log

log
log
log

1=log kf1=pkc1
2
3
4

10.26
16.42
19.08
21.08

1
2
3
4

18197008586
2.63027E+16
1.20226E+19
1.20226E+21

0=1/Pb(L)
pL=-log L

[L] 10
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
1.2
1.3
1.4
1.5
1.6
1.7
1.8
1.9
2
2.1
2.2
2.3
2.4
2.5
2.6
2.7
2.8
2.9
3
3.1
3.2
3.3
3.4
3.5
3.6
3.7

-pL

1
0.79432823
0.63095734
0.50118723
0.39810717
0.31622777
0.25118864
0.19952623
0.15848932
0.12589254
0.1
0.07943282
0.06309573
0.05011872
0.03981072
0.03162278
0.02511886
0.01995262
0.01584893
0.01258925
0.01
0.00794328
0.00630957
0.00501187
0.00398107
0.00316228
0.00251189
0.00199526
0.00158489
0.00125893
0.001
0.00079433
0.00063096
0.00050119
0.00039811
0.00031623
0.00025119
0.00019953

=1+1[L]+2[L] +3[L]0
1.21431E+21
4.84672E+20
1.93576E+20
7.73779E+19
3.09623E+19
1.24055E+19
4.97851E+18
2.00201E+18
8.07101E+17
3.264E+17
1.32512E+17
5.40546E+16
2.21793E+16
9.16541E+15
3.82022E+15
1.60876E+15
6.85772E+14
2.96517E+14
1.30328E+14
5.83568E+13
2.66757E+13
1.24716E+13
5.97266E+12
2.93292E+12
1.47751E+12
7.635E+11
4.04413E+11
2.19303E+11
1.21547E+11
68718127935
39545785709
23114549426
13693264810
8205473595
4964715288
3028234433
1859490163
1148164049
2

pkc
pkc
pkc
pkc

1
2
3
4

1=1[L]/Pb(L)
1

8.23511E-22
2.06325E-21
5.16592E-21
1.29236E-20
3.22974E-20
8.06096E-20
2.00863E-19
4.99499E-19
1.239E-18
3.06372E-18
7.54648E-18
1.84998E-17
4.50871E-17
1.09106E-16
2.61765E-16
6.21598E-16
1.45821E-15
3.37249E-15
7.67295E-15
1.7136E-14
3.74872E-14
8.0182E-14
1.6743E-13
3.40957E-13
6.76812E-13
1.30976E-12
2.47272E-12
4.5599E-12
8.22727E-12
1.45522E-11
2.52871E-11
4.32628E-11
7.30286E-11
1.2187E-10
2.01421E-10
3.30225E-10
5.37782E-10
8.70956E-10

1.49854E-11
2.9823E-11
5.93127E-11
1.17864E-10
2.33974E-10
4.6386E-10
9.18123E-10
1.81357E-09
3.57332E-09
7.01858E-09
1.37323E-08
2.67404E-08
5.1767E-08
9.95058E-08
1.89632E-07
3.57692E-07
6.6653E-07
1.22448E-06
2.2129E-06
3.92562E-06
6.82156E-06
1.15898E-05
1.92235E-05
3.10956E-05
4.90307E-05
7.53687E-05
0.000113025
0.00016556
0.000237277
0.000333372
0.00046015
0.000625338
0.000838481
0.001111466
0.001459169
0.001900249
0.002458137
0.003162249

