Diagrama de abundancia logaritmica de la concentracin de especies

para el sistema Co3+ en funcin del pNH3

0

0
-2
-4
-6
-8
-10
-12
-14

Log Ci

-16
-18
-20
-22

log[Co3+]
log[Co(NH3)3+]
log[Co(NH3)23+]

-24
-26
-28

log[Co(NH3)33+]
log[Co(NH3)43+]

-30

log[Co(NH3)53+]

-32

log[Co(NH3)63+]

-34
-36
-38

pNH3
9

Diagrama de abundancia relativa de especies para el sistema Co3+ en

funcin del pNH3
1

0.9

0.8

0.7
0

0.6

1
2

0.5

3
4

0.4

5
6

0.3

0.2

0.1

0
0

pNH3

log
log
log
log
log
log

1=log kf1=pkc1
2
3
4
5
6

7.3
14
20.1
25.7
30.8
35.2

1
2
3
4
5
6

19952623.15
1E+14
1.25893E+20
5.01187E+25
6.30957E+30
1.58489E+35

0=1/Pb(L)
pL=-log L

[L] 10
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
1.1
1.2
1.3
1.4
1.5
1.6
1.7
1.8
1.9
2
2.1
2.2
2.3
2.4
2.5
2.6
2.7
2.8
2.9
3
3.1
3.2
3.3
3.4
3.5
3.6
3.7
3.8
3.9
4

-pL

1
0.79432823
0.63095734
0.50118723
0.39810717
0.31622777
0.25118864
0.19952623
0.15848932
0.12589254
0.1
0.07943282
0.06309573
0.05011872
0.03981072
0.03162278
0.02511886
0.01995262
0.01584893
0.01258925
0.01
0.00794328
0.00630957
0.00501187
0.00398107
0.00316228
0.00251189
0.00199526
0.00158489
0.00125893
0.001
0.00079433
0.00063096
0.00050119
0.00039811
0.00031623
0.00025119
0.00019953
0.00015849
0.00012589
0.0001

=1+1[L]+2[L] +3[L] 0
1.58496E+35
3.98127E+34
1.00006E+34
2.51209E+33
6.3102E+32
1.58509E+32
3.9817E+31
1.0002E+31
2.51252E+30
6.31157E+29
1.58552E+29
3.98307E+28
1.00063E+28
2.51388E+27
6.31588E+26
1.58689E+26
3.98738E+25
1.002E+25
2.5182E+24
6.32954E+23
1.59121E+23
4.00104E+22
1.00632E+22
2.53187E+21
6.3728E+20
1.6049E+20
4.04437E+19
1.02003E+19
2.5753E+18
6.51036E+17
1.64849E+17
4.1826E+16
1.06389E+16
2.71459E+15
6.9532E+14
1.78947E+14
4.63218E+13
1.20757E+13
3.17497E+12
8.43326E+11
2.26724E+11
2

pkc
pkc
pkc
pkc
pkc
pkc

1
2
3
4
5
6

1=1[L]/Pb(L)
1

6.30932E-36
2.51176E-35
9.99937E-35
3.98076E-34
1.58473E-33
6.30878E-33
2.51149E-32
9.99801E-32
3.98007E-31
1.58439E-30
6.30706E-30
2.51063E-29
9.99369E-29
3.97791E-28
1.58331E-27
6.30164E-27
2.50791E-26
9.98008E-26
3.97109E-25
1.57989E-24
6.28453E-24
2.49935E-23
9.93722E-23
3.94965E-22
1.56917E-21
6.23093E-21
2.47257E-20
9.80361E-20
3.88304E-19
1.53601E-18
6.06615E-18
2.39086E-17
9.39944E-17
3.6838E-16
1.43819E-15
5.58824E-15
2.15881E-14
8.28109E-14
3.14964E-13
1.18578E-12
4.41065E-12

