ANLISIS DE RESIDUOS ORGNICOS EN MATERIALES DE

CONSTRUCCIN.
- OBJETIVO
- INTRODUCCIN
- EXPERIMENTAL. Reactivos e instrumentacin
- METODOLOGA
- RESULTADOS
MUESTRA B-05MC

tR

m/z

1128
4

175.0, 205.1,
220.1

1192
0

125.0, 157.0,
189.0

1243
1
1324
0
1688
5
1696
3

162.9,
198.0
103.9,
177.0
143.1,
270.2
147.1,
277.1

5
8
9

182.9,
149.0,
227.2,
219.1,

compuesto
identificado
methyl 4,4,7-trimethyl4,7-dihydroindan-6carboxylate
trimethyl
2methoxypropane-1,2,3tricarboxylate
1-ethyl-4,5,8trimethylnaphthalene
1,2-benzenedicarboxylic
acid, diethyl ester
hexadecanoic acid,
methyl ester
methyl-3-(3,5-ditertbutyl4-hydroxyphenyl)
propionate

nombre comn
ac carboxlico?

Qual
%
78

ac carboxlico?

83

naftalina ?

78

dietil fthalato

94

ac palmtico
C16:0
ac 3-(3,5-di-tertbutil-4 hidroxifenil)propionico

94
95

10 1700
3

187.1, 291.2,
306.2

13 1882
5
18 2123
7
25 2225
8
26 2265
1

143.0,
298.2
133.1,
559.1
149.0,
206.8
207.0,

255.2,
207.0,
167.0,
280.8

endo-3,4isopropylidenedioxy-exo2-phenylthio-6oxabicyclooctan-7-one
heptadecanoic acid,
16methyl-, methyl ester
1,1,1,3,5,7,7,7octamethyltetrasiloxane
bis(2-ethylhexyl)
phthalate
n,n'-disalicylidene-1,2diaminopropane

83

ac 16-metil,
heptadecanoico
silicona?

76

dioctyl fthalato

72

78

83

MUESTRA B-08MC

tR

1152
8
1192
0

3
4

m/z

1128 175.0, 205.1,

4
220.1
132.9, 163.0,
207.0
125.0, 157.0,
189.0

1243 162.9, 182.9,

1
198.0

compuesto
identificado
methyl 4,4,7-trimethyl4,7dihydroindan-6carboxylate
methyl phthalate

nombre
comn
ac
carboxlico?

Qual
%
78

trimethyl 2methoxypropane-1,2,3tricarboxylate
1-ethyl-4,5,8trimethylnaphthalene

ac
carboxlico?

83

naftalina ?

78

methyl fthalato 80

1689
3
1696
3

143.1, 227.2,
270.2
147.1,219.1,
277.1

hexadecanoic acid,
methyl ester
methyl-3-(3,5-ditertbutl4-hydroxyphenyl)
propionate

10 1854
2
12 1882
5

191.0, 207.0,
257.1
143.0, 255.2,
298.2

74

15 2155
9
16 2225
8
17 2228
9

144.7, 207.9,
281.0
149.0, 167.0,
206.8
118.5, 206.9,
280.8

4' methyl-2
phenylindole
heptadecanoic acid, 16- ac 16-metil,
methyl-, methyl ester
heptadecanoic
o
gibberellin A3
giberelina A3
bis(2-ethylhexyl)
phthalate
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilome
thylidyne)]
tetradecamethylheptasiloxane

dioctyl fthalato

72

cido
carblico?

83

silicona?

78

28 2389 207.0, 280.8,

2
354.8

ac palmitico

87

ac 3-(3,5-di-tertbutil-4hidroxifenil)propionico

95

76
83

MUESTRA BAZ001-02MC

1
2

tR

m/z

1129
2
1217
2

177.1, 205.1,
220.1
134.9, 163.0,
194.0

compuesto
identificado
6-methyl-2,4-di-tertbutyl-phenol
dimethyl p-phthalate

nombre
comn
cido
carblico?
tereftalato de
dimetila

Qual
%
87
93

1292 137.0, 165.0,

6
206.9

1692
4
1696
3

143.1, 227.2,
270.2
147.1, 219.1,
277.1

10 1699 187.1, 233.1,

5
291.2
11 1701 161.1, 187.1,
8
291.2

12 1854
2
13 1882
5

191.0, 207.0,
267.1
143.0, 255.2,
298.2

14 1900
6
22 2277
6

185.0, 289.1,
304.2
113.0, 207.0,
281.0

26 2356
2
28 2418
2

205.9, 280.8,
355.1
146.8, 207.0,
280.9

32 2533 206.9, 281.0,

7
355.1

MUESTRA BAZ001-03MC

2,3,4,5,6,7-hexahydro2,2,3-trimethyl-4benzofuranone
hexadecanoic acid,
methyl ester
methyl-3-(3,5-ditertbutyl4-hydroxyphenyl)
propionate

87
ac palmtico
C16:0

93

ac 3-(3,5-di-tertbutil-4hidroxifenil)propionico

95

2,7,8-trimethoxy-3 quinona?
methyl-5,6methylenedioxynaphtho1,4-quinone
endo-3,4isopropylidenedioxy-exo2-phenylthio-6oxabicyclo [3.2.1]octan7-one
4' methyl-2 phenylindole
heptadecanoic acid, 16methyl-, methyl ester
tri-o-tolylphosphine
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilomet
hylidyne)]bis
tranylcypromine,
pentafluorobenzoyl ester

83

74

ac 16-metil,
76
heptadecanoic
o
83
cido
carblico?

72

78
72

phenol, 2,2'-[(1-methyl-1,2ethanediyl)bis(nitrilomethylidyn
e)]bis-

4-hydroxyphenyllactic
acid, ethyl ester, di-tms

90

ac lctico?

83

 tR

1 1129
2
2 1192
0

m/z

1243
1
1335
0

162.9, 182.9,
198.0
167.1, 182.0,
207.0

1
0
1
1

1690
8
1695
5

143.1, 227.2,
270.2
147.1, 219.2,
277.1

1
2

115.0, 205.1,
220.1
125.0, 157.0,
189.0

compuesto identificado nombre

comn
6-methyl-2,4-di-tert-butyl- cido
phenol
carblico?
trimethyl 2ac
methoxypropane-1,
carboxlico?
2,3-tricarboxylate
1-ethyl-4,5,8naftalina ?
trimethylnaphthalene

Qual
%
87

8H
benzo[3,4]cyclobuta[1,2]cyclohep
ten-7(6H)-one

72

83
78

hexadecanoic acid, methyl

ester
methyl-3-(3,5-ditertbutyl4-hydroxyphenyl)
propionate

ac palmtico
C16:0

93

ac 3-(3,5-di-tertbutil-4hidroxifenil)propionico

99

1696 147.1, 219.1,

3
277.1

methyl-3-(3,5-ditertbutyl4-hydroxyphenyl)
propionate

ac 3-(3,5-di-tertbutil-4hidroxifenil)propionico

95

1
3

1700 187.1, 291.2,

3
306.2

1
4

1882 143.0, 255.2,

5
298.2

endo-3,4isopropylidenedioxy-exo2-phenylthio-6-oxabicyclo
[3.2.1]octan-7-one
heptadecanoic acid, 16methyl-, methyl ester

