Determinacin del SO 2 por Titulacin con Formacin de Complejos

Estandarizacin del EDTA

ml V
ml V
OH Ba
EDTA
1 . 0 0 . 20
5 . 0 3 . 13
2 ) (
=
=
M
ml OH molBa
molEDTA
g
OH molBa
g
g
ml
OH gBa
ml 01050 . 0
10 3 . 13
1
2 ) ( 1
1
33 . 171
2 ) ( 1
100
71
1000
2 ) ( 685 . 1
20
3
=

[ ] M EDTA 0105 . 0 =
Solucin Captadora
250 ml diluidos a 500 ml
[ ] [ ]
[ ]
[ ]
[ ] [ ]
[ ]
[ ] M cap
ml
ml M
cap
cap V V cap
M cap
ml
ml M
cap
cap V V EDTA
cap E
0028 . 0
250
) 500 )( 0014 . 0 (
0014 . 0
20
) 7 . 2 )( 0105 . 0 (
1
1
2 2 1 1
2
2
=
=
=
=
=
=
Hallando los moles iniciales de Ba
gBa m
moles V C n
Ba
Ba
09631 . 0
10 7 . 0
3
=
= =

Medio Ambiente
[ ] [ ]
[ ]
[ ]
[ ] [ ]
[ ]
[ ] M C
ml
M ml
C
C V C V
M C
ml
M ml
C
C V EDTA V
ml V
MA
MA
MA MA MA MA
MA
MA
MA MA EDTA
EDTA
0014 . 0
250
) 0007 . 0 )( 500 (
0007 . 0
20
) 0105 . 0 )( 4 . 1 (
4 . 1
2 2 1 1
=
=
=
=
=
=
=
moles n
Ba
3
10 3675 . 0

=
moles n
moles n
n n n
SO
SO
Baf BAo SO
3
2
3
2
2
10 3325 . 0
10 ) 3675 . 0 7 . 0 (

=
=
=
g m
SO
0213 . 0
2
=
[ ]
litros
gSO
SO
606 . 21
0213 . 0
2
2
=
[ ]
l
g
SO
4
2
10 858 . 9

=
Muestra tomada cerca del horno
[ ] [ ]
[ ]
[ ]
moles n
moles n
moles n
l M n
M C
ml
ml M
C
EDTA V C V
ml V
CO
CO
BAf
BAf
H
H
EDTA H H
EDTA
3
2
3 3
2
4
4
4
10 354 . 0
) 10 36 . 3 10 7 . 0 (
10 36 . 3
) 500 . 0 )( 10 72 . 16 (
10 72 . 6
25
) 6 . 1 )( 0105 . 0 (
6 . 1

=
=
=
=
=
=
=
=
2 2
0333 . 0 gSO m
SO
=
[ ]
litros
gSO
SO
296 . 13
0333 . 0
2
2
=
[ ]
l
g
SO 0025 . 0
2
=