950

TABLAS DE PROPIEDADES, FIGURAS Y DIAGRAMAS (UNIDADES SI)

TABLA A-28
Logaritmos naturales de la constante de equilibrio Kp
La constante de equilibrio Kp para la reaccin nA A + nB B nC C + nD D se define como Kp

PCnC PDnD
PAnA PBnB

Temp.,
K

H2 2H

O2 2O

N2 2N

298 164.005
500
92.827
1000 39.803
1200 30.874
1400 24.463
1600 19.637
1800 15.866
2000 12.840
2200 10.353
2400
8.276
2600
6.517
2800
5.002
3000
3.685
3200
2.534
3400
1.516
3600
0.609
3800
0.202
4000
0.934
4500
2.486
5000
3.725
5500
4.743
6000
5.590

186.975
105.630
45.150
35.005
27.742
22.285
18.030
14.622
11.827
9.497
7.521
5.826
4.357
3.072
1.935
0.926
0.019
0.796
2.513
3.895
5.023
5.963

367.480
213.372
99.127
80.011
66.329
56.055
48.051
41.645
36.391
32.011
28.304
25.117
22.359
19.937
17.800
15.898
14.199
12.660
9.414
6.807
4.666
2.865

H2O H2 + 1/2O2

H2O 1/2H2 + OH

CO2 CO + 1/2O2

92.208
52.691
23.163
18.182
14.609
11.921
9.826
8.145
6.768
5.619
4.648
3.812
3.086
2.451
1.891
1.392
0.945
0.542
0.312
0.996
1.560
2.032

106.208
60.281
26.034
20.283
16.099
13.066
10.657
8.728
7.148
5.832
4.719
3.763
2.937
2.212
1.576
1.088
0.501
0.044
0.920
1.689
2.318
2.843

103.762
57.616
23.529
17.871
13.842
10.830
8.497
6.635
5.120
3.860
2.801
1.894
1.111
0.429
0.169
0.701
1.176
1.599
2.490
3.197
3.771
4.245

1/

2N2

+ 1/2O2 NO
35.052
20.295
9.388
7.569
6.270
5.294
4.536
3.931
3.433
3.019
2.671
2.372
2.114
1.888
1.690
1.513
1.356
1.216
0.921
0.686
0.497
0.341

Fuente: Gordon J. Van Wylen y Richard E. Sonntag, Fundamentals of Classical Thermodyamics, versin ingls/SI, 3a. ed., Nueva York, John Wiley & Sons, 1986,
p. 723, Tabla A-14. Con base en informacin termodinmica proporcionada en JANAF, Thermochemical Tables, Midland, MI, Termal Research Laboratory, The
Dow Chemical Company, 1971.

18Appendix_01 ITALICAS.qxd 950

7/12/11 14:26:07