1
7
1
8

1885
6
2063
2

2155 144.7, 206.9,

143.1, 255.2,
298.3
146.9, 206.9,
280.9

83

ac 16-metil,
78
heptadecanoi
co
octadecanoic acid, methyl ac esterico
94
ester
C18:0
aminoacido dimethyl [2,4
72
dinitrophenylhydrazono] . arginina alpha?
alpha. -ketoglutarate
gibberellin A3

giberelina A3

83

0
2
1

9
281.0
2166 192.9, 206.9
9

2
5
2
6

2225
8
2226
6

2
7

2258 111.1, 162.0,

0
414.3

2
9

2325 125.1, 207.0,

5
438.3

3
2

2375 143.1, 339.2,

8
382.4

104.0, 149.0,
279.1
104.0, 149.0,
279.1

8.alpha.,12-Epoxy13,14,15,16, 17 ,19hexanorlabdane
bis(2-ethylhexyl)
phthalate
1,2-benzenedicarboxylic
acid, bis(2ethylhexyl)ester
ethyl 2-{-2'[1"-(6-formyl3,4-dimethoxyphenyl)
vinyl]-4',5'dimethoxyphenyl} acetate
2,3-didecyl-1,4naphthoquinone $$ 1,4naphthalenedione, 2,3didecyltetracosanoic acid, methyl
ester

74
dioctyl fthalato

83

fthalato

83
72

naftalina ?

78

ac miristico
C14:0 (no
seria

90

ac lignocrico?)

3
5
3
8

2438
7
2466
2

109.1, 137.1,
351.3
147.0, 221.1,
355.1

4
4

2727 221.1, 281.0,

0
355.0

5
4

3298 207.0, 280.9,

8
355.1

5
6

3582 207.0, 441.2,

4
678.4

MUESTRA C-02-MC

squalene

escualeno

3-(4-n,nac ferlico?
dimethylaminophenyl)
propenoic acid,2(diethoxyphosphinyl)-,
ethyl ester
bistrimethylsilyln acetyl
eicosasphinga
-4,11-dienine
1,1,3,3,5,5,7,7,9,9,11,11,1 silicona?
3,13-tetradecamethylheptasiloxane
7,13,19,25-tetra-tertbutyl-27,28,29,30tetrahydroxy
-2,3-bishomo-3oxacalixarene

87
90

80
72
83

tR

11920 125.0, 157.0,

189.0

12431 162.9, 182.9,

198.0
13350 167.1, 182.0,
207.0

m/z

11284 115.0, 205.1,

220.1

14080 106.9,
208.0
8 16885 143.1,
270.2
9 16916 143.1,
270.2
10 16956 147.0,
277.1

152.0,
227.2,
227.1,
219.1,

11 16995 187.1, 233.1,

291.2
12 18825 143.0, 255.2,
298.2

compuesto
identificado
methyl 4,4,7trimethyl-4,7dihydroindan-6carboxylate
trimethyl 2methoxypropane1,2,3-tricarboxylate
1-ethyl-4,5,8trimethylnaphthalene

nombre
comn
ac
carboxlico?

Qual
%
78

ac
carboxlico?

83

naftalina ?

78
72

8H
benzo[3,4]cyclobuta[1,2]cycl
ohepten-7(6H)-one

butyl 4methoxybenzoate
hexadecanoic acid,
methyl ester
hexadecanoic acid,
methyl ester
methyl-3-(3,5ditertbutyl-4hydroxyphenyl)
propionate

2,7,8-trimethoxy-3methyl-5,6methylenedioxynapht
ho-1,4-quinone
heptadecanoic acid,
16-methyl-, methyl
ester

86
ac palmtico
C16:0
ac palmtico
C16:0
ac 3-(3,5-di-tertbutil-4
hidroxifenil)propionico

94

quinona?

90

ac 16metilheptadec
anoico

76

93
98

13 18833 143.1, 255.2,

298.2
15 18998 140.9, 289.2,
304.1
16 20632 146.9, 206.9,
280.9
17 21158 100.1, 140.1,
295.2
20 21559 144.7, 206.9,
281.0
23 22258 149.0, 167.0,
279.2
24 25062 147.1, 206.9,
280.8
27 25973 146.9, 206.9,
280.9
28 26335 206.9, 281.0,
354.9
29 27050 147.0, 221.0,
280.9
31 28888 147.0, 206.9,
280.9

MUESTRA C-01MC

octadecanoic acid,
methyl ester
benzo[b]cyclopropa[1
m]fluornone
dimethyl [2,4dinitrophenyl
hydrazono] .alpha.ketoglutarate
ethyl 6-acetyl-1methyl-9H-carbazole2-carboxylate
gibberellin A3

ac esterico
C18:0
fluorenona?

bis(2-ethylhexyl)
phthalate
phenol, 2,2'-[(1methyl-1,2ethanediyl)bis(nitrilo
methylidyn
phenol, 2,2'-[(1methyl-1,2ethanediyl)bis(nitrilo
methylidyn
phenol, 2,2'-[(1methyl-1,2ethanediyl)bis(nitrilo
methylidyn
tetracosamethylcyclo
dodecasiloxane
phenol, 2,2'-[(1methyl-1,2ethanediyl)bis(nitrilo
methylidyn

91
83

aminoacido - 72
arginina alpha?
ac
carboxlico?

72

giberelina A3

83

dioctyl fthalato

72

cido
carblico?

72

cido
carblico?

72

cido
carblico?

78

silicona?

72

cido
carblico?

72

 tR

m/z

compuesto identificado

nombre comn Qual

%

168
85

143.1, 227.2,
270.2

hexadecanoic acid, palmitic acid

ac palmtico
C16:0

94

168
93

143.1, 227.2,
270.2

hexadecanoic acid, palmitic acid

ac palmtico
C16:0

94

169
63

147.0, 219.1,
277.2

methyl-3-(3,5-ditertbutyl-4- ac 3-(3,5-di-tert93
hydroxyphenyl) propionate butil-4 hidroxifenil)propionico

170
03

161.1, 187.1,
291.2

2,7,8-trimethoxy-3-methyl-5,6methylenedioxynaphtho-1,4quinone

quinona?

90

188
25

143.1, 255.2,
298.3

octadecanoic acid, Stearic acid

ac esterico C18:0

91

189
98

128.0, 289.2,
305.2

benzo[b]cyclopropa[1m]fluornone

fluorenona?