3.8 0.00015849
3.9 0.00012589
4
0.0001
4.1 7.9433E-05
4.2 6.3096E-05
4.3 5.0119E-05
4.4 3.9811E-05
4.5 3.1623E-05
4.6 2.5119E-05
4.7 1.9953E-05
4.8 1.5849E-05
4.9 1.2589E-05
5
0.00001
5.1 7.9433E-06
5.2 6.3096E-06
5.3 5.0119E-06
5.4 3.9811E-06
5.5 3.1623E-06
5.6 2.5119E-06
5.7 1.9953E-06
5.8 1.5849E-06
5.9 1.2589E-06
6
0.000001
6.1 7.9433E-07
6.2 6.3096E-07
6.3 5.0119E-07
6.4 3.9811E-07
6.5 3.1623E-07
6.6 2.5119E-07
6.7 1.9953E-07
6.8 1.5849E-07
6.9 1.2589E-07
7 0.0000001
7.1 7.9433E-08
7.2 6.3096E-08
7.3 5.0119E-08
7.4 3.9811E-08
7.5 3.1623E-08
7.6 2.5119E-08
7.7 1.9953E-08
7.8 1.5849E-08
7.9 1.2589E-08
8 0.00000001
8.1 7.9433E-09
8.2 6.3096E-09
8.3 5.0119E-09
8.4 3.9811E-09
8.5 3.1623E-09
8.6 2.5119E-09

712199067.3
443450576.5
276989371.8
173477590.4
108900015.8
68502503.66
43172972.83
27259512.52
17243982.97
10930054.34
6943277.497
4421800.129
2824273.745
1810162.267
1164966.767
753409.8518
490072.859
320952.1025
211859.1036
141117.1786
94958.53043
64620.60622
44512.71235
31057.29286
21956.84184
15729.55651
11414.81204
8386.047567
6231.659354
4679.004597
3545.772815
2708.761025
2083.739681
1612.404487
1253.869496
979.0816977
767.123657
602.7429974
474.6842492
374.5494358
296.0101327
234.2554831
185.6003659
147.20357
116.8624937
92.8617789
73.86046615
58.80702091
46.87477784

1.4041E-09
2.25504E-09
3.61025E-09
5.76443E-09
9.18274E-09
1.4598E-08
2.31626E-08
3.66844E-08
5.79912E-08
9.14909E-08
1.44024E-07
2.26152E-07
3.54073E-07
5.52437E-07
8.58394E-07
1.3273E-06
2.04051E-06
3.11573E-06
4.72012E-06
7.08631E-06
1.05309E-05
1.54749E-05
2.24655E-05
3.21986E-05
4.55439E-05
6.35746E-05
8.76055E-05
0.000119246
0.000160471
0.000213721
0.000282026
0.000369172
0.000479906
0.000620192
0.000797531
0.001021365
0.001303571
0.001659082
0.002106664
0.002669875
0.003378263
0.004268844
0.00538792
0.006793314
0.008557065
0.010768693
0.013539043
0.017004772
0.021333434

0.004049474
0.005166004
0.006569569
0.008332141
0.010543191
0.01331354
0.016779849
0.021109693
0.026507112
0.033218321
0.041537034
0.051808485
0.064430754
0.079851392
0.09855677
0.12105109
0.147822094
0.179291531
0.215751026
0.257288346
0.303714842
0.354510393
0.408804758
0.465410742
0.522913828
0.57980709
0.634645544
0.686187304
0.733493543
0.775972853
0.813371768
0.845725271
0.873286081
0.896449856
0.915688295
0.931496158
0.944353565
0.954701987
0.962931023
0.969372852
0.974301615
0.977935552
0.98044034
0.981932551
0.982482561
0.982116486
0.980816935
0.97852251
0.975126093

8.7
8.8
8.9
9
9.1
9.2
9.3
9.4
9.5
9.6
9.7
9.8
9.9
10
10.1
10.2
10.3
10.4
10.5
10.6
10.7
10.8
10.9
11
11.1
11.2
11.3
11.4
11.5
11.6
11.7
11.8
11.9
12
12.1
12.2
12.3

