Caudal total

Qportador
mcatalizador
t reaccion
gasto total
Agua/Ac. Acetico
Etanol
pureza
densidad (20C)
PM
moles
peso

%peso etanol
%mol etanol
%vol etanol
PM medio
Densidad media
GHSV
GHSV
GHSV etanol
WHSV
WHSV alim
WHSV etanol
Lquido
Etanol
Total

0.075 ml/min
60 ml/min
0.1 g
300 min
22.5 ml
3.7 molar
50.7 ml
98 %
0.789 g/ml
46.07 g/mol
0.85 mol
40 g

41.36
21.28
47.69

Gas

62.30 mL/min alimento

Densidad catal

agua
pureza
densidad (20C)
PM
moles
peso

0.3 g/ml

55.6 ml
100 %
0.998204 g/ml
18.02 g/mol
3.15 mol
56.7168 g

0.0439816175

23.98 g/mol
0.8900 g/ml
22014 h-1
73381 mL g-1 h-1
7953 mL g-1 h-1
85.1 h-1
40.1 h-1
16.6 h-1

21.46 mLetanol g-1 h-1

45.00 mL g-1 h-1

Perry
1 g/ml

T (C)=
Tiempo

Tiempo (s)

15min

1h

2h

3h

4h

5h

Tiempo
15 min
1h
2h
3h
4h
5h

H2
43071
49357
48775
54283
54535
38701

Tiempo
15 min
1h
2h
3h
4h
5h

Nombre
CPN-R1-15min
CPN-R1-1h
CPN-R1-2h
CPN-R1-3h
CPN-R1-4h
CPN-R1-5h

Tiempo
15 min
1h
2h
3h
4h
5h

Etanol

Catal. Inicial
Lana cuarzo

220102
1326016
2553764
13757962
11354514

CATALIZADOR
0.3000 g
0.2500 g

Catalizador
CAUDALES DE GASES
Caudal (ml/min)
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

CH4
24523
4037
35564
51926
46515
10005

CO2
930543
782877
776312
884590
916132
612021

N2
7180075
5410931
5385873
4572869
4391994
6068956

CAUDALES DE LIQUIDOS
Vaco
Lleno
Condensados
6.7250
7.3020
0.577
6.7360
7.7090
0.973
6.3060
7.4900
1.184
6.8930
8.1140
1.221
6.7320
8.0570
1.325
6.3090
7.4770
1.168
CROMATOGRAMA DE LIQUIDOS
Acetaldehdo
Acetona
Metanol

112549
1249742
2976574
1836182

125287
338933
759614

(Reloj del ordenador)

0,075 ml/min; 0,3g catal

Posterior
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

CO
41105
79874
28196
22864
9306
3981

#DIV/0!

#DIV/0!

#DIV/0!

#DIV/0!

#DIV/0!

#DIV/0!

CROMATOGRAMA DE GASES DE REACCIN

C2H2
C2H4
C2H6

g/min
0.03847
0.01986
0.02114
0.02035
0.02208
0.01947

Tiempo
0:15
1:04
2:00
3:00
4:00
5:00

Butanodiol

Total
0
345389
1777498
4563120
16734536
13190696

174768128
198979136
172175104
174846000
170696384

g muestra
0.3077
0.3094
0.3018
0.3052
0.3011

H2O
5129372
5187740
4243544
4104800
4152480
3942433

g butanodiol
0.0526
0.0599
0.0531
0.056
0.0532

Metanol

Acetaldehdo
270768
68351
121619
134977
155561
140512

Etanol

Acetona

TOTAL
13619457
11583167
10639883
9826309
9726523
10816609

REACTIVOS
PM agua

18.02

H2O/etanol

3.7

PM etanol

46.07

exp (g/ml)

0.89

wt%etanol

40.87

QN2 (ml/min)

60

Qreact (ml/min)

0.075

Ftotal (mol/min)

0.0027830571

GHSV (h-1)

22014

Fetanol (mol/min)

0.0005921398

WHSV (h )

16.5638162487 ref. etanol

FH2O (mol/min)

0.0021909173

GASES
Tiempo (min)

Qprod (ml/min)
15
1
2
3
4
5

PORCENTAJES

#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!

15
1
2
3
4
5

W/F (gh/mol)

H2
CH4
CO2
1.4328900E-006 2.3720116325E-008
1.7822499E-006 3.9191276849E-009
1.7484033E-006 3.4331742409E-008
0.000002081
0.00000005
2.0968609E-006 4.4815228241E-008
1.2110647E-006 9.7025502057E-009

H2
CH4
19.2989943536
23.29
26.22
29.96
29.84
21.25
H2

PORCENTAJES
BASE SECA

CONDENSADOS
MASA CONDENSADO

0 ref. etanol

-1

15
1
2
3
4
5

CO2
0.319476299
0.05
0.51
0.72
0.64
0.17

CH4

Tiempo
15
1
2
3
4
5

SELECTIVIDADES

Tiempo

CO

Acetaldehdo

Etanol
#DIV/0!
0.022
0.134
0.271
1.498
1.219
0.629

Acetaldehdo

15
1
2
3
4

CO
0
0.00
0.00
0.00
0.00
0.00

1.03
2.64
0.53
0.34
0.11
0.07

Acetona

#DIV/0!
3.83222524828752E-008
2.18674279455854E-005
0.0002480607
0.0006134678
0.000368279

C2H6

H2O

0
0
0
0
0
0

C2H4
0
0.00
0.00
0.00
0.00
0.00

C2H4
0
0
0
0
0
0

0
0
0
0
0
0

C2H6
0
0.00
0.00
0.00
0.00
0.00

C2H6
0
0
0
0
0
0

Metanol

5.201183208E-006
5.26036836E-006
0.000004303
4.1622672E-006
4.21061472E-006
3.997627062E-006

H2O
0
0.00
0.00
0.00
0.00
0.00

0
0
0
0
0
0

Acetaldehdo
Etanol
1.5154527E-007
3.8322252E-008
6.8156522E-008
7.5633736E-008
8.7152355E-008
7.8731475E-008