91

13 222
66

149.0, 167.0,
279.2

bis(2-ethylhexyl) phthalate

dioctyl fthalato

78

MUESTRA CC-05MC

tR

m/z

compuesto identificado

112
84

115.0, 177.1,
205.1

6-methyl-2,4-di-tert-butylphenol

116
85
125
96

147.1, 281.0,
326.8
175.0, 206.9,
263.1

74

1
0

162
49
168
85
169
63

104.0, 149.0,
223.0
143.1, 227.2,
270.2
147.0, 219.1,
277.2

tetradecamethylcyclohepta
silicona?
siloxane
4,8-cis-8b,8c-cis fluoreno?
2,2,4,6,6,8hexamethylperhydro3a,4a,7a,8atetraazacyclopentano[def]fl
uorene
isobutyl phthalate
isobutyl
fhthalato
hexadecanoic acid, methyl ac palmtico
ester
C16:0
methyl-3-(3,5-ditertbutyl-4- ac 3-(3,5-di-terthydroxyphenyl) propionate butil-4
hidroxifenil)propionico

1
1

170
03

161.0, 187.1,
291.2

quinona?

90

1
2

188
25

143.1, 255.2,
298.3

2,7,8-trimethoxy-3-methyl5,6methylenedioxynaphtho1,4-quinone
octadecanoic acid, methyl
ester

ac esterico C18:0

91

8
9

nombre
comn
cido
carblico?

Qual
%
78

86

86
94
93

1
3
1
4
1
9

197
36
199
25
222
66

191.0, 207.0,
281.1
147.1, 207.0,
281.1
149.0, 167.0,
279.2

gibberellin A3

giberelina A3

83

arabitol-1,2,3,4,5pentaacetate
bis(2-ethylhexyl) phthalate

glucosa?

74

dioctyl fthalato

78

MUESTRA CC-01MC

1
3
4
5

tR

m/z

1128
4
1168
5
1214
0
1259
6

115.0,
220.1
147.1,
326.8
167.0,
206.9
207.0,
277.9

1269
0
10 1626
4
11 1689
3

compuesto identificado
205.1,
281.0,
182.0,
283.1,

111.0, 152.1,
185.0
104.0, 149.0,
223.0
143.1, 227.2,
270.2

nombre
comn
methyl 4,4,7-trimethyl-4,7- ac
dihydroindan-6-carboxylate carboxlico?
tetradecamethylcyclohepta silicona?
siloxane
2,3'-dimethylbiphenyl

Qua
l%
83

fluoreno?
4,8-cis-8b,8c-cis2,2,4,6,6,8hexamethylperhydro3a,4a,7a,8atetraazacyclopentano[def]fl
uorene
3-methylamino-thixo-2,5tiofeno?
dimethyl-thiophene
isobutyl fthalato
isobutyl phthalate

78

hexadecanoic acid, methyl

ester

94

ac palmtico
C16:0

74
94

72
90

12 1696 147.0, 219.1,

3
277.2

methyl-3-(3,5-ditertbutyl-4- ac 3-(3,5-di-terthydroxyphenyl) propionate butil-4

hidroxifenil)propionico

93

13 1700 161.0, 187.1,

3
291.2

2,7,8-trimethoxy-3-methyl5,6methylenedioxynaphtho1,4-quinone
octadecanoic acid, methyl
ester
bis(2-ethylhexyl) phthalate

quinona?

90

ac esterico
C18:0
dioctyl fthalato

91

3,3-diethoxy-1,1,1,5,5,5hexamethyltrisiloxane
phenol, 2,2'-[(1-methyl-1,2ethanediyl)bis(nitrilomethyl
idyne)]bisgibberellin A3

silicona?

83

cido
carblico?

78

giberelina A3

83

15 1882
5
18 2226
6
24 2458
3
27 2479
5

143.1,
298.3
149.0,
279.2
190.8,
280.9
177.0,
281.0

255.2,

28 2483
4
29 2496
0
30 2500
7
31 2511
7
32 2515
6

137.0,
280.8
147.0,
281.0
190.0,
281.0
113.0,
281.1
147.1,
280.9

207.0,

33 2525
8
34 2530
6
35 2536
1

167.0,
207.0,
207.0,

3,3-Diethoxy-1,1,1,5,5,5hexamethyltrisiloxane
3,3-diethoxy-1,1,1,5,5,5hexamethyltrisiloxane
3,3-diethoxy-1,1,1,5,5,5hexamethyltrisiloxane
n,n'-disalicylidene-1,2diaminopropane $$ N,N'Disal

EST
DIFERENTE
DEL EXCEL

78

190.9, 207.0,
281.1
190.9, 207.0,
280.9
103.0, 207.0,
281.0

gibberellin A3

giberelina A3

83

36 2539
2
37 2550
2
38 2554
9
39 2556
5
42 2639
0

207.0, 280.9

tranylcypromine,
pentafluorobenzoyl ester
tranylcypromine,
pentafluorobenzoyl ester
gibberellin A3

43 2646
0
44 2650
7

132.9, 207.0,
280.9
207.0, 253.0,
280.8

162.8,
280.8
113.0,
280.9
133.1,
281.0
133.0,
280.8

207.0,

78

207.0,
206.9,
207.0,

206.9,
207.0,
207.0,
206.9,

3,3-diethoxy-1,1,1,5,5,5hexamethyltrisiloxane
N,N'-disalicylidene-1,2diaminopropane $$ N,N'Disal

tranylcypromine,
pentafluorobenzoyl ester
N,N'-disalicylidene-1,2diaminopropane $$ N,N'Disal
3,3-diethoxy-1,1,1,5,5,5hexamethyltrisiloxane
arabinitol, pentaacetate
(cas) $$

78
78
78

78
EST
DIFERENTE
DEL EXCEL

74

83
78
giberelina A3

72
74

EST
DIFERENTE
DEL EXCEL

72
72

glucosa?

74

45 2697 176.8, 206.9,

1
281.0
47 2741 132.9, 207.0,
1
281.0
48 2774 132.9, 207.0,
1
280.8

arabinitol-1,2,3,4,5pentaacetate
N,N'-disalicylidene-1,2diaminopropane $$ N,N'Disal
N,N'-disalicylidene-1,2diaminopropane $$ N,N'Disal
tranylcypromine,
pentafluorobenzoyl ester

EST
DIFERENTE
DEL EXCEL
EST
DIFERENTE
DEL EXCEL

78
74
78

MUESTRA PR-04MC

1
2

tR

m/z

1127
6
1128
4

175.0,
205.1,220.1
115.0, 205.1,
220.1

compuesto
identificado
6-methyl-2,4-di-tertbutyl-phenol
methyl 4,4,7trimethyl-4,7-

nombre
comn
cido
carblico?
ac
carboxlico?