1.9953E-09
1.5849E-09
1.2589E-09
1E-09
7.9433E-10
6.3096E-10
5.0119E-10
3.9811E-10
3.1623E-10
2.5119E-10
1.9953E-10
1.5849E-10
1.2589E-10
1E-10
7.9433E-11
6.3096E-11
5.0119E-11
3.9811E-11
3.1623E-11
2.5119E-11
1.9953E-11
1.5849E-11
1.2589E-11
1E-11
7.9433E-12
6.3096E-12
5.0119E-12
3.9811E-12
3.1623E-12
2.5119E-12
1.9953E-12
1.5849E-12
1.2589E-12
1E-12
7.9433E-13
6.3096E-13
5.0119E-13

37.41251843
29.90638442
23.95036349
19.22331128
15.47099358
12.4920075
10.12671533
8.248528295
6.757029642
5.572541483
4.631827676
3.884692197
3.291284522
2.819963885
2.445605729
2.148258334
1.912076909
1.724477647
1.57546624
1.457104785
1.363088526
1.288409757
1.229090934
1.181972716
1.144545637
1.114816409
1.091201745
1.072444013
1.057544257
1.045708985
1.03630791
1.028840381
1.022908718
1.018197035
1.014454414
1.011481547
1.009120115

0.026729021
0.033437676
0.04175302
0.052020174
0.06463709
0.080051185
0.098748703
0.121233748
0.147994023
0.179451333
0.215897497
0.257420652
0.303832742
0.35461447
0.408896654
0.465493365
0.522991515
0.579885742
0.634732738
0.686292441
0.733628067
0.776150595
0.813609451
0.846043218
0.873709154
0.897008684
0.916420822
0.932449609
0.945586904
0.956289
0.964964168
0.97196807
0.977604338
0.982128179
0.985751539
0.988648783
0.99096231

0.970472104
0.964353117
0.956506424
0.946611555
0.934290201
0.919110576
0.900598871
0.878260866
0.851616713
0.820250851
0.783876431
0.742409271
0.6960406
0.645292256
0.591035486
0.534457892
0.476973931
0.420090084
0.365250567
0.313696169
0.266364251
0.223844277
0.186387157
0.153954557
0.126289396
0.102990377
0.083578572
0.067550003
0.054412847
0.043710841
0.035035731
0.028031865
0.022395622
0.017871795
0.014248445
0.011351207
0.009037684

10.26
6.16
2.66
2

[CTOTAL]
0.001 M
Graficar 's vs pL y log Ci vs pL

pL (desde 0 a 2 unidades ms del pkc1)

2=2[L]2/Pb(L)

3=3[L]3/Pb(L) 3=4[L]4/Pb(L)

3
4
's=1
0.009900776 0.990077564
0.01243231 0.987533449
0.015600818 0.984345088
0.019560634 0.980353981
0.024500068 0.975365293
0.030646931 0.969141044
0.038273741 0.961392908
0.047701758 0.951775201
0.059302358 0.939879038
0.073493572 0.925229249
0.090728642 0.907286418
0.111472469 0.885457297
0.136160988 0.859117757
0.165138461 0.827652884
0.198569239
0.79051838
0.236324924 0.747325028
0.277856103 0.697942975
0.322070119 0.642614371
0.367250422 0.582052694
0.411063352 0.517498099
0.450695836 0.450695836
0.483144281 0.383775144
0.505629626 0.319030726
0.516058896
0.25864213
0.513414614 0.204394039
0.497955868 0.157467472
0.471166469 0.118351666
0.435467122 0.086887114
0.393782002 0.062410241
0.349082985 0.043946944
0.304018346 0.030401835
0.260684115 0.020706875
0.220542855 0.013915313
0.184457513 0.009244775
0.152793772
0.00608283
0.125548205 0.003970183
0.102472213 0.002573986
0.083175622 0.001659572