1.25888E-28
3.98087E-28
1.25885E-27
3.98076E-27
1.2588E-26
3.98057E-26
1.25873E-25
3.98028E-25
1.25861E-24
3.97981E-24
1.25842E-23
3.97908E-23
1.25813E-22
3.97791E-22
1.25767E-21
3.97606E-21
1.25693E-20
3.97314E-20
1.25577E-19
3.96851E-19
1.25393E-18
3.9612E-18
1.25102E-17
3.94965E-17
1.24644E-16
3.93145E-16
1.23922E-15
3.90289E-15
1.22793E-14
3.85829E-14
1.21036E-13
3.78925E-13
1.18332E-12
3.6838E-12
1.14239E-11
3.52594E-11
1.08197E-10
3.29676E-10
9.96002E-10
2.97855E-09
8.80041E-09

7.3
14
20.1
25.7
30.8
35.2

[CTOTAL]
Graficar 's vs pL y log Ci vs pL

pL (desde 0 a 2 unidades ms del pkc1)

2=2[L]2/Pb(L)

3=3[L]3/Pb(L) 4=4[L]4/Pb(L) 5=5[L]5/Pb(L) 6=6[L]6/Pb(L)

3
4
5
6
7.94297E-16
3.16215E-10
3.98091E-05 0.999960191
1.58481E-15
5.01162E-10
5.01162E-05 0.999949883
3.16208E-15
7.94278E-10
6.30918E-05 0.999936907
6.30907E-15
1.25883E-09
7.94265E-05 0.999920572
1.2588E-14
1.99506E-09
9.999E-05 0.999900008
2.51157E-14
3.16188E-09 0.000125877
0.99987412
5.01108E-14
5.01108E-09 0.000158464 0.999841531
9.99801E-14
7.9417E-09 0.000199486 0.999800506
1.99476E-13
1.25861E-08 0.000251126 0.999748862
3.97981E-13
1.99463E-08 0.000316128 0.999683852
7.94012E-13
3.16102E-08 0.000397949
0.99960202
1.5841E-12
5.00936E-08 0.000500936 0.999499014
3.16028E-12
7.93827E-08 0.000630559 0.999369361
6.30456E-12
1.25793E-07 0.000793698 0.999206177
1.25767E-11
1.99327E-07 0.000999001
0.9990008
2.50873E-11
3.1583E-07 0.001257342 0.998742342
5.00394E-11
5.00394E-07 0.001582384 0.998417115
9.98008E-11
7.92746E-07 0.001991288
0.99800792
1.99026E-10
1.25577E-06
0.00250559 0.997493155
3.96851E-10
1.98897E-06 0.003152303 0.996845708
7.91176E-10
3.14973E-06 0.003965273 0.996031576
1.57698E-09
4.98685E-06 0.004986854 0.995008158
3.14243E-09
7.89342E-06 0.006269963 0.993722141
6.25977E-09
1.24899E-05 0.007880585 0.992106918
1.24644E-08
1.97547E-05 0.009900794 0.990079438
2.48058E-08
3.12286E-05 0.012432347
0.9875364
4.93344E-08
4.93344E-05 0.015600892 0.984349725
9.80361E-08
7.78729E-05 0.019560779
0.98036125
1.94613E-07 0.000122793 0.024500354 0.975376659
3.85829E-07 0.000193373 0.030647491 0.969158751
7.63683E-07 0.000304028 0.038274834 0.961420373
1.50853E-06 0.000477039 0.047703881
0.95181757
2.97236E-06 0.000746624 0.059306454 0.939943946
5.83842E-06 0.001164919 0.073501402 0.925327831
1.14239E-05
0.00181057 0.090743453
0.90743453
2.22472E-05 0.002800756 0.111500107 0.885676834
4.30739E-05 0.004307392 0.136211696 0.859437701
8.28109E-05 0.006577907 0.165229549 0.828109404
0.000157856 0.009960023 0.198728584 0.791152745
0.000297855 0.014928106 0.236594537
0.74817762
0.000555268 0.022105628 0.278293363 0.699041322