0
0
0
0
0
0

0
0.00
0.00
0.00
0.00
0.00

Acetaldehdo
Etanol
2.0410996693
0.50
1.02
1.09
1.24
1.38

0
0.00
0.00
0.00
0.00
0.00

Metanol
70.0525553438
68.74
64.53
59.93
59.91
70.15

Total porcentaje
0
0
0
0
0
0

100
100
100
100
100
100

Metanol
#DIV/0!
#DIV/0!
0 2.6112550787865E-005
0 7.0656629244536E-005
0
0.0001622321
0
0
0
0

Acetona

#DIV/0!
0.000
0.0070676884
0.082
0.201
0.122
0.083

C2H4

C2H2
0.2882623959
0.81
0.18
0.13
0.04
0.02

C2H2

28.67
21.48
21.85
20.94
21.44
24.70

Etanol
15
#DIV/0!
1 6.8734924777E-005
2
0.0004141885
3
0.0008172123
4
0.0045721071
5
0.0036718575

15
1
2
3
4
5

CONVERSION

N2

1.14
0.17
1.49
1.85
1.64
0.60

Tiempo
PORCENTAJES

CO
C2H2
0 2.1402581612175E-008
0
0.000000062
0 1.2276283846512E-008
0 9.149314211072E-009
0 2.890301609052E-009
0 1.096377221127E-009

7.9996119383
6.61
7.53
8.16
8.33
7.03
CO2

69.16
75.71
76.12
76.88
76.81
74.63

Tiempo (min)

N2
5.9394617483914E-007
5.0573437455001E-007
5.01759711009776E-007
5.66739273791775E-007
5.85437758585596E-007
4.00825957842958E-007

Metanol
#DIV/0!
0.008
0.022836661
0.054
0.000
0.000

#DIV/0!
0.000
0.000
0.000
0.000
0.000
0.000

%Etanol
#DIV/0!
0.02
0.13
0.27
1.50
1.22

Caudal Condensados (g/min)

0.0385
0.0199
0.0211
0.0204
0.0221
0.0195

Etanol salida (mol/min)

#DIV/0!
9.63E-08
6.14E-07
1.20E-06
7.18E-06
5.15E-06

Conversin (%mol)
#DIV/0!
100.0
99.9
99.8
98.8
99.1

H2

CH4

CO2

N2

CO

C2H4

C2H6

Acetaldehdo

Acetona

Metanol

Acetona

Total moles
0 7.4247E-006
0 7.6526E-006
0 6.6679E-006
0 6.9448E-006
0 7.0278E-006
0 5.6990E-006

Acetona
0
0.00
0.00
0.00
0.00
0.00

Total porcentaje
100
100
100
100
100
100

tiempo (min)
15
60
120
180
240
300

Caudal alimentacion (g/min) Caudal agua en exceso (g/min)

0.0668
0.0074
0.0668
0.0074
0.0668
0.0074
0.0668
0.0074
0.0668
0.0074
0.0668
0.0074

SELECTIVIDAD CON EXCESO

tiempo (min)
S liquidos
15
60
120
180
240
300
SELECTIVIDAD SIN EXCESO
tiempo (min)

(%ww)
S coque
57.63%
29.75%
31.67%
30.49%
33.08%
29.16%
(%ww)
S coque

S liquidos

15
60
120
180
240
300

52.34%
20.98%
23.15%
21.81%
24.73%
20.32%

PORCENTAJES BASE SECA

15
1
2
3
4
5

0.00%
0.00%
0.00%
0.00%
0.00%
0.00%

(%vol)
CH4

H2

tiempo (min)

0.00%
0.00%
0.00%
0.00%
0.00%
0.00%

69.2
75.7
76.1
76.9
76.8
74.6
76.0

1.1
0.2
1.5
1.8
1.6
0.6
1.1

Caudal condensados (g/min) Caudal coque (g/min) Caudal gases (g/min)

0.0385
0.0000
0.0283
0.0199
0.0000
0.0469
0.0211
0.0000
0.0456
0.0204
0.0000
0.0464
0.0221
0.0000
0.0447
0.0195
0.0000
0.0473

S gases
42.37%
70.25%
68.33%
69.51%
66.92%
70.84%
69.17%
S gases
47.66%
79.02%
76.85%
78.19%
75.27%
79.68%

CO2

C2H2

CO
28.7
21.5
21.8
20.9
21.4
24.7
22.1

1.0
2.6
0.5
0.3
0.1
0.1
0.7

C2H4
0
0
0
0
0
0

C2H6
0
0
0.0
0
0
0

0
0
0
0
0
0

Total porcentaje
100
100
100
100
100
100