2.16605E-05
3.42414E-05
5.40938E-05
8.53853E-05
0.000134638
0.000212025
0.00033335
0.000523039
0.0008186
0.001277172
0.001984926
0.003070207
0.004721203
0.007208555
0.010912191
0.01634969
0.024200255
0.035314286
0.05069467
0.071434623
0.098601506
0.133068985
0.175320424
0.225267878
0.282142316
0.344501292
0.41036884
0.477480204
0.543570479
0.6066367
0.665119669
0.717983672
0.764703351
0.805186246
0.839664229
0.868581363
0.892495664
0.912002557

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

[Y4-]
[HY3-]
8.23511E-25 1.4985E-14
2.06325E-24 2.9823E-14
5.16592E-24 5.9313E-14
1.29236E-23 1.1786E-13
3.22974E-23 2.3397E-13
8.06096E-23 4.6386E-13
2.00863E-22 9.1812E-13
4.99499E-22 1.8136E-12
1.239E-21 3.5733E-12
3.06372E-21 7.0186E-12
7.54648E-21 1.3732E-11
1.84998E-20
2.674E-11
4.50871E-20 5.1767E-11
1.09106E-19 9.9506E-11
2.61765E-19 1.8963E-10
6.21598E-19 3.5769E-10
1.45821E-18 6.6653E-10
3.37249E-18 1.2245E-09
7.67295E-18 2.2129E-09
1.7136E-17 3.9256E-09
3.74872E-17 6.8216E-09
8.0182E-17
1.159E-08
1.6743E-16 1.9224E-08
3.40957E-16 3.1096E-08
6.76812E-16 4.9031E-08
1.30976E-15 7.5369E-08
2.47272E-15 1.1302E-07
4.5599E-15 1.6556E-07
8.22727E-15 2.3728E-07
1.45522E-14 3.3337E-07
2.52871E-14 4.6015E-07
4.32628E-14 6.2534E-07
7.30286E-14 8.3848E-07
1.2187E-13 1.1115E-06
2.01421E-13 1.4592E-06
3.30225E-13 1.9002E-06
5.37782E-13 2.4581E-06
8.70956E-13 3.1622E-06

0.927680867
0.940058274
0.949591666
0.956657804
0.96155041
0.964480731
0.965579519
0.96489913
0.96241507
0.958026846
0.951558465
0.942759445
0.931307738
0.916816651
0.898848428
0.876937628
0.850627362
0.819520412
0.783344628
0.742027695
0.695770506
0.645102867
0.590902655
0.534363029
0.476903079
0.420033106
0.365200392
0.313648113
0.266315409
0.223793015
0.186332707
0.1538967
0.126228243
0.102926215
0.083511765
0.067480931
0.054341876
0.0436383
0.034961912
0.027957018
0.022319961
0.017795502
0.014171675
0.011274094
0.008960347
0.007114805
0.005644012
0.004472711
0.003540469

0.067204538
0.054094707
0.043404714
0.034734145
0.027731417
0.022094977
0.017570659
0.013947036
0.011050003
0.008737309
0.006893432
0.005425014
0.004256898
0.00332876
0.002592307
0.002008948
0.001547887
0.001184567
0.0008994
0.000676737
0.000504041
0.000371218
0.000270095
0.000194015
0.00013754
9.6224E-05
6.64555E-05
4.53359E-05
3.05771E-05
2.04102E-05
1.34986E-05
8.85583E-06
5.76974E-06
3.73702E-06
2.40851E-06
1.5459E-06
9.8886E-07
6.30765E-07
4.01416E-07
2.54971E-07
1.61694E-07
1.02402E-07
6.47771E-08
4.09338E-08
2.58419E-08
1.62991E-08
1.02704E-08
6.46503E-09
4.065E-09