6.30932E-22
1.58481E-21
3.98082E-21
9.99921E-21
2.51164E-20
6.30878E-20
1.58464E-19
3.98028E-19
9.99749E-19
2.51109E-18
6.30706E-18
1.5841E-17
3.97856E-17
9.99206E-17
2.50938E-16
6.30164E-16
1.58238E-15
3.97314E-15
9.97493E-15
2.50396E-14
6.28453E-14
1.57698E-13
3.95608E-13
9.92107E-13
2.48697E-12
6.23093E-12
1.56009E-11
3.90289E-11
9.75377E-11
2.43442E-10
6.06615E-10
1.50853E-09
3.74198E-09
9.25328E-09
2.27937E-08
5.58824E-08
1.36212E-07
3.29676E-07
7.91153E-07
1.87934E-06
4.41065E-06

0.001 M

's=1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

[Co3+]
[Co(NH3)3+] [Co(NH3)23+] [Co(NH3)33+] [Co(NH3)43+]
6.30932E-39 1.2589E-31 6.3093E-25
7.943E-19 3.1622E-13
2.51176E-38 3.9809E-31 1.5848E-24 1.5848E-18 5.0116E-13
9.99937E-38 1.2588E-30 3.9808E-24 3.1621E-18 7.9428E-13
3.98076E-37 3.9808E-30 9.9992E-24 6.3091E-18 1.2588E-12
1.58473E-36 1.2588E-29 2.5116E-23 1.2588E-17 1.9951E-12
6.30878E-36 3.9806E-29 6.3088E-23 2.5116E-17 3.1619E-12
2.51149E-35 1.2587E-28 1.5846E-22 5.0111E-17 5.0111E-12
9.99801E-35 3.9803E-28 3.9803E-22
9.998E-17 7.9417E-12
3.98007E-34 1.2586E-27 9.9975E-22 1.9948E-16 1.2586E-11
1.58439E-33 3.9798E-27 2.5111E-21 3.9798E-16 1.9946E-11
6.30706E-33 1.2584E-26 6.3071E-21 7.9401E-16
3.161E-11
2.51063E-32 3.9791E-26 1.5841E-20 1.5841E-15 5.0094E-11
9.99369E-32 1.2581E-25 3.9786E-20 3.1603E-15 7.9383E-11
3.97791E-31 3.9779E-25 9.9921E-20 6.3046E-15 1.2579E-10
1.58331E-30 1.2577E-24 2.5094E-19 1.2577E-14 1.9933E-10
6.30164E-30 3.9761E-24 6.3016E-19 2.5087E-14 3.1583E-10
2.50791E-29 1.2569E-23 1.5824E-18 5.0039E-14 5.0039E-10
9.98008E-29 3.9731E-23 3.9731E-18 9.9801E-14 7.9275E-10
3.97109E-28 1.2558E-22 9.9749E-18 1.9903E-13 1.2558E-09
1.57989E-27 3.9685E-22
2.504E-17 3.9685E-13
1.989E-09
6.28453E-27 1.2539E-21 6.2845E-17 7.9118E-13 3.1497E-09
2.49935E-26 3.9612E-21
1.577E-16
1.577E-12 4.9869E-09
9.93722E-26
1.251E-20 3.9561E-16 3.1424E-12 7.8934E-09
3.94965E-25 3.9496E-20 9.9211E-16 6.2598E-12
1.249E-08
1.56917E-24 1.2464E-19
2.487E-15 1.2464E-11 1.9755E-08
6.23093E-24 3.9315E-19 6.2309E-15 2.4806E-11 3.1229E-08
2.47257E-23 1.2392E-18 1.5601E-14 4.9334E-11 4.9334E-08
9.80361E-23 3.9029E-18 3.9029E-14 9.8036E-11 7.7873E-08
3.88304E-22 1.2279E-17 9.7538E-14 1.9461E-10 1.2279E-07
1.53601E-21 3.8583E-17 2.4344E-13 3.8583E-10 1.9337E-07
6.06615E-21 1.2104E-16 6.0662E-13 7.6368E-10 3.0403E-07
2.39086E-20 3.7893E-16 1.5085E-12 1.5085E-09 4.7704E-07
9.39944E-20 1.1833E-15
3.742E-12 2.9724E-09 7.4662E-07
3.6838E-19 3.6838E-15 9.2533E-12 5.8384E-09 1.1649E-06
1.43819E-18 1.1424E-14 2.2794E-11 1.1424E-08 1.8106E-06
5.58824E-18 3.5259E-14 5.5882E-11 2.2247E-08 2.8008E-06
2.15881E-17
1.082E-13 1.3621E-10 4.3074E-08 4.3074E-06
8.28109E-17 3.2968E-13 3.2968E-10 8.2811E-08 6.5779E-06
3.14964E-16
9.96E-13 7.9115E-10 1.5786E-07
9.96E-06
1.18578E-15 2.9785E-12 1.8793E-09 2.9785E-07 1.4928E-05
4.41065E-15 8.8004E-12 4.4107E-09 5.5527E-07 2.2106E-05

