CAPITULO 7 (IMPARES)

ALUMNO: Leonardo Len Yanez

THE PROPERTIES OF PETROLEUM FLUIDS
McCAIN
7-1)

M STO=118.35

RSP = 98835

lb
lb mol

STO =47.24 lb/ ft 3

scf
1 lbmol
1 bbl
1 ft 3 STO

STB 380.7 scf 5.615 ft 3 47.24 lb STO

118.35 lbSTO
1 lbmol STO

= 115.83

lb mol SP gas
lb mol STO

RST = 408

0.478

1 lb mol S
118.35 lbSTO

scf ST gas 1 lb mol

1 bbl
1 ft 3 STO

STB
380.7 scf 5.615 ft 3 47.24 lb STO

lb mol ST gas
lbmol STO

115.83

Y SP

0.478

Y ST

X ST

115.83

Y SP +0.478

Y ST +
C1
C2
C3
i-C4
n-C4
i-C5
i-C5
C6
C7+

7-3)

102.092
8.44559
3.44015
0.6254
0.52123
0.2664
0.1969
0.18532
0.0463

0.2292
0.0845
0.0838
0.0234
0.014
0.00109
0.01061
0.00908
0.000956

0.0026
0.0054
0.0194
0.0148
0.0193
0.0312
0.0293
0.0902
0.7878

102.323
8.53549
3.54335
0.6636
0.5545
0.29869
0.23681
0.2846
0.83505
117.275

Y res

X ST
0.8725
0.07278
0.03021
0.00565
0.00412
0.00254
0.002019
0.002426
0.00712
1

945

scf
STB

STB
scf
=898.28
1.052 SP bbl
SP bbl

Ma = (16 0.0307 )+ (30 0.0191 )+ (44 0.0423 )+ (58 0.0147 )+ (58

0.0537 )+ (72 0.0310 )+ (72 0.0373 )+ (86 0.0622 )+ (202 0.7090 ) =

160.37

lb
lb mol

STO =49.8 lb/ft

P=115 psiaT =100 F

scfSP gas bbl mol 1 bblmol

ft 3 SP liq

lbmol
380.7 scf 5.615 ft 3 49.8 lb SP liq

RSP = 898.28

160.37 lb
lbmol

lb mol SP gas
lb mol SP liq
1.35
C1
C2
C3
i-C4
n-C4
i-C5
i-C5
C6
C7+

0=

1.0574
0.1302
0.0895
0.0132
0.0364
0.0085
0.0086
0.0049
0.00094

Xj

1.35

0.0307
0.0191
0.0423
0.0147
0.0537
0.0310
0.0373
0.0622
0.7090

Yj + Xj
1.0881
0.1493
0.1318
0.0279
0.0901
0.0395
0.0459
0.0671
0.7099
2.3496

Zj
0.4631
0.0635
0.0560
0.0118
0.0383
0.0168
0.0195
0.0285
0.3021
1

0 49.8
141.5
=
=0.798 API=
131.5
w 62.4
0

w =62.4 lb/ft

7-5)

Yj

API =

45.8

Gas Retrogado

= 1.35

M O=

5945
5945
lb
=
=128.13
API 8.8 55.28.8
lb mol

g=

R SP 1 g SP1 + R SP 2 g SP 2+ R ST g ST 4187 ( 0.666 ) +334 ( 0.946 ) +88 ( 1.546 )

=
=0.703
RSP 1 + RSP 2 + R ST
4609

0=

141.5
=0.757
API + 131.5

gR =

R g+ 460 0 0
4609 ( 0.703 ) + 4600 ( 0.757 )
=
=1.245
R+133300 0 / M O 4609+133300 ( 0.757/128.13 )

7-7)

M O=

5945
5945
lb
=
=106.35
API =64.7 R=171008
API 8.8 64.78.8
lb mol

g=

R SP g SP + RST g ST 170516 ( 0.646 )+ 492 ( 1.184 )

=
=0.647
R SP + RST
170516+ 492

0=

141.5
141.5
=
=0.721
API + 131.5 64.7+ 131.5

gR =

R g+ 460 0 0
171008 ( 0.647 )+ 4600 ( 0.721 )
=
=0.662
R+133300 0 / M O 171008+133300 ( 0.721/106.35 )

7-9)
TWO STAGE

g=

R SP g SP 99835(0.644)
=
=0.664 API=55.4 ( ST ) ; P=580 psia ; T =90 ; SG=0.644
RSP
99835

 0=

141.5
141.5
scf
=
=0.75 VEQ=1150
Fig . 74
API + 131.5 55.4 +131.5
STB

gR =

R SP1 g SP1 + 4600 0 + AGP

scf
= AGP=520
Fig .75
R SP 1+ VEQ
STB
99835 ( 0.644 ) +4600 ( 0.75 ) +520
=0.676= gR
99835+1150