Qual
%
78
83

1259
6

175.9, 207.0,
263.1

1364
9
1464
6
1477
2
1585
6

207.0,
355.0
101.0,
205.9
143.0,
242.2
143.0,
296.2

5
6
7
9

281.0,
163.0,
199.1,
213.2,

1689
3
10 1696
4

143.1, 227.2,
270.2
147.0, 219.1,
277.1

11 1700
3

161.1, 187.1,
291.2

12 1858
2
13 1880
1
14 1881
7
15 1882
5
16 1967
3

111.0,
264.2
143.1,
298.1
143.1,
298.2
143.1,
298.3
207.0,

19 2226
6
22 2335
0
23 2429
2

149.0, 167.0,
279.2
190.7, 207.0,
281.0
207.0, 281.0

25 2435
5

147.1, 206.9,
280.9

26 2444
2

146.8, 207.0,
280.9

27 2462
2

147.0, 221.1,
355.0

180.0,
255.1,
255.2,
255.2,
284.2

dihydroindan-6carboxylate
1,3-di-tert-butyl-2,480
diisobutyl-1,3,2,4diazadiboretidin
cyclododecasiloxane,
silicona?
72
tetracosamethyl
methyl butyl phthalate methyl fthalato 86
methyl tetradecanoate
/ normal chain
methyl
pentadecanoate /
normal chain
hexadecanoic acid,
Palmitic acid
methyl-3-(3,5ditertbutyl-4hydroxyphenyl)
propionate

ac miristico

91

ac
pentadecanoic
o
ac palmtico
C16:0
ac 3-(3,5-di-tertbutil-4
hidroxifenil)propionico

93

2,7,8-trimethoxy-3methyl-5,6methylenedioxynaphth
o-1,4-quinone
9-octadecenoic acid
(Z)-, oleic acid
octadecanoic acid,
methyl ester
octadecanoic acid,
methyl ester
octadecanoic acid,
Stearic acid
methanone, phenyl[4(2phenylethenyl)phenyl]
bis(2-ethylhexyl)
phthalate
gibberellin A3

quinona?

90

ac oleico

95

ac estearico

81

ac estearico

94

ac estearico

91

methanol?

83

dioctyl fthalato

78

giberelina A3

72

phenol, 2,2'-[(1cido
methyl-1,2carblico?
ethanediyl)bis(nitrilom
ethylidyne)]bistranylcypromine,
pentafluorobenzoyl
ester
tranylcypromine,
pentafluorobenzoyl
ester
bistrimethylsilyln
acetyl eicosasphinga-

93
97

83

83
74
86

28 2475
6

207.0, 280.9,
355.1

29 2478
7

206.9, 281.0,
354.9

31 2508
6

207.0, 280.9,
355.0

32 2516
4

207.0, 281.0,
355.9

33 2524
3

207.0, 281.0

34 2525
8
35 2531
3

190.9, 207.0.
281.1
136.4, 206.9,
281.0

36 2541
6
37 2549
4

190.8, 207.0,
281.0
147.0, 207.0,
281.0

38 2592
9

207.0, 249.0,
281.0

41 2638
2

207.0, 281.0,
358.0

42 2651
5

207.0, 281.0,
354.9

44 2657
0

127.0, 206.9,
281.0

47 2697
1

176.8, 206.9,
281.0

4,11-dienine
4-hydroxyphenyllactic
acid, ethyl ester, ditms
3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane
tranylcypromine,
pentafluorobenzoyl
ester
phenol, 2,2'-[(1methyl-1,2ethanediyl)bis(nitrilom
ethylidyne)]bisphenol, 2,2'-[(1methyl-1,2ethanediyl)bis(nitrilom
ethylidyne)]bis
gibberellin A3

ac lctico?

83

silicona?

83
83

cido
carblico?

72

cido
carblico?

83

giberelina A3

83

phenol, 2,2'-[(1cido
methyl-1,2carblico?
ethanediyl)bis(nitrilom
ethylidyne)]bisgibberellin A3
giberelina A3

72

1,1,3,3,5,5,7,7,9,9,11,
11,13,13tetradecamethylheptasiloxane
phenol, 2,2'-[(1methyl-1,2ethanediyl)bis(nitrilom
ethylidyne)]bisCyclotrisiloxane,
hexamethyl- (CAS) $$
1,1,3,3,5,5hexamethylcyclohexasiloxane $$
Hexamethylcyclotrisilo
xane $$ hexamethylcyclotrisiloxane $$
dimethylsiloxane
cyclic trimer
3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane
tranylcypromine,
pentafluorobenzoyl
ester
phenol, 2,2'-[(1methyl-1,2ethanediyl)bis(nitrilom

silicona?

72

cido
carblico?

72

silicona?

72

silicona?

78

72

78
cido
carblico?

78

49 2726
2

146.7, 206.9,
280.9

52 2907
6

147.0, 207.0,
281.0

53 2932
0

207.0, 280.9,
354.8

54 2934
3

207.0, 280.9,
355.0

57 2954
0

207.0, 281.0,
355.1

58 2958
7

132.7, 206.9,
281.1

59 2965
7

147.0, 206.9,
280.0

61 2992
5

191.0, 207.0,
281.0

62 3006
6

190.9, 207.0,
281.0

63 3016
0

147.1, 207.0,
280.9

65 3027
8

206.9, 280.8,
355.0

ethylidyne)]bis- $$ ocresol, .alpha.,.alpha.'(propylenedinitrilo)di$$ cuvan 80 $$ dmd $

$ keromet md $$ n,n'bis(salicylidene)-1,2diaminopropane $$
n,n'-disalicylidene-1,2diaminopropane $$
n,n'-disal
3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane
1,1,3,3,5,5,7,7,9,9,11,
11,13,13,15,15hexadecamethyloctasiloxane
tranylcypromine,
pentafluorobenzoyl
ester
phenol, 2,2'-[(1methyl-1,2ethanediyl)bis(nitrilom
ethylidyne)]bis- $$ ocresol, .alpha.,.alpha.'(propylenedinitrilo)di$$ cuvan 80 $$ dmd $
$ keromet md $$ n,n'bis(salicylidene)-1,2diaminopropane $$
n,n'-disalicylidene-1,2diaminopropane $$
n,n'-disal
3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane
3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane
tranylcypromine,
pentafluorobenzoyl
ester
3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane
3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane
tranylcypromine,
pentafluorobenzoyl
ester
4-hydroxyphenyllactic
acid, ethyl ester, ditms

silicona?

78

silicona?

80

74
cido
carblico?

72

silicona?

83

silicona?

83
83

silicona?

78

silicona?

83
78
78

66 3047
4

176.7, 206.9,
281.0

67 3086
0

147.0, 221.0,
355.0

tranylcypromine,
pentafluorobenzoyl
ester
compuesto de
silane,
[[(3.beta.,11.beta.,20S silicio?
)-pregn-5-ene3,11,17,20tetrayl]tetrakis(oxy)]te
trakis[trimethyl

72

compuesto
identificado
6-methyl-2,4-di-tertbutyl-phenol
tetradecamethylcyclohe
ptasiloxane
4,8-cis-8b,8c-cis2,2,4,6,6,8hexamethylperhydro3a,4a,7a,8atetraazacyclopentano[d
ef]fluorene
3-methylamino-thixo2,5-dimethyl-thiophene
$$ 3-

nombre
comn
cido
carblico?
silicona?