[Co(NH3)53+]
3.9809E-08
5.0116E-08
6.3092E-08
7.9427E-08
9.999E-08
1.2588E-07
1.5846E-07
1.9949E-07
2.5113E-07
3.1613E-07
3.9795E-07
5.0094E-07
6.3056E-07
7.937E-07
9.99E-07
1.2573E-06
1.5824E-06
1.9913E-06
2.5056E-06
3.1523E-06
3.9653E-06
4.9869E-06
6.27E-06
7.8806E-06
9.9008E-06
1.2432E-05
1.5601E-05
1.9561E-05
2.45E-05
3.0647E-05
3.8275E-05
4.7704E-05
5.9306E-05
7.3501E-05
9.0743E-05
0.0001115
0.00013621
0.00016523
0.00019873
0.00023659
0.00027829

3+
[Co(NH3)63+] Suma de [C] log[Co ]
log[Co(NH3)3+] log[Co(NH3)23+] log[Co(NH3)33+]
0.00099996
0.001 -38.20001729 -30.90001729 -24.20001729 -18.10001729
0.00099995
0.001 -37.60002177 -30.40002177 -23.80002177 -17.80002177
0.00099994
0.001
-37.0000274
-29.9000274
-23.4000274
-17.5000274
0.00099992
0.001
-36.4000345
-29.4000345
-23.0000345
-17.2000345
0.0009999
0.001 -35.80004343 -28.90004343 -22.60004343 -16.90004343
0.00099987
0.001 -35.20005467 -28.40005467 -22.20005467 -16.60005467
0.00099984
0.001 -34.60006883 -27.90006883 -21.80006883 -16.30006883
0.0009998
0.001 -34.00008665 -27.40008665 -21.40008665 -16.00008665
0.00099975
0.001 -33.40010908 -26.90010908 -21.00010908 -15.70010908
0.00099968
0.001 -32.80013732 -26.40013732 -20.60013732 -15.40013732
0.0009996
0.001 -32.20017288 -25.90017288 -20.20017288 -15.10017288
0.0009995
0.001 -31.60021763 -25.40021763 -19.80021763 -14.80021763
0.00099937
0.001 -31.00027397 -24.90027397 -19.40027397 -14.50027397
0.00099921
0.001 -30.40034489 -24.40034489 -19.00034489 -14.20034489
0.000999
0.001 -29.80043416 -23.90043416 -18.60043416 -13.90043416
0.00099874
0.001 -29.20054654 -23.40054654 -18.20054654 -13.60054654
0.00099842
0.001 -28.60068798 -22.90068798 -17.80068798 -13.30068798
0.00099801
0.001 -28.00086601 -22.40086601 -17.40086601 -13.00086601
0.00099749
0.001 -27.40109008 -21.90109008 -17.00109008 -12.70109008
0.00099685
0.001 -26.80137206 -21.40137206 -16.60137206 -12.40137206
0.00099603
0.001 -26.20172689 -20.90172689 -16.20172689 -12.10172689
0.00099501
0.001 -25.60217336 -20.40217336 -15.80217336 -11.80217336
0.00099372
0.001 -25.00273503 -19.90273503 -15.40273503 -11.50273503
0.00099211
0.001 -24.40344152 -19.40344152 -15.00344152 -11.20344152
0.00099008
0.001 -23.80432996 -18.90432996 -14.60432996 -10.90432996
