Parte1.

Reaccin de combustin del acido benzoico.

C 6 H 5COOH ( s )+

15
O 2( g) 7 CO 2( g)+3 H 2 O(l)
2

H= U + nRT
n=nproductosnreactivos=7

15
=0.5 mol
2

H=77127 0 cal/mol T =298.15 K R=1.987

cal
molK

mol
molK
1.987 cal/ ( 298.15 K )=770973.788 cal/mol

77127 0 cal/(0.5 mol )

Uac . benzoico=

770973.788 cal/mol

( 1122molg )=6319.46 cal/ g

Qganado=Qcedido
Qk+QH 20=( Qcombustion+Qalambre+ QHNO 3 )
K (Tf Ti )+ MH 20 CespH 20 ( Tf Ti )=Mac . benzo UCo mbMalambre Ualambr e

K=

Mac. benzo UCombMalambre UalambreMH 2OCespH 20(Tf Ti)

( Tf Ti )

Datos:

Masa acido benzoico=0.133 g

U alambre= 1400cal/g

Masa alambre =(Mi-Mf)=(0.0193-0.0134)=0.0059g

Masa H20= 2000g Ti= 24.87 Tf= 27.67 U acido benzoico=

-0.771cal/g

( 0.133 g ) 6319.46
K=

cal
cal
cal
( 0.0059 g ) 1400
(2000 g ) 1
(27.6724.87)
g
g
g
(27.6724.87)

K=2324.55 cal /

Parte2. Panditas
Q=MC T + K T
Q=M pandita Upandita + M alambre U alambre

Masa pandita= 1.0044g

M alambre= (Mi-Mf)= (1.0044g-0.0179g)=0.9865g

1bolsita de 55g = 175 cal

Ti= 27.43

Tf=28.8