0.00106512
0.000681012
0.000434047
0.000275903
0.000174973
0.000110737
6.99501E-05
4.41044E-05
2.77564E-05
1.74332E-05
1.09254E-05
6.82969E-06
4.2569E-06
2.64413E-06
1.63564E-06
1.00686E-06
6.16225E-07
3.74593E-07
2.25919E-07
1.35027E-07
7.98851E-08
4.67336E-08
2.70095E-08
1.54112E-08
8.67821E-09
4.82263E-09
2.64564E-09
1.43365E-09
7.68062E-10
4.07236E-10
2.13939E-10
1.11488E-10
5.76974E-11
2.96842E-11
1.51966E-11
7.74785E-12
3.93672E-12
1.99466E-12
1.00831E-12
5.08734E-13
2.56267E-13
1.28917E-13
6.47771E-14
3.25148E-14
1.63052E-14
8.16889E-15
4.08873E-15
2.04442E-15
1.02108E-15

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

1.4041E-12
2.25504E-12
3.61025E-12
5.76443E-12
9.18274E-12
1.4598E-11
2.31626E-11
3.66844E-11
5.79912E-11
9.14909E-11
1.44024E-10
2.26152E-10
3.54073E-10
5.52437E-10
8.58394E-10
1.3273E-09
2.04051E-09
3.11573E-09
4.72012E-09
7.08631E-09
1.05309E-08
1.54749E-08
2.24655E-08
3.21986E-08
4.55439E-08
6.35746E-08
8.76055E-08
1.19246E-07
1.60471E-07
2.13721E-07
2.82026E-07
3.69172E-07
4.79906E-07
6.20192E-07
7.97531E-07
1.02137E-06
1.30357E-06
1.65908E-06
2.10666E-06
2.66987E-06
3.37826E-06
4.26884E-06
5.38792E-06
6.79331E-06
8.55707E-06
1.07687E-05
1.3539E-05
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2.13334E-05

4.0495E-06
5.166E-06
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1.0543E-05
1.3314E-05
1.678E-05
2.111E-05
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0.00012105
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6.54722E-09

2.5526E-09
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1.49988E-18

5.09311E-16
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7.51722E-29

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
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1.4248E-05
1.1351E-05
9.0377E-06

[H2Y2-]
2.1661E-08
3.4241E-08
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1.3464E-07
2.1202E-07
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[H3Y-]
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2.45E-05
3.0647E-05
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8.3176E-05

4log[HY3-]
[H4Y]
Suma de [C] log[Y ]
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-3.8126075
-3.8986331
-3.9872034
-4.0779051
-4.1703746
-4.2642986
-4.3594108
-4.4554888
-4.552348
-4.6498369
-4.7478318
-4.8462325
-4.944958
-5.0439429

-5.5530169
-5.6557639
-5.7593121
-5.8638282
-5.9695182
-6.0766322
-6.1854686
-6.2963765
-6.4097558
-6.5260533
-6.6457524
-6.7693566
-6.8973654
-7.0302435
-7.1683864
-7.3120865
-7.4615054
-7.6166576
-7.7774091
-7.9434908
-8.1145241
-8.290054
-8.469584
-8.6526075
-8.8386331
-9.0272034
-9.2179051
-9.4103746
-9.6042986
-9.7994108
-9.9954888
-10.192348
-10.389837
-10.587832
-10.786233
-10.984958
-11.183943

log[H3Y-]
log[H4Y]
-5.0043308 -3.0043308
-4.9054482 -3.0054482
-4.8068526 -3.0068526
-4.7086171 -3.0086171
-4.6108327 -3.0108327
-4.513613
-3.013613
-4.4170991 -3.0170991
-4.3214656 -3.0214656
-4.226928
-3.026928
-4.1337506 -3.0337506
-4.0422556 -3.0422556
-3.9528324 -3.0528324
-3.8659473 -3.0659473
-3.7821518 -3.0821518
-3.702088
-3.102088
-3.6264905 -3.1264905
-3.5561801 -3.1561801
-3.4920496 -3.1920496
-3.4350377 -3.2350377
-3.3860912 -3.2860912
-3.3461165 -3.3461165
-3.3159232 -3.4159232
-3.2961675 -3.4961675
-3.2873007 -3.5873007
-3.2895318 -3.6895318
-3.3028091 -3.8028091
-3.3268256 -3.9268256
-3.3610446 -4.0610446
-3.4047441 -4.2047441
-3.4570713 -4.3570713
-3.5171002 -4.5171002
-3.5838854 -4.6838854
-3.656507
-4.856507
-3.7341037 -5.0341037
-3.8158943 -5.2158943
-3.9011895 -5.4011895
-3.9893939 -5.5893939
-4.0800039 -5.7800039