Qual
%
78

fluoreno?

78

tiofeno?

72

92

MUESTRA PR-23MC

1
3
4

tR

m/z

11276 115.0, 205.1,

220.1
11685 147.1, 281.0,
325.8
12596 207.0, 283.1,
277.9

12690 111.0, 152.1,

185.0

74

16893 143.1, 227.2,

270.2
10 16963 147.0, 219.1,
277.2

11 18825 143.1, 255.2,

298.3
13 19673 207.0, 284.2
18 21653 132.0, 207.0,
281.0
20 22266 149.0, 167.0,
279.2
23 22831 127.2, 206.9,
280.9
24 22933 206.9, 280.9,
355.2
29 23436 132.8, 207.0,
280.8
30 23648 191.0, 207.0,
280.9
31 24269 206.9, 281.1,
357.1
33 24442 146.8, 207.0,
280.9
36 24803 183.1, 207.0,
281.0
37 24834 137.0, 207.0,
280.8
38 25243 207.0, 281.0

39 25526 133.1, 206.9,

355.0

thiophenecarbothioami
de, n,2,5-trimethylhexadecanoic acid,
methyl ester
methyl-3-(3,5ditertbutyl-4hydroxyphenyl)
propionate $$ methyl
ester of 3-(3,5-di-tertbutyl-4-hydroxyphenyl)propionic acid
octadecanoic acid,
methyl ester
methanone, phenyl[4(2phenylethenyl)phenyl]arabitol-1,2,3,4,5pentaacetate
bis(2-ethylhexyl)
phthalate
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilome
thylidyne)
3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilome
thylidyne)]bis3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane
3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane
tranylcypromine,
pentafluorobenzoyl
ester
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilome
thylidyne
gibberellin A3
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilome
thylidyne)]bis3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane

ac palmtico
94
C16:0
ac 3-(3,5-di-tert- 93
butil-4
hidroxifenil)propionico

ac esterico
C18:0
methanol?

91

glucosa?

74

dioctyl fthalato

78

cido
carblico?

83

silicona?

78

cido
carblico?

72

silicona?

83

silicona?

78

83

74
cido
carblico?

78

giberelina A3

83

cido
carblico?

83

cido
carblico?

72

40 25565 133.1, 207.0,

281.0
41 25604 207.0, 280.9

45 26201 133.1, 207.1,

281.0
46 26264 207.0, 281.0
48 26319 190.9, 206.9,
280.9
49 26343 207.0, 281.0,
355.0
50 26382 147.0, 207.0,
281.0
51 26452 133.0, 207.1,
280.9
52 26507 207.0, 253.0,
280.8
53 26885 206.9, 281.0,
354.9
56 27639 146.9, 207.0,
280.8
57 28911 206.9, 280.9,
354.8
59 28966 207.0, 281.0,
431.9
61 29186 207.0, 281.0,
354.8
62 29343 207.0, 280.9,
355.0
63 29375 207.0, 281.0,
429.1
64 29547 190.9, 206.9,
280.9
65 29775 206.9, 280.9,
354.9

tranylcypromine,
pentafluorobenzoyl
ester
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilome
thylidyne)]
3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane
tranylcypromine,
pentafluorobenzoyl
ester
gibberellin A3

silicona?

74

cido
carblico?

72

silicona?

83
83

giberelina A3

78

3,3-diethoxysilicona?
1,1,1,5,5,5hexamethyltrisiloxane
cyclotrisiloxane,
silicona?
hexamethyltranylcypromine,
pentafluorobenzoyl
ester
arabinitol, pentaacetate glucosa?

83

tranylcypromine,
pentafluorobenzoyl
ester
d-mannitol,
hexaacetate
tranylcypromine,
pentafluorobenzoyl
ester
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilome
thylidyne)
3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilome
thylidyne)]bisphenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilome
thylidyne)]bisgibberellin A3

72

tranylcypromine,
pentafluorobenzoyl
ester

glucosa?

72
78
74

78
72

cido
carblico?

78

silicona?

78

cido
carblico?

72

cido
carblico?

78

giberelina A3

78
72

68 30969 207.0, 281.0,

355.0

tranylcypromine,
pentafluorobenzoyl
ester

72

MUESTRA SM-01MC

1
2
3
4

tR

m/z

112
92
115
20
116
85
118
89

121.0,
220.1
133.0,
194.0
281.1,
503.0
118.9,
166.0

205.1,
163.0,
326.9,
151.0,

compuesto
identificado
6-methyl-2,4-di-tertbutyl-phenol
methyl phthalate

nombre
comn
cido
carblico?
methyl fthalato

tetradecamethylcyclohe silicona?
ptasiloxane
benzaldehyde,3,4benzaldehdo?
dimethoxybenzaldehyd
e

Qual
%
90
90
87
91

5
6

7
8
9
10
11
13
16

124
23
125
96

106.0, 136.0,
163.0
175.1, 263.1,
278.1

126
90
132
32
132
40
141
36
142
69
147
72
162
49

111.1,
185.0
105.0,
177.0
105.0,
177.0
104.0,
181.0
133.0,
192.0
143.1,
242.2
104.0,
223.1

ethylmethylphthalate

methyl fthalato

83
78

149.0,

fluoreno?
4,8-cis-8b,8c-cis2,2,4,6,6,8hexamethylperhydro3a,4a,7a,8atetraazacyclopentano[d
ef]fluorene
tiofeno?
3-methylamino-thixo2,5-dimethyl-thiophene
ethyl phthalate
ethyl fthalato

149.0,

ethyl phthalate

ethyl fthalato

95

163.0,

methyl 2-ethylhexyl
phthalate
cinnamic acid, pmethoxy-, methyl ester
tetradecanoic acid,
methyl ester
1,2benzenedicarboxylic
acid, bis(2methylpropyl) ester
methyl 3,4dimethoxycinnamate

methyl fthalato

72

ac cinmico?

76

ac miristico

90

dietil fthalato

90

ac 3,4dimetoxicinmico

94

ac palmtico
C16:0
ac 3-(3,5-di-tertbutil-4
hidroxifenil)propionico

94

152.0,

161.0,
199.2,
149.0,

17 164
45

146.9, 191.0,
222.0

18 168
93
19 169
63

143.1, 227.2,
270.2
147.1, 219.1,
277.1

hexadecanoic acid,
methyl ester
methyl ester of 3-(3,5di-tert-butyl-4hydroxyphenyl)propionic acid

20 170
03

161.1, 187.1,
291.2

21 172
07
22 172
15
23 177
49

104.0, 149.0,
223.1
104.0, 149.0,
223.1
221.0, 237.0,
252.1

endo-3,4isopropylidenedioxyexo-2-phenylthio-6oxabicyclo[3.2.1]octan7-one
butyl phthalate

25 188
25
26 191
71
27 211
11

143.1, 255.2,
298.2
113.1, 141.0,
169.1
101.0, 129.0,
241.1

78
95

98

83

butyl fthalato

91

n-butyl isobutyl
phthalate
3,4,5trimethoxycinnamic
acid methyl ester
octadecanoic acid,
methyl ester
11-n-decyldocosane

butyl fthalato

91

ac 3,4,5dimetoxicinmico

90

ac esterico C18:0

90

hexanedioic acid,
mono(2ethylhexyl)ester

cido
adpico o cido
hexanodioico?

