>> T=372;R=0.082 ;P=0.

99;%presion
>> Tc=647.30

Tc =

647.3000
qq
>> Pc=220.5

Pc =

220.5000

>> w=0.34

w=

0.3400

>> k=0.37464+1.54226*w-0.26992*w^2

k=

0.8678

>> alfa=(1+k*(1-(T/Tc)^0.5))^0.5

alfa =

1.1000

>> a=0.45724*alfa*(R*Tc)^2/Pc

a=

6.4262

>> b=0.07780*R*Tc/Pc

b=

0.0187

>> A=a*P/(R*T)^2

A=

0.0068

>> B=b*P/(R*T)

B=

6.0781e-04

>> raices=roots([1,-(1-B),(A-3*B^2-2*B),-(A*B-B^2-B^3)]);

z=max(raices)

z=

0.9937

>> v=R*T*z/P

v=

30.6192

>> % datos de gases ideales

>> T=372;R=0.082 ;P=0.99;%presion
>> V=(R*T)/P % ecuacion de los gases ideales

V=

30.8121

>> %Ecuacion. S.Redlich

T=372;R=0.082 ;P=0.99;%presion
Tc=647.30;Pc=220.5;w=0.34;
k=0.48508+1.55*w-0.15613*w^2

k=

0.9940
>> alfa=(1+k*(1-((T/Tc)^0.5))^2)

alfa =

1.0582

>> a=0.42748*((R^2)*(Tc)^2.5)/Pc

a=

138.9629

>> b=0.08664*(R*Tc)/Pc

b=

0.0209

>> A=a*alfa*P/(R*T)^2

A=

0.1565

>> B=b*P/(R*T)

B=

6.7687e-04

>> raices=roots([1,-1,(A-B-B^2),-(A*b)]);
>> z=max(raices);
>> v=R*T*z/P

v=

25.0635

https://es.wikipedia.org/wiki/Ecuaci%C3%B3n_de_tercer_grado
http://www.modeladoeningenieria.edu.ar/mei/repositorio/catedras/fundamentos
/MaterialApoyo/Apunte_IntroProg_Matlab.pdf
http://www.mat.ucm.es/~jarrieta/asignaturas/calculocomputacional/apendicePr
actiac5.pdf
http://www.vaxasoftware.com/doc_edu/qui/vanderwaals_esp.pdf
https://books.google.com.pe/books?
id=K1M4iJHKS1UC&pg=PA75&lpg=PA75&dq=ecuaciones+de+gases+ideales+
y+reales+en+matlab&source=bl&ots=lFJ-eG2HqO&sig=dqIqSmbz0F773pjCxd2TW6hIhQ&hl=es419&sa=X&ved=0CCwQ6AEwA2oVChMIopOrj6XZyAIVhhYCh0kGwn1#v=onepage&q=ecuaciones%20de%20gases%20ideales%20y
%20reales%20en%20matlab&f=false
http://www.academia.edu/6228571/II.-GASES_REALES

http://www.modeladoeningenieria.edu.ar/mei/repositorio/catedras/msa/apuntes
/Ejemplos_MATLAB_Ecuaciones_No_Lineales_en_IQ_MSA.pdf
http://www.mathworks.com/help/matlab/ref/roots.html?s_tid=srchtitle

close all
clear all
%Ecuacion de Van der wall
T=372;
R=0.082;
P=(0.5:0.01:2);
Tc=647.30;
Pc=220.5;
w=0.34;
k=0.37464+1.54226*w-0.26992*w^2;
alfa=(1+k*(1-(T/Tc)^0.5))^0.5;
a=0.45724*alfa*(R*Tc)^2/Pc;
b=0.07780*R*Tc/Pc;
A=a*P/(R*T)^2;
B=b*P/(R*T);
raices=roots([1,-1*(1-B),(A-3*B.^2-2*B),-(A.*B-B.^2-B.^3)]);
z = max(raices);
v=R*T*z./P;
plot(P,v)
title('P-V')
xlabel('PRESION')
ylabel('VOLUMEN')