7-11)
THREE STAGES

g=

R SP g SP 4187(0.666)
scf
=
=0.666 VEQ=1200
Fig . 72
RSP
4187
STB

0=

141.5
141.5
scf
=
=0.758 AGP=455
Fig .73
API + 131.5 55.2+131.5
STB

gR =

R SP1 g SP1 + 4600 0 + AGP 4187 ( 0.666 )+ 4600 ( 0.758 ) + 455

=
=1.25
R SP 1+ VEQ
4187+ 1200

7-13)

Yj

C1
C2
C3
i-C4
n-C4
i-C5
i-C5
C6
C7+

0.8814
0.0730
0.0297
0.0054
0.0045
0.0023
0.0017
0.0016
0.0004

T cj (

Y j T cj (

R )

R )

342.91
549.50
665.64
734.04
765.20
828.68
845.38
913.18
1110

302.24
40.11
19.769
3.9638
3.443
1.9059
1.437
1.461
0.444
347.77= Tpc

Pcj (psia)

666.4
706.5
616.0
527.0
550.6
490.4
488.6
436.9
385

Y j Pcj (psia)

587.36
51.57
18.295
2.845
2.4777
1.1279
0.8306
0.699
0.154
665.36= Ppc

Condiciones del reservorio: P = 6500 psia y T = 225 = 685 R

T pr =

T
685
P
6500
=
=1.82 P pr=
=
=9.77
T pc 374.77
P pc 665.36

Segn figura 3-7

V M =

z=1.12

zRT 1.12(10.73)(0.85)
ft 3
=
=1.266
P
6500
lb mol

M STO=118.35

M ST liq=

lb
lb mol

STO =47.24 lb/ ft 3

M STO 118.35
ft 3 STO
=
=2.50
STO
47.29
lb mol STO
V
3

STO lbmol gas res ==

B wg =

2.50
ft STO
=0.021
117.275
lb mol res gas
V

1.266
bbl res gas
=60.28
0.021
STB

7-15)
T = 105 =565 R P=650 psia

gR=
1.25 Segn la fig 3-11

T pr =

T pc =490 R P pc =588 psia

T
565
P 650
=
=1.15 P pr=
=
=1.11
T pc 490
P pc 588

Segn la figura 3-7) z = 0.71

B wg = 0.00502Z ( RSP 1 +VEQ ) T /P

0.00502(0.71)( 4187+1200)565
bbl res gas
=16.7
=
650
STB

B wg

7-17)
A partir del ejercicio 7-12)

g=

R SP g SP
scf
=0.676 VEQ=1250
RSP
STB

0=

141.5
scf
=0.759 AGP=480
API + 131.5
STB

gR =

THREE STAGES:

RSP 1=8885

R SP1 g SP1 + 4600 0 + AGP 8885 ( 0.676 ) + 4600 ( 0.759 )+ 480

=
=0.98
R SP 1+ VEQ
8885+1250

gR =0.98 fig311 T pc=442 R P pc =625 psia

Por lo tanto:

scf
STB

T pr =

T 535
P 625
=
=1.21 P pr =
=
=1
T pc 442
P pc 625

Z = 1.67 segn fig. 3-7)

B wg = 0.00502Z ( RSP 1 +VEQ ) T /P

0.00502 ( 1.67 ) ( 8885+1250 ) 535

res bbl gas
=72.7
625
STB

7-19)

B wg = 1000000

R SP 1=? ( Ej 712)

B wg = 0.00502Z ( RSP 1 +VEQ ) T /P

1000000 =

R SP 1=

0.00502( 1.67)( R SP 1+ 1250) 535

625

1000000(625)
scf
1250=139348452.9
0.00502(1.67)( 535)
STB

7-23)

C1
C2
C3
i-C4
n-C4
i-C5
i-C5
C6
C7+

Yj

Lcj

0.8814
0.0730
0.0297
0.0054
0.0045
0.0023
0.0017
0.0016
0.0004

1010.0
1769.6
2516.1
3251.9
3262.3
4000.9
4008.9
4755.9
5502.5

Y j Lcj

Zj

Y j 1Zj

890.2
129.18
74.72
17.56
14.68
9.20
6.815
7.609
2.201
1152.165

0.9980
0.9919
0.9825
0.9711
0.9667
0.9480
0.9420
0.9100
0.8520

0.0394
0.00657
0.003928
0.000918
0.000149
0.000524
0.000409
0.00048
0.000153
0.05253

BTU / scf

Lc ideal
Z

Z = 1-

( Y j 1Zj ) Lc=

Z = 1-

( 0.05253 )2=0.9972 Lc =

1152.165 BTU / scf

0.9972
Lc =1155.4

BTU
scf