72
83

28 222
66
30 237
58
33 270
58

104.0, 149.0,
279.2
143.0, 207.1,
382.3
147.1, 221.0,
281.0

bis(2-ethylhexyl)
phthalate
bikaverin

dioctyl fthalato

83
72

bistrimethylsilyln
acetyl eicosasphinga4,11-dienine

72

MUESTRA SM-03MC

tR

m/z

112
76
116
85
124
62

115.0, 205.1,
220.1
147.1, 281.0,
326.8
206.9, 235.1,
250.0

125
96

207.0, 263.1,
277.9

126
43

179.1, 206.9,
319.0

126
90
10 168
93
11 169
63

111.0, 152.1,
185.0
143.1, 227.2,
270.2
147.0, 219.1,
277.2

3
4

compuesto
identificado
6-methyl-2,4-di-tertbutyl-phenol
cycloheptasiloxane,
tetradecamethyl
2,3-dihydro-5,5dimethyl-5Hbenzo[b]pyrano[3,4-b]
[1,4]dithiin
4,8-cis-8b,8c-cis2,2,4,6,6,8hexamethylperhydro3a,4a,7a,8atetraazacyclopentano[d
ef]fluorene
4-trifluormethyl-6-(2furyl)-(4toluidido)pyrimidin
3-methylamino-thixo2,5-dimethyl-thiophene
hexadecanoic acid,
methyl ester
methyl-3-(3,5ditertbutyl-4-

nombre
comn
cido
carblico?
silicona?

Qual
%
78
74
80

fluoreno?

78

74
tiofeno?

72

ac palmtico
C16:0
ac 3-(3,5-di-tertbutil-4

94
93

12 169
95

187.1, 291.2,
306.2

14 188
25
15 222
66
16 252
51

143.1, 255.2,
298.3
149.0, 167.0,
279.2
146.9, 207.0,
280.9

17 255
65

133.1, 207.0,
281.0

20 260
05

207.0, 280.9

hydroxyphenyl)
propionate

hidroxifenil)propionico

2,7,8-trimethoxy-3methyl-5,6methylenedioxynaphtho
-1,4-quinone
octadecanoic acid,
methyl ester
bis(2-ethylhexyl)
phthalate
3,3-diethoxy1,1,1,5,5,5hexamethyltrisiloxane
tranylcypromine,
pentafluorobenzoyl
ester
Phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilome
thylidyne)

quinona?

90

ac esterico C18:0

91

dioctyl fthalato

78

silicona?

78

tranilcipromina?

74

cido
carblico?

83

nombre
comn

Qual
%
83

silicona?

80

MUESTRA TC-08MC

tR

m/z

compuesto identificado

112
76

115.0, 205.1,
220.1

116

147.1, 281.0,

3-(2,2dimethylpropylidene)
bicyclo[3.3.1]nonane2,4-dione
cycloheptasiloxane,

85
125
96

326.8
207.0, 263.1,
277.9

126
43

179.1, 206.9,
319.0

169
00
10 169
63

143.1, 227.2,
270.2
147.0, 219.1,
277.2

11 170
03

161.0, 187.1,
291.2

12 186
37
13 188
25
14 188
33
19 201
13

111.1,
265.1
143.1,
298.3
143.1,
298.2
113.3,
280.8

207.1,

26 231
53
27 235
38
29 242
69
30 243
08
31 243
63

132.9,
281.1
113.1,
414.2
127.1,
281.1
207.0,
473.2
132.9,
280.9

207.0,

32 244
73
34 247
56
35 247
71
36 248
03

132.8,
281.0
207.0,
355.1
132.9,
280.8
183.1,
281.0

207.0,

6
9

255.2,
255.2,
206.9,

141.2,
206.9,
281.0,
206.9,

280.9,
206.9,
207.0,

tetradecamethyl
4,8-cis-8b,8c-cis2,2,4,6,6,8hexamethylperhydro3a,4a,7a,8atetraazacyclopentano[de
f]fluorene
2,3-diphenyl-5-methyl6H-thieno[3,2-d]-1,3oxazin-6-one
hexadecanoic acid,
methyl ester
methyl-3-(3,5ditertbutyl-4hydroxyphenyl)
propionate
2,7,8-trimethoxy-3methyl-5,6methylenedioxynaphtho1,4-quinone
9-octadecenoic acid (Z)-,
methyl ester
octadecanoic acid,
methyl ester
Octadecanoic acid,
methyl ester
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilomet
hylidyne)
tranylcypromine,
pentafluorobenzoyl ester
2-n-heptadecanyl-4,4dimethyloxazoline
3,3-diethoxy-1,1,1,5,5,5hexamethyltrisiloxane
tranylcypromine,
pentafluorobenzoyl ester
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilomet
hylidyne)]
3,3-diethoxy-1,1,1,5,5,5hexamethyltrisiloxane
4-hydroxyphenyllactic
acid, ethyl ester, di-tms
tranylcypromine,
pentafluorobenzoyl ester
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilomet
hylidyne)]

fluoreno?

78

83
ac palmtico
C16:0
ac 3-(3,5-di-tertbutil-4
hidroxifenil)propionico

93

quinona?

90

ac oleico

90

93

ac estericoC18:0 94

ac esterico C
18:0
cido
carblico?

91
72

83
80
silicona?

78
72

cido
carblico?

78

silicona?

74

ac lctico?

83
74

cido
carblico?

78

37 248
42

207.0, 281.1

39 259
81
40 261
70

112.8, 207.0,
280.8
177.0, 206.9,
280.9

42 264
92

146.9, 207.0,
281.0

43 265
15
44 265
78
47 273
09

207.0, 281.0,
354.9
132.7, 207.0,
280.9
147.1, 207.0,
280.9

48 274
11

132.9, 207.0,
281.0

49 277
33
51 281
57
52 281
65
53 282
83

207.0,
354.9
147.1,
280.9
132.7,
280.9
132.9,
281.0

56 285
03
57 286
36

207.0, 280.9,
354.9
132.9, 206.9,
281.1

281.0,
206.9,
207.1,
207.0,

MUESTRA TC-14MC

phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilomet
hylidyne)]
3,3-diethoxy-1,1,1,5,5,5hexamethyltrisiloxane
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilomet
hylidyne)]
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilomet
hylidyne)]bis3,3-diethoxy-1,1,1,5,5,5hexamethyltrisiloxane
tranylcypromine,
pentafluorobenzoyl ester
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilomet
hylidyne)
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilomet
hylidyne)]
tranylcypromine,
pentafluorobenzoyl ester
tranylcypromine,
pentafluorobenzoyl ester
gibberellin A3

cido
carblico?

