Homework 3

Paulina Rocha Sanchez

"1. NO+O3-NO2+O2
TS = 298.15

2. H+C2H6-H2+C2H5

[K]

T1 = 600

[K]

T2 = 400

[K]

K1 1 = 9.68 x 10 7

[dm 3/mol*s]

K1 2 = 3.38 x 10 7

[dm 3/mol*s]

K2 1 = 3.82 x 10 7

[dm 3/mol*s]

K2 2 = 840000

K3 2 = 2.01

ln

ln

K1 1
K1 2
K2 1
K2 2
K3 1
K3 2

[dm 3/mol*s]

[dm 6/mol2*s]

K3 1 = 2.1

ln

3. 2NO+O2-2NO2"

[dm 6/mol 2*s]

E1
8.31434 [kJ/kmole-K]
E2
8.31434 [kJ/kmole-K]
E3
8.31434 [kJ/kmole-K]

ln ( K1 1 ) =

ln ( A1 )

ln ( K2 1 ) =

ln ( A2 )

ln ( K3 1 ) =

ln ( A3 )

T1
1

T1
1

T1

1
T2
1
T2
1
T2

E1
8.31434 [kJ/kmole-K] T1
E2
8.31434 [kJ/kmole-K] T1
E3
8.31434 [kJ/kmole-K] T1

Homework 3
Paulina Rocha Sanchez

1.380622e23

K1 1 =

6.626196e34

K2 1 =

K3 1 =
c

[J/K] TS

1.380622e23

[J/K] TS

6.626196e34
1.380622e23

[J-s]

exp

[J-s]

[J/K] TS

6.626196e34

[J-s]

exp

exp

DG 1
8.31434 [kJ/kmole-K] TS
DG 2
8.31434 [kJ/kmole-K] TS
DG 3
8.31434 [kJ/kmole-K] TS

6.212 x 10 12

A1 =

c exp

A2 =

c exp

A3 =

c exp

dS 1
8.31434 [kJ/kmole-K]
dS 2
8.31434 [kJ/kmole-K]
dS 3
8.31434 [kJ/kmole-K]

dH 1 =

E1

8.31434 [kJ/kmole-K] TS

dH 2 =

E2

8.31434 [kJ/kmole-K] TS

dH 3 =

E3

8.31434 [kJ/kmole-K] TS

Resultados
Factor pe-exponencial
A_1=7.939E+08 [dm^3/
mol*s]
A_2=7.900E+10 [dm^3/
mol*s]

Energia de
Activacion
E1=10498
[KJ/mol]
E2=38085
[KJ/mol]

A_3=2.292 [dm^3/ mol*s]

E3=437 [KJ/mol]

G
DG_1=27440
[KJ/mol]
DG_2=29745
[KJ/mol]
DG_3=71184
[KJ/mol]

S
dS_1=-74.54
[J/K*mol]
dS_2=-36.29
[J/K*mol]
dS_3=-238
[J/K*mol]

H
dH_1=8019
[kJ/mol]
dH_2=35606
[kJ/mol]
dH_3=-2042
[kJ/mol]

Homework 3
Paulina Rocha Sanchez
#2
En base a la tabla mostrada abajo y dado que la dos primeras reacciones bimoleculares :

Y para la tercera reaccion que es trimolecular:

Homework 3
Paulina Rocha Sanchez