0.00098754
0.001 -23.20544689 -18.40544689 -14.20544689 -10.60544689
0.00098435
0.001 -22.60685058 -17.90685058 -13.80685058 -10.30685058
0.00098036
0.001 -22.00861386 -17.40861386 -13.40861386 -10.00861386
0.00097538
0.001 -21.41082764 -16.91082764 -13.01082764 -9.710827642
0.00096916
0.001 -20.81360508 -16.41360508 -12.61360508 -9.413605079
0.00096142
0.001 -20.21708668 -15.91708668 -12.21708668 -9.117086679
0.00095182
0.001 -19.62144628 -15.42144628 -11.82144628 -8.821446283
0.00093994
0.001 -19.02689804 -14.92689804 -11.42689804 -8.526898045
0.00092533
0.001 -18.43370438 -14.43370438 -11.03370438 -8.233704375
0.00090743
0.001
-17.8421847
-13.9421847
-10.6421847 -7.942184699
0.00088568
0.001 -17.25272471 -13.45272471 -10.25272471 -7.652724715
0.00085944
0.001
-16.6657856
-12.9657856 -9.865785599 -7.365785599
0.00082811
0.001 -16.08191228 -12.48191228 -9.481912284 -7.081912284
0.00079115
0.001 -15.50173966 -12.00173966 -9.101739661 -6.801739661
0.00074818
0.001 -14.92599529 -11.52599529 -8.725995287 -6.525995287
0.00069904
0.001 -14.35549715 -11.05549715 -8.355497151 -6.255497151

log[Co(NH3)43+] log[Co(NH3)53+] log[Co(NH3)63+]

-12.50001729 -7.400017289 -3.000017289
-12.30002177 -7.300021766 -3.000021766
-12.1000274 -7.200027402 -3.000027402
-11.9000345 -7.100034496 -3.000034496
-11.70004343 -7.000043428 -3.000043428
-11.50005467 -6.900054672 -3.000054672
-11.30006883 -6.800068828 -3.000068828
-11.10008665 -6.700086648 -3.000086648
-10.90010908 -6.600109082 -3.000109082
-10.70013732 -6.500137323 -3.000137323
-10.50017288 -6.400172875 -3.000172875
-10.30021763
-6.30021763
-3.00021763
-10.10027397 -6.200273969 -3.000273969
-9.90034489
-6.10034489
-3.00034489
-9.700434164 -6.000434164 -3.000434164
-9.500546538 -5.900546538 -3.000546538
-9.300687983 -5.800687983 -3.000687983
-9.100866012 -5.700866012 -3.000866012
-8.901090076 -5.601090076 -3.001090076
-8.701372057 -5.501372057 -3.001372057
-8.501726893 -5.401726893 -3.001726893
-8.302173359 -5.302173359 -3.002173359
-8.102735034 -5.202735034 -3.002735034
-7.903441522 -5.103441522 -3.003441522
-7.704329959 -5.004329959 -3.004329959
-7.505446888 -4.905446888 -3.005446888
-7.306850576 -4.806850576 -3.006850576
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