78

silicona?

83

cido
carblico?

72

cido
carblico?

72

silicona?

78
72

cido
carblico?

72

cido
carblico?

74

72
78
giberelina A3

74

phenol, 2,2'-[(1-methyl- cido

1,2carblico?
ethanediyl)bis(nitrilomet
hylidyne)]
gibberellin A3
giberelina A3

72

phenol, 2,2'-[(1-methyl- cido

1,2carblico?
ethanediyl)bis(nitrilomet
hylidyne)

78

78

 tR

m/z

115.0, 205.1,
220.1

112
84

115
28
6
133
50
9
168
93
10 169
63

132.9,
207.0
167.1,
207.0
143.1,
270.2
147.1,
277.1

163.0,

11 169
95

187.1, 233.1,
291.2

13 185
42
14 188
25

191.0, 207.0,
267.1
143.0, 255.2,
298.2

15 206
32

146.9, 206.9,
280.9

19 222
58
21 229
57
22 229
73
28 243
00

149.0,
279.2
132.8,
280.9
146.8,
280.8
207.0,
429.0

182.0,
227.2,
219.1,

167.0,
207.0,
206.9,
280.9,

compuesto
identificado
methyl 4,4,7-trimethyl4,7-dihydroindan-6carboxylate
methyl phthalate
benzo[3,4]cyclobuta[1,2
]cyclohepten-7(6H)-one
hexadecanoic acid,
methyl ester
methyl ester of 3-(3,5-ditert-butyl-4hydroxyphenyl)propionic acid

nombre
comn
ac
carboxlico?

Qual
%
78

methyl
fthalato

80
72

ac palmtico
C16:0
ac 3-(3,5-ditert-butil-4
hidroxifenil)propionico

2,7,8-trimethoxy-3 quinona?
methyl-5,6methylenedioxynaphtho1,4-quinone
4' methyl-2 phenylindole
heptadecanoic acid, 16methyl-, methyl ester
dimethyl [2,4dinitrophenylhydrazono]
.alpha.-ketoglutarate
bis(2-ethylhexyl)
phthalate
d-Mannitol, hexaacetate

87
95

90

74

ac 16-metil,
76
heptadecanoi
co
aminoacido - 72
arginina
alpha?
dioctyl fthalato 72
glucosa?

1,1,1,3,5,7,7,7silicona?
octamethyltetrasiloxane
3,3-diethoxy-1,1,1,5,5,5- silicona?
hexamethyltrisiloxane

72
74
78

MUESTRATM-03MC

tR

1 112
76
2 115
28
8 162
48
9 168
93
1 188
1 25

m/z

1
2

206
32

146.9, 206.9,
280.9

1
6
1
7

222
58
224
23

149.0, 167.0,
279.2
207.0, 236.7,
281.0

114.9,
220.2
132.9,
207.0
103.9,
223.1
143.1,
270.2
143.0,
298.2

163.0,

compuesto
identificado
6-methyl-2,4-di-tertbutyl-phenol
methyl phthalate

methyl fthalato

80

149.0,

isobutyl phthalate

isobutyl fthalato

80

227.2,

hexadecanoic acid,
methyl ester
heptadecanoic acid,
16-methyl-, methyl
ester
dimethyl [2,4dinitrophenylhydrazo
no] .alpha.ketoglutarate
bis(2-ethylhexyl)
phthalate
gibberellin A3

ac palmtico
87
C16:0
ac 1678
metilheptadecanoico

205.1,

255.2,

nombre comn Qual

%
cido carblico? 80

aminoacido arginina alpha?

72

dioctyl fthalato

72

giberelina A3

72

MUESTRATM-08MC

tR

m/z

1127
6
1192
0

114.9, 205.1,
220.2
125.0, 157.0,
189.0

1199
9
1258
8

113.1, 155.1,
183.1
125.8, 207.0,
263.1

11 1689
3
12 1695
5

143.1, 227.2,
270.2
147.0, 219.1,
277.1

13 1851
9
14 1854
2
15 1881
7
16 1882
5
23 2155
9

109.1,
294.3
191.0,
267.1
143.1,
298.2
143.1,
298.2
144.7,
281.0

2
3
5

263.2,
207.0,
255.1,
255.2,
206.9,

compuesto
identificado
6-methyl-2,4-di-tertbutyl-phenol
trimethyl 2methoxypropane-1,2,3tricarboxylate
triacontane

nombre comn Qual

%
cido carblico? 80
ac carboxlico?

83

triacontano

78

7,8,9,10-tetrahydro-5,6dimethyl-5Hbenzo[b]carbazol-7-on
hexadecanoic acid,
methyl ester
methyl ester of 3-(3,5-ditert-butyl-4hydroxyphenyl)propionic acid
8,11-octadecadienoic
acid, methyl ester
4' methyl-2 phenylindole

carbazol?

72

ac palmtico
C16:0
ac 3-(3,5-di-tertbutil-4 hidroxifenil)propionico

87

ac 8,11-octadienoico

81

octadecanoic acid,
methyl ester
octadecanoic acid,
methyl ester
gibberellin A3

ac esterico C18:0

90

ac esterico C18:0

91

giberelina A3

83

91

74

24 2166 192.9, 206.9

9
28 2225 149.0, 167.0,
8
279.2
29 2265 207.0, 280.8
1
30 2277 113.0, 207.0,
6
281.0
34 2297
3
36 2335
8

146.8, 206.9,
280.8
207.0, 280.9,
355.0

39 2352
3
40 2356
2
43 2408
0
44 2418
2

206.9,
354.9
206.9,
355.1
206.9,
429.9
146.8,
280.9

280.9,
280.8,
280.9,
207.0,

47 2434 133.1, 207.0,

0
280.9

60 2580 132.9, 206.9,

8
280.9

8.alpha.,12-Epoxy13,14,15,16,17,19hexanorlabdane
bis(2-ethylhexyl)
phthalate
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilomet
hylidyne
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilomet
hylidyne)]
1,1,1,3,5,7,7,7octamethyltetrasiloxane
1,1,3,3,5,5,7,7,9,9,11,11
,13,13-tetradecamethylheptasiloxane
3,3-diethoxy-1,1,1,5,5,5hexamethyltrisiloxane
tranylcypromine,
pentafluorobenzoyl ester
4-hydroxyphenyllactic
acid, ethyl ester, di-tms
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilomet
hylidyne)]
phenol, 2,2'-[(1-methyl1,2ethanediyl)bis(nitrilomet
hylidyne)
]bis- $$ o-Cresol,
.alpha.,.alpha.'(propylenedinitrilo)di- $$
Cuvan 80 $$ DMD $$
Keromet MD $$ N,N'Bis(salicylidene)-1,2diaminopropane $$ N,N'Disalicylidene-1,2diaminopropane $$ N,N'Disal
tranylcypromine,
pentafluorobenzoyl ester

74
dioctyl fthalato

72

cido carblico?