-4.1726014
-4.2668452
-4.3624631
-4.4592434
-4.5570279
-4.6557064
-4.755212
-4.8555181
-4.9566376
-5.0586223
-5.1615645
-5.2655991
-5.3709068
-5.4777175
-5.5863135
-5.6970313
-5.8102607
-5.9264402
-6.0460471
-6.1695799
-6.297534
-6.430371
-6.5684841
-6.7121636
-6.8615699
-7.0167165
-7.1774688
-7.3435573
-7.5146037
-7.6901535
-7.8697109
-8.0527707
-8.2388435
-8.427474
-8.6182523
-8.8108189
-9.0048654
-9.2001322
-9.3964048
-9.5935091
-9.7913066
-9.9896898
-10.188579
-10.387918
-10.587675
-10.787837
-10.988412
-11.189429
-11.390939

-5.9726014
-6.1668452
-6.3624631
-6.5592434
-6.7570279
-6.9557064
-7.155212
-7.3555181
-7.5566376
-7.7586223
-7.9615645
-8.1655991
-8.3709068
-8.5777175
-8.7863135
-8.9970313
-9.2102607
-9.4264402
-9.6460471
-9.8695799
-10.097534
-10.330371
-10.568484
-10.812164
-11.06157
-11.316716
-11.577469
-11.843557
-12.114604
-12.390153
-12.669711
-12.952771
-13.238843
-13.527474
-13.818252
-14.110819
-14.404865
-14.700132
-14.996405
-15.293509
-15.591307
-15.88969
-16.188579
-16.487918
-16.787675
-17.087837
-17.388412
-17.689429
-17.990939

-11.593017
-11.795764
-11.999312
-12.203828
-12.409518
-12.616632
-12.825469
-13.036376
-13.249756
-13.466053
-13.685752
-13.909357
-14.137365
-14.370244
-14.608386
-14.852087
-15.101505
-15.356658
-15.617409
-15.883491
-16.154524
-16.430054
-16.709584
-16.992607
-17.278633
-17.567203
-17.857905
-18.150375
-18.444299
-18.739411
-19.035489
-19.332348
-19.629837
-19.927832
-20.226233
-20.524958
-20.823943

-18.293017
-18.595764
-18.899312
-19.203828
-19.509518
-19.816632
-20.125469
-20.436376
-20.749756
-21.066053
-21.385752
-21.709357
-22.037365
-22.370244
-22.708386
-23.052087
-23.401505
-23.756658
-24.117409
-24.483491
-24.854524
-25.230054
-25.609584
-25.992607
-26.378633
-26.767203
-27.157905
-27.550375
-27.944299
-28.339411
-28.735489
-29.132348
-29.529837
-29.927832
-30.326233
-30.724958
-31.123943

Diagrama logaritmico de concentraciones para las especies de Y4- en

funcin del pH

Log Ci

0
-1
-2
-3
-4
-5
-6
-7
-8
-9
-10
-11
-12
-13
-14
-15
-16
-17
-18
-19
-20

10

11

pH
12

log[Y4-]

log[HY3-]
log[H2Y2-]
log[H3Y-]
log[H4Y]

Variacin de la abundancia de especies para el sistema Y4- en funcin

del pH.
1
0.9
0.8
0.7
0.6
F

0.5

1
2

0.4

3
4

0.3
0.2
0.1
0

6
pH

10

11

12