
0
0
1000
2000
3000
1000 2( 0.00021000)+1.0014
1000 3+ 5108
y =31012
y=0.8484
0.00022200
2200 2()+1.0014
2200 3 +5108
y=31012
y=0.771456
4000
5000
6000
4000 (0.00024000)+1.0014
4000 3 +5108
12
y=310
y=0.8094
12
y=310
=0.7
T PC =375 R
663 R
=1.768
375 R
PPR =
5000 psia
=7.518
665 psia
z=0.96
P=7000 psi
T =220 F680 R
=0.9
2 Nitrogeno
4 Dioxido de Carbono
6 Hydrogen Sulfide
PR =
7000 psi
=11.006
635.984 psi
T R=
680 R
=1.6
423.81 R
=M /M A
M =G . E( M A )=( 0.9 )( 28.9 )=26.01
mol
lb
@1 atm=0.0118 centipoise
Solucion de gas
300
200
100
0
0
500 1000150020002500300035004000
e)
a)
0.8
0.6
0.4
0.2
0
0
Bls
Bo
BF=
250106 Bls
1.31 Bls /BF
BF=190.8 STB
e)
Rsia=
Gi
BN
Gi=RsiBN
Gi=567
PCS
6
9
190.810 BF=108.210 PCS
BF
f)
V T =V 60 (1+ ( T 60 ) )
V T =1(1+ 0.0006 ( 16060 ))
V T =1.06 Bls /BF
0,25
Rs =
( SCF
STB )
SCF
500 psia=125
psia
STB
g=0,0282692
SCF
=10625 SCF
STB
ZT
0,9580 R
ft 3
=0,0282692
=0,02951
P
500 psia
SCF
V R =9374 SCF0,02951
ft 3
=276,65 ft 3
SCF
18
P
Rso
Y g=
Y g =0.00091T 0.0125API
3
P(10 )
141.5
API +131.5
P/ Pb
o= ob
P)
B)
=109,574 200 F
1,12166
=0,287 cp
wt
1+ V
1+ V
bW =
wt
4
7 2
V =1,0001010 1,3339110 T +5,5065410 T
2
13
V =1,9530110 PT 1,7283410
T P23,58922107 P2,253411010 P2
wt
4
7
2
V =1,0001010 1,3339110 180+5,5065410 180 =0,0161
2
10
2
7 60002,2534110 6000 =0,0134
V =1,95301109 ( 6000180 )1,728341013180600023,5892210
bW @ 6000 psia =(10,0161) ( 10,0134 )=0,970
bbl
STB
7 10002,253411010 10002=9,652104
V =1,95301109 ( 1000180 ) 1,7283410131801000 23,5892210
bW @ 1000 psia =(10,0161) ( 19,652104 )=0,980
V O @ 14,7 psia=
cc1bbl
=3,14 103 bbl
158987,29 cc
bbl
STB
bbl
3
=3,177 10
STB
El signo negativo indica que ese volumen fue expulsado del tanque