83

cido carblico?

72

silicona?

74

silicona?

74

silicona?

78
78

ac lctico?

78

cido carblico?

72

cido carblico?

72

72

MUESTRA VR-03MC

tR

1 1152
8
2 1243
1
4 1259
6

m/z

compuesto identificado

132.9, 163.0,
207.0
162.9, 182.9,
198.0
206.9, 263.1,
280.9

methyl phthalate

111.1,
185.0
104.0,
223.1
143.1,
270.2
147.1,
277.2

Qual
%
80

1-ethyl-4,5,8trimethylnaphthalene
4,8-cis-8b,8c-cis2,2,4,6,6,8hexamethylperhydro3a,4a,7a,8atetraazacyclopentano[def]fl
uorene
nonanedioic acid, dimethyl
ester
isobutyl phthalate

naftalina ?

78

fluoreno?

72

ac azelaico

74

isobutyl fthalato

86

hexadecanoic acid, methyl

ester
methyl ester of 3-(3,5-ditert-butyl-4hydroxyphenyl)-propionic
acid

ac palmtico
C16:0
ac 3-(3,5-di-tertbutil-4
hidroxifenil)propionico

93

quinona?

90

1
0
1
1

1268
2
1624
8
1689
3
1696
3

1
2

1699 187.1, 233.1,

5
291.2

2,7,8-trimethoxy-3-methyl5,6methylenedioxynaphtho1,4-quinone

1854 191.0, 207.0,

4' methyl-2 phenylindole

152.0,

nombre
comn
methyl fthalato

149.0,
227.2,
219.1,

98

74

267.1

1
4
1
5
1
6
1
7
2
2

1858
9
1882
5
1889
6
1914
7
2203
8

111.1,
264.2
143.0,
298.2
111.0,
279.1
187.1,
290.1
111.1,
320.3

2
3
2
5
2
9

2225
8
2297
3
2386
0

149.0, 167.0,
279.2
146.8, 206.9,
280.8
207.0, 281.0,
355.1

3
0

2392 147.0, 206.9,

3
280.9

3
2
3
3
3
4
3
7
3
8

2463
8
2533
7
2543
1
2580
8
2588
7

100.1,
365.3
206.9,
355.1
206.9,
355.3
132.9,
280.9
207.0,
355.1

222.2,

206.9,

9-octadecenoic acid, methyl

ester
heptadecanoic acid, 16methyl-, methyl ester
1,2,7,8-dibenzacridine

275.1,

benzo[c]fluorenone

207.0,

13-docosenoic acid, methyl

ester,
(Z)bis(2-ethylhexyl) phthalate

ac ercico

76

dioctyl fthalato

72

1,1,1,3,5,7,7,7octamethyltetrasiloxane
phenol, 2,2'-[(1-methyl-1,2ethanediyl)bis(nitrilomethyli
dyne)]
phenol, 2,2'-[(1-methyl-1,2ethanediyl)bis(nitrilomethyli
dyne)]
3-methylpentacosane

silicona?

74

cido
carblico?

72

cido
carblico?

72

3-metilpentacosano

78

4-hydroxyphenyllactic acid,
ethyl ester,di-tms
4-hydroxyphenyllactic acid,
ethyl ester, di-tms
tranylcypromine,
pentafluorobenzoyl ester
phenol, 2,2'-[(1-methyl-1,2ethanediyl)bis(nitrilomethyli
dyne)]

ac lctico?

83

ac lctico?

74

255.2,

280.3,
281.0,
281.1,
206.9,
281.0,

MUESTRA VR-08MC

ac oleico

94

ac 16-metil,
heptadecanoico
dibenzacridine
?
fluorenona?

76
76
87

72
cido
carblico?

78

 tR

1 112
84
6 145
44

m/z

compuesto identificado

175.0, 205.1,
220.1
121.0, 135.0,
163.1

1
0

147
72
162
49
168
93
169
63

143.1,
243.2
103.9,
223.0
143.1,
270.0
127.0,
292.1

methyl 4,4,7-trimethyl-4,7dihydroindan-6-carboxylate
9-hydroxypyrimido[1,6a]pyrimidin-4one
tetradecanoic acid, methyl ac mirstico
ester
isobutyl fthalato
isobutyl phthalate

1
1

169
95

187.1, 233.1,
291.1

1
2

170
03

161.0, 187.1,
291.1

1
3
1
6

172
07
185
42

104.0, 149.0,
223.1
191.1, 279.1,
336.2

1
7
1

185
82
188

111.1, 222.2,
264.2
143.1, 255.2,

8
9

199.1,
149.0,
227.2,
277.1,

nombre comn Qual

%
ac carboxlico? 78

hexadecanoic acid, methyl

ester
1,2,3,4-tetrahydro1,1,4,4,6pentamethyl-5,7dinitronaphthalene
endo-3,4isopropylidenedioxy-exo-2phenylthio-6oxabicyclo[3.2.1]octan-7
-one
2,7,8-trimethoxy-3-methyl5,6methylenedioxynaphtho1,4-quinone
butyl phthalate

ac palmtico
C16:0
naftalina ?

72
87
90
93
72

90

quinona?

90

butyl fthalato

91

2h-1-benzopyran-2-one, 6methoxy-7-[(2-oxo-2H-1benzopyran-7-yl)oxy]methyl 9-octadecenoate

cumarina?

70

ac oleico

94

octadecanoic acid, methyl

ac esterico

94

8
1
9
2
5
2
8

25
207
81
255
34
260
36

298.2
185.0, 239.1,
299.2
207.0, 281.1,
354.9
181.9, 207.0,
280.9

3
0

265
08

132.8, 207.0,
280.9

3
1
3
2

266
65
268
61

147.1, 206.9,
281.0
146.9, 207.0,
280.8

3
3
3
4

269
24
269
63

207.1, 280.9,
354.9
207.0, 280.9,
355.0

ester
dehydroabietic acid

C18:0
ac dehidroabitico

96

3,3-diethoxy-1,1,1,5,5,5hexamethyltrisiloxane
phenol, 2,2'-[(1-methyl-1,2ethanediyl)bis(nitrilomethyl
idyne)]
tranylcypromine,
pentafluorobenzoyl
ester
3,3-diethoxy-1,1,1,5,5,5hexamethyltrisiloxane
tranylcypromine,
pentafluorobenzoyl
ester
gibberellin A3

silicona?

72

cido
carblico?

72

giberelina A3

72

gibberellin A3

giberelina A3

78

72
silicona?

72
72